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By R. Hogg

INTRODUCTION As mineral particles are made smaller and smaller, it follows that their surfaces assume a greater and greater importance. In the extreme, the colloidal systems are characterized by the complete dominance of surface over bulk properties. Surface characteristics and properties will clearly influence any fine-particle processing operation. Comminution, for example, is a process of creating new surface. Agglomeration, on the other hand, may involve the reduction of surface area and the forces involved are generally surface forces. All mineral separations, solid-solid as well as solid-fluid, involve the treatment of two or more phases (solid plus liquid and/or gas). As the interfacial area increases, so will its effects on processing. Both physical and chemical separations are influenced by interfacial phenomena. Gravity separations are usually performed in a liquid phase and may be affected, for example, by the wetting characteristics of the solids. Flotation processes, of course, are based on the exploitation of differences in surface properties. Hydrometallurgical processing usually involves interfacial chemical reactions, e.g. leaching. The rates of such reactions depend on surface area and may be influenced by electrochemical effects in the electrical double layer at the solid-liquid interface, or by adsorption of reactant and/or product species from solution. In characterizing a mineral surface, it is important to consider first the surface area, since this determines the relative importance of the interfacial effects. The structure and chemical composition of the surface, which may depend on segregation of impurities within the solid and on adsorption from the external environment as well as on the bulk composition of the solid, will generally determine such

Jan 1, 1980

By F. Palmay, R. D. Gwilym, P. Eng

INTRODUCTION As the experience in Canada indicates, it is becoming more and more common to evaluate major mining projects, especially those relating to uranium, with respect to their environmental effects. As part of this evaluation public hearings are becoming the rule rather than the exception. In this area the 1970's and presumably the 1980's can be characterized as the age of "Environmental Assessments" or "Environmental Impact Statements" which form the basis of these hearings. These documents tend to require significant amounts of research, data collection and effort in their preparation, and tend to be closely scrutinized by the hearing body and by groups in opposition to the project. This opposition is becoming more organized and sophisticated. The assessment or impact document, together with the evidence supporting it during the hearings can: (a) mean the difference between a lengthy and hence costly hearing and a smoother, shorter and less expensive one, (b) result in requirements for extensive modification at the expense of the proponent to his project, (c) result in the proponent being required to carry out extensive studies, research or monitoring programs, and (d) conceivably may in certain situations result in the project actually being turned down. Therefore, while on the one hand it is important to have available technical answers to concerns relating to uranium, its associated and perceived hazards, it is getting more and more important to be able to present these answers in both a written and oral format in such a way as to meet the criticism and concerns of the opposition, be they citizens in general or special interest groups including environmental lobbyists. JURISDICTION From a Canadian perspective, the first legal question to be answered is which level of government has jurisdiction over uranium mines in general and specifically over aspects relating to the environmental effects, including the health and safety aspects, of uranium mines and

Jan 1, 1980

By Graylin R. K, dea T. R, O&apos

The Wolgan Seam of the Upper Permian IlIawarra Coal Measures of the Western Coalfield of New South Wales consists of high volatile, low sulphur, medium hard coking coal with high fluidity. This seam, 1·8-2·4m thick, in the Wolgan area, dips gently at 1°_20 ENE and lies at 160-440m below the deeply dissected surface of the western margin of the Blue Mountains plateau.A detailed study of the deposit has revealed that the Wolgan Seam consists of four main coal plies separated by three distinct stone bands. Each of these subunits is lenticular and displays individual physical, chemical and mineralogical characteristics which exhibit distinct spatial distribution patterns across the area. Most noticeable is the presence of long linear ESE-trending zones of low ash - high volatiles - high fixed carbon - high fluidity which delineate the major distributary pattern within the deltaic environment of coal formation.This seam contains some of the highest fluidity coal in the world.The Wolgan area, close to the western margin of the Sydney Basin, is characterized by:I. a regional, closely spaced, homogenous joint fracture pattern dominated by an orthogonal pair set trending 3400 and 0700, to which the face- and butt-cleat directions respectively of the Wolgan Seam are sub-parallel, and2. a more widely spaced, heterogenous, cross-cutting pattern of regional structural fractures. Zones of bad roof conditions are probably associated with these lineaments which are subvertical and trend in three majordirections, viz., 005°,035° and 115°.

