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By Fujio Ishii

The deoxidation of liquid nickel and nickel binary alloys with silicon has been determined at temperatures between 1500°C and 1650°C using quartz crucibles in order to investigate the deoxidation of nickel based alloys. The equilibrium constant of the deoxidation reaction in liquid nickel and the effects of the different alloying elements such as chromium, molybdenum, tungsten, iron, cobalt and coppcr on the activity coefficient of oxygen in liquid nickel have been established.

Jan 1, 1993

By R. D. Schmidt, M. J. Friedel

Unsaturated permeability and flow capacity exist where copper mineralization is disseminated in segmented, very-low-permeability ore blocks. The US Bureau of Mines (USBM) investigated this condition for application to in situ, copper-leach mining at the Cyprus Casa Grande mine site. Moisture retention properties are derived and combined with scanning-electron-microprobe data to characterize the host rock's mineralogy, texture, pore size, distribution and permeability. Finite element modeling is used to estimate saturated permeability and the ambient degree of saturation and to gain insight into appropriate in situ leach design. Recommended design modifications for optimized solution distribution and maximum recovery from the Casa Grande ore require: • well pressure injection exceeding 1500 psi and recovery wells operating in a suction mode, or • secondary, permeability enhancement by explosive rubblization. In the former, the lack of conditioning and the use of lesser pressures will result in leach solutions confined to the macrofractures. With the latter requirement, pressures can be reduced to 500 psi, with improved recovery and solutions containment.

Jan 1, 1993

By Rolando Campos

Until 1970, the Caletones Smelter of CODELCO-CHILE, División El Teniente, operated under the conventional pyrometallurgical process used by most of copper smelters. The annual copper production varied around 165.000 tons. The failure in the commissioning of the "oxygen smelting" technology in Peirce- Smith converters (1970-1972), forced further introduction of transcendental changes in the Caletones smelter operating scheme. Implemented technological innovations were based on wide studies and research works performed by División El Teniente. This paper presents a summary of technological modifications introduced, their impact on production and energetic performances, and short and medium terms improvement plans.

Jan 1, 1993

By Ted H. Eyde

Natural Zeolites are a less expensive and in certain applications a superior alternative to organic ion exchange resins. Mining and metallurgical waste streams are difficult to treat because the effluents which contain potentially valuable heavy metals such as copper, lead, and silver are often highly acidic and contain significant quantities of suspended solids. Under rigorous operational conditions, certain natural zeolites can remove the metals, which if desired can be recovered by either elution or conventional smelting techniques. There are significant differences in cation exchange rate, selectivity and capacity as well as resistance to either high or low pH, blocking cations and tolerance to elevated or depressed temperature and pressure not only between different zeolite minerals but between the same mineral from different deposits. Applying natural zeolites to the treatment of mining and metallurgical waste streams depends on matching the specific zeolite to the effluent by characterization of the zeolite minerals.

Jan 1, 1993

By Q Liu, P D. Katsabanis

The energy output of crushed AN/FO, crushed AN/FO mixed with Aluminum (5%, 6.4% and 9.4% A1 by mass) and a commercial emulsion explosive has been measured using a detonation calorimeter. The charges had a diameter of 10 mm and were heavily confined by a 11 mm thick copper shell. In order to achieve stable detonation glass microballoons were used in the explosives so that the density of the AN/FO charges would be around 1.1 g/cc. The charges were detonated in vacuum and the detonation products were analyzed using gas chromatography. It was found that energy values were very close to calculated values obtained by ideal detonation codes.

Jan 1, 1993

The Prospect to Pipehead Tunnel is a component of the Sydney Water Board's multi-million dollar Drinking Water Quality Program to improve the quality of Sydney's potable water supply to meet revised national health guidelines. The tunnel project involves the construction of seven kilometres of 3.9 metre diameter machine bored tunnel which is to be lined with a three-metre diameter steel liner. The paper describes the fully integrated planning and design approach and management technique used to enable this major project to proceed to meet the requirements of a tight construction program.

Jan 1, 1993

The viability of physico-chemical purification methods such as selective flocculation for separation of two components having similar chemical composition and same crystal structure but different surface properties is demonstrated. Loss of selectivity was observed in a dolomite-dolomite mixture with Polyethylene Oxide (5 million molecular weight) as the flocculant. Hetero-flocculation was minimized using a low molecular weight PEO (MW -105) as the site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at 100% recovery level.

