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By Andrew Ritter, Victor I. Montenyohl, Stephen R. Winzer

Thirty-seven open pit production blasting operations have been monitored using high-speed cameras running between 500 and 7000 frames per second. Analysis of the resulting films reveals irregularities in timing including sequencing errors and crowding (holes firing less than 8 ms apart), confirming results of laboratory testing of ms delay blasting caps (Winzer, 1978). Where blasting parameters are otherwise constant and within recommended guidelines (stemming, spacing, burden, etc.), timing problems dominate the overall performance of the blasting operation. Model tests in layered Homalite 100, designed to simulate joint or bedding planes in rock, indicate the importance of the stress waves generated by the explosive in developing the crack network which is ultimately responsible for the fragmentation seen in the resulting muckpile. These mechanisms are strongly supported by high-speed film studies at Pinesburg, Maryland. Experiments in controlling relief in deep shots (where depth approaches the lateral extent of the bench blasted) using borehole geometry and hybrid initiation systems (electronic timer and pyrotechnic delays) were carried out. The results suggest that the 1 me/ft. of burden guideline developed by Bergmann et aI., 1974 is too short, and that much longer times are necessary to optimize fragmentation and muck digability. Longer times are found to reduce noise, vibration, and flyrock.

Jan 1, 1979

By C. Ogasawara

This document describes the direction and progress of the Bureau of Mines Oil Shale Mining Environmental Research Program as of January 31, 1979. It is aimed at focusing the Bureau's role in environmental research supporting oil shale development with respect to the activities of other involved government agencies and private industry. Environmental considerations in oil shale extraction, such as ecological disturbances, health and safety hazards, waste management, and socioeconomic impacts, are discussed along with the type of research known to be planned by organizations to ameliorate these problems.

Jan 1, 1979

By John A. Meech, J. G. Paterson

Activated carbon is a strong adsorbent for amyl xanthate, capable of removing from solution up to a quarter of its own weight in xanthate. In selective flotation system where depression is unstable, separation efficiency increases with activated carbon additions. The improvements observed are brought about by two mechanisms. First, by removing stripped and residual collector ions from solution, competition between depressant and xanthate is reduced and depression is stabilized. In addition, the texture of the froth phase at high pine oil concentrations is modified by activated carbon such that better drainage between the air bubbles takes place, alleviating the mechanical entrapment of depressed mineral particles. In treating a bulk copper/lead concentrate produced from GECO ore, selectively between galena and chalcopyrite is increased when activated carbon is used. Although the rate of flotation of galena is marginally lowered by activated carbon, a small extension in the duration of flotation allows the lead recovery to increase by 19% at the same recovery of copper. An addition rate of 0.75 kg/ton (1.5 lb/st) of bulk concentrate is suggested as optimum from this testwork. However, the actual level used in the mill is dependent upon the residual concentrations of collector and frother in the bulk concentrate pulp.

Jan 1, 1979

By D. E. Traut

The effect of various ion concentrations on uranium absorption from a sodium carbonate solution by a strong-base, anion resin was investigated by the Bureau of Mines in support of its objective to help assure an adequate uranium supply for future needs. The studies were conducted to improve the recovery of uranium from in situ leach solutions by ion exchange. The effects of carbonate, bicarbonate, chloride, and sulfate ions were examined. Relatively low (less than 5 g/l) concentrations of chloride, sulfate, and bicarbonate were found to be detrimental to the absorption of uranium. High (greater than 10 g/l) carbonate concentrations also adversely affected the uranium absorption. In addition, the effect of initial resin form was investigated in tests of the chloride, carbonate, and bicarbonate forms; resin form was shown to have no effect on the absorption of uranium.

Jan 1, 1979

By P. D. R. Maltby

This paper describes the background and markets for calcium carbonate and silica sand in Canada, as well as the results of recent test work carried out at the Ontario Research Foundation. Tests on sericite, tremolite, vermiculite, barite and graphite are also mentioned.

Jan 1, 1979

By D. B. Stewart

This paper reports on an investigation undertaken to determine the exhaust gas temperatures of operating underground mining equipment. The effectiveness of platinum catalytic purifiers is discussed. From exhaust temperatures, it is concluded that LHD engines are highly loaded, haulage truck engines are moderately loaded and utility vehicle engines are lightly loaded.

Jan 1, 1979

By Daryl R. Tweeton, Jerry R. Riding, Grant Buma, Frank J. Rosswog

In situ solution mining of uranium has environmental advantages over conventional mining. The leaching of uranium, however, alters the ground-water quality in the aquifer where the mining occurs. Currently, regulations require that the ground water be restored to approximately its original condition. This paper, a summary of a study funded by the Bureau of Mines, reviews the state of the art in restoring ground-water quality after in situ uranium leaching. Current restoration practices discussed include disposal of liquid wastes in deep disposal wells and evaporation ponds, producing from all wells during restoration, and recirculating water purified in surface plants. Methods for predicting the effectiveness and cost of current techniques are presented. Possible alternative techniques are also described. Two restoration operations are discussed.

