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By Richard L. Unger

The Crewstation Analysis Programs (CAP) is a package of computer programs that can be used to analyze some human engineering aspects of crewstation design (such as visibility and illumination) that have particular significance in underground mining. It was developed under the U. S. Bureau of Mines (USBM) Health, Safety and Mining Technology program at the Pittsburgh Research Center, Pittsburgh, PA. This manual describes the steps necessary to collect data in the laboratory to develop luminaire profiles for the CAP illumination analysis. It also describes how the CAP Illumination Model calculates illumination. 1.1 How CAP Calculates Illumination 1.1.1 Background -CAP currently includes assessments of visibility and illumination in the surrounding work area. The advantage of using computers for these types of analyses is that many design iterations can be tested quickly and efficiently to learn the effects of changes. This reduces the need for expensive testing using physical mockups. Another advantage is that design ideas can be tested in situations where it would not normally be possible. For instance, the effects of modifications to a lighting system or canopy design on visibility could be tested while the machine remains in service.

Jan 1, 1994

By Thomas S. Jones

This report discusses processing and use of the principal forms of manganese. The focus is on trends in the United States in the 20th century and specifics of domestic manganese material flows as of about 1990. To protect proprietary data, quantitative assessments are limited to the iron and steel industry, which accounts for about 90% of consumption. Nonmetallurgical uses are considered qualitatively. Approximate disposition of a U.S. cumulative consumption during 1901-90 of an estimated 69 million st of manganese is estimated to be iron and steel slag, 69%; nonmetallurgical uses of a dissipative na¬ture, 10%; iron and steel scrap, 9%; National Defense Stockpile, 3%; unidentified and/or including items in service, 10%. In slag from iron blast furnaces and steelmaking, manganese is present as a minor, relatively im¬mobile component, which so far has been uneconomical to recover. Construction and road building are main applications for these slags. Steel slag contains the greater amount of manganese. Studies by others of global manganese fluxes and the effect of human activities on them also are discussed. One source concludes that the main effect of human activities, via deforestation and agricultural activities, has been to increase the rate of transport of manganese to the oceans.

Jan 1, 1994

By Nenad Spoljaric

Greensand, greensand marl, and green earth are names given to sediments rich in the bluish green to greenish black mineral known as glauconite. The word glauconite is derived from the Greek word glaukos, meaning bluish green. The term "greensand" as a rock name for a glauconite-bearing sediment is more appropriate than "greensand marl," a term that has been doggedly perpetuated in the literature. Because of its potash and phosphate content, greensand was mined and marketed as a natural fertilizer and soil conditioner for more than 100 years. The advent of manufactured fertilizers with adjustable nutrient ratios led to a decline in the use of greensand in agriculture. The material has since been recognized as useful in water treatment. Unfortunately, despite large reserves and world- wide distribution, glauconite has not been utilized to any significant commercial extent because no major application has been found for a substance with its chemical composition and properties. This is probably due mostly to a paucity of research on its potential commercial uses. Extraction of potash received considerable attention during and just after World War I. Because of relatively high extraction costs and a generally low potash content (viz., less than 8%), glauconite lost its appeal as a source of this commodity. Historical Background Greensand was used as a fertilizer in New Jersey in the latter part of the 1700s. During the early 1800s its use became more common; applications of as much as 22.5 kg/m2 were sometimes made, although recommendations for agricultural use suggested 4.5 to 11 kg/m2 (Tedrow, 1957). Many crops, especially the forage type, were said to improve with greensand application; however, because of its slow release of potash, large quantities were required. Certain greensands that contain sulfur and sulfide minerals are harmful to plant growth, and these were classified as poison, burning, or black marls. The availability of higher grade potash salts from other mineral sources and the manufacture of prepared fertilizers displaced the agricultural use of greensand during the latter 1800s. During the mid-1800s the greensand industry, centered in a small section of the eastern United States, grossed more than $500,000/y. Toward the end of the century, however, annual production had dwindled to less than $100,000 in value. By 19 10 there were only six or eight greensand producers grossing less than $5,000/y each (Tyler, 1934). There was a brief revival of the US industry during World War I because of the curtailment of foreign potash, especially from Germany. During the latter 1940s and early 1950s greensand was again recommended as a food nutrient for plants and farm crops. Agronomic studies discussed its potential as a soil additive that gradually releases potash and many trace element nutrients essential for plant growth (Tedrow, 1957). Greensand was sold with the idea that it would condition soil and absorb and hold water while its base exchange properties would release trace elements. For a short time glauconite was used in certain parts of New Jersey as a binding additive in the brick industry, and in the 1800s it was used for making green glass (Cook, 1868). In the early 1900s the base exchange properties of glauconite were recognized for water treatment and the mineral gained acceptance as a water softener. Mansfield (1922) does not mention base exchange even though this phenomenon was known in 1916 or earlier. From 1916 through 1922 several patents for the use of glauconite as a water softening agent were granted. A method was also patented for treating greensand to improve it for water softening and ready regeneration with common sodium chloride brine (Borrowman, 1920, Spencer, 1924, Kriegsheim and Vaughan, 1930). Treated glauconite, on contact with water containing magnesia or lime, takes up magnesium or calcium ions and releases sodium ions. This exchange is limited to the outer surface of glauconite grains, and when all the surfaces have absorbed their capacity, the grains must be regenerated. Regeneration, simply stated, consists of treating or backwashing the glauconite with a sodium chloride solution, which replaces the hard water elements with sodium, thus reviving the glauconite. The process has become more sophisticated due to competition among companies in the water softening business. Greensand products for water softening generally consisted of several different grades distinguished by the particular treatment the glauconite was given during processing. The standard greensand water softener was produced from natural glauconite that was only washed and classified. Its characteristics for water softening are given in [Table 1].

