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By N. Arbiter

Evidence for the floatability of sulphide minerals without collector is analyzed and it is shown that results obtained with ores, in contrast to those with single minerals or mineral mixtures, depend on many additional variables, some identified and others not. Because of the prevailing low levels and costs of collectors for most sulphide ores, it is unlikely that collectorless flotation will have commercial applications, so that continued research on the subject may be justifiable on theoretical but not on practical grounds.

Jan 1, 1993

By Charles L. Kimbell

Following the pattern established in the 1989 edition of this study, the concept of data availability must be addressed, because there are perceptible changes from year to year, and the availability of accurately reported, precisely defined statistics and nonstatistical information provides the only sound basis for analytical studies of any type. As the countries of eastern Europe, including the numerous states that formerly comprised the U.S.S.R., undergo the transition from centrally planned economies' to market economies, there has been a perceptible increase in information availability for rather obvious reasons. Any industrial operation seeing economic assistance from government and/or private sources outside the country in which the facility is sited must provide some appraisal of its operations at the time it seeks assistance, as well as some information on previous performance to serve as tools in evaluating its potential under the proposed development scheme for which it seeks financial assistance. This situation, coupled with governmental recognition that concealment of much of the national mineral production, trade, and consumption data for purposes of national security probably never was really necessary and certainly proved unnecessary with the end of the so-called cold war, has led to the publication of increasing amounts of both statistical and nonstatistical information in the countries undergoing economic transition.

Jan 1, 1993

By Charles L. Kimbell

The series summarizing the prices of the major nonferrous metals on the stock exchanges of the United States and the United Kingdom has been continued this year in tables 23 and 24. Time constraints have prohibited preparation of other price information that has appeared in this study in previous years. Users are urged to consult the 1993 USBM publication Metal Prices in the United States through 1991, which gives an analysis of historical price series and trends, or the 1993 edition of Mineral Commodity Summaries for current U.S. prices on non fuel commodities, and to utilize U.S. Department of Energy sources for information on fuel material costs.

Jan 1, 1993

By Hayashida O, Numata Y

Ultraviolet and infrared spectroscopic analyses and the extended lluckel molecular orbital method were applied to determine the electronic and binding states of 2-mercaptobenzothiazole and the adsorption system of 2-mercaptobenzothiazole on pyrite. 2-mercaptobenzothiazole exists rather in thione form than in thiol forru and the two adsorption peaks in solution were assigned to both 7t--?rt* transitions. 2-mercaptobenzothiazole chemically adsorbs on pyrite mainly due to forming the bond between iron (pyrite) and sulphur (2-mercaptobenzothiazole).

Jan 1, 1993

Flue gases from electrical power station boilers, roasting, metallurgical and chemical plants could be treated by flotation using conventional flotation machines. The flue gases are introduced into the pulp instead of the air. The flotation media is a suspension of Ca(OH)2 or CaCO3 or a solution of NH4OH etc containing Na oleate as collector and frother. The SO2 and dust content of the initial flue gases were experimentally reduced by 100 to 1000 times in one flotation operation. The velocity of the flue gases through flotation machines could reach approximatively 0.4 to 0.5 m/s and more against 1.5 m/s reached in scrubber absorbers used for this purpose, but the quality of purification is expected to be better for flotation, which is essential for the cases of heavy polluted metallurgical and chemical flue gases. For some chemical plants the flue gases flotation media may be different and more suitable as compared to the above mentioned media. The proposed flotation method could be used for separation of dry grinded ores in the form of aerosols, with a realisation of flotation from a closed space (gas bubble in the pulp) onto the interface liquid-air where the particles are attached inside the bubbles.

Jan 1, 1993

By Brian Fulcher

The Fort Lawton Parallel Tunnel was built in 1990 - 1991 by Morrison Knudsen Corporation (MK) as an integral part of Seattle METRO's planned expansion of the Westpoint Treatment Plant. The project included a concrete lined 2542 m (8,340 ft) long tunnel bored in sands and clays under the presence of methane gas and over 27.4 m (90 ft) of ground water table. The tunnel roughly paral¬lels an existing and still operating 3.65 m (12 ft) diameter tunnel originally completed in 1909. The parallel tunnel was constructed using a Lovat 4.72 m (15 ft-6 in) earth pressure balanced TBM with ribs and timber lagging as primary support. The tunnel alignment crossed under as much as 91.4 m (300 ft) of overburden as well as twin mainline railway tracks; terminating in a shaft adja¬cent to the Seattle ship canal. The project was completed in June, 1991 after a final "wet-tap" tie-in to the existing brick-lined sewer; over five months ahead of the contract schedule. This paper will describe the construction methods, job site conditions and difficulties encoun¬tered on this very challenging and successful project.

