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By George W. Healy

The direct retorting of zinc sulfide concentrates in the presence of lime and carbon was examined on a laboratory scale with ten-gram charges of loose mix or fifteen-gram ones of pellets. A slow stream of nitrogen swept through the furnace tube over the boat of reactants, carrying with it the zinc vapor, which condensed on a rolled-up steel sheet near the exit, permitting weight of zinc produced to be obtained after completion of a run. Variables explored were percent of theoretical reagents, temperature, and time. During the runs gas samples were analysed periodically, and the content of CO2, CO and nitrogen were obtained. The quantities of the carbon gases could be calculated because the nitogen flow rate was measured. The gases were also examined for sulfur species, but neither COS nor SO2 could be detected at maximum sensitivity. Zinc recovery increased with excess carbon and lime and with temperature. It ranged from 77% at a ten percent deficiency to 90% at a ten percent excess at 1100°C. Going to 1200°C and theoretical reagents gave 93% recovery. Increasing time from 200 minutes to 300 minutes increased zinc yield by up to 10%. Results from sphalerite and a commercial concentrate from AMAX gave generally similar results. The reaction rate of zinc sulfide as sphalerite and of calcined sphalerite indicated that the latter reacted almost twice as fast, and recovery of zinc was five percent higher. Though the retorting step using sulfide, lime, and carbon proved to be non-polluting, it was feared that on storage the calcium sulfide in the residues would decompose, giving off noxious gases. Consequently the stabilization of the residues by oxidation was essayed. Because of the presence of unreacted zinc sulfide, the first product of oxidation was S02. Reaction of CaS to CaSO4 was incomplete, going from 20% at 800°C to 90% at 1200°C. Thus the non-polluting nature of the process as a whole is in doubt, and its economics are likely to be unfavorable compared to the traditional way of calcining the concentrates, followed by retorting of the oxide with carbon.

Jan 1, 1982

By Alvaro Lucio

The continuous increase of the fuel oil price compelled CV3D to look for an alternative fuel. Charcoal was selected as the alternative energy source. This paper justifies its selection, describes charcoal properties, the methods for using charcoal in the pelletizing and shows the results of the in-plant tests.

Jan 1, 1982

By Charles L. Greening

MARTIN MARIETTA CEMENT at Martinsburg, West Virginia, has been and presently is engaged in coupling present open pit with old underground workings. Various drilling and blasting techniques have been introduced in an endeavor to achieve optimum results. This paper will relate to three roof shots at Martinsburg, one of which realized a controlled blast of 248,000 tons of material.

Jan 1, 1982

By Dr. Peter J. Conroy

The current study is part of the U.S. Department of Energy's (DOE) on-going subsidence research program. The long-term objective of the DOE program is to develop analytical methods of subsidence prediction applicable over a broad range of geologic and mining conditions encountered in the United States. The DOE currently has several contracts in progress to develop a sound data base that can be used in the development of predictive models. Dames & Moore is currently under contract to the DOE to collect and analyze detailed subsidence and hydrologic data from a coal mine employing longwall mining methods in the Eastern Coal Province. Work under Contract No. DE-AC22-80PC 30335 began in October of 1980 and will continue through September of 1984. This paper summarizes the work that has been completed through September of 1981 and presents the results that have been achieved during this period. Technical difficulties encountered during both the installation and monitoring phases are discussed, and recommendations for future work are presented.

Jan 1, 1982

By Allister McLeod

Coal is expected to play a major role in energy supply in the next 20 years. Oil is a convenient and still reasonably abundant fuel. However, its major sources of supply are regions where there is nervousness about political stability. Uranium is a more efficient fuel - but there is a continuing community apprehension regarding its use. What coal may lack in efficiency, it makes up in long term availability and competitive overall cost. Moreover, diversity of source ensures stable long-term supply. In this way, a major role for coal in the world energy scene is assured. Cyclical considerations aside, demand for coal will increase significantly and it will meet a substantial share of new energy demand, replacing oil and gas in major industrial and electric utility markets. By around the year 2000, coal's share of world energy could reach 30% and rival oil as the largest single source of energy.

