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By M. Tsunekawa, T. Takamori, T. Hirajima

In spherical agglomeration in water, the pattern of the growth behaviour of agglomerates is essentially determined by the surface chemical properties of the particles and the oil-water interface. When particles are suitably hydrophobic and oil-water interfacial tension is not too low under an adequate condition for agglomeration, large agglomerates are formed in the initial stage and micro- agglomerates do not appear. When particles are poorly wetted by oil and the interfacial tension is low, initially micro-agglomerates are formed and, after certain aging time, they grow to large agglomerates in a relatively short time without formation of intermediate size agglomerates. Under adequate conditions, the amount of oil and power input do not produce any remarkable effect on the pattern of growth.

Jan 1, 1980

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

By D. D. Young

During the 1970's a number of covered storage facilities were constructed in North America to store and handle large quantities of bulk, solid materials. This trend, away from outdoor storage piles, will probably continue at a stronger pace in the 1980's. This paper attempts to answer some of the questions often raised about the economics of large covered storage facilities. The paper is in four parts: 1. Why Build a Storage Facility? 2. 2. Common Components of Storage Systems With Details of Six Storage Facilities 3. Results of a Study for 50,000 Mg Clinker Storage 4. Guidelines for Conducting a Study to Select a Storage System.

Jan 1, 1980

By R. Simard

"Conventional exploration strategies identify many mineral deposits as potentially interesting, although only a few of them turn out to be of economic importance. In the context of exploration for sulphide nickel deposits in the Canadian Shield, a decisional model, based on a statistical study of parameters relative to nickel deposits as well as to barren sulphide occurences, has been developed.Because such geophysical variables as gravimetry, aeromagnetism and topography could be related to the relative importance of nickel-bearing deposits, a statistical analysis of 13 such variables was carried out for 98 targets which were considered promising after conventional exploration. Among these 98 targets are36 sulphide nickel deposits in the Canadian Shield and 62 drill-tested non-economic occurrences. The results of this study led to the development of a linear logistic model that permits evaluation, for each of the targets, of the probability of finding a nickel deposit of potential commercial interest. This decisional model can thus complement conventional exploration strategies.RésuméLes stratégies conventionnelles d'exploration définissent un très grand nombre de cibles comportant un inténet minier potentiel dont seules quelques-unes correspondent à des gisements économiquement importants. Dans Ie cadre de l'exploration des dépôts nickélifères du Bouclier Canadien, nous avons défini un modelé de décision fonde sur l'étude statistique de divers paramètres relatifs tant aux gisements d'importance qu'aux cibles dites stériles.Ayant fait l'hypothèse que certaines variables géophysiques (gravimétrie, aéromagnétisme et topographie) peuvent suffire à fournir des indications sur l'importance relative d'un gisement nickélifère, nous avons entrepris l'analyse statistique de 13 variables évaluées sur un échantillon de 98 cibles considérées comme potentiellement intéressantes par les stratégies conventionnelles d'exploration. Ces 98 cibles se composent de 36 dépôt nickélifères d ‘importance recontrés sur tout Ie Bouclier Canadien et de 62 cibles stériles reconnues par forage. Nous avons défini à l'aide de ces données un modèle logistique linéaire. Ce dernier nous permet d'évaluer pour chacune des cibles les chances de trouver un gisement. Ce modèle de décision peut done s'inscrire comme outil complémentaire aux stratégies conventionnelles d ‘exploration."

