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By E. H. Cho

An acid mine drainage sludge sample containing 3.6% Mn, 0.18% Ni, 0.15% Co and 0.39% Zn was obtained from the central part of West Virginia and leached with sulfuric acid at pH 3 and at room temperature. Air was bubbled through the leach solution to precipitate the iron content from the solution at pH 4.5. The leach solution contained 258ppm Zn, 105ppm Ni, 90ppm Co and 2050ppm Mn. Three distinctive solvent extraction studies were performed to selectively extract these metal ions in a sequential operation with DEHPA, Cyanex 272, and then Lix 84. The AIO ratio was 1 and the extractants were diluted 10 times with kerosene. A study of solvent extraction with DEHPA showed that Zn could be extracted without Ni or Co up to pH 2.75. A pH of 2.75 is considered to be the optimum pH to maximize the selective separation of Zn from Mn. The separation factor of Co over manganese suggests that the two metal ions be extracted together by Cyanex 272. The separation factor of Co over Ni indicates that these two metal ions can be separated most effectively around pH 5.3. Also, Ni can be effectively extracted by Lix 84 above pH 5.5.

Jan 1, 1993

By Dai Q

The mechanism of flotation of potash ores with long chain primary amines has been assessed. Since at high electrolyte concentration in saturated brine the electrical double layers of the interacting particles and bubbles are entirely compressed, the induction time measurements confirmed the elimination of kinetic factors associated with the energy barriers opposing particle-to-bubble attachment under such conditions as could be expected. The lack of the kinetic hindrance resulted in the correlation found between the contact angles on the KCl surfaces and the sylvite flotation measured under the same physico-chemical conditions. The iep values and acid numbers obtained for various Esso oils tested as extenders in the flotation of coarse potash ore fractions confirmed the base oils with high content of nitrogen-bearing compounds to be good extender oils. The performance of such oils could further be improved by dissolving in them a small amount of long-chain aliphatic amine.

Jan 1, 1993

By Fabjanczyk M. W

The design of underground mine roadways (tunnels) requires a detailed understanding of the in situ stressfield, the rock failure modes, the performance characteristics of reinforcement or support members and assessment of the stress state about the roadway. Definition of these factors, together with monitoring of roadway behaviour during both development and extraction operations, allows rational design procedures to be undertaken.The design approach utilised computational techniques to simulate the behaviour of the strata about the opening for a range of anticipated stressfields and various reinforcement options. Field validation studies are conducted to confirm the design expectations.

Jan 1, 1993

By Y. M. Jiang, D. W. Park, S. M. Lee

A vast majority of longwall operations in the US use shield-type hydraulic supports to provide ground control along the longwall face. The three-dimensional, finite-element technique combined with a progressive failure approach was utilized to simulate interaction between shields and surrounding strata and determine various loading conditions. In addition, a separate finite-element model of the shield structure was made to study responses of each longwall shield to the different loading conditions. Shield responses under various loading conditions and the shield characteristics, such as shield stiffness, the ability of resisting horizontal forces, and the effect of shield height, were studied based on the results from finite-element analyses. The results can provide the basis of effective shield design and be used for evaluation of the shield performance. It is suggested that a technique incorporating the finite-element method be developed to evaluate real-time shield performance for the purpose of effective ground control.

Jan 1, 1993

By M. L. Matt

The Pittsburgh Safety and Health Technology Center of the Mine Safety and Health Administration has developed the Mine Emergency Responsiveness Development (MERD) program to improve the reaction and response of mine personnel in mine emergency situations. The MERD program simulates problems that may be encountered in underground mine fires, underground mine explosions or surface mine accidents. Since its inception in 1982, the MERD program has been presented to MSHA, Industry, Labor and State Government Personnel. The program is extremely versatile and is easily adapted to suit various training requirements. It gives the participants the opportunity to experience some of the emotions, frustrations and successes of a mine emergency in a controlled environment without having to be involved in one. Past participants have indicated that this training has better prepared them in actual emergency situations through increased awareness and advanced preparation of plans and resources. In 1992, a Mine Simulation Laboratory, which simulates a coal mine and metal/nonmetal mine, was built to improve training for mine emergencies and prevention and fighting of mine fires. This facility has been included in the MERD Program to provide realistic and practical training for mine rescue teams and MERD participants in advanced mine emergency operations. This paper presents an overview of the MERD program.