Jan 1, 1982

By K. Shen, A. J. Sinclair, N. Champigny

"Fluid inclusion studies from the Cinola deposit indicate low salinities and low C01 contents of the ore fluid. This supports a suggestion that the mineralizing fluids originated from pore water in the fluviatile host rock (mid-Miocene Skonun Formation). Bimodal distribution of filling temperatures suggests the existence of at least two temperature regimes centred on 160°C and 270°C during mineral deposition. Independent age and stratigraphic evidence indicates that depth of mineralization is between 1.1 and 1. 8 km, corresponding to a hydrostatic load of between 110 and 170 bars.RESUMELes donnees sur les inclusions fluides du gisement Cinola indiquent de basses salinites et basses teneurs en C01 . Ceci confirme que les fluides mineralisants ont ete derives de l'eau interstitielle prise dans les sedimentsfluviatiles hates. La distribution bimodale des temperatures d'homogenisation implique !'existence de deux regimes de temperature concentrees vers 160°C et 270°C pendant Ia mineralisation. La profondeur alaquelle le gisement s'est forme est evaluee d'etre entre 1.1 et 1.8 km a partir d'informations stratigraphiques independantes: ceci correspond a des pressions hydrostatiques de 110 a 170 bars."

Jan 1, 1982

By John C. Nigro

This Bureau of Mines report summarizes the performance characteristics of a 30-day around-the-clock gasification-pelletizing test conducted in October and November of 1980 with North Dakota Indianhead lignite. Gasification was conducted in a commercial-size, 6.5-it-diam, Single-stage, fixed-bed, atmospheric pressure producer with a rated capacity of about 30 million Btu/hr. Iron oxide pellets made from a commercial hematite concentrate were fired with the low-Btu gas in a 2.8-ft-diam by 35-ft-long pilot plant rotary kiln at a rate of 900 lb of pellets per hour. Gasifier operations at fuel feed rates up to 3 tons of lignite per hour and hematite pellet induration with raw 160-Btu/std ft3 lignite gas are described.

Jan 1, 1982

By A. W. Mitchell

Barite occurs as bedded and vein-type deposits in Nevada along a north-northeast trending zone that Parallels the Antler orogenic belt. The Nevada bedded deposits presently supply 85% of domestic barite production, used primarily as a weighting agent in the petroleum drilling industry. The ore bodies are controlled structurally and stratigraphically along regional and local structural breaks in siliceous eugeosynclinal rocks of lower to middle Paleozoic age. Evidence for the origin of the barite includes sedimentary and hydrothermal features, indicating that localization probably took place along fractures in the sea floor.

Jan 1, 1982

By Evans U. Jegbefume

A plane strain two-dimensional finite element model employing the method of negative reaction loading has been used to model roof collapse and subsidence resulting from the underground gasification of coal in regions of soft overburden such as that found in Texas. The model included dry zones of rock around the cavity. Roof collapse was included by considering the final state of stress in the elements and removing those that had undergone tensile failure. The two-dimensional plane strain model was extended to include thermal loading and thermal softening of the roof rock. Roof collapse initiation and growth of the cavity were modelled by examining the portion of the rock immediately above the cavity under thermal and hydrostatic load. The model was extended to include linear creep using the method of incremental strains. The overburden was modelled as a generalized Kelvin material.

Jan 1, 1982

By B. E. Davis

As part of its program to increase the domestic availability of critical minerals, the Bureau of Mines conducted characterization and beneficiation studies on a St. Johns County, Fla., phosphate ore that was mined by borehole mining. Results revealed that the ore from this test mine was mostly sand-size carbonate-fluorapatite and quartz and contained 24.6 percent P205. Concentration by various flotation techniques produced phosphate concentrates that ranged, in percent, from 30.0 to 31.4 P205, 0.73 to 0.80 MgO, and 2.8 to 7.2 acid insoluble. Recovery of the phosphate from the ore ranged from 89.4 to 96.3 percent.