Jan 1, 1993

By A. J. Miscoe, W. M. McKewan

A unique machine for inducing bending fatigue in wire ropes was built at the U.S. Bureau of Mimes' Pittsburgh Research Center. This machine can produce nine levels of degradation through repetitive cycling of long samples of wire ropes of the types used in the mining industry. This report provides an analysis of the results of the first wire rope to be fatigued on this machine. These results have indicated that as a wire rope accumulates bending cycles, its strength first decreases because of wear and then in- creases due to cold working of the wires. As the amount of cold working increases, more and more of the embrittled wires break and the strength of the rope decreases rapidly. In this test, application of several of the regulatory retirement criteria to various sections of the rope suggests that there may be some inconsistency among them.

Jan 1, 1993

By J Lyall Workman, Peter N. Calder

"Presplitting is a technique mines and quarries may use to produce high quality final pitwalls. Damage from backbreak can be minimized, thereby insuring the final pit walls standat the designed angle. Thus costly excess waste removal is avoided. Safety in the pit isenhanced. Control blasting is an essential component of procedures to maintain the stabilityof final pit walls prone to failure."

Jan 1, 1993

By J. W. Matousek

In the flash smelting of copper sulfide concentrates, the course of reactions from the burner tip, through flame "burn-out" (the point of oxygen depletion), to settled matte and slag is of particular interest in understanding the mechanisms of the process. Numerous reaction sets can be proposed to describe the chemical changes that might be taking place, but from outside the furnace no one set offers an obvious advantage in explaining the actual processes involved. Only a combination of mathematical modeling and flame and bath sampling can achieve this result. This paper shows that flash smelting, while still reasonably orderly, is a more complex process than suggested by the technical literature.

Jan 1, 1993

Hilton Mine is located 20 km north of the city of Mount Isa and Isa Mine in far north west Queensland. The sealed road used by the 500 employees to commute from the city is part of the Barkly Highway linking Mt Isa to the Northern Territory.Although discovered in 1947, major underground development did not start until late-1982 and first cut-and-fill production in mid-1987. The J53 exploration shaft was sunk in 1970-73 and the main P49 shaft in 1973-75. Since January 1990, most of Hilton ore production has been treated in the Hilton Concentrator, and concentrates trucked in slurry tankers to Isa for smelting or shipping.

Jan 1, 1993

By Jin C, Shuyi L, Yuanbiao Z

This paper describes the structure, performance, principle and effectiveness of a new laboratory type of composed-forces field separator utilising the composition of the magnetic force, vibrating force, pulsating force, gravity and fluid-viscous force etc to separate fine feebly magnetic valuable minerals. Compared with the pulsating high gradient magnetic separator, this separator possesses unique advantages of higher enrichment ratio and higher recovery of the magnetic component.

Jan 1, 1993

By F. M. Doyle, Jiang Tao, Xu Shi, Chen Jin, E. Peters

Tafel curve technique and leaching tests have been applied to study the kinetics of gold leaching with thiosulfate. Results show that cupric ions and ammonia play the part of catalysts in the leaching of gold with thiosulfate. The activation energy of gold dissolution is calculated as 27.99 KJ/mol in the absence of both cupric ions and ammonia. However, the energy is reduced to 15.54 KJ/mol in a solution of 0.01 mol/L Cu (NH3)2 4* and 0. 5moVL total ammonia. The reaction order of Cu (NH,) g is one in the range of 0.001~0.1mol/L. These results support the electrochemical-catalytic mechanism pro- posed by the authors and explains the behavior of cupric ion and ammonia (Jiang Tao, et al., 1993)

Jan 1, 1993

By Quinn P, Robertson G, Agar GE

The replacement of diphenylguanidine (DPG) for separating INCO Bessemer matte with a water soluble collector requires a frother since most collectors do not have frothing properties. The objective of this study was to identify a non persistent frother which produced a deep froth and collapsed rapidly, while maintaining acceptable metallurgical separation. Incremental rougher flotation tests failed to differentiate any metallurgical benefit through the use of a specific frother, so other tests were employed to identify the candidate frother. The equilibrium froth height and rate of froth collapse (froth stability) of several commercial frothers were evaluated as a function of frother concentration using a 'frothmeter' apparatus. Frothers evaluated were methyl isobutyl carbinol (MIBC), Pine Oil, triethoxy butane, Dowfroth SA1263, Dowfroth 250C, Dowfroth 200 and Allied Colloids CRNI-1002. Dowfroth SA1263 produced the largest froth height, and TEB had the greatest rate of froth collapse. Frothers with properties similar to Dowfroth SA1263 and Dowfroth 250 were rejected due to their persistent froths. TEB was rejected because it has a low flash point and Pine Oil could be a nuisance to add to a flotation column. Therefore, the preferred frothers were declared to be Dowfroth 200 or Allied Colloids CRNl-1002.

