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By Tong Zhilin

The reasons why the pits were formed on the cathode in the process of Ni electrowinning and the methods how to prevent these pits from forming are described. Some examples are presented. It has 'been proven that P507 and P204 present in the electrolyte can effectively prevent pits from forming on the cathode.

Jan 1, 1993

The Mobile Miner MM130 (Figure 1) is designed to tunnel or mine in hard rock. It has a 4.1 m diameter cutterhead mounted on a horizontal axis which in turn is perpendicular to the line of the machine. The cutterhead rotates at 15 rpm and is supported on a boom which swings the cutterhead through a horizontal arc.

Jan 1, 1993

By Ray Zelinski

Caltrans sponsored a research project in 1992 which incorporated proprietary and generic pile types. The piles were subjected to axial tensile/compressive loads in deep, soft soils. Descriptions of various pile types and systems, scenarios leading to the proposal to test the systems, and load test results were/will be provided by other presenters at this seminar. Therefore, this paper will focus on the issues surrounding use of test results and proprietary pile systems on Caltrans construction projects. The primary issues facing Caltrans during implementation are as follows: 1) producing pile cap designs for a range of pile types and loads; 2) providing construction specifications which allow fair competition among the system vendors, yet assure design and ultimate capacities; 3) Develop quality control standards for pile system materials and installation techniques which guarantee pile durability for static and dynamic loads; and 4) assure that foundations have adequate lateral capacity.

Jan 1, 1993

By Zhanjing Yu

In this paper, an equation is developed to characterize the relationship between the UBC and plate size using a boundary integral approach. The equation was validated by the results from mo& than seventy (70) plate loading tests of different sizes conducted in various underground coal mines throughout the Illinois Coal Basin. The equation indicates that the UBC decreases as the plate size increases. The fundamental solution for this boundary integral problems is the Boussinesq equation. The load exerted by the plate on the floor surface is assumed to be uniformly distributed. Both normal and tangential loads are considered. It is also assumed that the floor fails in shear in a plate loading test. The equation may provide the mine operators with a useful tool to obtain from a plate load test of any plate size the UBC value required by the regulations.

Jan 1, 1993

By Gonzalez-Dominguez J. A, Dreisinger D. B

At Cominco's Zinc Refinery at Trail, British Columbia impurities are removed from zinc sulphate electrolyte by a two-stage purification process using zinc dust. Copper, cadmium and thallium are removed in the first stage whereas cobalt is removed in the second stage. Cobalt removal kinetics are affected by soluble antimony and copper additions to the electrolyte. This study was focused on the kinetics of cobalt removal by zinc powder cementation. Experimental variables included copper and antimony concentrations, pH and temperature. Common organic additives employed in zinc plants were studied to determine potential interactions with the cobalt removal process. Cementation products obtained from laboratory experiments and plant practice were studied using SEM. A number of significant results were obtained: 1. Copper and antimony ions were sustantially removed from solution during the early stages of the cementation reaction (within the first 15 minutes). Cobalt cementation kinetics are slow and follow a first order kinetic regime. 2. A drop in the cobalt removal rates can be correlated with a rise in the Eh of the slurry. 3. Ligninsulphonate, Percol 351 and animal glue at levels of 2 mg/L significantly impede cobalt cementation.

Jan 1, 1993

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability of mine safety management personnel to apply analytical techniques to injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objectives and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. In this volume, the quantitative procedures that have been developed for the mine-specific analyses of accident/injury experience data are presented and their applications are demonstrated in a summary form through case study examples. The quantitative procedures will aid mine safety management personnel to develop focused accident prevention strategies including training, as well as to justify the investment in such proactive programs through cost-benefit analyses.

Jan 1, 1993

Mining software systems have provided a basis for integration of resource, survey, and design functions. They can similarly provide a basis for incorporating ground conditions into the process.Exploration and mine geologists have a prime role to play in this process, extending their responsibilities further across the geological spectrum, into exploration of ground conditions, analyses of results, and assessments of their implications for mining. Ground conditions are as much a part of the geology of a prospect or mine as its mineralisation, and can have critical imnlicationa for mining.