Jan 1, 1982

By Masami Hayashi

The Bureau of Mines conducted laboratory studies to investigate methods for desilicating sodium aluminate solution derived from leaching a limestone-anorthosite sinter with 10-pct Na2C03 solution. Desilication tests were made at atmospheric pressure to determine the effects of time and additions of lime and desilication residues. A two-stage, countercurrent desilication procedure was developed to reduce the Si02 content sufficiently to meet specifications for cell-grade A1203. Both stages were conducted at boiling temperatures at atmospheric pressure. Reagent lime was charged as desilication seed to the partially desilicated solution in the second stage, and a product (desilication residue) precipitated by the lime addition was charged to the freshly leached solution in the first stage. Average A1203 loss in the desilication circuit was 5.8 pct, and the product solution contained less than 0.04 g/l Si02. Complete precipitation of A1203 by carbonation resulted in a hydrate containing less than 0.01 pct Si02. Calcination of this hydrate would produce A1203 meeting the 0.015 pct Si02 specification for cell-grade material.

Jan 1, 1982

At the Annual General Meeting of the Chamber of Mines of South Africa, held in Johannesburg on 29th June, 1982, the following leading members of the mining industry were elected to office for the 1982-1983 term: Mr W. W. Malan President Mr C. T. Fenton Vice-President Mr G. Y. Nisbet Vice President William Wouter Malan was born in Springs on 7th November, 1928, and was educated at the Springs High School and the University of the Witwatersrand, where he obtained a B.8c degree in mining engineering. Diamond Mines. Mr Nisbet became a consulting engineer of the Anglo American Corporation in 1972, and a deputy managing director of the Gold Division in 1974. George Young Kisbet was born in Benoni in 1923 and was educated at Pretoria Boys High and the University of the Witwatersrand. Mintek reports Report 2010D A process for the recovery of rare-earth oxides from monazite. (First published 16th March, 1979). Report 2073D A preliminary investigation of the concentration process at Ucar Minerals Corporation. (First published 19th September, 1980). Report 2092D The recovery of pyrite from gold ore by gravity separation. (First published 28th November, 1980). Report M13 Factors affecting the production of fines during the screening and handling of highcarbon ferromanganese.

Jan 1, 1982

By Kathryn A. Mrotek

The textural growth patterns of nodules from two areas in the North Pacific and the South Pacific are characterized by mottled, columnar and compact-type zones. Amorphous material (mainly iron and manganese hydrox-ides) is a botryoidal-forming phase in the mottled and columnar zones. Crystalline material (platy crystals of birnessite and crystallites of todo-rokite) is found primarily in the mottled zones on botryoidal structures or as long-protruding structures growing onto that portion of the nodule in contact with the underlying sediments. The long-protruding mottled zones contain little or no biogenic debris, suggesting that these zones grew un-interruptedly within the underlying sediments. The coalition of spheroidal knobs comprising some of the nodules also suggests a relatively long residing time within the sediments. It appears that crystalline material (the usual host to associated valuable metals) forms in a quiet environment and as a result of direct nodule association with the underlying sediments.

Jan 1, 1982

By Donald L. Bott

A computer model called the Quality Compliance Model was developed to optimize the mine planning and sequencing in area coal mining with respect to the limit on pounds of sulfur dioxide per million BTU imposed by regulations. The objective of the model is to maximize the amount of high sulfur coal mined from various benches while meeting the specified compl'ance standards. Given multiple seams and multiple benching operations, the mining sequence from each pit is simulated. The rate of mining is controlled such that the in-pit blending will maximize the usage of high sulfur coal and meet compliance standards. The compliant coal can be stockpiled for usage at a later date, or it can be disassociated. This calculation can be based on any given rate of production, i.e., from as small a unit as a unit train to as large as monthly or yearly production.