Jan 1, 1980

Vitrinite reflectance forms the basis of a study of coal rank variation in two areas of the Upper Hunter Valley, New South Wales, on the northern margin of the Sydney Basin. A selective analysis procedure, based on samples rom twenty-two boreholes, has resulted in a small range of reflectance values for each sample and consequently a high degree of significance for calculated mean values. The patterns of rank distribution derived from these data have facilitated an interpretation of the rclative timing of coalilication and deformation in each area.This study provides support for the suggestion by several authors that there were at least two periods of folding in the tJpper Hunter Valley. In the Hebden-Ravensworth area, minor folding took place after most of the coalilication was completed.To the west, in the region of the Muswellbrook Anticline, coalification occurred during or after the formation of this major structure. Tectonic instability during deposition of the Singleton Super-Group, in the region of the Hunter-Thrust on the basin margin, is evidenced by rank variation suggesting differential subsidence across this zone.

Jan 1, 1980

By E. D. Stephenson

As part of the British Steel Corporation?s development plan during the 1970?s, it was decided to concentrate its bulk steelmaking processes based on the BOS at 4 major Works with access to deepwater ore terminals, for the supply of high-grade imported ores. These 4 sites were at: - 1. Rarenscraig Works in Scotland where the ore terminal would be hilt at Hunterston on the west coast some 50 miles away. Bavenscraig was already an integrated Works but suffered from having to discharge ore 27 Glasgow tenxinus on the River Clyde, which could only accommodate vessels up to 25,000 tonnes. In the future, ore was to be unloaded at Runterston and shipped by a rail-link into Ravenscraig, The new ore terminal would have the potential to unload vessels up to 300,000 tonnes. - 2. Port Talbot Works in south Vales where the existing harbour was developed to discharge large ore carriers. This again was an existing Integrated Works and the benefits of the new harbour also applied to Llanwern Works which was another integrated Works some 50 dies to the east, which would now receive ore from Port Talbot.

Jan 1, 1980

By Clifford B. Farris

Introduction Shale Mining Problems The mining problems an oil shale operator will face are largely determined by the process. Candidate oil recovery processes are surface (above ground processing of mined oil shale), modified in situ (underground with some shale removed), and true in situ (completely underground with no shale removed). The shale removed for modified in situ (MIS) is generally processed by surface techniques. The mining problems are different for each category. Fig. 1 depicts the diversity of western shale deposits. Mining for surface operations will employ underground mining techniques in common use but the scale will be larger. A typical oil shale operation is expected to require 75,000 to 250,000 st (68 000 to 226 800 tons) a stream day of crushed oil shale. This is above the upper limit of current mining operations. Major problems in¬clude: (1) lack of good engineering design properties for oil shale, especially when interbedded with saline minerals at depths below 1,000 ft (305 m); (2) presence of water, hydrogen sulfide, and methane in some areas; (3) necessity for mine disposal of as much retorted oil shale waste as possible; and (4) control of en¬vironmental impacts of mining. Portions of the oil shale deposits in Colorado, Wyoming, and Utah and significant portions of the Devonian shales in the eastern U.S. are adapted to surface mining. No major technological problems are apparent outside overburden thicknesses up to 1,000 ft in the West. However, numerous political and environmental dif¬ficulties have arisen. One major oil shale developer cancelled a planned surface mining operation and currently is pursuing a modified in-situ plan. The eastern shales are closer to the surface than the western, but suffer from many of the same environmental and political problems. Modified in-situ operations face much more severe mining problems than surface efforts. Because the mined stope (called an in-situ "retort" by processors) acts as a retorting process vessel subject to gas flow, combustion, and temperatures between 1,500° and 2,000°F, mining is under highly restrictive limitations. This processing method involves removing between 20 and 40% of the shale deposit and then blasting the roof and walls into the mined space, where the oil is recovered by retorting. Major problems are: (1) swell factor severely limited; (2) need for consistent size distribution of blasted shale; (3) even filling of stope (in-situ retort) by blasted shale with consistent permeability throughout; (4) scaleup of blasting techniques, after optimization; (5) protection of retort pillars and roof during and after retorting; (6) prevention of groundwater percolation; (7)use of ANFO explosive in wet holes; (8) disposing of surface-retorted shale waste in stope; and (9) restoration of site. True in-situ operations are less well developed than surface or MIS processes. No actual mining is done, as the true in-situ processes generate permeability in the highly