Jan 1, 1993

By Richard C. Travis, Edward C. Dowling

A detailed kinetic study of the flotation installation at the Metcalf Concentrator revealed a rougher flotation circuit operating under less than optimal conditions. Based on these results, a project was initiated to approximately double the rougher flotation capacity by increasing the installed volume from 780 cubic meters to 1,560 cubic meters. This project, which was completed in early 1991, replaced the existing cells with larger capacity cells. A comprehensive analysis of results demonstrates significant metallurgical benefits. INTRODUCTION/BACKGROUND The Metcalf Concentrator is located in Morenci, Arizona and is part of Phelps Dodge Morenci, Incorporated. Sumitomo Metal Mining of Arizona is a minority partner in the operation with 15% interest. The Metcalf Concentrator is the newer and smaller concentrator and operates in conjunction with the Morenci Concentrator. Operating capacity at Metcalf is currently 48,000 TPD of ore on a 365 days per year basis. The Metcalf Concentrator was commissioned in 1974 at a 30,000 TPD operating rate for the purpose of treating ores originating in the Metcalf Mine. The mine takes its name from the former town of Metcalf which was named for Robert Metcalf who was credited with discovery of the mineral district. The predominant ore mineral is chalcocite which occurs as a secondary enrichment closely associated with iron pyrite. The host rock is largely granodiorite and quartz monzonite. The original rougher flotation circuit consisted of a total of six rows of Wemco 8.5 cu. meter (300 cu.ft.) flotation machines treating pulp from the two grinding sections (Sections A and B). Each row was configured in a 4-4-4 arrangement. Shortly after startup the throughput rate was increased significantly without sustaining a recovery loss. This increase was achieved by raising the target value for the particle size of the cyclone overflow which is the rougher flotation feed. Shortly thereafter, the capacity of the pump and cyclone began to restrict further increases in throughput. After testing, two 66 cm. (26-in.) cyclones and a 12-in. X 12-in. centrifugal pump replaced the original classification equipment. As a result of these modifications, the grinding section could routinely process in excess of 42,000 TPD. Due to the increased tonnage rates, limitations in the rougher flotation circuit performance were observed. In an effort to improve the performance of rougher flotation with this higher throughput, the speed of the flotation mechanisms was increased from 230 RPM to 250 RPM. This change improved the suspension of the coarser feed and induced additional air into the pulp. It did, however, apply additional strain to the motors, shortening their life. At these elevated processing rates, it was found that the dart valves operated almost entirely at the top end of the control range and could not efficiently handle upsets from the grinding section. This was remedied by lowering the end overflow weir and allowing some of the tailings to overflow the end weir. However, in order to obtain acceptable recovery levels, the flotation pulp was maintained at a high level, adversely influencing the rougher concentrate grade.

Jan 1, 1993

By R. Gong, R. Bhaskar

The development of a three-dimensional mathematical model for evaluating airflow fields at a continuous miner face is described. The model utilizes three-dimensional incompressible flow, mass continuity, and momentum (Navier-Stokes) equations to predict the airflow velocity at the face. Obstacles and equipment in the face area are modeled using appropriate boundary conditions. Parameters such as flow velocity and face dimensions can be modified and evaluated for various schemes, such as exhausting and blowing ventilation, using either brattice or tubing. A model such as the one described, with additions for local effects, can be used to evaluate novel face ventilation ideas before initiating expensive full-scale tests or field studies. The model described is a step in the direction of advanced predictor models.

Jan 1, 1993

By Basillo CI

The adsorption mechanisms of various thiol collectors can be subdivided into four classes: chemisorption, EC-mechanism, catalytic oxidation and metathetical substitution. The chemisorption mechanism occurs at potentials below the thermodynamic potentials for the metal-thiol compound formation and is reversible. The EC-mechanism occurs when the mineral is sufficiently oxidised to liberate metal ions to form metal-xanthates; therefore, it is observed with more easily oxidisable minerals and/or with collectors having large pK values. Thionocarbamates adsorb on sulphide minerals via the EC-mechanism due to their large pK values. Although the adsorption occurs at very low potentials as compared to xanthates, it is irreversible with large overpotentials. On the other hand, the adsorption of modified thiophosphates and thiophosphinates occurs near the thermodynamic potentials because of the low pK values. The metathetical substitution is believed to occur only when a mineral is highly oxidised. These classifications are useful for studying the effects of electrochemical potentials and the molecular structure on the collector adsorption Mechanisms.