Jan 1, 1979

By Brian Raymond

This paper will outline the problems and solutions of the new generation washeries, as well as the recent technological advances which are being considered for future coal preparation plants. The subjects to be covered will include: - reasons for considering coal preparation plants; - raw coal crushing and handling systems; - types of coal cleaning equipment being used versus new equipment being considered; - fine coal circuit sizing; - clean coal centrifuging and dewatering; - thermal dryer problems and changes; - fine refuse dewatering systems; - clean coal storage problems and changes; - materials handling within the plants; and - control systems for preparation plants. The design and integration of the various circuits that form a modern coal preparation plant have led to the creation of an exciting new field of industrial research. As the need for energy sources increases, efficient methods of preparing coals for specific markets will become more important.

Jan 1, 1979

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

Measure the daily exposure of individual miners to alpha particles emitted by radon daughters (radioactive decay products of the radon gas present in the mine atmosphere). Approach A dosimeter worn by a miner counts alpha particle emissions from radon daughters, RaA (Polonium 218) and RaC (Polonium 214), collected on a filter, and stores the gross count for later readout. How It Works A pump draws air into the detector assembly where radon daughters are collected on a filter. The detector, a solid state surface barrier type, is mounted in the filter head behind a thin mylar disc which serves as a moisture barrier. When a radon daughter decays and its alpha emission strikes the detector, the alpha particle causes a pulse of electrical charge in the detector. The circuits used to condition and count the electrical pulses generated in the detector are represented by the other blocks shown in the simplified block diagram. Each pulse is first amplified.

Jan 1, 1979

By Robert J. Wright

The purpose of this paper is to propose a classification of uranium deposits that is believed to be well suited to the needs of uranium exploration and resource assessment. By way of background some observations are offered about mineral exploration in general, and uranium in particular. Attention is first given to the we of models in mineral exploration. Some general principles of mineral deposit classification, the basis for model formulation, are then considered. Finally, the uranium classification is presented.

Jan 1, 1979

By William M. Greenslade

As the search for minerals leads to deeper mines the need to control water inflow into mine shafts and mine workings will grow. As shal¬lower more readily available minerals are exploited, ore bodies which were previously uneconomic be cause of their depth will now become attractive targets. In known mining districts new ore bodies are being discovered down dip of existing ones. In the west many metal deposits are being developed in rocks of the mountain front pediments, frequently covered by several hundred feet of saturated alluvium. Greater depth often means that workings are developed well below existing water tables, creating high hydrostatic heads adjacent to mine workings. The purpose of this paper is to review some of the methods available for determining if water control will be necessary and to present some of the techniques for locating water bearing zones and the amount of water to be expected. The paper will concentrate on problems associated with water control in mine shaft development, although many of the exploratory techniques are similar to those needed for assessing overall mine water inflow problems. A brief case history on water control problems in mine shafts in the Grants mineral belt of northwestern New Mexico is presented. Water control during shaft sinking presents some unique features. First, the problem is a relatively short term one, since water control is often necessary only while the shaft is being sunk. Control measures may be necessary only while the shaft is open into the water bearing zone and the lining installed and cemented. Secondly, limited working space within the shaft area presents difficulties in handling large amounts of water inflow. The presence of water in the shaft working area increases sinking time and the potential hazard to miners. Finally, there is the economics of shaft sinking. While the shaft is being sunk no ore is being produced and there is every incentive to minimize costs.

Jan 1, 1979

By Roger K. McLimans

Sphalerite in the ores is multi-banded. Based on color and textures, bands in samples separated by a few kilometers may be correlated. Darkness of color is directly related to iron content. Isotopic and fluid inclusion data indicate that temperatures of ore deposition were 225°C-50°C. The agreement between these two sets of data suggests that chemical and isotopic equilibrium were established. The salt content and hydrogen and oxygen isotopic compositions are similar to present-day values of oil field brines suggesting a similar mode of origin. Ore transport and deposition are not adequately explained by either chloride or bisulfide complexing. Necessarily, other mechanisms were involved.

Jan 1, 1979

Discussion of the above paper by G. J. van JAARSVELDt Mr Ortlepp's paper is important, and deals with a subject towards which much controversy and insufficient basic scientific logic, in my opinion, have been directed. He attempts to remedy some of our unscientific popular misconceptions, and for this we thank him. However, I regret to say that experience has shown that some of his statements cannot be allowed to pass unchallenged. Author's reply Mr Van Jaarsveld's contribution is welcome because it provides an opportunity for me to clarify certain points that were perhaps not adequately explained in the paper.

