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By D. C. Lynch

While a sizable amount of data exist as to the activity and distribution of minor elements between matte and metal, there has been no unifying theory presented delineating the form of dissolution of these elements in molten sulfides. In order to alleviate that deficiency the literature concerning the behavior of As, Sb, Bi and Pb in mattes is reviewed. Models present in the literature, regarding the thermochemical behavior of minor elements, are tested, and new models are presented and evaluated using thermodynamic theory. The results of those analyses are used to predict optimum conditions for the volatilization of minor elements. The dearth of data on the behavior of minor elements in nickel mattes requires that this review focus on copper- iron mattes. An effort is made, however, to utilize basic knowledge regarding nickel sulfides and the interaction of nickel with the minor elements to predict the behavior of those elements in nickel-copper and nickel-iron mattes.

Jan 1, 1993

By R. J. Grant, D. W. Scott, M. A. Cooper, E. R. Shannon

"The Brunswick No.12 site concentrator processes 10,500 tonnes per day of a complex lead, zinc, copper and silver ore producing four concentrates by differential flotation. Research over the years has led to increased understanding about the mineralogical and flotation characteristics of the ore. A pilot plant study conducted at Lakefield Research, primarily designed to investigate the technical feasibility of semi-autogenous grinding, provided an opportunity to test recent theories about grind size,, reagent schedule and flowsheet configuration.A fundamental approach was taken with each of the unit processes involved in grinding and flotation. Basic operating and metallurgical criteria were established in each area and a step-by-step implementation program initiated in the plant.Significant improvements in metallurgical and financial performance have been realized through the application of basic grinding and flotation principles using conventional milling equipment and without major capital expenditure. Current operating practice is detailed and metallurgical advancements cited.INTRODUCTIONBrunswick Mining and Smelting operates one of the world's largest lead and zinc mines near Bathurst, New Brunswick. Brunswick is a publicly traded company with majority ownership held by Noranda Minerals (63%). In addition to the No. 12 underground mine, the company operates a lead smelter and phosphate fertilizer plant in Belledune, N.B. and maintains a 25% interest in a joint venture with Noranda Minerals' Heath Steele mine near Newcastle, N.B. Through the four operations, a total of 2000 people are directly employed with fixed assets totalling Cdn$187 million (BM&S, 1991)."

Jan 1, 1993

By W. E. Lindquist

Roasting of refractory gold ores has the primary goal of oxidizing sulfides and organics to improve gold recoveries prior to leaching. Commercial installations currently utilize bubbling and circulating fluidized beds. The principle of flash roasting is aimed at a more cost effective method of whole ore roasting for large throughput applications. Results of pilot plant testing and scale up to commercial design will be discussed in further detail in this paper.

Jan 1, 1993

By R. McCulloch

Exploration activity in metallic minerals continued to decline in Montana in 1992 as companies either reduced budgets or left the state. The number of active projects dropped another 50% from 1991. Expenditures were 3% to 6% of 1989's 28.6 million. Many of the major mining companies closed offices in Montana. Although depressed commodity prices have hurried the exodus, continuous changes in environmental regulations, as well as the Mining Law of 1872, without regard to economic effect have had the most serious impact. Many companies indicate that Third World countries present a more stable business environment than the United States. Grassroots projects are nearly non-existent, while late-stage programs continue cautiously. Exploration activity continued at the following projects: Garnet, Pegasus Gold; Southern Cross, Asarco; Elkhorn, Goldfields; 7-Up-Pete, Phelps Dodge and Canyon Resources; Miller Mountain, Pegasus Gold; Sheep Creek, Cominco American Resources; Checkerboard, Kennecott and BHP Utah International; Emigrant Creek, Pegasus Gold; and Crevise, American Copper and Nickel. All mineral activity, whether on private, state or federal land, is regulated by the Montana Department of State Lands under three classes of permits - Small Miner Exclusion Statements (SMES), Exploration Licenses and Operating Permits. A total of 230 Exploration Licenses are active in the state with 26 of those being new. However, there are only 433 projects current in Montana, with many of those in the reclaiming stage. The majority of exploration projects consist of individuals expending time rather than money on properties. The number of mines functioning under operating plans declined by one when W.R. Grace closed its Zonolite operation.