Jan 1, 1993

BlIP Minerals is a large, diversified, international mineral producer. This paper describes the company's operating strategy, and identifies the role of mineral processing in this strategy through three examples: the column flotation installation at Escondida in Chile, the leach-SX-electrowinning plant, proposed for Escondida, and the whole-ore roasting process being constructed for the Syama gold operation in Mali. It is concluded that the application of appropriate and sometimes novel mineral processing technologies can achieve significant benefits in reduced operating cost, improved product quality, and in some cases the exploitation of previously uneconomic deposits, thereby providing strategic advantages to the company.

Jan 1, 1993

By K. Fuenkajorn, S. Serata

Discussion by S. Serata and K. Fuenkajorn Background Results of the above study in the August 1991 issue of Mining Engineering offer valuable lessons in the solution of cutter-roof problems. The original study plan was initiated by the discussion authors to solve the problems using the "stress control method" of mining (Serata 1976, 1982; Serata, Carr and Martin, 1984; Serata and Gardner, 1986; Serata, Gardner and Preston, 1986; Serata, Gardnerand Shrinivasan, 1986; Serata and Kikuchi, 1986; Serata, Preston and Galagoda, 1987) However, the plan and the planner were changed to the arrangement reported in the paper. The change was considered reasonable at the time due to the mine engineers' uncertainties about the stress control method. Consequently, the basic principle of the study was shifted from the original stress control method to the method described in the paper, which will be called the "yield pillar method" for the purposes of this discussion. The paper convinces the reader that the yield pillar method fails to solve the cutter-roof problems. This doesn't mean that the stress control method also fails. Actually the contrary is true, as discussed below. Limitation of the yield pillar method The paper illustrates clearly how poorly the yield pillar method performs in solving the problem. The reason for this failure is the lack of the protective stress envelope needed to stabilize the cutter roof. Unfortunately, the protective envelope cannot be formed properly without utilizing the stress control method of mining. Changing the pillar size does not make much difference in the roof stability. Stress measurement The key issue is how to form the global stress envelope to make the gate entries safe for production. Therefore, measuring the stress condition of the ground around the mine opening is critically important to solving the cutter-roof problem, regardless of the method applied. With regard to the stress measurement, there is a serious question as to the reported stress state of [6 i = -51.7 MPa (-7499 psi), G2 = -44.5 MPa (-6458 psi) and 63 = -30.8 MPa (-4465 psi)]. It is mechanically impossible to have such a stress state at any location in the mine ground since the known initial vertical stress [o,,] is less than or equal to 800 psi. There may be a large stress state in the [61] direction, but that is possible only at the expense of the [63] value. Having the above stress tensors in the mine is simply impossible. The questionable, reported stress values could be attributed to the application of the overcoring method, which tends to produce erroneously large stress values in the extremely nonelastic mine ground. Stress control method The paper should be considered as a major contribution demonstrating the limitation of the yield pillar method. At the same time, the paper does not disprove the stress control method. However, in comparing the paper with stress control studies conducted in other similar failing grounds, the stress control method appears to be able to solve the problem more effectively. Therefore it is advisable that the mine not give up its efforts to solve the problem. [•] References Serata, S., 1976, "Stress control technique - An alternative to roof bolting?," Mining Engineering, May. Serata, S., 1982, "Stress control methods: Quantitative approach to stabilizing mine openings in weak ground," Proceedings, 1st International Conference on Stability in Underground Mining, Vancouver, BC, Aug. 16-18. Serata, S., Carr, F., and Martin, E., 1984, "Stress control method applied to stabilization of underground coal mine openings," Proceedings, 25th US Symposium on Rock Mechanics, Northwestern University, June, pp. 583-590. Serata, S., and Gardner, B.H., 1986, "Benefits of the stress control method," invited paper, American Mining Congress Coal Convention, Pittsburgh, PA, May 7. Serata, S., Gardner, B.H., and Shrinivasan, K., 1986, "Integrated instrumentation method of stress state, material property and deformation measurement for stress control method of mining," invited paper, 5th Conference on Ground Control in Mining, West Virginia University, Morgantown, WV, June 11-13. Serata, S., and Kikuchi, S., 1986, "A diametral deformation method for in situ stress and rock property measurement," International Journal of Mining and Geological Engineering, Vol. 4, pp. 15-38. Serata, S., Preston, M., and Galagoda, H.M., 1987, "Integration of finite element analysis and field instrumentation for application of the stress control method in underground coal mining," Proceedings, 28th US Symposium on Rock Mechanics, Tucson, AZ, pp. 265-272.