Jan 1, 1993

By M. C. Baumann

The Getchell Mine is located in Humboldt County, Nevada, approximately 70 km northeast of Winnemucca. Slope management has been a critical factor in the feasibility of mining operations since they began in the early 1930's. Although underground entries began in 1937, underground production was limited because hanging walls consisting of clay gouge and crushed rock tended to collapse into the workings. Controlling these collapses required extensive timbering. Due to these poor ground conditions, surface open-pit mining was the primary mode of production from 1938 to 1967 with only minor contributions from underground operations. Mining was suspended in 1967 due to economic pressures. From 1960 to 1967, the previous operator mined the property in three open pits. Initially, these pits were constructed with footwall benches, but these failed. These failures were aggravated by construction of 60° slopes in footwalls with shale partings dipping into the pit at 43° to 60°, resulting in large planar failures and wedge failures. In response, the previous operator adopted a slope parallel to the bedding planes.

Jan 1, 1993

By H. Michael Breza

Texasgulf Inc. installed bucketwheel excavators and overland conveyor sysems at its Aurora, NC phosphate mine o increase the productivity and flexibilty of the surface mining operation. This ;ystem has significantly improved overrall. Its flexibility is evidenced by adapation to operation requirements, such is mining area moves, movement of xcavated overburden to designated ites, selective handling of overburden, poll placement contouring, and proiding an environmentally sound and afe operation. The system's productiv:y is evidenced by case studies relating. overall production, excavation rates nd cost-effectiveness. There are many competing alternaves available for excavating uncon)lidated overburden: truck-shovel, raglines, dredges and bucket wheel ticavators. These alternatives also may used in tandem to recover reserves icated at greater depths.

Jan 1, 1993

By R. V. Ramani, S. Tan

In this paper, several commonly used computer truck-dispatching criteria are evaluated. A computer-oriented truck-dispatching and production simulator was developed to provide data for comprehensive cross comparison among the dispatching criteria. The definitions, primary considerations, characteristics and performances of these dispatching criteria were investigated. From the simulation results, it was concluded that, in general, no one criterion can dominate all others. However, several dispatching criteria that have good potential to increase performance can be identified. All basic dispatching criteria, including minimizing truck waiting time, waiting shovel with minimum waiting time, minimizing truck saturation, maximizing truck momentary productivity or optimization of truck routes, provide local optimal solutions. To obtain a direct global optimization solution for this complex stochastic process does not appear to be likely Therefore, the search for an optimal dispatching criterion that will fit all conditions may not be realistic. It may be necessary to search for a hybrid combination of the several truck dispatching criteria that have good potential for a given situation. An approach to selecting such a hybrid dispatching criterion is presented.

Jan 1, 1993

By F. Shen

Qualitative and quantitative results obtained during the physical modeling of the molten aluminum flow in a tundish using an aqueous system are presented. Surface tuft, free-surface powder and laser sheet visualization techniques were utilized for qualitative studies, whereas laser Doppler velocimetry was used to elucidate the 3-D flow regimes quantitatively. The results of the study are used for validation of the CFD codes, and to explore the effect of the alterations below the nozzle in order to: (1) decrease turbulence levels, and (2) collect the inclusions. Near the nozzle, the interaction of the impinging jet and the inclined walls gives rise to vortex structures. Downstream of the nozzle, two counter-rotating secondary cells diminish in strength. As flow turns through the bend, a separation region is created. The flow heading into the closed duct is seen to be nonsymmetric. A video tape highlighting the major findings is presented.