Jan 1, 1982

By Gordon M. Pugh, David G. Rasmussen

INTRODUCTION The two unit operations in cut-and-fill stoping that would benefit most from increased mechanization are drilling blastholes and moving broken ore to the ore¬passes. Drilling in current practice is done with hand¬held jackleg and stoper drills. Broken ore is commonly moved from the face to the orepass by a small slusher. This type of equipment can be easily moved through the raises. Hand-held drills have a slow drilling rate and require one operator for each machine. Drilling can be done much faster by small jumbo-mounted machines as two or more drills can be operated by one miner. Load-haul-dump (LHD) units move broken ore from the face to one or more orepasses at a much faster rate with less loss and dilution than slushers. These units are mobile and may be used at more than one place during a shift. The problem which must be overcome in applying this higher degree of mechanization is the restricted means of access inherent in current practices. Cut-and¬fill methods are usually applied to mining veins that are narrow, irregular in dip and strike, or where ground con¬ditions require the support of sand fill. The mechanized equipment which is needed to accomplish high produc¬tion cannot be raised or lowered through raises without being disassembled. A jumbo which will give the desired performance would be mounted on a rubber-tired carriage with a diesel engine for propulsion. Twin hydraulic booms run by a small air motor would carry pneumatic drills. Over¬all dimensions of the unit would be about 8 m (26 ft) in length, 1.6 m (5'/z ft) in width, and 1.6 m (5'/z ft) in height. An LHD of the desired capacity would be rubber¬tired and either diesel or electric-powered. The overall dimensions of a 2.3-m (3-cu yd) unit will be about 8 m (26 ft) in length, 1.8 m (6 ft) in width, and 1.5 m (5 ft) in height. It will weigh about 12 700 kg (28,000 1b). It can readily be seen that conventional raises can¬not handle this size equipment. The most desirable means of access enables equipment to be driven into the stoping areas. Ramps can enter the stope by being driven upward in the vein walls or by being developed in the vein on top of the fill as the stope advances. This ramp system not only permits the use of rubber-tired equipment in multiple working places but also enables its removal for repairs without component breakdown. In the proposed method, as in conventional cut-and¬fill stoping, sand fill will replace the mined-out ore. By constructing an inclined timber floor at one end of the stope, a ramp can be maintained on top of the fill and advanced as the stope is advanced cut by cut (Fig. 1). The ramp is, therefore, developed during the stoping process and is only driven as a tunnel when rising over and around the sill and crown pillars. A stoping section consists of three blocks of different geometric shapes. The first and last blocks to be mined will be triangular in the plane of the vein, and the blocks between will have the shape of parallelograms (Fig. 1). The first block will develop the initial ramp by breast stoping and filling to the ramp floor (Fig. 2). The ramp will need to be completed through to the next level be¬fore stoping of the subsequent block can begin. The subsequent blocks are mined by back stoping with the next ramp being developed at the other end of that block (Fig. 3). The length of each subsequent block can be varied without changing the slope of the ramp. As the new ramp is developed, the previous ramp is filled along with the stope cut. Access up and down is maintained through the stope. The final block is again breast stoped as no new ramp will be developed at the end line for jumbo egress. Boreholes provide ventilation between levels as well as utility access. They can also provide a secondary escapeway for personnel during periods of development. These boreholes would be located about 3 to 4.5 m (10 to 15 ft) in the footwall and spaced about 183 m (600 ft) apart along the vein. The orepasses are spaced about 61 m (200 ft) apart in the vein. This spacing allows not only a short tram for the LHD unit but also provides surge capacity for the ore between haulage trains. These passes are raised from the haulage levels. As development progresses, the raises are driven through the sill pillar, and then car¬ried in the fill as stoping progresses. Ventilation and utilities can be maintained through an orepass when it is not needed for ore. The end line orepasses are intended for this purpose as well as for personnel emergency egress. Overall dimensions and criteria assumed to illustrate the ramp method of access in a highly mechanized cut¬and-fill stope are: haulage level spacing of 61 m (200 ft); ramp gradient of 17%; average dip of approximately 1.57 rad (90°); initial stope length of 358 m (1177 ft); subsequent stope length of 179 m (588 ft); average stoping width of 3 m (10 ft) ; sill pillar thickness of 3.6 m (12 ft); crown pillar thickness of 1.8 m (6 ft); bored raises of 1.5-m (5-ft) diam; and cribbed orepasses of 1.2 x 1.2 m (4 x 4 ft) through the sill pillar and 1.2 m (4 ft) square inside the cribbed portion. DEVELOPMENT The ramp access system lends itself well to conduct¬ing the several phases of development concurrently. Haulage Drifts and Raises The first development step will be to drive the 3 x 3-m (10 x 10-ft) haulage drifts above and below