Jan 1, 1994

By A. J. Paul, K. O. Yu

"Today, foundries are moving towards the use of models and design tools to gain a competitive advantage in producing castings of high desired quality. This leads to a growing alliance between foundries, software developers and researchers seeking to model, visualize and understand the phenomena taking place during the casting process. In addition, there is a need to develop affordable techniques to produce parts in small lot sizes. This leads to the development of a Flexible Manufacturing System consisting of: (1) up-front computer-aided engineering; (2) computer integrated proto typing with solid freeform fabrication; and (3) fabrication of the actual mold and related equipment to cast the part.This paper discusses some of the developments that are taking place today in the areas of modeling the physical phenomena during the casting process as well as towards developing a Flexible Manufacturing System for producing cast parts. Areas that require most work involve prediction of defects and mechanical properties using simplified analyses. In addition, electronic data sharing for collaborative engineering between geographically dispersed team members is also discussed. Case studies are presented showing successes as well as failures.IntroductionCasting, one of the oldest forms of metalworking, has recently seen a flurry of developments in the area of solidification modeling. These developments have come about after the realization that, in order to stay competitive, foundries need to reduce their scrap rate and production costs, and increase casting quality. Even though this is not new knowledge for foundry engineers, the tools to help them achieve this goal are just being developed and put in place for use by foundries. Several state-of-the-art software packages are currently available to analyze the solidification behavior in complex shaped castings. These packages make use of several different approaches for solving the various problems associated with casting processes. The overall architecture of a comprehensive solidification modeling system is shown in Figure 1."

Jan 1, 1994

By F. Kassabji

This publication presents the main experimental and theoretical results on the recovery of aluminum scrap (dross and Used Beverage Can) without use of any addition of fluxing salts. Dross and UBC's processing experiments have been conducted in a rotary plasma furnace operating in the transferred and non-transferred mode, using different plasma gases. The investigation involved the treatment of more than 100 kg of dross and other aluminum residues using plasma torches with less than 100 kW power. The experimental work showed that this process is .far more economical and kind to the environment than the conventional route using a salt flux. An equilibrium thermodynamic calculation at elevated temperature makes possible the prediction of by-products at various temperatures for different plasma gases.

Jan 1, 1994

By Hongfa Hu, Stavros A. Argyropoulos

"This paper describes a mathematical model which simulates numerically reaction driven fluid flow phenomena. The driving force of this reaction is an exothermic heat of mixing. In addition, the model predicts the heat and mass transfer phenomena where both heat source and heat sink co-exist in close proximity. The heat source is generated by an exothermic reaction. The heat sink is formed by a moving boundary such as the melting of a solid. This type of phenomena occur quite often in various metal processing operations in which exothermic additions are immersed in liquid metals. The model is based on the SIMPLER algorithm and uses an enthalpy method to predict the fluid flow, temperature, and concentration fields. The results indicate that the exothermic mixing reaction was responsible for an abrupt rise in temperature around the moving boundary. The intensity of this reaction was also found to be responsible for the enhanced convection of fluid and the acceleration of the moving boundary. The modelling results were also verified by experimental work which included velocity and temperature measurements in a low temperature physical model. IntroductionAlloying additions are used extensively in the treatment of liquid metals during metallurgical processes. The alloying additions introduced into liquid metals can be classified into various classes, each of which follows its own route[l]. As a major group, the exothermic additions follow two different steps during their assimilation into liquid metals. In the first step, upon immersion, a metal shell solidifies around such additions, and then melts back. At this point, the second step commences. During this second step, due to the mixing of the addition with a liquid metal, an exothermic reaction occurs, which liberates large amounts of heat, resulting in an enhanced convection in the liquid metal surrounding the addition."