Jan 1, 1993

By G. J. Kipouros, P. W. Kingston, W. F. Caley

"Current practice in advanced materials processing has involved the dispersion of a second-phase, commonly SiC, glass, or other non-metallic fibres/whiskers/particulates to enhance physical characteristics of the matrix. These matrices may be either ceramic or metallic but in either case it is important that the physical and chemical properties of each phase be compatible. The dispersed, finely divided second phase is often both expensive and foreign-produced and may exhibit chemical instability at elevated temperatures. Thus, it would appear that certain naturally-occurring industrial mineral fibres/whiskers/particulates might offer an attractive and low-cost alternative. Suitable candidates, such as wollastonite and sillimanite, are available in Canada and may be milled to produce particles whose shape is appropriate for this application. It is suggested that wollastonite, in particular, may be a useful modifying agent in metal matrix composites utilizing AI, Al-Si, Zn-Al or other light metals and alloys. In addition, the possible use of these minerals in ceramic matrix materials is also addressed, with reference to a preliminary thermodynamic analysis of the systems involved.IntroductionBackgroundA composite material may be thought of as consisting of a matrix component, the properties of which are improved by the addition of a second component or dispersed phase which forms a distinct three-dimensional interface with the matrix. This matrix is commonly either metallic or ceramic, which leads to the two most popular types of composites: metal-matrix composites (MMC); and ceramic-matrix composites (CMC).Such materials are by no means new. Early composites include fiberglass, mixtures of plaster and horsehair in wall plastering, as well as use of natural materials such as bamboo in fishing rods. Some of the newer applications include high strength, low-weight bicycle rims, as well as the more familiar role in aircraft and automobile engine components."

Jan 1, 1993

By Ghiani M, Currelli L, Fuganti A

the results of an experimental study aimed at beneficiating a complex ore containing bastnaesite and other rare-earth minerals, with associated barite and fluospar are illustrated. Owing to its minero-petrographic, physico-mechanical and structural characteristics, the crude ore is not amenable to classic concentration methods, such as flotation, magnetic and gravity separation. Therefore the technical feasibility of selective disintegration followed by size classification has been studied, whereby bastnaesite and the other rare-earth minerals can be concentrated into the finest size fractions. Leaching and subsequent extraction of rare-earth metals by liquid-liquid separation represents the final stage of beneficiation.

Jan 1, 1993

By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

By Mariana H. Staia

Thermodynamic calculations based on the free energy minimization method were performed for the system Ti-Fe-Mn-0-C1-C in order to evaluate the chemistry associated with the chlorination of an ilmenitic concentrate using CCl4. In the calculations various weight ratios of FeTi03/ CC14, a , were considered, which varied between 0.32 to 0.98 at temperatures ranging from 673 K to 1273 K , at atmospheric pressure. The results obtained indicated that the operating conditions for a process in a packed bed reactor, which implies the chlorination of both Fe and Ti, are 0.39 < a < .49 at T 1173 K.

Jan 1, 1993

Zinc concentrates from the newer mines and from proposed developments provide both opportunities and processing challenges to the conventional roast-leach electrowin smelters. These concentrates are often characterised by low iron, elevated silica, possibly high manganese, and levels of elements such as germanium which may cause concern. In addition, environmental constraints on residue disposal are forcing significant changes to some smelter practices. Iron in concentrate, and the resulting environmental impact of residue disposal are now major questions. However, normal concentrate tariff structure provides a disincentive against smelters taking high grade concentrate and oxide fume. Processing technology to cope with these changes is reviewed, as is de-watering and materials handling of ultra-fine concentrate. Within a few years, such fine concentrates will account for up to 1 000 000 t/y of contained zinc. New processing technologies including novel transport methods, siliceous leach circuits, manganese removal cells and front-end smelting will become significant in zinc smelting.

Jan 1, 1993

By Douglas Lindsey, Glenn Hazen, Shad Sargand

"With the innovation of computational equipment, an exact analysis of structures as dynamic systems is more approachable. Accordingly, the dynamic system can be established, if the natural characteristics such as the natural frequency and the damping fraction of a system are known. Through dynamic analysis, the response of a structure can be predicted from ground vibration, and it becomes possible to forecast the damage potential to the structure with reasonable accuracy. Most vibration will appear as single harmonic or superposition of waves that consists of several harmonics with different frequencies. A vibration signal can be expressed, therefore, as the function of sine waves. If a signal is periodic, the particular harmonic with the smallest frequency will befundamental and frequency of the others will be multiples of the fundamental frequency."