Jan 1, 1993

By C. A. Young

In-situ Fourier transform infrared/internal reflection spectroscopy (FT ?IR/IRS) has been extended to study oleate adsorption at a calcite surface. The birefringent and transmission limitations of calcite were overcome by using an appropriately designed optical setup and a near-infrared (NIR) spectrometer. An adsorption isotherm was determined at pH 9.2 and room temperature. Comparison with the fluorite/oleate adsorption isotherm determined by the same technique indicates that oleate abstraction by calcite can be as much as one order of magnitude larger than that by fluorite. Nevertheless, the hydrophobicity of the fluorite/oleate surface is greater for equivalent adsorption densities as indicated by contact angle measurements and flotation results. The monolayer region has been confirmed to be chemisorbed oleate at both calcite and fluorite surfaces. Furthermore, multichannel laser Raman spectroscopy (MLRS) showed that chemisorbed oleate at the fluorite surface undergoes a double-bond reaction with oxygen to form an epoxide/polyether complex. Such a reaction, however, could not be detected at the calcite surface. These phenomena are discussed in terms of the intrinsic surface properties of the mineral systems as well as the adsorption density and the cross-linking/polymerization reaction of the adsorbed oleate film.

Jan 1, 1993

By P. Bevilacqua, M. C. Williams, T. P. Meloy

We will bet you that, without prior programming within 10 minutes, we can design and simulate a 10,000 unit operation separation circuit. We will even do it at your place. We do it all the time. [ ] There are no tricks; we do it in a spreadsheet. We do it in those user friendly spreadsheet such as Quattro Pro. Spreadsheets must be user friendly. Accountants use them as do managers, business men, lawyers, doctors and salesmen. What these users seldom realize, is how powerful a mathematical tool a spreadsheet is. Among their other capabilities, spreadsheets can do a finite element analysis. That is why they are useful for accounting. That is also why they are more useful to engineers in the mineral industry. Spreadsheets are ideally suited for the engineering problems in the mineral industry. We have used then for solving problems in: a) mine ventilation; b) circuit design and optimization of dense media, flotation and sizing; c) comminution circuit design; d) shaking tables; e) Humphrey spirals; f) sluice ways and channel flow; g) lock particle and liberation problems; h) tunnel and shaft stress problems; i) cascadograph simulation; j) complex heat transfer problems; k) flow in porous media; and sheet flotation (Figure 1). Mineral industry problems presented on or with a spreadsheet are an excellent teaching instrument, problem statement and solution tools and sales devices. Spreadsheets answer easily, quickly and reliably many mineral industry engineering problems. What makes spreadsheets so useful to the mineral industry. The short answer is: they are easy to use; mineral industry problems fit the spreadsheet format. Those reasons are part of the answer. The real answer lies with the structure of the spreadsheet itself. Essentially, a spreadsheet is a "finite element analysis" form of computer software. Many mineral industry problems are readily solved by finite element analysis techniques. While some in the mineral industry may think they have never heard of finite element analysis, most use it weekly if not daily. Any profit and loss statement is essentially a finite element instrument. In fact, any array of numbers where one number is related to another may be construed as a finite element analysis product. Finite element analysis is a common daily activity. To get an appreciation of a finite element analysis, think of a monthly sales forecast for the next year. For each product and for each month, there exists a dollar figure for the forecasted amount of sales. In the forecast statement, for a given product in a given month, there is a "box" where the forecasted figure is presented. The forecast figure in that box was arrived at through some type of formula. The formula probably required some information from other neighboring boxes in the master forecast statement. Voila, one has a finite element analysis. Today the analysis would be done in a spreadsheet. A typical mineral industry problem is ventilation in an underground mine. Think of a rectangular room and pillar mining operation. Each room has air entering at a given pressure and velocity and air leaving at another pressure and velocity. During steady state, the air entering and leaving the room is determined by conditions in the adjacent rooms. One can readily model the room and pillar mine layout in a spreadsheet, and then find the flow in and out of each room at steady state. Change the flow by moving a brattice cloth or blocking off a path way and one gets a new air flow profile. Change the numbers on the spreadsheet that reflect