Jan 1, 1994

By Per-Anders Persson

This chapter deals with the concepts ofshock waves aud detonation waves together, because a detonation wave is really a shock wave, supported by the explosive reaction that the shock wave ignites and propagates as it travels through the explosive material. In the context of rock blasting, furthermore, there is justification for treating shock waves and detonation waves together, because the mechanical effect of the detonation in an explosive in a drillhole in rock is propagated and its effects are spread throughout the surrounding rock by means of a shock wave The overall performance of an explosive in rock blasting or any other application is of course dependent on how much thermal energy is released in the chemical reaction that occurs when the material detonates, and on how much useful mrc!~amcal work the reaction products can do as they expand. A major portion of this chapter deals with the prediction and measurement of explosive performance, a subject which is now still in a process of rapid development.

Jan 1, 1994

By B. Andersen, P. Somasundaran

An accurate knowledge of the interactions among mineral particles and between such particles and dissolved and precipitated species is important in developing efficient separation processes. In this investigation, interactions relevant to dispersion and selective reagent adsorption (the two main prerequisites for selective flocculation) within Florida phosphatic clay Waste were studied. Initial studies with artificial slimes, consisting of pure clay and phosphate minerals, showed dispersion of artificial slimes to be relatively easy. The problems that were encountered during selective flocculation of the artificial slimes were due to unselective polyacrylic acid adsorption on clay, which was caused by the presence of multivalent calcium ions on the exchangeable cation positions on the clay surfaces. This problem could be solved by exchanging calcium for sodium, which reduces the interaction between the polymer and the clay surface. This procedure, however, was not successful for mineral mixtures. Natural slimes were found to be much more difficult to disperse. This was attributed to the presence of cementing materials such as humic substances and Al and Fe (hydr)oxide precipitates. Selective removal of these cementing materials resulted in good dispersion and partial separation. A further increase in the separation of natural slimes is most likely determined by the presence of calcium on the clay surfaces, as was found for the artificial mixtures.

Jan 1, 1994

By D. W. Davis, P. Landais, L. J. Robb

Abstract -Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Pb-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter ?13C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoid­ and sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By T. H. Courtney, B. R. Murphy

"Nominal room temperature mechanical alloying (MA) has been used to synthesize the high melting temperature NbC and Cu-NbC composites. Elemental powders of Cu and Nb were alloyed in the presence of either graphite or hexane to form nanocrystalline NbC or a Cu-NbC composite. Through control of hot-isostatic-pressing (H/Ping) parameters, we have been able to minimize microstructural coarsening during densijication, and have processed fully dense bulk compacts of both single phase NbC and two-phase Cu-NbC while maintaining a nanocrystalline or near-nanocrystalline structure. These materials generally exhibit high strength and low fracture toughness. However, mechanical properties vary significantly depending upon the Cu content and the method of NbC synthesis (graphite or hexane).INTRODUCTIONMechanical alloying (MA) has been recently used to synthesize a variety of inorganic solids; sulfides (1-2), nitrides (3), borides (4), and carbides (3, 5-8). One advantage of this processing route is that synthesis of fairly high melting temperature materials takes place at what is nominally room temperature. Another advantage is that the structures generated are often nanocrystalline in scale, with attendant interesting properties. The consolidation of these fine structures into near fully dense or fully dense materials while limiting microstructural coarsening is a challenge that has just recently seen limited success (5, 9). We report here on some recent studies of ours dealing with crystallite size and structural analysis of NbC and CuNbC composites consolidated to full density from mechanically alloyed powders. Bulk mechanical properties and their dependence on milling parameters are also presented."