Jan 1, 1982

By R. W. Thompkins

"PREFACEThis paper will be published in three parts. Part 1, in this issue, will cover the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.Part 2, to appear in the October issue, will deal with radiation theory applied to uranium ores, other radon migration factors , fact ors affecting the radon gas release rate, measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade, and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and give some example calculations.1.0. Occurrence of Uranium1.0.1. Uranium is widely distributed in nature. Sedimentary rocks contain less than igneous or metamorphic rock s and as the outer 10 miles of the earth's crust is composed of 95 per cent igneous and 5 per cent sedimentary rock, it has been estimated that about 1.3 x 1014 tons of uranium exist in the earth's crust.1.0.2. It is not surprising, therefore, that radiation has existed naturally in the ear h ever since the beginning of time. It is found in such places as:(1) non-uranium mines;(2) houses not close to or connected to uranium mines;(3) ground-water tables supplying drinking water to large populations.1.0.3. All mines do not necessarily have abnormal radiation in them, but it is possible for many mines to have abnormal levels of radiation. Therefore, all underground mining operations should be tested for radiation."

Jan 1, 1982

By Mould GR

Gas drainage has been practiced for many years mainly for safety reasons in various countries in Europe, in the U.S.A., the U.K. and Japan. Legislation has been developed to control the production, transport- ation and utilisation of methane and associated gases. Gas drainage is now being carried out at some Australian Collieries, but as this is a new venture little specific legislation is available. This paper briefly describes the drainage methods and legislation applied overseas, gives a brief history of gas drainage in N.S.W. and indicates the deficiencies of the present legislation. It outlines the approach to new legislation which will deal comprehensively with gas drainage operations and utilisation in New South Wales.

Jan 1, 1982

By Julianne H. Glarmaty, Peter J. Conroy

INTRODUCTION In 1970 the percentage of underground coal extraction by longwall mining methods in the U.S. was 2.1 percent. This figure rose to 4.4 percent in 1976 and is expected to rise to 12 percent by the year 1985. This figure represents 46.0 million tons (51.0 million st) of annual production (Kuti, 1978). In addition, OSM regulations are placing emphasis on subsidence prediction. Section 784.20 of the Office of Surface Mining regulations for underground mining permit applications requires the sutauission of a subsidence control plan which may include monitoring. Because of its nature, longwall mining does not have flexibility in leaving pillars under structures as does room and pillar. Mining in some areas, particularly in the Eastern Coal Field, is approaching more developed areas; therefore, a greater number of structures are expected to be undermined in the near future. Subsidence engineering is becoming an important aspect of mine planning, and should be directed at predicting potential structural damage. The question operators are increasingly faced with is "what will be the subsidence effects for a specific structure at a specific location in respect to a longwall panel?" The most significant variable in assessing the subsidence effect on structures is not vertical subsidence. The variables of strain and tilt are responsible for more structural damage than is the vertical movement. Table I presents threshold values of strain for various structures (Geddes 6 Cooper, 1962). Based on National Coal Board experience, horizontal strain is approximately inversely proportional to the radius of curvature of a circular portion of a subsidence profile; therefore, the radius may be useful in estimating the magnitude of strain caused by subsidence (Hoebs, 1982). The radius of curvature can be determined by the following equation:

Jan 1, 1982

By Mark Davis

As a follow-on to previous investigations, reduced treatment levels for the optimum fire retardant/preservative system were evaluated. An impregnation of 3.5 lbs/ft3 of Fyreprufe followed by 3.5 mils of Albi 107A plus an Albi 144 top coat provides adequate flammability and flame spread protection. However, there is a significant loss in compressive strength at this retention level, particularly parallel to the grain. A pilot-size pressure impregnation cell was installed for use in treating larger quantities of wood. Based on the optimum fire retardant/preservative treatment system - Fyreprufe/ACC impregnation followed by Albi 107A/144 intumescent paint - a model treatment pro¬cess was developed, capable of handling 3 million board feet per year. Associated annualized costs per thousand board feet (K bd. ft.) for treating 12" x 12" timber were calculated to be: Impregnation: $-63.00/K bd. ft. Coating: $112.00/K bd. ft. A literature search was conducted to identify materials and techniques suitable for a localized stench warning system for heated mine timbers. Based on this review, a number of stench warning concepts were developed. Those based on surface coating were given a preliminary laboratory evaluation.

