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By Charles T. Staniek

Following a dragline relocation at Agrico's Fort Green phosphate mine in 1986, the recovery plant experienced a significant decrease in flotation performance. Through weeks of trial and error testing, we discovered we could restore recoveries by conditioning feed at pH's higher than we had used historically. The higher pH's essentially increased flotation cell kinetics, although we still do not understand the exact mechanism at work. Armed with new-found appreciation of pH modification, we initiated a program to determine the optimum modifier for us, from both a performance and environmental perspective. Environmental considerations were important because ammonia, the standard industry modifier, is a plant nutrient and higher usage rates could affect the quality, of our recycle process water. This paper describes the research and development work spanning a 3 year period that culminated in making a major change in our reagent suite when we replaced ammonia with soda ash on a permanent full-time basis.

Jan 1, 1993

By Bret E. Leisemann

The geomechanical environment in which highwall mining must operate represents a hybrid between surface and underground operations. Mine design must take into consideration the complexities associated with unsupported spans, pillars with extreme aspect ratios and the instability related to the interaction between coal extraction and the highwall stability. The rock mass adjacent to the highwall, and for a significant distance in, is affected by lateral stress relief and blast damage. This paper describes a rigorous site investigation program aimed at providing some of the input parameters for the design of highwall mining layouts at the Moura Mine and focuses upon defining the nature and extent of the relaxed zone behind the highwall. The combination of borehole imaging and C factor analysis allows delineation of blast damage and relaxation of the rock mass immediately adjacent to the highwall excavation, as well as the more subtle relaxation effects deeper into the rock mass. This has led to the formulation of a proposed geomechanical model for the relaxed zone for direct input into highwall instability analysis and mine design.

Jan 1, 1993

By S. N. McIntosh

Column bioleaching was evaluated by the U.S. Bureau of Mines as a means of recovering manganese from a low-grade ore from the Three Kids deposit in Southern Nevada. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms. Diluted molasses medium was provided as nutrient for the microorganisms. The medium was recirculated through the ore bed until the sugars were spent. Two methods were evaluated to recover manganese from the sugar depleted bioleaching solution: (1) adsorption with a weak cation exchange resin followed by stripping and precipitation techniques, and (2) direct precipitation of the manganese using ammonium carbonate. Both methods removed up to 95 pct of the solubilized manganese from the medium as a carbonate salt. After manganese removal, the medium was replenished with fresh molasses and recycled back through the column. More manganese was effectively leached. This process of manganese solubilization and recovery followed by replenishment and recycling of the medium was repeated until 98 pct manganese was extracted from the ore.

Jan 1, 1993

Potential hlghwaJl mining reserves in Australia are large, but geotechnical and operating conditions are quite different from those where highwall mining has evolved in the USA. In order to achieve safe and effective resource recovery, equipment and procedures should be developed to penetrate 250 m in the Australian mining environment. This paper identifies key auributes to be incorporated in such machinery and methodology. These suggestions are intended to promote discussion on innovations to satisfy Australian requirements for highly productive, safe and environmentally acceptable techniques.

Jan 1, 1993

By R. G. Johnston

Minerals have many uses in paint systems. These roles include use as primary and extender pigments, sheen control, film durability enhancement, and rheology control. These and other uses of minerals in paints, and the effects of mineral quality variations on coatings performance are discussed. As coatings performance requirements become more demanding, tighter consistency of important mineral properties, such as particle size distribution and purity, is becoming increasingly vital. Future directions of mineral use to meet projected environmental restrictions and performance demands on coatings, including the use of advanced minerals technologies, are examined.