Jan 1, 1980

By George Innes

The soda ash business in the United States has undergone a sweeping technological change in ihe last 20 years. In a world where synthetics are continuzlly replacing natural products, here we have exactly the opposite, a syntheric chemical being replaced by a natural product. This change is nearly complete in the U.S. and is beginning to take place in Europe and other parts of the world.

Jan 1, 1980

By D. Raicevic

The presence of residual uranium and other radionuclides in the uranium mill tailings are posing a continuous health concern to the surrounding environment. The slow generation of sulphuric acid from residual sulphide minerals is the cause of persistant dissolution and discharge of many metallic components of the tailings. The most effective long term solution to these problems would seem to be to produce chemically stable tailings. This paper describes two possible answers to the objective: (1) Removal of radionuclides and pyrite from tailings by mineral dressing techniques; some 60 - 68% of the residual uranium, 70 - 75% of the radium, 60 - 65% of the thorium and 95 - 98% of the pyrite have been rejected from the Elliot Lake tailings. The decontaminated tailings contained 0.003% uranium, 50 - 60 pCi/g radium226, 0.01% thorium and less than 0.1% sulphur as pyrite. (2) Preconcentration of radionuclides and pyrite by beneficiation from Elliot Lake ores prior to leaching; applying this approach about 97% of the uranium, 95% of the radium, 92% of the thorium and 98.5% of the sulphides were concentrated in a radionuclide and pyrite concentrates comprising 25% and 8% of the ore, respectively. The preconcentration tailings (waste) produced contained 0.004% uranium, 20 - 25 pCi/g radium226, 0.005% thorium and less than 0.1% sulphur as pyrite. Economic and environmental advantages of both approaches and the leaching of the concentrates are also discussed.

Jan 1, 1980

By B. Zane Egan

The Calsinter process for recovery from fly ash involves sintering the fly ash with calcium sulfate and calcium carbonate at 1200°C, followed by a dilute sulfuric acid leach step. Flue gas desulfurization sludge containing calcium sulfite, calcium sulfate, and unreacted calcium carbonate may be substituted for the calcium sulfate and calcium carbonate. Conversion of aluminum in fly ash by the sintering process to an acid-leachable species was measured as a function of sintering time and temperature in the range of 800°-1200°C The sinter-leach steps were investigated using thermogravimetric analysis, x-ray diffraction, scanning electron microscopy, and elemental analysis. SEM photographs indicated that the glassy spheroids in the original fly ash were converted to a crystalline structure by the sintering reaction.

Jan 1, 1980

By J. M. Kuchta

The chemical and thermal criteria used for predicting the spontaneous combustion hazard are briefly reviewed and data are presented to characterize the gas desorptions and self-heating tendencies of 29 U.S. coals. Closed vessel desorption experiments showed that CO, CO2, and CH4 are the main gases evolved and that the CO, CO/?O2 index, and 02 absorption rate increase with decreasing rank and increasing oxygen content of the coal. In this Bureau of Mines report, the effects of temperature, moisture, and other variables are discussed together with the application of the data to the complex conditions encountered in a mining environment. An important finding is that the presence of CO alone in a mine is not necessarily an indication of a self-heating reaction of the coal. Based upon experiments conducted in an adiabatic-type calorimeter, the self-heating temperatures of lignite and subbituminous coals can be as low as 30° C, whereas the bituminous coals require a temperature of about 60° C or more. The self-heating hazard is greatest when the coals are dried and exposed to a high humidity condition, apparently as a result of the "heat-of-wetting." Generally, the hazard is greatest with the western coals of the United States.