Jan 1, 1980

By William E. Galloway, Gary E. Smith, Christopher D. Henry

INTRODUCTION Studies relating to the Oakville aquifer as presented in this report and by Henry et al. (this volume), are part of a larger , comprehensive examination of regional and local stratigraphic, hydro- geologic, and geochemical parameters within the Oakville Formation recently completed by the Bureau of Economic Geology. The Oakville serves both as a major Gulf Coast aquifer and an important uranium host (Fig. 1). Regional and local controls on hydrodynamics and hydrochemistry have important implications for hydrochemical exploration, the establishment of premining baseline parameters, and the design of post mining restoration procedures. Investigations of the Oakville Formation were de- signed for the purpose of determining the response of the aquifer to uranium extraction and were funded by the U.S. Environmental Protection Agency under grant numbers R-805357-01 and R-805357-02. Physical Stratigraphy Physical stratigraphic analysis shows that the Oakville Sandstone, a lithostratigraphic unit deposited by a major coastal-plain f luvial system, consists of five mappable, component depositional elements (Figs. 2 and 3). Each major component element is the product of one or more rivers traversing the Miocene coastal plain. In turn, each river possessed a unique sediment load, discharge characteristics, and source terrane. Consequently, each element exhibits distinguishing geometric and compositional parameters that potentially influence the flux and hydrochemical evolution of contained ground waters (Galloway, Henry, and Smith, in preparation). The Oakvil le Sandstone, as mapped and interpreted as a lithostratigraphic unit in the study area, corresponds closely to the Jasper aquifer system, an equally well-defined Gulf Coastal Plain hydrogeologic unit (Baker, 1978). Principal surrounding hydrogeologic units include the underlying Catahoula confining system, the Jasper aquifer system itself, and the overlying Burkeville confining system (lower Fleming mudstones). The Evangeline aquifer system includes much of the Fleming Formation. The Jasper aquifer system is bounded above and below by relatively less transmissive, finer grained confining systems, although absolute transmissivity varies greatly within both the Jasper and confining units. Lithostratigraphic and hydrogeologic boundaries coincide almost exactly within the Hebbronville flu- vial axis (Fig. 3). Correspondence of geologic and hydrostratigraphic boundaries is good within the George West axis; farther to the northeast the correlation of the Jasper aquifer with units mapped as Oakville Formation diverges to varying degrees. A complete analysis of these trends and a study of the depositional facies comprising the Oakvillle are included in Galloway, Henry, and Smith (in preparation). REGIONAL HYDROGEOLOGY The stratigraphic, compositional, and structural framework of the Oakville Formation and the mosaic of interrelated depositional facies that are combined in this framework play a key role in defining the hydrogeology of the Oakville. Furthermore, a combination of climate and hydrogeology, as well as past and present socioeconomic conditions, has determined water and land use patterns within the region of Oakville outcrop. Utilization of Oakville Ground Water Stratigraphic control for determining which wells produce ground water from the Oakville aquifer was established by preparing structural and isopach maps of the Oakville Formation using regional electric log cross sections. Surface elevation and screened interval data (or total well depth, if open-hole completion techniques were used) from each water well, combined with the stratigraphic data, allowed accurate assessment of the producing aquifer for individual wells. Information on well and screen depths, water levels, and usage of water from

Jan 1, 1980

By J. M. Stuve

Low-temperature heat capacities of chiolite (Na5Al3F14) were determined by adiabatic calorimetry in the temperature range 5.8 to 300 K. The derived standard entropy (S°, 298.15) was 115.6 ± 0.2 cal/deg-mole. High temperature enthalpies relative to 298.15 K were obtained by precision drop calorimetry up to 1,000 K. Tables of experimental data and related thermodynamic functions are given for the temperature range of experimental observations.

Jan 1, 1980

By R. M. Parlman

Interest is increasing in obtaining incremental improvements in mineral recoveries in flotation processes because of changing world economic conditions. Research on collector reagents, long indispensable components in flotation systems may provide the cheapest and simplest route to higher metal recoveries. Sulfhydryl group - containing compounds (-SH) and their salts, e.g., dithiophosphates, xanthates and a few other derivatives are commonly used to promote the flotation of sulfide minerals. Alkyl mercaptans, another class of sulfhydryl compounds, have long been known to have collecting properties but have been relegated to dormancy for one reason or another. This paper reports results from new investigations of alkyl mercaptans, trithiocarbonates, and a petroleum oil with a variety of western domestic and Canadian ores for copper and molybdenum sulfides recovery. Specific opportunities are pointed out to the industry for mineral recovery enhancement through the use of the proper reagent combination.