Jan 1, 1993

By Ronald T. Mayerle

In-1992, the U.S. Bureau of Mines conducted a mineral investigation of the Anderson Mountain study area, including RARE II area 4-942, in Lemhi County, Idaho. The 7,340-ha study area lies within the Salmon National Forest about one kilometer north of the old mining town of Gibbonsville (pop.: 100). The eastern boundary of the study area is formed by the crest of the Bitterroot Range. The crest also serves as the continental Divide, and as the border between Idaho and Montana. The study area lies within the Gibbonsville Mining District, an important past producer of gold from lode and placer deposits. Since the 1870's, several hundred claims for both types have been located in the study area. Thirty-six current (1992) lode claims and two patented claim groups (one lode and one placer) are wholly or partially in the study area. No placer claims are current. In all, twenty-seven lode and five placer properties in and adjacent to the study area were investigated. Workings on the properties included 2 caved shafts; 36 caved adits; 8 open adits; 120 small pits, cuts, and trenches; and 4 large dozed cuts.

Jan 1, 1993

By S. P. Rivers

The stainless steel industry re1ies on nitric-hydrofluoric acid (HNO,/HF) pickling solutions to remove surface contaminants and maintain the corrosion resistance of the steel. More stringent environmental guide1ines are expected to be placed on the disposal of these solutions which could significantly increase processing costs. The U.S. Bureau of Mines has been conducting research to develop a process for recycling depleted pickling solutions, thus reducing the quantity of by product acids generated. Research has shown that F- can be liberated from the predominant iron fluoride species (FeF,') by using oxalic acid in an electrodialysis cell. Ion selective membranes allow dissolved metals in the depleted solution to be replaced with hydronium ions by metathesis, thereby regenerating the HF. The regenerated HN03/HF is then retained in the pick1ing solution. This paper reports on the research effort at the U.S. Bureau of Mines Rolla Research Center to apply electrodialytic recycling to HN03/HF pickling solutions.

Jan 1, 1993

By H. E. Wyslouzil

The highly competitive nature of the international iron ore market has forced producers to improve the quality of their pellets. The demand for low acid pellets suitable for direct reduction has resulted in an increase in the number of plants utilizing reverse froth flotation for silica reduction. Column flotation is being favoured for this service due to the low capital and operating cost of the equipment, as well as improved metallurgical performance when compared to conventional flotation cells. This paper describes the benefits of column flotation and discusses some important aspects of circuit design.

Jan 1, 1993

By M. B. Cortie

An account is given of the development of ferritic stainless steels since their discovery in the early years of this century. The alloys became very widely used in the 1950s, the market during that decade being driven strongly by a demand for automobile trim made of ferritic stainless steel. The production of ferritic stainless steel declined as a proportion of the total at the end of the 1950s as consumer preferences changed. However, the market is now growing strongly again, this time driven by a demand for oxidation-resistant alloys for motor-vehicle exhaust systems. The tonnages produced, applications, and market shares of the various alloys are discussed and compared. Trends in world stainless-steel production, product forms, technological development, and usage are examined.

Jan 1, 1993

By Charles L. Kimbell

For 1991, the aggregate value of world international export trade in mineral commodities was roughly estimated at $685 billion in current 1991 dollars. The estimated level was about 6 % higher than that for 1990, but still more than 3 % below the record high set in 1980, and the year was the fifth in a row in which the value of exported minerals advanced. Table 8 provides a data series for the estimated value of world export trade in all mineral commodities from 1979 through 1991, as well as a breakdown of this total into fuel and non fuel commodities. The data shown are based on the historically more traditional and realistic (from the viewpoint of data availability) practice of reporting trade values for the year before the year of review. Despite the considerable increase in the dollar value of mineral commodity exports, their share of total export merchandise trade declined to 19.1 % in 1990 from 19.7% in 1989. At 19.1 %, this share was very near the recent year record low of 19.0% reached in 1988. Comparable 1991 figures were not available in time for inclusion here, but it is expected that the mineral commodity share of the total will be little altered from that of 1990.