Jan 1, 1993

By Andrew P. Schissler

Cyprus Shoshone is an underground coal mine in southern Wyoming owned by Cyprus Coal Company, a subsidiary of Cyprus Minerals Company. To date, seven longwall panels have been extracted from the pitching seam under increasing depth of cover from 150 ft to 1200 ft. The purpose of this paper is to describe the geology, rock mechanics needs identification, design, testing and successful application of the current headgate/tailgate cribbing system. The immediate roof of the Shoshone is unique in that the first 50 ft of lithology is interbedded mudstones. The mudstone is slickensided, highly friable and has characteristics of unconsolidated fill relative to self-spanning and beaming abilities. Finite element modelling analysis of the overall geomechanical environment showed the mudstone to yield under applied longwall abutment stress. Roof bolt system design methodology also pinpointed the relative weakness of the mudstone roof. In-mine entry vertical convergence and weight response from the mudstone identified the need to design a crib which had superior weight capacity over a wide range of convergence. Design of a structure ensued to achieve the superior strength properties of wood parallel to the grain and the displacement properties of wood perpendicular to the grain. Testing of the prototype structure along with other alternative wooden cribs was done at the U.S. Bureau of Reclamation facility in the Denver Federal Center, Colorado. The test results verified the design. Crib placement pattern was chosen to maximize support with a confined core crib under the high convergence area. The design has been successfully installed in over 5,000 ft of headgate entry in the 11 left panel.

Jan 1, 1993

By J. N. Van der Merwe

The South African coal-mining industry uses a uniform safety-factor formula for non-squat pillars, incorporating a coal-strength constant that was derived empirically by Salamon and Munro in the 1960s. The constant is 7,2 MPa. Since that time, collapses of pillars at relatively high safety factors have occurred in the Vaal Basin. Analysis of the post-1960s&apos; collapses indicated that the strength constant for the Vaal Basin is 4,5 MPa. A crude method for the prediction of the minimum life span of pillars in the Vaal Basin is presented.

Jan 1, 1993

By Hare G

The emphasis in Australia, until recently, has been on large scale mining methods with drive sizes in excess of 4.5 metres square and the acceptance of high dilution ratios, even when working in relatively narrow orebodies. The rising cost of extracting and treating the recovered ore and the lower prices available in the world markets has seen a growing trend to narrow mining methods.Traditionally narrow orebody mining has been carried out using hand held drilling methods and rail mounted boggers. Recent advances in mobile equipment now offers the operator of narrow method mines the opportunity to completely mechanise the mine from the drilling, through bogging to haulage, while maintaining minimal dilution in drive sizes to two metres wide or less.

Jan 1, 1993

By J. Chia, M. H. Kobler, J. Cheung, M. J. Robison

INTRODUCTION The Lake Merced Transport is being constructed as part of San Francisco&apos;s Clean Water Program. The Clean Water Program, which began in the early 1970&apos;s, is designed to control wet weather, storm sewage overflows into the Pacific Ocean and San Francisco Bay. To accomplish this goal, a system of large underground storage and transport facilities, pump stations, modernized treatment plants, and outfalls is being built. By 1991, eighty percent of the system had been completed and was in operation. One of the remaining projects for the Clean Water Program is the Lake Merced Transport. The Lake Merced Transport is located in the extreme southwestern portion of San Francisco, as shown in Figure 1, Project Location. The transport will convey dry weather flow from the existing Lake Merced Pump Station to the Westside Pump Station. During wet weather, the transport will fill with sewage and runoff, with a storage capacity of 36 million liters. The Lake Merced Transport was expected to be excavated entirely within the Colma Formation, an alluvial deposit consisting of weakly cemented sand. Once excavation of the access portal at the Sloat/Great Highway parking lot began, it became evident that a portion of the tunnel would be excavated through beach/dune sand. Based upon the expectations of the Geotechnical Design Summary Report (GDSR), encountering beach/

Jan 1, 1993

By John Bullock

Limestone and dolomite quarries were mapped to determine specific failure mechanisms for the various geologic and structural conditions. Algorithms for analyzing these mechanisms were incorporated into a software package together with ranges of physical properties such as joint shear strength, angle of internal friction, and cohesion for specified lithologic units. Reliability options using Monte Carlo sampling and sensitivity studies are included to evaluate alternative highwall designs. The package is designed to facilitate progressive stability evaluation of quarry highwalls as mining continues. This package includes an optimum design protocol that can be followed to avoid the potential of massive failure. The program was developed in conjunction with the quarry industry and is demonstrated using case studies.

Jan 1, 1993