Jan 1, 1980

By Stephen D. Cramer

The Bureau of Mines conducted a study in which the magnetic fraction of urban refuse was used as melting stock in the preparation of high-strength, low-alloy and carbon steel. Product steels, made from incinerated steel can scrap, nonincinerated-nondetinned steel can scrap, nonincinerated-detinned steel can scrap, and dilutions of these scraps with No. 1 heavy melting scrap, were used in continuing tests in industrial, rural, and marine environments to determine the effect of residual elements and atmospheric pollutants on their atmospheric corrosion resistance. The respective commercial steels were exposed at the same time to establish baseline corrosion data for the test sites. Weight-loss data are reported for atmospheric exposures of 0.5, 1.0, 1.5, and 3.8 years. The marine environment was the most corrosive; the industrial environment was the least corrosive. The atmospheric corrosion resistance of the carbon steel was improved 25 pct by using incinerated scrap and nonin-cinerated-nondetinned scrap in the steelmaking process. In no case was the atmospheric corrosion resistance of carbon steel degraded by using the magnetic fraction of urban refuse as melting stock. The presence of sulfur in the corrosion film was the most important factor affecting the corrosion resistance of the steels. With increasing sulfur concentration, the rate of the corrosion reaction was reduced and the corrosion film became more protective. The residual elements in the product steels most responsible for improving corrosion resistance were copper and tin. These elements tended to increase the concentration of sulfur in the corrosion film. At the levels present in the product steels, Cr, Ni, and Pb had no observable effect on the corrosion resistance of the steels.

Jan 1, 1980

By Earl Cook

Introduction Men like physical power because it gives control over nature and over other men. Physical power comes in two common forms: explosive and non-explosive. In both forms, the most powerful devices yet invented make use of nuclear energy: on the one hand, the hydrogen or fusion bomb, and, on the other hand, a nuclear power plant. For some nations, nuclear power offers a measure of independence not otherwise available in a time of diminishing and unevenly allocated fossil fuels. Consequently, it has great attraction. Unfortunately, the application of nuclear energy (especially fission energy) to either explosive or electrical power entails a singular risk, that of injury from ionizing radiation, both natural and induced; this risk is found in all stages of the nuclear-fuel cycle, from mining of fissionable materials to the disposal of wastes produced in the "burning" of nuclear fuels. The health costs of nuclear power were not fully assessed in the early stages of the development of nuclear technology and some of them were not properly guarded against, either in the USA, which led the world into the nuclear age, or in Canada, which followed an independent path. What I shall do in this paper is to sketch the history of nuclear regulation in our two countries, to point out what I consider similarities and differences, and to suggest that regulatory history, as perceived by a concerned public, has a great deal to do with what is possible today and probable tomorrow, in other words, with public acceptance or rejection of the nuclear option. The U.S. situation As we sow, so shall we reap. In the USA, further expansion of the nuclearpower industry has been almost stymied by government actions that reflect mounting public concern. There is no national storage facility for spent reactor fuel and it has been decided not to reprocess it; consequently, existing power plants are about to choke on their own wastes. Since the Three Mile Island accident, no new nuclear plants have received operating licenses, although several are ready to start up. The uncertainty of future government action has caused the abandonment of plans for a number of new nuclear plants. In addition, many research projects related to medicine and agriculture, which produce low-level radioactive wastes, are about to be shut down for lack of licensed disposal facilities. Some would maintain that this situation has come about because of the low benefit-to-cost

Jan 1, 1980

By G. W. Elger

The Bureau of Mines conducted laboratory and larger scale studies on samples of domestic perovskite and ilmenite ore concentrates to devise a procedure for recovering TiC from these ores. From the concentrates, mixtures of titanium and calcium carbides were produced. The carbides were then ground and reacted with water. This reaction decomposed the CaC2 to acetylene and hydrated lime and simultaneously liberated the TiC. Using a combination of elutriation and gravity-separation techniques to separate the hydrated lime, approximately 93 pct of the titanium was subsequently recovered as purified carbide containing 54 to 70 pct titanium with CaO content as low as 0,6 pct. This combination of techniques can be used to separate more than 90 pct of the CaO from the TiC. Therefore, this carbiding procedure is a viable method for treating titaniferous materials, including perovskite, that contain more than 20 pct CaO. Tests made in a static-bed reactor showed that for the reaction of TiC with elemental chlorine to produce titanium tetrachloride (TiCI4), a temperature of at least 940° F is desirable to achieve a suitable extraction of titanium in a laboratory chlorination reactor. In fluidized-bed tests at 840° F, 98 pct of the titanium contained in TiC was extracted.