Jan 1, 1993

Traditionally, the Lead Lode at Broken Hill has been represented on presentation plans, cross sections and diagrams in scientific papers as a solid black mass, around which the more 'interesting' and 'structurally useful', wall rocks appear to wrap. Structural analysis of the Broken Hill orebodies has usually turned to these wall rocks to determine the structural history of the mineralisation.This tendency to represent the orebody as a massive single entity is incorrect and the aim of this paper is to illustrate that sulphide orebodies (in this case Lead Lode), are a dynamic part of the mine stratigraphy. They can preserve a great deal of useful structural information that can be recorded with detailed internal mapping.Three main categories of ore type are recognised in Lead Lode; Stratiform ores, Mobilised ores and Metasomatically altered ore. The ore types in these categories occupy or have formed in distinct structural and stratigraphic positions and have clearly recognisable inter-relationships.

Jan 1, 1993

By M Surtees

The Limpopo region in southern Africa is considered to be a favourable target for the discovery of base and precious metal mineral deposits. The integration of gravity, geomagnetic, LANDSAT data and geotectonic history is used to formulate an ore deposit model which can be used in the implementation of mineral exploration programmes. Field work was carried out to test and refine the model.

Jan 1, 1993

By Park. D. W., Y. M. Jiang, L. A. Morley, W. Keeton

Underground room-and-pillar mining operations in the Warrior Coal Field in Alabama frequently suffer instability due to soft floors and thinly-laminated immediate roofs. This investigation concerns a mine that was experiencing ground-control problems with weak floor conditions. Several roof falls occurred locally, and as much as 0.6 m (2 ft) of floor heaves have been experienced. The paper presents the results of comprehensive analyses conducted on floor heave, roof sagging, pillar- penetration and floor bearing capacity using instrumentation and numerical modeling.

Jan 1, 1993

By Ronald O. Harma

Iron ore pellets made from concentrates produced from low grade iron ores are the primary iron bearing feedstock for iron making in North American blast furnaces. Steelmakers are demanding increasingly higher quality to provide for improved blast furnace productivity, efficiency, product quality and environmental compliance. Unfortunately, this higher quality iron ore product must be produced from the vast deposits of low grade iron ores that are becoming increasingly poorer in quality with regard to mineral liberation and ease of concentration. Since some of these low grade iron ores require grinding to as fine as 90% -500 mesh (25 microns) for liberation and since more of the silicious gangue and other minor undesirable constituents must be removed to provide the higher quality, we have come to depend on flotation to do the added work. Flotation technology and other preflotation unit operations must improve to meet these increasing demands. In many cases, flotation equipment, reagents and circuit operating performance have improved little during the last two to three decades. Mechanical flotation cells have grown from 14 cubic meters (500 cubic feet) to over 84 cubic meters (3000 cubic feet) to help reduce capital and operating costs; however, flotation metallurgical performance has not improved, Column flotation has only recently shown promise in improving metallurgical performance for iron ore rougher flotation. Previous column flotation success was mainly in scavenger and cleaner flotation steps for treating minerals other than iron ore. Although some new flotation chemicals have been developed for removal of silica and other minor constituents under widely varying mineralogical scenarios, recovery of iron mineral has not improved. The operation and control of flotation circuits have become more challenging because of the increasing workload on flotation. Better sensing, process control and operation of flotation circuits are essential as we go forward. Iron ore upgrading by flotation can be classified into either anionic or cationic methods. Anionic flotation of either iron oxide or silicious gangue is accomplished by collector type, pH control and selective chemical activation . Similarly, cationic flotation of silica or iron oxides is accomplished by collector type, activation and/or pH control. Removal of other minor constituents is achieved by using specialty chemicals under controlled conditions for preflotation, co-flotation or post flotation steps. Generally, anionic flotation is used for floating cleanly liberating crystalline oxidized iron ores such as hematite, specularite and martite. Earthy and hydrated oxides such as hematite and geothite can be upgraded with either anionic or cationic collectors after controlled dispersion of slimes or prior removal of slimes. Anionic flotation of silicious waste can be achieved by calcium activation of silica. For magnetic iron ores small amounts of locked silica particles (middlings) can be removed by cationic silica flotation, which is the only method in commercial use in North America today. Historically the efficiency of these iron ore flotation processes has been restricted by the loss of fine iron particles (minus 500 mesh) to the tailings product. New technology is required to overcome this loss and improve overall flotation performance. Development of technology for more selective separation of silica and other minor undesirable constituents from iron ore will provide both quality and cost benefits to the iron and steel producers. Development of future iron ore production in North America will face stiffer technical challenges. These new and undeveloped iron ore deposits are largely oxidized (non-magnetic) and by nature contain more slimes and other undesirable constituents. Unless other new technology evolves, flotation will be the major treatment process required to upgrade these difficult low grade iron ores.