Jan 1, 1994

By Gerald R. Dickens

Massive sulfide ores and Fe-Mn oxyhydroxide precipitates represent two extremes of a spatial continuum of hydrothermal deposition along oceanic ridges. Elemental variations across this continuum are of interest to economic geologists as a prospective geochemical exploration tool. Theoretical considerations suggest that certain physical and chemical parameters can be used to model compositional variations within the far-field (i.e., Fe-Mn oxyhydroxide) component as a function of distance from ridge axis; however, testing and verification of such models generally has been precluded because the few available distal hydrothermal sediment sequences have been sampled at low resolution and/or are highly diluted with biogenic components (e.g., siliceous and calcareous tests). Recent ocean drilling (ODP Leg 145; Sites 885/886) in the North Pacific successfully recovered an extensive record of "biogenic-free" distal hydrothermal precipitates from an area approximately 60 km south of the Chinook Trough at longitude 168.1 °W. Geophysical and geomorphological evidence suggests the Chinook Trough is the southern lithospheric scar marking initiation of late Cretaceous north-south rifting, implying that recovered hydrothermal materials record distal hydrothermal precipitation from the now-subducted Kula-Pacific spreading ridge. The Chinook Trough hydrothermal sequence is a continuous 15 my record of "biogenic-free" hydrothermal Fe-Mn oxyhydroxide precipitation mixed with eolian clays. It was deposited during the late Cretaceous, early Paleocene (80-65 Ma) as the perpendicular distance from ridge axis increased from 75 to 600 km. A high-resolution geochemical analysis of this hydrothermal sequence reveals distinct trends for the up-core (equivalent to increasing distance from ridge) distribution patterns of Fe, Sc, As, and rare earth elements (REE). Iron concentrations exhibit an S-shape distribution pattern with respect to increasing

Jan 1, 1994

By M. L. Smith

The U.S. Bureau of Mines Cost Estimating System (CES) has been used for prefeasibility analysis and mine cost engineering since 1978. In the past, prefeasibility analysis with CES has involved the solution of regression equations. The new generation of CES uses an object-oriented expert system in a Windows? environment. Knowledge bases are structured around generic mine models which access shared knowledge bases for system design.

Jan 1, 1994

By John C. Stankus

In this paper, an innovative concept in longwall tailgate support is discussed. This new concept utilizes a new high capacity roof truss system in lieu of conventional wooden crib block. The first field test was conducted at Bailey Mine and was very successful. Similar tests have been installed in other mines and seams. An extensive instrumentation plan was designed and implemented in the truss test area. The test data has shown that the dynamic roof truss system effectively controls the various abutment pressures caused by longwall mining thus maintaining a stable tailgate entry.

Jan 1, 1994

By C. L. Schaidle

Computers and communications technology have revolutionized many industries. In earthmoving, this revolution has just begun. The major changes are still to come, but they are just around the corner. This paper presents a vision of this up-coming revolution in our industry. This vision is comprehensive. It includes basic communication, machine monitoring and diagnostics, job and business management, planning and operations, and machine control. For our industry to realize maximum benefits from the information age, we must have a vision of the future that is shared by technologists, machinery producers, and miners.

Jan 1, 1994

The most common method used for cleaning the fine fraction in today's coal preparation plants is froth flotation. Past research and practice has found that froth flotation achieves excellent separation efficiencies for fine coals having only a small fraction of middling particles. However, its efficiency decreases sharply as the concentration of middling particles increases due to the flotation of high-ash particles having a small amount of hydrophobic coal present at the coal surface. Since gravity-based processes are much more efficient at treating middlings, the application of centrifugal washing for fine coal cleaning has been studied with an emphasis on the primary cleaning of fine circuit feed. Results will be shown from a parametric study using a Falcon centrifugal concentrator which reveals that the separation performance is a function of particle size, bowl geometry, feed solids content, and feed rate.

Jan 1, 1994

By Xirneng Zhu

The electrochemical behavior of Pittsburgh and Illinois coal pyrite in basic and neutral borate/sulfate solutions was investigated. In the transpassive region, aggressive oxidation of pyrite occurred. The reaction products in this region were Fe(III) oxide, sulfate ion and partially oxidized sulfur intermediates. The formation of sulfur and polysulfides was identified by in-situ Raman spectroscopy. The growth kinetics of the reaction product film, resulting from transpassive oxidation of coal pyrites, were studied using chronoamperometry measurement with both stationary and rotating disk electrodes. The reaction rate was well correlated by a paralinear rate equation. The effects of electrode rotation speed, solution pH and temperature were examined. The kinetics were compared to those for mineral pyrite.

Jan 1, 1994

By Richard C. Williams, Herman Pieterse, Ken Thomas, K. S. Fraser, Ron H. Colquhoun