Jan 1, 1993

By Steven V. Crum, David E. Siskind

In response to its own concerns and those of the public, industry and regulatory agencies, the Bureau of Mines is studying the impacts of low-frequency blast vibrations on structures. Previous research has identified potential problems associated with low-frequency ground vibrations and also found that their existence was not particularly rare, given large surface mine blasts and certain geologic conditions. Only a limited amount of data existed in the blast vibration literature on structure response to ground-vibration frequencies below 6 Hz.

Jan 1, 1993

By P. G. Corser

A gold and silver open-pit mine located in northwestern Chile contracted ACZ in 1991-92 to assess the stability of their spent ore pile and to determine the cause and magnitude of cyanide contamination associated with leaching operations. The mine is a conventional open-pit located at an elevation of approximately 4,800 meters (m.) (15,744 feet). A spent ore pile is located approximately 2,000 m. southwest of the mine and approximately 1,000 m. northeast of the active pad and plant facilities. The pile was constructed on a gentle northwest slope dipping 12 to 13 degrees. The pile is bordered by a small river to the northwest and by a larger river to the northeast. Both rivers eventually flow into Bolivia. Heap leaching and processing commenced at the mine in 1988. Since 1988, nearly 6.0 million tons of ore at an average grade of 1.96 grams/ton (0.07 ounces/ton) of gold and 52 grams/ton (1.83 ounces/ton) of silver have been treated by cyanide heap leach methods with zinc (Merrill Crowe) precipitation. In approximately three years of operation, the mine has yielded more than 225,000 ounces of gold and over 1.5 million ounces of silver. Currently ore is agglomerated and hauled to the leach pad by truck and is top loaded to produce a 5-meter lift height. Four contiguous reusable (on/off) leaching pads were constructed with an asphalt layer above a carefully compacted sub-base of High Density Polyethylene (HDPE) liner and screened fines. Leach solution of pH 10-11 containing 1.2 to 1.5 gram/liter of cyanide is applied to the heap at a rate of 10 liter/hour/square meter for a total active application period of 30 days. Leached (spent) ore is transferred to the spent ore pile located approximately 1,000 meters to the northeast. The pile currently contains approximately 6 million tons of spent ore. The pile liner, which has been constructed over a prepared sub-grade consists of three geosynthetic layers (geotextile/flexible membrane liner/geotextile). Long term objectives include washing the pile to recover an additional 3 to 4 percent gold and silver.

Jan 1, 1993

By J. O. Marsden

This paper presents an overview of the innovative methods for gold and silver extraction that have been put into actual practice in North America since 1987. It is an update of a paper of the same title which was presented by Sass and Mansanti at the AMC conference in San Francisco in 1987. New practices, new equipment and variations of older practices that have been introduced in the last five years are discussed in each of the following categories: process selection trends, comminution, gravity concentration, flotation, oxidation, agitated and vat leaching, heap leaching, solution concentration and purification, zinc precipitation, electrowinning, tailings disposal detoxification, and reclamation.

Jan 1, 1993

By Charles L. Kimbell

Annual global steel industry investment is partly mirrored in the data for selected market economy countries that appear in table 13 for 1988-90. No reasonably comprehensive 1991 data were available for inclusion in this study, and the partial reporting available was so incomplete that it was impossible to demonstrate whether the level advanced or declined from the 1990 level of nearly $15.5 billion. Moreover, with the radical changes that are now being effected in the steel industries of the states that were the U.S.S.R. and its CMEA partners, it is most regrettable that comprehensive and comparable data, both current and historic, on investment in this area are not available. Updated information on market economy country petroleum industry capital and exploration expenditures by geographic area has been included in table 14, and it is evident that there was a substantial upturn in investment in 1991. The level of almost $74.5 billion was 14.5 % above the 1990 level and included gains in every topical category and geographic area. The source of information for this table has been changed to the Oil and Gas Journal Database from the previously used Chase-Manhattan Bank study of Capital Investments of the World Petroleum Industry, which has been discontinued. Because of this source change, it has been necessary to modify the structure of the table somewhat, but its total scope of coverage is regarded as basically unchanged. It should be noted that the grand total, as well as some of the detail appearing for 1987, corresponds precisely with those in the previous source.