Jan 1, 1993

Mineral exploration is the business of finding and defining ore deposits. Ore bodies are developed into mines and mines supply every mineral and metal upon which our society is built. Whether it be steel for our bridges, cement and aggregate for our concrete, coal for our power stations, copper for our wire, phosphate for our fertiliser or gold for our jewellery it first must he found, then mined and processed before we can use it. There is no other way.

Jan 1, 1993

By J. R. Hindman

The vermiculite review arrived too late for the June issue. In 1992, production of commercial vermiculite in the United States increased 1 % to 170 kt (187,000 st), according to the US Bureau of Mines. The estimated value of vermiculite concentrate was $13.6 million, yielding an average value of $80/t ($72.50/st). Vermiculite is used in several physical forms. Use of the thermally exfoliated product include light weight aggregates, horticultural growth media, thermal insulation applications and absorbents for spill control and liquid waste containment. The untreated commercial concentrates are used as intumescent fillers in plaster board, gaskets and paints. Several chemically modified vermiculite products include clay-sized dispersions and granules for treating flue gas. South Africa was the only major foreign source of vermiculite used in the United States. It exported about 40 kt (44,000 st) to the United States last year. In 1992, Palabora Mining Co. began processing vermiculite in a new beneficiation mill at Phalabowra. It produced about 164 kt (181,000 st). Minor sources of foreign vermiculite concentrates consumed in the United States included about 140 kt (154,000 st) from China. Brazil also exports some concentrate to the United States.

Jan 1, 1993

By Timothy J. L. Haley

The population of the Rhondda underwent a spectacular rise as energy requirements increased in the mid-nineteenth century. The rapid expansion in the demand for coal transformed the population from a few hundred sheep farmers in the eighteenth century, into a thriving coal-based economy of some 168,000 inhabitants in 1924. Cochrane (1958) put forward the idea that the differential migration of more healthy men from the Rhondda Fach during the period since the peak of population in 1924, had resulted in a respiratorily-impaired residual population. This idea was used to explain the reduced survival of miners & ex-miners aged 55-64 years from this valley as compared with a similar group from Leigh in England. Using the proportional hazards regression model of Cox (1972), a comparison is presented of the exact twenty-year mortality of migrant and non-migrant miners & ex-miners and non-miners from the Rhondda Fach. The analysis makes allowance for the pattern of migration throughout the twenty-year period and adjusts for the confounding influence of variables such as age, occupation, and category of Simple Pneumoconiosis. The results indicate that contrary to expectation, any effect of migration upon mortality is manifest only at higher ages. Furthermore, for these men, the migrants have worse survival than the non-migrants. Also, contrary to expectation in the light of work by the British Coal Board (Soutar et al, 1982) there is no evidence of increased mortality amongst men with category I simple pneumoconiosis. INTRODUCTION [The Background] In September 1950, the Medical Research Council's Pneumoconiosis Research Unit at Penarth in South Wales initiated a study of lung disease in the smaller of the two Rhondda Valleys - the Rhondda Fach. At that time, the primary interest was in assessing the possible role of pulmonary tuberculosis in the aetiology of the serious (complicated) form of coal-workers' pneumoconiosis, i.e. Progressive Massive Fibrosis. The Rhondda Fach is situated in South Wales, some 25 km north-west of Cardiff. It is a narrow winding river valley about 12 km long, and approximately 1 km wide. The name means Little Rhondda; there is a corresponding Big Rhondda - the Rhondda Fawr. Together, these valleys make-up most of the Rhondda Municipal Borough. Following the initial survey in 1950-51, there have been several follow-up studies of this population. In addition, amongst numerous other investigations to unravel the aetiology of coal-workers' pneumoconiosis, Medical Research Council teams studied various other (sample) population groups, particularly in the industrial areas of the adjacent Aberdare Valley, and in Staveley and Leigh in England. The agricultural areas of the Vale of Glamorgan in South Wales, and Annandale in Scotland were also studied.