Jan 1, 1979

By Corate L. Brierley

Low-grade porphyry copper ores containing chalcopyrite as the primary mineral was leached by two strains of acidophilic, thermophilic microbes belonging to the genus Sulfolobus. Leach tests were conducted in glass columns heated to 60-70° C. Pinto Valley and San Manuel ores sized to -1/2 inch + 50 mesh were effectively leached by the thermophilic organisms, but pinto Valley and Cyprus Bagdad ores sized to -2 inch + 1/2 inch resisted leaching. Aeration did not contribute measurably to bacterial copper extraction, since two columns, one inoculated and one sterilized, having a rest/ leach cycle without recurrent aeration exhibited copper extraction patterns similar to those of the aerated columns. Distilled water can be substituted for 9K medium without diminishing copper extraction. Decreasing the pH of the leachate to about 1.8 enhanced the extraction of copper from pinto Valley ore with the thermophilic microbes. Thiobacillus ferrooxidans was found to be relatively ineffective at copper extraction from pinto Valley ore. Of eleven solvent extraction reagents tested, Adogen 364 and Warsol at concentrations of 0.1% and 0.012 were inhibitory to oxygen uptake by the two Sulfolobus strains. Di-2-ethyhexyl phosphoric acid at concentrations of 0.1%, 0.01% and 0.001% were totally inhibitory to the respiration of both organisms.

Jan 1, 1979

By George A. Snyder

The presence of moderate to high concentrations of colloidal clays in coal preparation plant waters can cause serious operating and economic problems for a coal company. Among the host of possible problems are the following: 1) Poor separation of clays in the plant thickener, resulting in: a) Increased ash in the clean coal. b) Increased specific gravity of the wash water and decreased coal recoveries at the desired quality. c) Increased thickener operating costs in trying to overcome the problem. 2) Decreased solid concentrations in the thickener underflow and increased pumping requirements to meet solids withdrawal requirements.

Jan 1, 1979

By Robert J. Mitchell

A general approach to mine backfill design, including laboratory testing procedures, is outlined in this paper. Relationships between certain design parameters are developed and the effect of other factors is discussed. It is concluded that the inclusion of backfill design calculations at an early stage of mine design can often produce over-all design economies. Not only are the data needed for backfill plant and tailings disposal area design, but also the pillar recovery method and over-all mine stability are dependent on the attainable fill properties.

Jan 1, 1979

By S. L. Crouch

A. C. Dieringt The procedure described by Professor Crouch for the modelling of mining in faulted ground allows the elastic and inelastic deformation to occur simultaneously, that is, fault slip occurs while an element is being mined. The energy release rates (ERR) shown in Crouch's Fig. 10 are apparently calculated from his equation 9 using the i total deformation Din (see the upper load line of Fig. I) Refractories The institute of 'Gesteinsh iittenkunde' of the technical university at Aachen, the Refractories Research Institute at Bonn, and the Verein Deutscher Eisenshiittenleute (VDEh) at Diisseldorf are to hold the XXII International Refractory Colloquium on 27th and 28th September, 1979, at Aachen.

Jan 1, 1979

By J. E. Dutrizac

A pyritic Zn-Pb-Cu ore waspercolation leached with acidified ferric sulphate solutions; zinc and copper were leached, lead was oxidized, but not dissolved, and pyrtte was essentially unattacked. High zinc extractions were achieved after a few months leaching, and substantial zinc solution concentrations could be produced by recycle of the oxidized solution. The leaching rate was generally controlled by the transport of the ferric sulphate oxidant. Zinc extractions increased with increasingferric ion concentration or flow rate, but were essentially independent of the concentrations of sulphuric acid, ferrous sulphate, cupric sulphate or chloride ion. The leaching rates were insensitive to the height of the ore column once a minimum height had been exceeded (0.8-1.0 m). Elemental sulphur was the principal sulphidic reaction product, but variations in the ratio of sulphur to sulphate produced anomalous temperature effects.

Jan 1, 1979

Professor Somasundaran has given an excellent presentation of the numerous problems which remain to be solved before the selective aggregation of fine particulates is likely to see broad commercial application in the beneficiation of mineral fines. However it is useful, I think, to reiterate some of the major problem areas. The over-riding factor which has limited the development of selective aggregation techniques is that processes such as coagulation and flocculation tend to be inherently non-selective. Conditions which favor the aggregation of one kind of fine particles usually favor the aggregation of all kinds of particles. As Professor Somasundaran has pointed out, the state of aggregation of a fine-particle dispersion is primarily determined by the forces of interaction between the individual particles. In most systems, the dominant forces are: 1. van der Waals - London Dispersion forces between the particles themselves 2. electrical double layer forces 3. steric forces between adsorbed layers on the surfaces of the particles. The London Dispersion forces between like particles are always attractive, but for dissimilar particles dispersed in a fluid medium can, in some cases, lead to a net repulsion. Electrical double layer forces always lead to repulsion between like particles but can, again, cause either attraction or repulsion for dissimilar materials. The steric forces, which are by far the least understood of the three types, can also lead to attraction or repulsion depending on condi-

Jan 1, 1979