Jan 1, 1980

By Brenda J. Morrison

Anything to do with radioactive waste disposal in these days is regarded in a very negative light and with the thought that no possible good could come of anything connected with it. However, it should be remembered that the Austrian government's disposal of some tailings from the Joachimsthal mines resulted in what was probably the most important scientific discovery of this century. In 1898 the Austrian government agreed to give a Polish research assistant working at the School of Physics in Paris one ton of tailings to enable her to carry on her research. Her meagre stipend and the lack of a research grant did not allow her to purchase the ore which was relatively expensive. The uranium oxide in it being used to colour the famous Czechoslovakian glassware. As we all know, from this ton of ore Marie Curie by her own physical labours extracted one gram of radium. When she started this research she was pregnant with her first child. Nothing of course was known at the time about the biological effects of radiation. Very shortly, of course, the acute effects such as skin burns were observed but it was some years before the chronic effects were noted. It is impossible to estimate to what cumulative amount of radiation that Marie, Pierre and their daughter Irene were exposed but it must have been enormous and it took its toll. Marie complained for many years of fatigue and exhaustion and at one point she was seriously ill with some kidney problem which was probably due to toxic effects of ingestion of uranium. She lived until she was 67, however, and died of leukemia. Her eldest child, Irene, who carried on her work, did not live as long; she died of leukemia at 57. The other daughter, Eve, related how her mother and she went on a skiing holiday not many years before her death, and how her mother at this time would swim 300 meters at a stretch. (Curie, 1937). This suppleness of limb could have been due to the anti-inflammatory action of radiation. Even today, patients in France with certain types of rheumatic conditions are treated with injections of radium, where other anti-inflammatory drugs such as aspirin or cortisone have not worked. (Bertrand, Legras and Martin). All this anecdotal information is just to point out that it is an ill wind that blows no good. The risks connected with uranium waste disposal and tailings piles are

Jan 1, 1980

By D. Brion, J. J. Prédali, J. Hayer

The need to grind volcanic-sedimentary ores very finely (d80 < 20 µm) so as to liberate Pb, Zn, and Cu sulfides from their pyritic gangue causes difficulties in selective flotation. The pyrite, which accounts for 70-80% of the mineral content, is insufficiently depressed by the usual pH and NaCN techniques. To determine better depressing methods, the surface evolution of pyrite during flotation was followed by ESCA spectroscopy to compare the stability range in the Eh-pH diagram. Surface iron hydroxide was formed, which is the main pyrite-depressing factor. NaCN appears to play a more restrictive part, since no ferricyanides were detected, except for very small amounts at pH 7.

Jan 1, 1980

By McGuirk. C. H.

The Port of Conneaut, long regarded as a leader in advanced bulk material handling technology, recently incorporated into its existing facility a new, multi-million dollar coal transfer-storage system. While the basic principles of conveyorized bulk material handling remain unchanged in the new system, design modifications such as rotary dumping of railroad cars, automated car feed to dumper, belt rip detection for conveyor belting, bucket wheel continuous production, and other innovations make The Pittsburgh and Conneaut Dock Company&apos;s complex worthy of classification as the "Port of Tomorrow - Today". The Pittsburgh & Conneaut Dock Company, the "Port of Tomorrow - Today", 1s a bulk materials storage and transfer facility located on Lake Erie, 68 miles east of Cleveland, 30 miles west of Erie, PA., and 138 miles north of Pittsburgh. Figure 1 shows an aerial view of the facility. It is designed to handle over 25 million tons per year of metallurgical and steam coals, direct shipping ore, fine ores, concentrates, pellets, limestone, and dolomite. Inbound shipments of iron ore and limestone are received from Minnesota, Michigan, Labrador, and Quebec. Coal arrives from Pennsylvania, Ohio, Virginia, West Virginia, and Maryland. Rail service is provided by the Bessemer & Lake Erie Railroad Company.