Jan 1, 1993

By Mohammed Z. Islam

As cities are growing all over the world, the need for urban transportation facilities are on the rise. Designers (of these facilities) today are faced with a number of constraints for their design, of the most is the space limitation and impact of new construction activities to the community. A typical subway station, as the focus of this paper, is approximately 600 to 1000 feet long, 50 feet wide and 2 to 3 story high. With such a large volume of construction activities, it is easily realized why underground stations are becoming obvious choice for larger cities eventhough the cost could be 2 1/2 to 3 times as much as an aerial station and 4 to 5 times that of an at-grade station [O'Neil et. al.(1977)]. Since cost is an important factor which is always increasing, therefore, the designer should have a good planning, consider alternatives for design and come up with a realistic design with minimum impact to the community. This paper is about the geotechnical considerations that the designer should be aware of. PLANNING A 1977 report [O'Neil et. al.(1977)] on the construction costs for a number of underground subway stations indicate that about 4 0% of the cost is site-controlled, 35% is structural items, and 25% is finish and equipment. It is seen that of opportunity exists for cost savings in the site selection and proper use of the site. Once the site is selected, the cost of construction become controlled by urban conditions at the site, geotechnical conditions, station size and depth. Therefore, the design-solution is very much site-specific. The geotecnical designer should collect the following information at the early phase of the design:

Jan 1, 1993

By Trent A. Tempel

In 1989 Newmont Gold company initiated a project to develop a treatment process for higher grade refractory gold ores to be mined from deposits along the Carlin Trend in Nevada. Extensive laboratory and pilot testing have identified a unique whole ore roasting process for oxidizing these ores prior to gold recovery by conventional cyanidation techniques. Subsequent detailed engineering studies by Fluor Daniel evaluated three different dry grinding flowsheets for feed preparation to this roasting circuit. The selected flowsheet will incorporate a two compartment ball mill with an attached drying chamber that is driven by a 11.2 MW (15,000 hp) wrap-around motor.

Jan 1, 1993

By Xia Guangxiang, R. Y. Wan, Yang Hanlin, M. C. Fuerstenau

The mechanism and kinetics of pretreatment on pyritic gold concentrate with the catalytic oxidation acid leach (COAL) process were studied in the temperature range of 80-100°C and oxygen pressure range of 230-1013 kPa, with sodium lignosulfonate (SL) and mixed medium of sulfuric acid (11 g/[ ]) and nitric acid (5.5 g/ [ ]). The results show that nitric acid acts as a catalyst, the surfactant changes the hydro-phobicity of resulting elemental sulfur to favor the oxidation of pyrite, and the oxidation-determining step would be the chemical reaction between nitric acid and pyrite. When about 80% of pyrite contained in the concentrate is oxidized, the gold cyanidation extraction exceeds 95 % . The nitric acid in solution can be recycled and used again.

Jan 1, 1993

By Jia X

Three-dimensional microscopic modelling techniques involving specific calculations based on direct computation of the Brownian, van der Waals, Born, electrical double layer repulsion, bulk, hydrodynamic and external forces (gravity, magnetic etc) acting on and between each particle in a mineral dispersion are now feasible using advanced computer processor architectures. This contribution surveys the hardware requirements, the advantages and limitations of the approach for enabling prediction of dispersion behaviour a priori. The notion of developing a generic particle simulator, akin to the use of molecular modelling in the area of drug design, based on inputting process-relevant data (solution chemistry, mineral solids properties, hydrodynamics etc) is discussed. The methodology is illustrated with application examples involving: predictions of coagulation of mineral fines; shape and size of magnetically-flocculated hematite; and the kinetics of fouling of membrane surfaces and walls.

Jan 1, 1993

By D. J. McCracken

The lithium review did not arrive in time for publication in the June issue The estimated consumption of lithium minerals as raw materials to the glass, ceramic and metallurgical industries in 1992 was 85.5 kt (94,200 st). That equates to about 12 kt (13,200 st) of lithium carbonate equivalent (LCE). An additional 150 kt to 200 kt (165,000 to 220,000 st), or 7.5 kt to 10 kt (8200 to 1100 st LCE), were used in the production of lithium chemicals. The 1992 consumption represents an overall decrease of 3.5 kt (3800 st), or 500 t (550 st) LCE, from 1991. This was a direct result of a worldwide reduction in glass demand due to the economic recession. There are three major producers of lithium minerals. Gwalia Consolidated Ltd. (formerly Lithium Australia Ltd.) in Western Australia and Tantalum Mining Corp. (Tanco) in Manitoba, Canada, both produce spodumene ore. Bikita Minerals, in Zimbabwe, is the largest producer of petalite. Bikita also has the capacity to produce small volumes of spodumene concentrate. The Cyprus Foote spodumene operation at Kings Mountain, NC, ceased production in 1992. It once produced about 2 kt/a (2200 stpy) of "high iron spodumene" for uses other than in the manufacture of lithium chemicals. The lithium products of the major producers are shown in Table 1. The current resources of 13 Mt (14.3 million st) of LCE in the western world will supply demand for more than 50 years.