Jan 1, 1980

By W. P. Diamond

The explosion hazard of methane-air mixtures has become an increasingly serious mine planning problem, and an advance assessment of methane gas potential can therefore be essential for a safe and economic mine development program. As part of its coal mine health and safety program, the Bureau of Mines has developed a simple, inexpensive test to measure the methane content of coal samples obtained from exploration cores. The gas content of coal per unit weight as determined by the direct method test can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if degasification of the coalbed in advance of mining should be considered. Since the Bureau began measuring the gas content of coal samples in 1972, experience has led to equipment and procedural changes, the most significant of which has been the development of a ball mill for crushing the coal sample to release the residual gas at the end of the desorption test period. This revised procedure replaces the crushing box and graphical methods described in earlier Bureau publications. The results of 583 direct method tests are summarized in tabular form. These results include data on the gas content of 125 coalbeds in 15 States.

Jan 1, 1980

By J. M. Stuve

This Bureau of Mines investigation measured the low-temperature heat capacities of FeOC1(c) and FeC13(c) in the temperature ranges of 6 to 305 K and 4.6 to 300 K, respectively. The standard entropies (S°, 298.15 K) of FeOCl(c) and FeC13(c) were derived as 19.73±0.03 cal/deg-mole and 35.33±0.07 cal/deg-mole. A large lambda transition was observed in the heat capacity of FeC13(c) at 8.4 K. The standard enthalpy of formation (?H°f, 298.15 K) of FeOC1(c) was determined to be -98.23±0.22 kcal/mole by HC1 solution calorimetry. High-temperature enthalpy measurements (H-H298.15) of FeOC1(c) were determined to 700 K by precision drop calorimetry. Standard thermodynamic formation data and related functions were tabulated at various temperatures for FeOC1(c) and FeC13(c).

Jan 1, 1980

By B. S. Covino

The Bureau of Mines, U.S. Department of the Interior, is conducting research to devise substitute corrosion-resistant materials by using ion implantation to form alloyed regions near the surfaces of metals. These alloys were prepared by implanting 25-kev Cr+ and/or Ni+ ions into iron. Their resistance to corrosive attack was evaluated by determining their anodic polarization behavior under potentiodynamic conditions in a solution containing sodium chloride, boric acid, and sodium borate. These electrochemical studies have shown that the general corrosion resistance of ion-implanted alloys was comparable to nominally equivalent bulk alloys. The pitting-corrosion resistance of the ion-implanted alloys was superior to that of iron, although not as good as that of most of the bulk alloys tested.

Jan 1, 1980

By E. A. Rychkun

"For the last 700years of recorded economic history, man has been subjected to alternating inflationary and deflationary patterns. Through this period of time, a severe deflationary pattern has developed approximately every 55 years, creating 12recordable occurrences. Through the last two centuries, this severe deflationary phenomenon has come to be known as a depression. As these depressions have repeated themselves regularly, they are cyclic. This in turn leads to the question of whether the 13th cycle will also repeat itself in the form of a depression. As this cycle is now 51 years old, we must consider the possibility at about 1984.In analyzing a 700-year record of consumer prices in Southern England, the 55-year cycle appears to vary in shape and intensity. This varying phenomenon is due to the effect of longer cycles upon which each one ""rides "". Because each cycle effectively rides on the next largest, which in turn rides on the next largest and so on, the combined measured effect of all cycles together at any point in time is always unique. This means that anyone cycle can never repeat itself in an exact identical manner. The combined effect therefore is what we observe in the form of prices and, as cycles interact, variations in deflation are produced . The ""science"" of economics attempts to quantify and develop theory on situations which are never identical and hence can be conservatively classified as a useless predictive tool.This means that more unconventional approaches may be required to predict our economic future. In looking at previous depression cycles, it is possible to recognize similarities in human behaviour patterns and hence the resulting economic movements. These behaviour patterns create major events or influencing factors which set the scene for a major deflationary condition. The way in which these factors occur, however, is not predictable. As more and more of these similar events are identified in each cycle, we can increase our confidence on the probability of the last event occurring (a depression). By also unravelling the set of larger cycles, we can determine the potential combined effect at any point in the future.This paper presents a system of cycles ranging from 800 years to 3 years which appear to operate in our economic system. By so doing, a long-term projection into the next century can be made. Finally, the paper deals with the main controlling similarities within the depression cycle, to show that a comparison with our current cycle implies that a major deflationary collapse in the mid 1980's is virtualy inevitable."