Jan 1, 1980

By Malcolm D. Flavel

Much has been said and written about the world&apos;s, and particularly the united states of America&apos;s, energy crisis. The relative changes between cost components of production have altered because the days of cheap energy have now gone. Decisions that made capital investment reduction attractive to treat large tonnage lower grade ore bodies appear to be no longer valid because average energy costs for comminution that were less than 1 cent per kilowatt hour in 1972, are now more than 3 cents and will shortly become 6 cents according to some projections. Increased capital investment to improve processing energy efficiencies are certainly going to be pursued. Energy today is the largest cost component in the average mineral production facility. It takes more than 12000 kilowatt hours to produce one ton of finished steel and more than 60000 kilowatt hours for each ton of copper and aluminum.

Jan 1, 1980

By J. S. Dunning

One Federal Bureau of Mines research goal, to minimize requirements for domestically scarce mineral commodities through conservation and substitution, can be accomplished by utilizing more abundant elements such as iron, molybdenum, and titanium. An example of this research is the study of precipitation-hardening, iron-base alloys containing molybdenum and titanium, as substitutes for the high-tonnage stainless steels that are high in imported nickel and chromium. The precipitation hardened iron-base alloys are strengthened by a dispersion of the ternary Laves phase, Fe2 (Mo, Ti). Aluminum and chromium additions changed the solid solubility limits of molybdenum and titanium in a-iron and affected the composition of precipitating phases. A baseline composition of Fe-7Mo-2Ti was selected to study the effects of aluminum and chromium additions on the precipitation-hardening mechanism and microstructure and was also used in studies of mechanical properties and oxidation resistance. The study yielded workable, precipitation-hardening alloys, with elevated temperature strengths equivalent to or superior to types 304 and 316 stainless steels. Chromium and aluminum additions in combination were more effective in providing oxidation resistance than either addition was alone.

Jan 1, 1980

By Michael J. Martinson

Mine ventilation has been evolving as a separate field of study since the middle of the nineteenth century, and some practitioners might assert that mine ventilation has come of age as a discrete field in the last decade or two. Certainly the extensive literature now available on many facets of the subject, international congresses, the phenomenal upsurge of interest in mine ventilation in the United States of America since the passage of the 1969 Federal Coal Mine Health and Safety Act, and the existence of a virile mine ventilation society in South Africa with its own monthly journal all point in this general direction; on the other hand the lack of a rational design philosophy for ventilating mines suggests that mine ventilation may still be on the threshold of maturity. To generalise, many mines are still ventilated simply to comply with arbitrary statutory regulations, or with some ill- defined notion of reducing the risk of injury associated with the atmospheric environment in mines. Hazards in this category include oxygen deficiency, toxic gases and particulates, pathogenic gases and aerosols, explosive gases and dusts, and extreme climatic conditions. Although many mines are ventilated to abate the risk of a specific injury, there is inevitably a spectrum of latent and patent atmospheric hazards in every underground mine. The writer (Martinson, 1976) has previously drawn attention to the dearth of material on mine ventilation design in textbooks and technical journals, and to the overly simplistic approach sometimes adopted in the limited work published on the subject. The available material undoubtedly contains useful technical data and persuasive views, but seemingly could not be used to demonstrate the rational engineering approach to mine ventilation design advocated in the present paper. The range of papers presented at the 1975 and 1979 Congresses, and the diverse interests and affiliations of delegates, emphasize the multidisciplinary nature of mine ventilation. Easily recognisable topics include: Fluid mechanics Thermodynamics Heat transfer Flames and combustion Aerosol physics Radiation physics Geophysics and geomechanics Occupational diseases Epidemiology Industrial physiology Despite these heterogeneous connections there can be little doubt that mine ventilation is fundamentally an engineering field and not an off-shoot of some other branch of applied science. The distinction is important because mine ventilation has essentially developed as a form of ad hoc trouble- shooting, and in the process mining engineers have relied extensively on the assistance of experts drawn from other fields. Thus historically there has been limited scope for the application of rational design techniques, and personnel enlisted from scientific disciplines may not have had any previous experience in the intricacies of engineering design.

