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Experience in evaluating grade control at operating mines has shown that a number of similar errors re-occur in diverse settings. These can be broadly classed as technical errors, and procedural or grade contra management errors. Examples of typical errors are presented a; generalised case studies. A brief explanation of why the recommender solution worked is also presented for each case.

Jan 1, 1993

By Mingmin Dou

The behaviour and deportment of indium during the precipitation of sodium jarosite from Fe2(S04)3 - Na2SO4 solutions were investigated. Indium is readily precipitated with sodium jarosite, and the extent of In precipitation increases as the In concentration of the solution increases. It was shown that In 3+ substitutes for Fe 3+ in the jarosite structure to form a nearly ideal solid solution series. On a molar basis, the precipitation of Fe is slightly favoured over that of In, and the difference is reduced as the pH increases. Sodium jarosite precipitation becomes kinetically rapid at temperatures >70¦C, but increasing temperatures in the range 70 to 150¦C affect neither the relative precipitation of In and Fe nor the composition of the jarosite product. Low Na2SO4 concentrations result in reduced product yields and jarosite precipitates in which H3O' > Na+. The hydronium-rich precipitates have reduced In contents. Increasing the ZnSO4 concentration of the solution slightly increases the quantity of jarosite formed and results in the incorporation of -0.3 per cent Zn in the jarosite structure. Otherwise, the presence of ZnSO4 has no significant effect on the composition of the jarosite. Seeding accelerates the rate of jarosite precipitation but has a negligible influence on the deportment of In. The jarosite precipitation reaction at 98¦C is relatively rapid and near-steady state conditions are achieved in - 6 h even in the absence of seed. The initially precipitated jarosite is slightly enriched in In with respect to Fe. The ferric ion concentration of the solution has a significant influence on both the amount of jarosite formed and its composition. In particular, the jarosites precipitated from dilute Fe3+ media have significantly enhanced In contents. Hence, it may be possible to recover - 25 per cent of the dissolved In, at the 1000 mg/L level, in a jarosite precipitate assaying - ten per cent In by the controlled oxidation-precipitation of sodium jarosite from a ferrous sulphate processing solution.

Jan 1, 1993

By Horrocks KRS, Smitham JB, Ellison JF

This paper describes the development and installation of equipment for continuously measuring separating density in the dense medium cyclone circuits of the four million tpa Port Kembla B/C plant coal washeries. Monitoring equipment consisting of magnetic coils and differential pressure cells were installed in U-tubes taking the full flow of magnetite from the drain sections of the product drain and rinse screens. The monitoring equipment measures overflow magnetics concentration and overflow density continuously and has operated since 1989. From these measurements and calibration trials, the separating density of operating cyclone modules can be inferred reliably. Variographic analyses of the data show that medium density control to +/- 0.002 RD units and separation density control to +/- 0.007 RD units are achievable. Either method for measuring separation density can be used with approximately the same accuracy, although the overflow density measurement technique suffers from the need to have regular flushing of the Dp cells which complicates the signal analysis. Data from the plant shows that separation density can be controlled by regulating medium density, but the assumption of a constant offset between medium density and separation density is erroneous.

Jan 1, 1993

By Rashkovski GB

Until recently amalgamation has been the main process forextracting large gold particles from gravity concentrates obtainedduring the dressing of ores and placer gold deposits.Development of new technology for treating the gravityconcentrates was necessary because of the harmful effect ofmercury on subsequent production processes and theenvironment. The harmful effect of mercury is particularlyevident in the resin-in-pulp process that is widely applied inRussia.