Jan 1, 1980

By Patrick Linehan

Vibration and air blast noise from blasting were evaluated during a research program which was sponsored by the U. S. Bureau of Mines. Blast variables were studied using small scale model (SCM) tests to evaluate specific variables as well as interactive effects, followed by experiments with production blasts at the surface coal mines. Experimental data showed that the primary variables affecting the ground vibration amplitude are the charge weight per delay and the length of the delay interval. Blast variables having a significant effect on the overpressure amplitude include the charge weight per delay, the length of the delay, burden and spacing, stemming amount and type, direction of initiation, charge depth and amount of detonating cord and cover.

Jan 1, 1980

By K. M. Tompson, R. L. Armstrong, C. I. Godwin

"Tungsten skarn deposits on the Clea property in the Selwyn Mountains, Y. T., are related genetically to a quartz monzonite stock, about 500 metres in diameter at the surface. Lower Paleozoic sedimentary rocks are metamorphosed for a distance of 3 km from the stock. Tungsten-bearing skarn mineralization within the altered sedimentary rocks is of two types: sulphide-rich pods and calc-silicate beds. The most significant scheelite concentration is in calc-silicate beds near or adjacent to the quartz monzonite stock. Discordant K-Ar and Rb-Sr isotopic dates indicate that the stock is probably of early Late Cretaceous age, 94 Ma or slightly older, and that it cooled slowly. High initial 87Srl86Sr ratios and disequilibrium relationships between K-jeldspar phenocrysts and groundmass minerals in the porphyritic phase of the granitic rock , and between different granitic rock specimens, indicate contamination of crystallizing magma by old sialic continental crust which extends westward under the Selwyn Basin.This study is significant to regional tungsten exploration. Granitic rocks associated with tungsten deposits, in this part of the Canadian Cordillera at least, appear to have specific isotope characteristics that indicate they were generated at a specific time and in a particular way.IntroductionThe Clea tungsten skarn property (Fig. I) is owned by Canex Placer Limited, and lies in the Selwyn Mountains (Bostock, 1948) near the eastern margin of the Selwyn Basin (Wheeler and Gabrielse, 1972), Yukon Territory. The property covers a 20-square-mile area centered near latitude 62°47 ' north and longitude 129°52' west, and is accessible by helicopter. An airstrip and the terminus of a summer-use gravel road at MacMillan Pass, Yukon, are about 20 miles to the northnorthwest.This paper deals mainly with the geochronemetry of granitic rocks from a stock associated with tungsten mineralization on the Clea property. We show that these rocks have specific characteristics that not only define the genesis of this stock, but also have significance for regional tungsten exploration around plutons in the Canadian Cordillera."

Jan 1, 1980

A preliminary study was conducted by the Bureau of Mines to determine the effect of humidity on salt mine airborne dust levels. Results showed less dust where the humidity was elevated. Dust reductions appeared to be dependent on the equilibrium between humidity and salt.

Jan 1, 1980

By H. Weber

This paper is in three parts. Part I discusses the various types of cement clinker coolers now in full-scale operation. Part II is a detailed study of the criteria for selection of the type of cement clinker cooler best suited for a given installation. Part III covers a number of cooling problems and their solutions in some of the metals industries. The large and world-wide problem of cement clinker cooling has motivated much study and development and the coverage here of this work is somewhat detailed. In contrast the cooling problems of the metals industries are quite varied between industries and often quite different from plant to plant in the same industry because of basic differences in the requirements of the particular material being processed. Therefore the coverage of metals industries coolers is somewhat more general. It is believed that all of the technology covered here may be of interest to those working with the problems of cooling hot materials.