"The Banick Goldstrike Mines Inc. (Goldstrike) operation is located in Eureka County in north-central Nevada on the Carlin geological trend. Gold in the sulphide mill feed, occurs primarily as submicroscopic inclusions or possibly solid solution in a pyrite and marcasite matrix. Sulphide mill feed is pretreated in a pressure oxidation plant allowing gold recoveries of 90 per cent and greater to be achieved. Anticipated 1994 gold production for the sulphide gold facility is approximately 1,500,000 ounces.In January 1989 American Banick Resources Corporation (Banick) announced the US$365 million Betze Development Plan for the Goldstrike property. The Betze plan was based on a three (3) staged expansion of the original 4,500 STPD oxide gold plant. This expansion would involve addition of ore and gold processing capacity and the total conversion of all ore handling facilities to treating Betze sulphide ores.Phase 1 of the Betze Development Plan involved the construction of a pressure oxidation circuit, including a single autoclave and supporting ancillary services. The pressure oxidation circuit was commissioned in February 1990. Currently a throughput of 2,000 STPD is being achieved.Phase II of the Betze Development Plan, commissioned throughout April and May 1992, included the expansion of grinding, leaching, and gold recovery facilities enabling the treatment of combined oxide, and sulphide ore. Pressure oxidation capacity was increased by the addition of two (2) autoclave circuits each treating 2,600 STPD of sulphide ore and other required ancillary services. By June 1992, the Phase II gold facility had achieved a combined throughput of 15,000 STPD of oxide and sulphide ore.Phase Ill, the final stage of the Betze Development Plan, was successfully commissioned in February and March 1993. This final stage of development increased the design throughput of the pressure oxidation plant to 15,000 STPD by the addition of three (3) autoclave circuits with combined capacity of 7,800 STPD."

Jan 1, 1994

By Robert B. Parsons

"The Canadian tax treatment of mining operations outside Canada is not as attractive as the treatment of Canadian operations. Further, the Canadian company that invests abroad a host of complex rules. This month, Tax Notes examines some of the major Canadian tax considerations confronting the Canadian company that wants to invest abroad. IntroductionCanadian-based mining companies are investing abroad more than ever before. These foreign investments trigger a complex set of tax rules that are distinct from the rules that apply to Canadian investments. In most cases, careful tax planning is mandatory if the company's tax liabilities are to be minimized. This article summarizes the main tax considerations that need to be taken into account with respect to a mining investment outside Canada.Branch Versus SubsidiaryOne of the first questions that arises in connection with a prospective foreign investment is ""Should we invest directly (that is, in a branch operation), or should we invest through a foreign subsidiary?"". In the case of a branch operation, the Canadian company owns and operates the business directly - that is, the foreign business assets are part of the Canadian legal entity. In the case of a foreign subsidiary, the foreign business operation is owned and managed by that subsidiary. The tax treatment of a branch and a subsidiary can be quite different."

Jan 1, 1994

By Philip W. Holland

This U.S. Bureau of Mines (USBM) report describes a chromatographic method that is used for rapid field determinations of carbon dioxide in natural gas streams at a USBM helium production facility. The method employs a commercially available portable gas chromatograph that is equipped with a 10-m fused-silica capillary column coated with a porous polymer. The instrument operating parameters permit determinations to be performed over a concentration range of 10 ppm to 10 pct with a frequency of 20 samples/h. The speed at which determinations can be performed is an important factor when evaluating efficiency or troubleshooting processes at the helium facility.

Jan 1, 1994

By Robert L. Virta

An asbestos substitute is any material that replaces asbestos in a commercial product. There are many asbestos substitutes, each with its own unique physical and chemical properties. Substitutes can be inorganic or organic, fibrous or nonfibrous, and natural or synthetic. They also can be used as a direct substitute for asbestos or as a replacement product. Probably in no other field is the diversity of substitute materials so great. The concept of asbestos substitutes is not new. The first major effort to develop asbestos substitutes was undertaken by the federal government. The United States has always been dependent on foreign sources for strategic-grade asbestos, and during World War II, the government was concerned that these supplies would be cut off. Strategic-grade asbestos was critical in many electrical and thermal insulation applications (electrical insulation, battery plate separators, flame-proof boards, insulation for rocket components, etc.). A reliable supply of nonstrategic-grade asbestos also was required for general civilian and military applications, such as in brakes, clutches, and construction materials. The government not only initiated a major search for deposits containing strategic-grade asbestos, it also funded research on synthesizing asbestos in the laboratory and developing products that did not contain strategic- grade asbestos. These efforts, as well as those conducted by the private sector, generally were unsuccessful. In the late 1960s and early 1970s, a second major effort to develop asbestos substitutes began because the general public was concerned about the health threat posed by the release of asbestos fibers during the manufacture, use, repair, and disposal of asbestos-containing products. Strict regulations covering the mining and manufacturing sector already had been enacted because of the issue of occupational exposure. The issue then became environmental exposures. Environmental regulations were enacted, and through time they became more strict. The combination of increasingly strict environmental regulation, maturing of some asbestos markets, and liability issues prompted many manufacturers to discontinue asbestos product lines or search for asbestos substitutes. As a result, asbestos usage dramatically declined from the 1970s to the present (Table 1).

Jan 1, 1994