Jan 1, 1993

By J. H. Lazarus

The evolution of backfill-distribution systems for deep gold mines is examined. The status of current technology for the design of backfill-distribution systems is considered with reference to pipeline pressure gradients, pipeline wear rates, and slurry flow regimes. The effect of an increase in the relative density of the slurry on the performance of backfill-distribution systems is illustrated. Future trends regarding the design of backfill-distribution systems are discussed.

Jan 1, 1993

By Dennis B

The Hilton Mine, 20 km north of Mount Isa was discovered in 1947. The underground mine has been a significant producer from 1989. The long development history is the result of complex orebody geometry, difficult metallurgy, dewatering problems and competition for development funds from the then expanding Isa Mine at Mount Isa. At present it produces 1.4 million tonnes annually. Its 21 million tonnes of reserves are necessary to supplement Isa Mine production.Hilton Mine is located in the Urquhart Shale formation of the Mount Isa Group, within the Mid Proterozoic Mount Isa Inlier. The seven developed orebodies have suffered strong structural deformation. Each orebody has a unique mixture of mineralogy and texture which effects ore value and metallurgical performance. These characteristics have proven useful for correlation purposes.The faulting and folding have caused difficulties with orebody interpretation, geomechanical complexities and has influenced the choice of mining methods: Initial cut and fill and open scope designs have given way to bench mining methods in response to better understanding of the eedloav and economic constraints.

Jan 1, 1993

By Erich U. Petersen

Discussion by Erich U. Petersen Harbuck et al. (1990) present results of research on sulfuric acid leaching of a germanium-gallium ore and shed considerable insight on possible extraction methods for gallium and germanium. However, the presentation does not give sufficient details to evaluate the research, so some of the conclusions may not be as applicable as stated. The objective of this communication is to indicate that relevant and easily obtainable geological and technical information was omitted. Consequently, on this basis, alternative explanations for some of the data are possible. Discussed below are the omission of: • pertinent geological, mineralogical and geochemical literature; • details regarding the determination of germanium concentration in quartz by electron microprobe; and • details on the calculation of the amount of germanium locked in quartz. "These topics are important since the determination of the amount and locus of "unrecoverable, locked germanium" may have an important impact on the economics and methods of germanium extraction and the directions of future research. Harbuck et al. state that "A key to increasing germanium extraction is understanding the mineralogy of the ore." However, only two studies are cited that in some manner describe the mineralogy of the ores. In addition, both of these studies were very preliminary, of limited scope and examined very few

Jan 1, 1993

By M. L. Gupta, S. P. Banerjee, D. C. Panigrahi

The paper describes the computer simulation of climatic conditions in the longwall workings in India. For this simulation work the longwall panels have been divided into two segments, viz; the intake gate segment and face segment. Two computer models, one based upon transient heat and moisture transfer algorithm of McPherson (1986) and the other on quasi-steady algorithm of Starfield and Bleloch (1983), have been developed for intake gate segments. Similarly two computer models, one based upon the transient heat flow in cylindrical tunnel with certain modifications of McPherson algorithm (1986) and the other on linear heat flow concept, have been developed for face segment. The models incorporate the necessary running and spot heat sources present in their respective segments. In addition to this the goaf heat flow parameters have been incorporated in the models for the face segments. Continuous recording of important thermal parameters have been carried out in several longwall faces in India to validate these models and the results have been presented.

Jan 1, 1993

By R. J. Roman

The results of column leaching tests on 3 different mixed oxide/sulfide ores from a Chilean deposit are presented. The 3 samples contained different ratios of oxide copper minerals to chalcocite and chalcopyrite. The results of the column leach tests are interpreted in light of the shrinking core model for coarse particle leaching. The copper recovery from the oxide minerals and the sulfide minerals each conforms to the shrinking core model with the total recovery equal to the weighted average of the individual minerals. The use of column test results to predict field heap leaching results using the multi-mineral shrinking core model is discussed.

Jan 1, 1993