Jan 1, 1980

By Dennis E. Stover

Grade control for in situ uranium leaching is maintaining, at desired levels, the uranium concentration in the pregnant lixiviant which feeds the extraction (ion exchange) circuit. This differs from grade control in conventional mining in that in situ grade control is imposed subsequent to rather than prior to leaching without the direct observation and control possible in conventional mining and milling. Grade control is a necessary engineering task through the entire project life, beginning with preliminary evaluation and design and ending only when the final wells are shut in. More specifically, this task is associated with designing the initial well field, maintaining productivity during well field operations, and planning well field expansions to compensate for the depletion of existing wells. Our aim during each of these phases is to maximize uranium productivity while ensuring that we are developing information necessary for future phases. Throughout this task, we remain cognizant of the fact that uranium productivity is a function of both the complex geologic and operational parameters of the project. A minimum list of significant geological factors must include the following: . Host formation mineralogy . Uranium mineralogy . Permeability . Ore quality (grade and thickness) Our concerns are not limited to average or general descriptions of these factors. The interactions among the factors as well as localized variations among them are far more important in obtaining high productivity from a deposit. For example, an ore body may display an average permeability of one darcy but have its high grade ore confined to regions with permeabilities less than 500 millidarcies. This relationship between ore grade and permeability must be understood early in the project life if the operation is to be successful. Similarly, the fundamental operating parameters for the well field include those items which enable us to distribute the lixiviant within the ore as well as the chemistry which will dissolve the uranium minerals. A minimum list of such factors will include: . Well design . Well efficiency . Well bore damage . Pattern size and shape . Oxidant type and concentration . Complexing agent concentration - pH The interactions between these variables and the complex geological variations create a situation which often defies quantitative analysis. Hence, we have adopted a statistical approach when correlating production history with these parameters and the quality of the correlations improves as the number of wells operated increases. However, the correlations are often specific to an ore body. We find that we must tailor the process to meet the unique geologic parameters of each ore body. PHASE 1: INITIAL WELL FIELD DESIGN Designing the initial well field is perhaps the most difficult phase because we have the smallest data base from which to predict performance. We will have conducted numerous laboratory tests and, perhaps, field pilot tests to select the lixiviant system and to characterize the geologic parameters. However, we will learn a great deal more about the deposit and its productivity during actual commercial scale operation. Fully acknowledging its limitations, we will, as a starting point, assume that uranium productivity will be directly proportional to the quality and quantity of recoverable reserves. Future deviations from this assumption will be plentiful and result from our limited understanding of the aforementioned interactions between and among the operational and geological factors. However, in planning the initial field, estimation of the quantity of leachable uranium present at levels above the economic grade and grade-thickness limitations is a priority task. (The concentration of uranium in the ore, the ore grade, is expressed in units of weight percent. The grade-thickness of the ore is the product of the average grade and ore thickness expressed in units of percent-feet.) These parameters provide a direct indication of the quality and quantity of ore. They are determined from gamma logging of closely spaced drill holes (50 to 100 foot centers being typical) accompanied by uranium core analysis or direct uranium assay logging. Gamma- logging measures gross gamma radiation which emanates from uranium decay products and indicates only the possible presence of uranium. Direct uranium assays are necessary to confirm this presence and the true location and quality of the reserve. From this information, an estimate of the in-place uranium reserve is formulated. Utilizing the above data, we begin to assess the quantity and quality of the leachable reserve. Analysis of self-potential and resistivity logs in conjunction with uranium logs will identify those zones which contain uranium and display apparent high permeabilities. Similarly, zones with extensive calcite cementation or dense clay sedimentation are located and uranium within such zones is excluded. (Interpretation of these logs should be confirmed

Jan 1, 1980

By J. E. Nesset, J. A. Finch

A model of the fully-loaded condition of particle accumulation on the matrix of a high gradient magnetic separator is developed. The model accurately predicts the build-up profiles reported recently by Friedlaender et al. A powerful development from the model is that loading (volume of accumulated material per unit volume of matrix) is uniquely defined by a dimensionless group, called the loading number, NL. From direct measurements, NL proved superior to the dimensionless group proposed by Watson as a measure of loading. The fine size limit of hematite recovery is examined using NL.

Jan 1, 1980