Jan 1, 1993

By Morley C

The Mount Charlotte gold mine is located 0.75 km east of the General Post Office in Hannan Street, Kalgoorlie WA and about 3.5 km north of the Fimiston Operations on the famous Golden Mile.Mechanised underground bulk-mining at Mount Charlotte has been in continuous operation since 1963. For the 30-year period ending December 1992, the mine produced 22 million tonnes (Mt) of ore for a recovery of 2.73 million ounces. During 1991/92, the mine produced 1.53 Mt of ore at a head grade of 3.15 gramshonne (g/t) for a recovery of 135 822 ounces.The principal ore source at Mount Charlotte has been the Charlotte Orebody which is now largely mined out. Since 1990, approximately 75 per cent of production has been sourced from the Reward Orebodies. The Charlotte Orebody was a relatively homogeneous quartz stockwork with simple geometry and average bulked grades in the range of 4.0 to 5.5 g/t. This is in contrast to the Reward Orebodies and the more recently defined Charlotte Deeps and Maritana Stockworks, which have complex grade distribution and geometry with lower average bulked grades (2 to 4 g/t). The lower grades are principally due to the decreased density and volume of stockwork venation and related vein halo alteration. Typically, these stockworks comprise a patchy mosaic of quartz veins and vein swarms, with irregular distribution and geometry within the quartz gabbro host rock.

Jan 1, 1993

By S. C. Cohen, A. F. Mikkelsen

"This paper describes the improvements made to the operation of a liquid phase, 300°C, heat transfer system in the paste plant of an aluminum smelter. These improvements were achieved by replacing the original heat transfer fluid, a synthetic aromatic, with a new technology, petroleum-based product. This new fluid, Calflo HTF, provided better thermal stability, with lower toxicity, and improved plant working conditions.The procedures for fluid selection, changeout and performance monitoring are described along with a summary of control analysis over the last three years."

Jan 1, 1993

By Milan Lj. Stamatovic

The hydrometallurgical recovery of zinc from recycled blast furnace dust from a steel plant (Smederevo Metallurgical Company - Yugoslavia) was investigated. The dust contained 22% Fe, 17% Zn and 0.2% Pb. X-ray diffractometry showed that the main components were hematite and magnetite, in combination with zinc oxide and a very low content of lead oxide. Individual particles were generally spherical and ranged in size from 10 to 150 microns; 63% were less than 33 microns in diameter. An effective hydrometallurgical approach proved to be by caustic leaching followed by electrowinning. Recovery of zinc in the form of zinc powder was over 90%. This powder can be used for the cementation of impurities in the conventional hydrometallurgical process for zinc production.

Jan 1, 1993

By John P. Dunford

U.S. Bureau of Mines researchers are investigating the ability of mine-wide monitoring systems already in place at many coal operations to provide a direct link between geotechnical instruments and the mine-wide monitoring console on the surface. This paper describes a number of field tests using instruments such as-string potentiometers to measure roof-to-floor closure and bed separation and pressure transducers to monitor pillar loading. The advantages of using existing systems include on-site data collection and analysis, real-time understanding of geological conditions, and long-term data recovery from areas that have become inaccessible to mine personnel. However, because data are generated constantly, large files develop very quickly. In many cases, the data are redundant, such as during times of reduced mining activity or in areas not yet in the vicinity of active mining. To reduce the volume of data, a software program was written that eliminates unnecessary readings and generates a more concise file that can be output to a mine-wide monitoring system, personal computer, or as hard copy.

Jan 1, 1993

By M. S. Riyaz Ulla

The Hutti Greenstone belt, located in the northern side of Dharwar Craton, India, contains several promising gold fields. It is predominantly composed of meta-volcanics with minor intercalations of meta-sedimentaries. Alkali-SiO2 and Zr-P2O5 diagrams, immobile element trends, and an iron-rich trend on the AFM diagram indicate that the volcanic suite is low-potassium tholeiitic basalt. The lower Mg number, MgO-TiO2, MgO-Ni, and Ni-Zr plots reveal that the basalt was derived from a fractionated, highly evolved magma generated by 10-20% melting of the mantle at 1100°C and 5 kb pressure. The chemical variations suggest that the Hutti metabasalt represents volcanic arc rocks generated at a converging plate margin.

Jan 1, 1993

By Eric R. Bauer

The ground control aspects of extended depth-of-cut mining are presented in this U.S. Bureau of Mines report. A trend analysis of extended cut approvals was performed. A comparative review of roof fall fatalities for extended and nonextended cut mining is included. Current ground control guidelines for extended cut approval are summarized. The problems and concerns of this extraction system are addressed, and typical extended cutting face operations are described.

Jan 1, 1993

By Ahmed M. Nofal

This article reviews some important characteristics of the known Egyptian phosphate deposits, such as mining conditions, transport criteria, quality of products affecting their export markets and utilisation in fertilizers industry. Special attention will be given to the newly discovered large deposit of Abu-Tartur with some billion tons of ore reserves. A big project is now under implementation on Abu-Tartur deposit where the long-wall method of underground mining will be applied and a flow sheet of beneficiation will be in operation including a particular feature nontraditional in phosphate processing: high-intensity magnetic separation to eliminate dolomite impurities. Comparison with some international phosphates will be tried in order to trace the situation of Egyptian phosphates in the world market.

Jan 1, 1993