Jan 1, 1982

By G. A. Swanquist, E. M. Morales

INTRODUCTION The idea of water management and control at the Church Rock Mill operations began to take shape in February 1979. At that time, we were already investigating the feasibility of decreasing the fresh water requirements so that the solids would become the limiting factor in tailings impoundment utilization. The area for solution evaporation could be kept at a fraction of the normal requirements under the standard process of full water usage. The Church Rock Mill is an acid leach circuit followed by solids/liquid separation with thickeners in counter current decantation, and solvent extraction. Following the normal design of acid leach circuits, reuse of tailings solution was not incorporated in the original mill process design. INITIAL WATER CONTROL INVESTIGATIONS The investigations to decrease the fresh water requirements centered around modifying the grinding circuit from the present semi-autogenous grinding (SAG) mill in closed circuit with hydrocyclones, to open circuit grinding with a rod mill. The open circuit grinding with the SAG mill and rod mill in series had the potential of decreasing the water requirements for grinding and leach dilution by approximately 50% or 1.4 m3/min (300 gpm). The grinding pulp density would be maintained at 70 to 72% solids, and the leach dilution to 50% solids would be accomplished with acid tailings liquor recycle. In such a grinding circuit arrangement, the SAG mill would provide the primary or coarse grind, and the rod mill would be used for the fine grind. By the SAG mill and rod mill series grinding method of water control and other secondary water controls in various places downstream from the grinding circuit, the required necessary evaporation area was estimated at 120 acres of liquid surface. A second method of water control at grinding was investigated. A two-stage cyclone classification circuit appeared to have a good potential of achieving the same water reduction at a much lower capital and operating cost. However, in retrospect, this would not have been a viable method since a high slime recycle load would have been established hindering classification. The use of reagents to neutralize the acid tailings solution was not considered seriously at that time, since it would have materially increased operating costs, although it would have also allowed more tailings solution recycle and consequently, less fresh water usage. However, with the tailings solution deposition area available at that time, it was not then necessary to incur the high cost of neutralization. The control expected by the series grinding of semiautogenous and rod mills would have been sufficient to maintain a water consumption/evaporation equilibrium well in line with the available land area. IMPLEMENTATION OF NEUTRALIZATION OPERATIONS During the summer of 1979, the UNC Church Rock Mill experienced a tailings dam breach which resulted in a prolonged mill shutdown. Upon resumption of operations at the end of October 1979, tailings deposition was restricted to a small portion of the tailings impoundment area. Figure 1 shows the general tailings area and the limits of the present deposition area in the central part including the borrow pits. These borrow pits had been excavated to provide materials for tailings dam construction. Immediately after resumption of operations, it became evident that it would be necessary to control the quantity of liquid to be evaporated because of the small confined area available for tailings solution deposition and to maximize the deposition time in the tailings area. The water control required had to be exercised on a large scale, and to be in operation as quickly as possible. An obvious solution was to reuse the tailings liquor in mill process. Immediate steps were taken to install the necessary equipment for tailings neutralization on an interim basis. Anhydrous ammonia was selected as the primary neutralization reagent since it was the quickest system that could be placed in operation. Previous laboratory tests indicated fair results with ammonia neutralization. Such a system required a minimum of installed equipment and handling. INITIAL NEUTRALIZATION OPERATIONS Actual neutralization operations began on November 26, 1979. The raffinate solution which normally would have been discarded was pumped to a 3.7 m (12ft) diam by 4.3 m (14ft) tank for reagent contact, see Figure 2. At this tank, anhydrous ammonia was added directly from the tanker trailers and controlled at pH 7.0 nominally. Agitation was provided by air sparging. The neutralized product formed a highly viscous slurry in the grinding circuit which resulted in pumping and cyclone classification problems.

Jan 1, 1982