Jan 1, 1993

By J. E. Murphy, R. Y. Wan, K. R. Sandgren, M. C. Fuerstenau

As part of a U.S. Bureau of Mines program to evaluate alternatives to sodium cyanide in gold leaching, three organic nitrile compounds were tested for their effectiveness as gold lixiviante. The organic compounds examined were malononitrile, acetonitrile, and cyanoacetamide. The reagents were tested on an oxide ore, two carbonaceous ores, and a eulfidic ore. Acetonitrile and cyanoacetamide were shown to be ineffective gold leachante. Malononitrile was the most successful of the organic lixiviants. On an oxide ore, malononitrile performed shilarlyto sodium cyanide with extractions of around 80 pct. For carbonaceous "preg-robbing" oree, sodium cyanide was completely ineffective while malononitrile extracted 24 pct of the gold. When using a resin-in-leach technique, extraction with sodium cyanide increased to 60 pct and the extraction with malononitrile increased to 80 pct. On the sulfide ore, sodium cyanide and malononitrile performed similarly with 80+ pct extraction as long as the pH of the malononitrile solution wae maintained above 10.5. Malononitrile is six times less toxic than sodium cyanide as measured by LD, levels. Therefore, malononitrile has a significant advantage over eodium cyanide, but its high cost and undemonstrated usefulnees make it unlikely to gain acceptance.

Jan 1, 1993

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By R. G. Reddy

The effect of solid particles on viscosity behavior of Na2O-O-B2O3-SiO2 melts of composition XSio2/XNa2o =0.5 and in the temperature range of 900- 1150 K was studied. Samples were analyzed by X-ray diffraction and optical microscopy. The results showed that a crystalline phase (NaBO2) was formed and its amount increases with decrease in X,, from 0.50 to 0.25. The experimental viscosity values were compared with the predicted values using our viscosity model developed earlier. At low temperatures, for low content of B2O3 , the experimental values exhibits a large deviation from the predicted values. It was concluded that the deviation was due to the formation of solid particles in the molten slags. The existence of these solid particles increased the viscosity values significantly. A new viscosity model was developed to include the effect of solid particles.

Jan 1, 1993

By Catharine T. Fogg

The U.S. Bureau of Mines investigated the availability of platinum, palladium, and rhodium from 16 deposits in four market economy countries (MEC's). Major recoverable products include 164 Moz of platinum, 80 Moz of palladium, 13 Moz of rhodium, 24 Moz of ruthenium, 4 Moz of Iridium, 2 Moz of Osmium, and 10 Moz of gold. The 12 deposits in the Republic of South Africa are estimated to account for 96.7 pct of total recoverable platinum. The base-case scenario estimates the long-term cost of production including recovery of capital, but provides no return on the investment or O-pct discounted cash-flow rate of return (DCFROR). The total production costs in January 1990 U.S. dollars ranged from $325/oz to $1,288/oz of platinum compared to an average January 1990 price of $492/oz. Approximately 83 pct of total recoverable platinum was economic at a cost level of $4S0/oz or less. At the IS-pct DCFROR, only 26 pct of total recoverable platinum was economic. For platinum-group metals (PGM), attention has been focused on the ratios of the three primary metals: platinum, palladium, and rhodium. Sensitivity analyses were performed to determine the impact long-term rhodium price increases could have on the total cost of production for platinum and palladium.

Jan 1, 1993

By Saurabh Rastogi, Vikram Shishodia, B. Pitchumani

Comminution is a unit operation which consumes major part of energy in mineral processing industries such as fertilizer production. Ball mills are widely used for size reduction of a given ore to the liberation size that is required in further beneficiation processes. In grinding of materials much effort is concentrated on control of top size of the product and this results in production of fines, also creates secondary problems of pollution due to the difficulty in the collection of fine particles. The present work has been carried out to control product size distribution for rock phosphate grinding in an Industrial Ball Mill of 600 TPD. The plant data are taken for a given feed distribution and mill operating conditions. The information at various Ball Size distributions are collected. The comminution functions such as specific rate of breakage and breakage distribution functions are estimated by back calculation technique to solve the mass balance equation. A simulation program is written to study the product size distribution obtained for various ball size distribution.

Jan 1, 1993

By S. C. Suboleski, R. Zhao

A Simulation/Animation Model (SAM) with several unique features has been developed for continuous mining in room-and-pillar production systems. Initial cut data are generated by the program based on a short list of general section parameters, and is graphically displayed on the screen for checking and editing. This portion of the program includes several intelligent features. For example, a different cut sequence will be generated for uni-directional section ventilation than for bi-directional flow. Once the data are accepted, the entire simulation may be viewed in animation. Effectively, much of the data are checked visually by watching the actions of the mining equipment. Following the simulation, results are summarized as bar and pie charts, as well as printed output. In addition to the extensive use of graphics, the program contains several advances in simulation techniques as well.