Jan 1, 1993

By Jim Weeks

In July 1986, the United Mine Workers of America (UMWA) asked Secretary of Labor William Brock to form an advisory committee to advise the Mine Safety and Health Administration (MSHA) on rules and regulations concerning the use of diesel powered equipment in underground coal mines. The request was made under the Mine Health and Safety Acts of 1969 and 1977. The union's principal concern was with the chronic and acute health effects of breathing diesel exhaust. In July 1988, the advisory committee recommended that MSHA promulgate a variety of health and safety regulations. It also concluded that diesel particulate matter should be considered carcinogenic (MSHA, 1988). Now, seven years later, there are nearly twice as many pieces of diesel powered equipment in underground coal mines. MSHA, however, has not promulgated a single regulation to govern the use of this equipment. MSHA must fulfill its public responsibility to protect the health of miners. Regulations that take account of the considerable body of knowledge concerning these health effects must be a top priority of the incoming assistant secretary of labor for MSHA.

Jan 1, 1993

By Robert S. Ondrey, Robert A. Haney, Kenneth G. Fields

As part of an MSHA program to assess the effectiveness of dust control parameters for longwall mining operations, respirable dust studies were conducted on six longwall sections. The purpose of these studies was to evaluate the influence of airflow and production on longwall dust control. The sections were sampled for 3 to 35 shifts. In addition to dust, ventilation and production measurements, other dust control and operational parameters were measured. The water spray system at each operation conformed with generally recommended practices. Therefore, improvements to the dust control system would be most appropriately achieved through improvements to ventilation along the face. Two methods of assessing the influence of ventilation and production were used. For two of the six mines where extensive sampling (22 and 35 shifts) was conducted, multiple linear regressions were used to relate the dust concentration versus airflow and production data. For these two mines, statistically significant correlations existed between concentration and both production and airflow. The multiple regressions fit to the data indicated that for every 0.47 m3/s (1,000 cfm) increase in airflow, there would be approximately 0.04 to 0.07 mg/m3 reduction in dust concentration; and, for every 1,000 ton increase in production, there would be approximately 0.15 to 0.50 mg/m3 increase in dust concentration. For the four mines with limited data (3 to 10 shifts), as well as for the two mines with extensive sampling, an average ratio of airflow per ton of coal mined was calculated by proportioning the airflow to production and the designated occupation personal respirable dust exposure to a 2.0 mg/m3 concentration. The airflow-to-tons ratio required to maintain a 2.0 mg/m3 dust concentration ranged from 0.0038 0.0071 m3/s per ton (8 to 15 cfm/ton). Both of these data treatments were used to calculate airflow requirements based on normal production rates. For the two mines where both the regression and airflow-to-tons ratio were calculated, results from the two methods agreed within 25 percent.

Jan 1, 1993

By Y. S. Roditis

Traditionally, open pit optimization has been used to produce a single outline which can guide the pit design. This paper describes how a series of optimum nested pits are utilized to: a. produce different mining sequences and to help in mine planning and phase design; b. evaluate different metallurgical processes, production scenarios and equipment size; c. investigate the sensitivity of a project to prices, recoveries, production rates, costs, ultimate pit slopes etc.

Jan 1, 1993

The location of the Inglewood Goldfield is 40 km north-west of Bendigo on the Calder Highway and covers an area of over 1600 hectares. The field was discovered during the 1850s gold rush and over 16 000 people camped on the field. Mining first began in 1859 and since then more than seven tonnes of gold has been removed from four major lines of reef. Most of the gold was won in the period between 1900 and 1940.. Goldquest NL currently has leases over approximately 1550 hectares and through its historical research has identified 142 known reefs.