Jan 1, 1993

By N E. Whitehead

An application to mine an ilmenite-rich sand deposit in Westland led to public concern about potential radioactive hazards should the ore be further processed to recover zircon or monazite. A review recommended that any material involved in the heavy mineral sand industry containing more than 0.05% thorium, uranium or their mixture should be considered a radioactive substance and, for mining purposes, a notifiable product. Safeguards for those occupationally exposed would operate via the Radiation Protection Regulations. The major safety requirement would be the minimisation of dust in certain operations.

Jan 1, 1993

By J. C. Johnson, W. G. Pariseau, D. F. Scott, F. M. Jenkins

In situ stresses are important input data for the design of safe, stable stope layouts and extraction sequences. However, it is commonly assumed that normal and shear stress gradients in a stress field are negligible and, consequently, that stresses are uniform throughout the region of analysis. To evaluate these assumptions and to provide input data for an analysis of a shaft pillar mining plan, in situ stresses were measured at the Homestake Mine, Lead, SD, using overcoring on hollow inclusion cells and borehole deformation gauges. These measurements were used with conventional least squares, best fit data reduction schemes. The results showed that normal stresses within the shaft pillar were less than, but comparable to, those estimated from finite-element modeling. Shear stresses were an order of magnitude less than normal stresses and varied considerably from site to site. Possible causes of this variability include effects of scale, elastic moduli, anisotropy, and axial strain. Because of the variability, it is not possible to determine the magnitude of horizontal stress gradients.

Jan 1, 1993

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

By Barria J, Mencho J, Gonzalez GD

An extended Kalman Filter is used to build an on-line estimator of total ore, fine ore and water hold-ups in a SAG mill. In addition, an equivalent grinding rate from coarse to fine ore, as well as the discharge rates of solids (fines) and water are also estimated as part of the adaptation procedure of the model used for the Kalman Filter. The measurements used in the Kalman Filter estimator are the total mill weight provided by load cells, and inferred discharge flows of fines and water from flow and density measurements performed downstream. The net ore and water feed to the SAG mill are used as inputs to the estimator, and also the proportion of fine ore in the feed. As an example of how to introduce robustness in the estimation in the face of sensor bias errors, an estimation of the load cell bias error is introduced in the estimator, thus providing self calibration. The estimator presented in this paper has been tested by simulation using a detailed SAG mill mechanistic dynamic model comprising 27 size fractions well fitted to a pilot mill. The maximum error in the estimation of the operational variables - total and fine ore as well as the mill contents under different operating conditions - is about ten per cent.

Jan 1, 1993

By F. T. Paleari

Radial gas holdup profiles have been measured in a 50x400 cm flotation column using a multi-cell conductivity probe. Three different bubble generation systems were examined: up to eight vertical filter cloth spargers, three horizontal filter cloth spargers, and three (horizontal) Cominco-type spargers. The variables tested were: number of spargers, symmetry of their arrangement, and height above spargers. Batch water with up to 20ppm frother concentration was used. The general observation is that the profiles tend to be uniform (i.e. flat) with some exhibiting a slight wavy shape. The vertical sparger arrangement proved the most difficult to achieve profile symmetry. The horizontal spargers gave uniform profiles at right angle to their length but a decreasing gas holdup along their length; the Cominco-type spargers gave slightly less scatter in the data. Switching off selected spargers (to simulate malfunction) did not produce strong asymmetry in the profiles.

Jan 1, 1993

By W. L. Cornell

The processing of lead tailings for removal of the heavy metals produces concentrates upgraded in Co and Ni values. Reflected light microscopy, scanning electron microscopy, image analysis, and Vickers hardness measurements were used to identify mineral species, associations, degree of liberation, and distributions to the test products. Siegenite and bravoite were the most common species encountered, but violarite and enriched pyrite and marcasite phases were also identified. Liberation for the Co and Ni minerals contained in the tailings was 20 micrometers or less.