Jan 1, 1993

By Dal Sun Kim, Michael K. McCarter

"Comminution (crushing and grinding) of rock materials is energy-intensive and expensive. Mucheffort has been directed to improve the efficiency of conventional milling practice, but relatively littleattention has been given to the potential benefits of blast-induced damage on comminution processes. To help assess this effect, research has been conducted at the IRECO Laboratory and the Generic Center for Comminution at the University of Utah. The objective of this research is to investigate the effect of shockinduced “crack-like” damage on rock properties and subsequent breakage efficiency for three petrologically different rock materials under laboratory conditions. In order to evaluate the effect of shockinduced damage, a quantitative measure of rock damage is needed. For this purpose, a scalar variable (0) is proposed."

Jan 1, 1993

By Robert B. Hopler

The history of bulk loaded explosives begins with the loading of black powder and RRP (Railroad Powder) into vertical boreholes. The early air place, net of black powder and nitrostarch dynamites is covered, as are the brands and formulas of the nitroglycerinsensitized "Bagged" powders.

Jan 1, 1993

By G. Mbuyi Kamba, J. Patigny, E. Jacques

Traverse anemometry is still widely used today. In this paper an investigation of the influence of three factors which are believed to contribute to the resulting error of the method, is reported. They are the shape of the traversing path, the size of the vane anemometers and the air velocity pattern. These factors are experimentally studied on a test facility developed specially for this purpose. Taking into account the results of 576 measurement sessions, as well as published information, some preliminary conclusions are drawn, and additional questions are raised.

Jan 1, 1993

By Baxter D. A

This paper, one of two written about the Queensland Railways Brunswick Street tunnels presented at the VIII Australian Tunnelling Conference, 1993, describes the design and monitoring aspects of the railway tunnels built between Central Station and Brunswick Street Station.The design was mainly influenced by the need to minimise settlement of buildings above the route. The performance of the design details and the monitoring of the tunnels are briefly described.Appendices include extensions to the work of Curtis in the analysis of circular tunnels in a viscoelastic ground.Reference: Asche, H R and Baxter, D A, 1993. Design and ground support monitoring of the Brunwick Street rail tunnels, Brisbane, VIII Australian Tunnelling Conference.

Jan 1, 1993

By Y. Topkaya, R. E. Johnson, B. R. Palmer, R. B. Bhappu, Ronald J. Roman

The hydrodynamics of the leaching solution in leach heaps is known to be one of the important variables in the performance of the heap. The solution hydrodynamics are also important in the decommissioning of a heap where the aim is to flush out the residual dissolved metals and the remaining reagents. Chemical engineers have studied the hydrodynamics of "trickle bed" reactors for 40 years in an attempt to relate the performance of trickle bed reactors to flow conditions. Their work is reviewed with emphases on areas of similarity to heap leaching.

Jan 1, 1993

By C. Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in the flotation circuit were calibrated using a dynamic grinding/flotation simulator. Predicted values are multiplied by g/t ratios to calibrate reagent flow. The transfer functions are currently integrated into the distributed control system at Les Mines Selbaie.INTRODUCTIONThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970's there have been numerous publications dealing with practical applications of flotation process control. A review of that literature shows that basic feedback and feedforward controls are the two preferred strategies for flotation processes. Some advanced control schemes started to emerge (e.g. Zaragoza and Herbst, 1988). Feedforward and feedback aim at reducing the effect of the following flotation process disturbances (e.g. McKee, 1991):0 Changes in throughput;0 Changes in feed grade;0 Changes in particle floatability (size, liberation, surface oxidation ... );0 Deliberate changes of set-point;Feedforward strategy acts on manipulated variables, mainly reagent addition, to attenuate the effect of disturbances such as changes of feed rate and grade. The feedforward strategy is driven by measurements of disturbances. Feedback control acts to compensate unmeasured disturbances, such as ore floatability, and to bring process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by set-point error, caused by either a deliberate change of set-point or unaccounted disturbances.This paper proposes a way to improve feedforward control schemes by addition of a simple model of solids transportation. The feedforward strategy considered in this paper is of ratio type, i.e. the manipulated variable is changed according to a predefined ratio between this variable and the measured disturbances. A typical example is the ratioed reagent addition to mass flow of ore."