Jan 1, 1980

By E. I. Jurgens, K. E. Hanney, D. C. Comrie, R. H. Fletcher

Introduction The reclamation of mine/mill tailings areas is undertaken for a variety of objectives including safety, appearance, economical use of lands and forests and long term storage of a future resource. The establishing of criteria for these objectives at any site is a shared task of the government and mining company. Our attention in this paper is directed to uranium mine/ mill tailings as they are handled in the Canadian industry and in the unique Canadian climate. We focus our attention on the state of the art. Uranium is a ubiquitous mineral forming an average of 4 g per tonne of the Earth&apos;s crust. Ores are mined at about 500 g per tonne so that the residual content of uranium in tailings is comparable to average background levels. However, as in most mine/mill operations, the ore contains other minerals that become readily mobile after milling operations. Thus the main objective of tailings impoundment is the stability both physically and chemically of the mobile materials. Since the requirements for the operation and construction of tailings areas in Canada have changed considerably over the past decade, there exists a great many mine/mill tailings areas which while considered adequate in their day, would not meet modern criteria. However, most of these installations pose no concern or hazard to the public. The proximity of mine/mill development to inhabited land areas has necessitated more stringent modes of tailings operations and provisions for tailings site reclamation. The more important of these have been: 1) the prevention of dyke failure, with large liquid-solid outflows onto adjoining lands, and 2) the prevention of seepage from the tails of pollutants such as chlorides, sulphides, heavy metals and radionuclides. Uranium mill tailings are discharged as a slurry from the concentrator after the removal of generally only about 1000 g, or less, per tonne of uranium from the as-mined ore. As a consequence, a great volume of low level activity waste is generated. The amount of tailings is expected to grow in quantity in the future even faster than the increase in yellowcake production, as the demand for energy

Jan 1, 1980

By Joseph L. Condon

The U.S. Department of the Interior, Bureau of Mines, is doing research on methods to obtain premining information on problems such as detection of old mine workings, abandoned oil wells, channel sands, faults, and other geologic features that are undesirable from a production or safety aspect. Techniques being developed to acquire the necessary information include seismic and electromagnetic. The seismic methods include high-resolution seismic and acoustic methods applied from the surface and inseam channel waves applied under- ground. The electromagnetic, or radar, methods are applied from the surface, from boreholes, and from the working face underground. All of these methods are useful under certain site-specific conditions, but none of these methods is universally applicable for all mining conditions.

Jan 1, 1980

By S. Chander, V. N. Sharma

Nickeliferous laterite ore from Sukinda, Orissa (India), consists of very fine particles agglomerated into larger aggregates. The ore is chemically and mineralogically complex and presents many characterization and beneficiation problems. In this study the results of a detailed investigation to characterize the ore by several techniques are discussed. Various techniques used for characterisation include elemental analysis, electron microscopy, electronspectroscopy for chemical analysis, x-ray and electron diffraction, differential thermal and thermogravimetric analyses, EDAX analysis, Mössbauer and infrared spectroscopy. Generally one method compliments the other and it is shown that a combination of several techniques is necessary to fully characterize the ore. The scope and limitations of the techniques are also discussed.

Jan 1, 1980

By Robert F. Kehrman

As part of the Bureau of Mines research on the In-Situ Uranium Leaching, various geophysical resistivity measuring techniques were -evaluated to identify a rapid reliable method for detecting the underground migration of lixiviant outside of the planned limits. Surface and downhole galvanic resistivity and controlled source audio-magnetotelluric (AMT) methods were tested at an in-situ uranium mine in Northern Wyoming during start-up of a new mining area. Downhole galvanic and AMT were the most promising techniques.

Jan 1, 1980