Jan 1, 1993

By D. Raghavan

In recent years, the environmental issues related to the landfill shortage received considerable importance. Many polymeric solid wastes have high resistivity to chemical and biological degradation, and options are sought by which these wastes can be recycled and reused, or reduced in volume. The present study investigated the biodegradation of polyethylene by Aspergillus niger, and biodesulfurization of rubber by pure and mixed cultures of Thiobacillus thiooxidans and Thiobacillus ferrooxidans. The fungus, A. niger, was found to metabolize portions of polyethylene. Quantitative calorimetric measurements revealed that the amorphocity of the sample decreased during biodegradation. Removal of sulfur from synthetic rubber samples containing 2 to 15% sulfur, was studied in shake flask experiments and the associated oxygen consumption was studied in Warburg respirometers. The mixed bacterial cultures were more effective in the desulfurization of rubber samples than the pure cultures of T. thiooxidans and T. ferrooxidans. The data obtained in these studies may have far reaching consequence for the development of new effective processes regarding the remediation and management of discarded polymeric packaging wastes and car tire rubber materials.

Jan 1, 1993

By S. Lu

The particle-bubble attachment and the rupture of formed aggregates in flotation cell were investigated in terms of turbulent regime. It was found that the particle-bubble collision rate is closely correlated to the energy barrier between particles and bubbles, and no adhesion takes place for the hydrophilic particle-bubble system due to the introduced ?capture efficiency? f(a) being zero. The values of an especially defined Weber number, i.e. the ratios of turbulent stress to aggregate strength in the inertial subrange of turbulence were estimated, the results showed that the detachment of a particle from a bubble involved in an aggregate is mainly caused by the turbulent stress only in the impeller zone, no bubble splitting occurs both in the impeller zone and in the bulk zone.

Jan 1, 1993

By Leonard A. Eros

In many mining applications it is not practical to use gravity takeups. In these situations hydraulic takeups are often utilized. Performance specifications are often compromised by designs which have inherently high internal friction and inefficient hydraulic designs. This results in performance which does not match the requirements of the conveyor system. A computer model has been built to check unit efficiencies and field measurements have been taken which verify the results.

Jan 1, 1993

By Harrison R. Cooper

INTRODUCTION AND SUMMARY Phosphate matrix beneficiation is the process of providing a mineral product suitable for downstream chemical processing to yield high analysis chemical fertil- zers. Extraneous contaminants, clays and gangue solids, are separated by screening and flotation. Reject materials always carry with them some phosphate mineral values, however. A continuing objective is minimizing phosphate losses discarded with tailings as a principle factor in maintaining beneficiation efficiency. The quest for efficiency, and improved productivity, during beneficiation is hampered by disturbances arising from among the following: o Natural variance of phosphate deposit compositions, o Minimal control over managing ore matrix supply to the plants, o Screening and flotation mechanical upsets and inefficiencies. Production personnel, in recognizing these factors, attempt corrections for changed process conditions. This response usually has limited effect. Efforts of product- ion personnel to correct for upsets of the process may often diminish efficiencies rather than improve them. Lack of prompt data for analysis of process streams is an important contributing cause of inefficient operation. Discussion in this paper examines methods for improved process control in Florida phosphate beneficiation with particular emphasis on use of on-stream analysis to aid gaining productivity. The Florida Institute of Phosphate Research has supported demonstration of on-stream analysis applicable to improved process control. Concurrently, work is proceeding world-wide in the phosphate industry toward practical on-line analysis technology. Table 1 summarizes viable methods for real-time analysis data as result of work by individual companies and research organizations. A recently completed investigation (sponsored by the Florida Institute of Phosphate Research) of beneficiation efficiency was carried out in two Florida beneficiation plants using a newly developed on-stream analyzer for phosphorus (1). BPL measurements were taken at frequent intervals over two to three weeks of routine operation. Grades are expressed in "BPL", with one BPL, or bone phosphate of lime unit, equal to 0.46 P^Y2^YO^Y5^Y. The time series of feed and tailing BPL data were evaluated by statistical procedures. Results show avoidable losses can be five per cent or greater of mineral values in feed. Use of modern process control methods in Florida phosphate mining began several years ago (2, 3). Benefits of stabilizing control used in one of the two plants where data were collected for the investigation, in comparison to manual control in the other, are outlined. Process control technology developments reported from European and South African phosphate mining operations are also noted (4, 5). It is now well accepted that advanced control techniques can increase beneficiation productivity by better management of losses. However, to make advanced control effective, real-time measurements are needed of feed and tailings BPL as well as mass flow rates.

Jan 1, 1993