Jan 1, 1993

By Michael S. Wieland

This report discusses the U.S. Bureau of Mines research regarding the desensitization and malfunction of cap-sensitive explosives deployed in underground coal mines. Delay blasting in underground coal generates severe shock waves and rifting forces that fracture and heave coal. These dynamic interactions can damage other charges still remaining in the delay pattern. The debilitating impacts precipitate degrees of reduced charge performance ranging from misfires to weak detonations or out-of-sequence firings. Damaged charges react poorly, perform less useful work, and/or generate atypical fumes with higher toxicity.

Jan 1, 1993

By E. vanHuyssteen

A method of establishing the relationship between the mineralogy of a sinter and its subsequent processing behaviour in a lead blast furnace is demonstrated. It involves: 1) analyzing the Zn-spinels, hardystonite, larsenite, Pb-silicates, Pb-arsenates, Pb-(Ca)-sulphates and other femtes with an electron microprobe; 2) determining the extent of elemental substitutions in various mineral structures; 3) establishing a sequence in which the various phases formed during sintering. In this manner the relationship between the bulk chemistry of a sinter formulation and the speciation of elements into various phases in the sinter can be established. Specifically, the-substitution of Mg for Zn in hardystonite significantly influences sinter production. Mg substitution releases Zn into the surrounding matrix. This Zn reacts with the Pb-silicate to form larsenite thereby reducing the amount of Pb-silicate available for anhydrite digestion. Excessive amounts of residual anhydrite thus result if the sinter formulation is based solely on the CaO/Si& ratio.

Jan 1, 1993

By J. R. B. Lima

The present work emphasizes the selection in the separation of the apatite/calcite by the direct anionic flotation versus the double flotation, with a reverse second stage of the Jacupiranga phosphate ore. The double flotation would allow the obtaining of two concentrated solutions: one of them mainly constituted by a calcium carbonate material (CaCO3) and the other one, phosphatic (apatite). The calcium carbonate concentrated solution is used for the production of cement. The presence of phosphatic material in the calcium solution is not desirable, phosphor being a harmful element to cement. On the other hand, smaller quantities of calcite in the phosphate concentrate would represent a substantial economy in the processes of production of phosphated fertilizers. These processes make use of sulfuric acid to the solubilization of the apatite and the presence of calcium material consumes acid. Also that, when carbonates are solubilized, unwanted products are formed resulting in losses in the process and diminishing the quality of the fertilizer produced. These characteristics are discussed in the paper and are compared to another Brazilian phosphate ore, the reverse route of which can be considered more adequate. The results are discussed according to recent discoveries, and special emphasis is given to the use of corn starch and its crucial role in promoting the selection in the direct flotation process.

Jan 1, 1993

By Onal G, Celik MS, Dogan MZ

Chromite tailings assaying 21.2 per cent Cr2O3 was upgraded to 48.7 per cent Cr2O3 at a recovery of 72.0 per cent using column flotation with a mixture of anionic collectors at pH 11. Electrokinetic methods were used to elucidate the mechanism of collector adsorption and correlate the findings with the optimum flotation conditions. Multivalent constituent ions such as Cr3+, A13+, Fe2+ and Mg2+ were found to adsorb on chromite surface and shift the zpc of chromite in the direction of oxide form of the mineral. The anionic collectors also imparted a negative charge to chromite in the entire pH region. The higher zeta potentials obtained upon adding the anionic collectors is ascribed to the adsorption of anionic surfactant onto the positively charged chromite surface. The positive sites are generated through formation of significant amount of hydroxy complexes of magnesium at pH 11. Complementary infrared data reveal the absence of a shift in the spectra indicating the possibility of physical adsorption in the system.

Jan 1, 1993