Jan 1, 1993

By W. K. Collins

Engineered Scavenger Compounds (ESCs), developed by the U.S. Bureau of Mines, are a novel class of compounds that can selectively recover a desired element from a solid or molten alloy. Lithium titanate (Li2Ti3O7 or L'20-3T'02) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (Al-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both are metastable, the hexagonal phase that forms during the scavenging of Li from Al-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li2Ti3O7 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1993

By Peter Florian

At 5:50 am on October 1, 1992, the new $800 million Pittsburgh International Airport Midfield Terminal opened its gates to the world after five years of construction and more than 24 years of planning. Despite numerous design changes, this massive project was completed on time and substantially within budget. The importance of this airport to Allegheny County and the Pittsburgh region was recognized 24 years earlier by Allegheny County Commissioners Tom Foerster and the late Leonard Staisey. Staisey and Foerster established a program to acquire land for the "Airport of the Future".

Jan 1, 1993

As part of the U.S. Bureau of Mines (USBM) program to characterize subsidence this combination of software and hardware has been used to remotely monitor overburden response to longwall mining. Background The principle of time domain reflectometry (TDR) is being used by the USBM to monitor strata displacements induced by mining. This capability has been enhanced by the availability of cable testers with serial communication modules that allow users to get TDR records in digital form. Actual field installations involve coaxial cables that arc hundreds of meters long, and the many records obtained when monitoring such long cables on a daily basis motivated development of software to view interactively and compare waveforms and to analyze signature changes. Time domain reflectometry (TDR) was developed in the 1960's as a method to locate discontinuities in coaxial transmission cables. The concept has been extended to measurement of properties of materials into which probes are embedded, such as water content of soil, and evaluation of coaxial cable dielectric behavior. This technique was adapted by the USBM in 1975 for use in checking the movement of rock during underground mining. Coaxial cables are grouted into a rock mass that is expected to cave, and progressive rock movement causes the cable to deform. Consequently, there is a progressive change in cable electrical properties that produces changes in TDR pulse reflection signatures. TDR technology has been advanced by Northwestern University to the point where it is now possible to distinguish shear deformation from tensile deformation, and to quantify rock mass displacements, by analyzing these changes in TDR signatures.

Jan 1, 1993

This paper addresses the role of mine geology in mining geotechnics. The role is assessed and discussed in terms of five main elements; geotechnical complexity, geological complexity, mine scale, percentage sampling and geological uncertainty. Lastly, the overall objectives and mine geology requirements are listed in terms of the various mine development stages; exploration, feasibility-design and operating.

Jan 1, 1993

By Wencai X

The conversion relationship between the Bond Work Index W1, specific output of mill and the energy efficiency of grinding were developed using dimensional analysis. These relationships were validated and the value of the conversion coefficient ~ was also obtained using a new installed device for measuring grindability of ores. With the new simulating algorithm the mill specifications, output and size distribution of grinding products of industrial mills can be calculated based on laboratory measured results. This algorithm is more accurate and simpler than any of the other empirical relationships. KEYWORDS: Conversion coefficient method, grindability, grinding Constant.

Jan 1, 1993

By Chen B

In recent years great efforts have been made in the optimisation of ball mill operation. This paper describes a methodology developed for modelling and optimising the steady-state grinding process. Thirteen basic similarity numbers of the process are derived. Based on these similarity numbers, we build a group of mathematical models which give a full description of the relation between dependent and independent variables. The parameter estimation and multi-objective optimisation of the grinding process have been done using these models, and validated with experiments in a continuous laboratory-scale ball mill.

Jan 1, 1993