Jan 1, 1993

By M. Liu

The use of surfactants shows great potential for the removal of hydrophobic organics from soils by in-situ washing techniques. Lab-scale soil washing experiments were performed using sodium dodecylsulfate (SDS), an anionic surfactant, and anthracene, a highly hydrophobic compound. The results of this research show that the solubility of anthracene increases linearly with an increase in SDS concentration above the critical micellar concentration. Furthermore, SDS can be effective in removing anthracene from contaminated sand.

Jan 1, 1993

Segregation roasting tests were carried out on Zaire cobalt oxide ores assaying about 2% Co and 3.5 to 6.5% Cu. The major parameters tested during the laboratory investigations were temperature, dosage and type of reducing agent, dosage and type of chloridizing agent, and particle size. Results showed that standard conditions suited to the segregation of copper ores, i.e. low temperature and low dosages of reducing and chloridizing agents, resulted in the segregation of copper only, while conditions suited to the segregation of lateritic nickel, i.e. higher temperature and increased dosages of reducing and chloridizing agents, led to a successful segregation of both copper and cobalt. Under the best conditions, 88% of the cobalt and 98% of the copper could be recovered in a concentrate assaying 32.5% Cu and 8.5% Co. Alternatives to process such a concentrate are briefly reviewed.

Jan 1, 1993

By J. Sharp, R. Arnold, P. Rusin, T. Young, N. A. Sinclair

Many oxide silver and molybdenum deposits remain undeveloped because chemical extraction yields poor recoveries or is environmentally unacceptable. Bioreductive leaching of such ore samples at MBX resulted in high extractions of silver and molybdenum. When baseline, three-day, cyanide bottle-roll tests were conducted on manganiferous-oxide silver ore, 13.7% of the silver was extracted. In contrast, 86% of the silver was microbially solubilized into the organic growth medium by bioreduction with 99.8% dissolution of manganese. A followup cyanide bottle-roll test yielded an additional 8.5 % silver dissolution, for a total extraction of 94.5%. Baseline, three-day, acid bottle-roll tests of the iron-oxide molybdenum ore Yielded 1.8% molybdenum. However, bioreduction solubilized 93.3% of the molybdenum into the growth medium. An additional 0.3% molybdenum was solubilized during the followup acid bottle-roll test. Microbial treatment of refractory oxide ores with bioreductive bacteria resulted in higher extractions of silver and molybdenum than conventional chemical leaching. The bioleaching process occurred at a near-neutral pH at ambient temperatures. The bacterial solubilization of silver and molybdenum was achieved without the use of cyanide or sulfuric acid.

Jan 1, 1993

By R. Tremblay, M. Burrows

"In the summer of 1990, pilot scale testing of a Jameson cell was carried out at Falcon bridge Limited, Kidd Creek Division. The Jameson cell is self aspirating and has fewer mechanical parts, thus it has a lower operating cost compared to conventional cells. This lower operating cost combined with positive pilot scale results, justified the evaluation of two full scale cells in the plant. The plant test had two mandates:1. Gain a thorough understanding of the cells operation and design constraints.2. Develop a flow sheet to replace three divisions of copper cleaner flotation.This paper provides an overview on the installation, commissioning and evaluation of the two Jameson cells acquired. The current status of the test program is also discussed.IntroductionThe Falcon bridge Limited-Kidd Creek Division concentrator is located in Timmins, Ontario. The concentrator, commissioned in 1966 and expanded in 1978, consists of four parallel grinding and flotation divisions utilising small cell (60 ft3) technology. With increasing pressure to maintain low operating unit costs a series of studies were undertaken to assess the impact of new technologies in the flotation circuits. The goals of the project were to improve productivity through increased metallurgical performance and/or reduced operating costs.One of the technologies investigated was the Jameson cell designed by Dr. Graeme Jameson of the University of Newcastle and marketed by MIM Holdings Limited, Australia. This style of column technology was chosen based on its potential for reduced capital and operating cost versus large conventional cells.The success of pilot testwork in 1990 led to the installation of two production sized Jameson cells beginning in October 1991. The units were to be used to confirm pilot results and determine equipment requirements for flotation modernisation. This paper will discuss the results and experiences Kidd Creek has had with the Jameson cell from pilot scale through installation and commissioning of the plant units."

Jan 1, 1993