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By J. O. Jensen

A method is described for the determination of cyanide in gold slurries, based on amperometry. The measured current is proportional to the concentration of cyanide, and is not effected by pH or by the concentration of oxygen in solution. It is also unaffected by other ions that may be present in gold-leaching solutions, including sulphide, thiocyanate, and thiosulphate. The current depends on the temperature, and an activation energy of 17,9 kJ/mol was determined Since the current is controlled by the mass transfer of cyanide to the anode, it depends on the conditions of agitation. In tests on an operational gold plant, slurry was pumped directly from the top of the leaching tank, through the measuring cell and back into the tank. The results indicate that the instrument is a promising alternative to the instruments currently available. The readings from the instrument remained in calibration for at least two days, showing that the instrument would need to be re-calibrated by the operating staff at regular periods.

Jan 1, 1994

By A. A. Hejja

The effect of composition on electrical conductivity, viscosity and liquidus temperature of the slags was investigated in the temperature range of 1300" to 1450°C. The synthetic slags containing CaO, MgO, SiO,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Platinum Group Metals) from the Merensky Reef of South Africa. FeO and SiO, were found to affect the viscosity and conductivity the most while liquidus temperature depended on MgO content in addition to these. The activation energy for electrical conduction was found to vary from 67 to 159 kJ/mol and that for viscosity from 125 to 209 kJ/mol. Optimization of the slag composition was attempted on the basis of opposite trend of the viscosity-electrical conductivity relationship with slag composition.

Jan 1, 1994

By Stuart M. S, Allen P. B

The Childe Harold deposit was mined by the Granny Smith Joint Venture (GSJV) from late-March through to early-December 1993. This was a fast-tracked mining project whose history began with an offer to purchase agreement being signed at the end of October 1992. A feasibility study was completed by the end of December 1992 after completion of a reverse circulation (RC) and diamond drilling program. Subsequent additional definition drilling culminated in a remodelling of the reserve by March 1993, by which time all necessary governmental and company approvals had been granted. The crucial aspect of mining Childe Harold quickly was to maintain oxide ore supply to the Granny Smith mill at the maximum possible rate for blending with existing fresh ore stocks. As a result, high production rates had to be balanced with

Jan 1, 1994

By Jogre A. S Tenório

he aim of the present investigation was to investigate technological features of the Fe-NbC dissolution in liquid Fe-C alloys. Fe-NbC is a Ferro-niobium alloy with 7%C, has a particle size smaller than 150 pm and its micro constituents are polygonal niobium carbides and an iron matrix. The obtained dissolution time was less than one-minute and the yields were in the range of 80-90% at 1873 K. In the Fe-NbC dissolution process, the dissolution occurs at first, and as a consequence the niobium carbides become free to dissolve. These carbides will dissolve until the melt reaches a saturation point. The non-dissolved carbides remain trapped in the liquid or will form a dross. The addition yields decreases when the niobium concentration reaches this limit value, that depends on the carbon concentration. These define a saturation curve.

Jan 1, 1994

By Zhang Qi

For the most part, the flying piece is serious endangerment in the demolition blasting. To prevent the endangerment, a large number of materials are needed as the protection. Therefore, the determination and design way of the flying distance of piece in demolition blasting have been concerned extensively. Previously, the experienced or half experienced formula was adopted to calculate the distance of the flying pieces. The calculating values of the distances of flying pieces are not identical with the practice results. The problems concerning the design way of flying distance of pieces are researched in the paper.

Jan 1, 1994

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Jan 1, 1994

By Stephen M. Jasinski

This report describes the materials flow of mercury in the United States. It examines the mining and production of mercury and the manufacturing, uses, and ultimate disposal of mercury. Materials flowcharts were prepared for 1989 and 1990. An effort was made to include estimates for all major anthropogenic sources including fossil fuel combustion, waste incineration, and nonferrous metal mining operations. Mining and mineral processing released about 100 mt/yr of mercury to the environment in both 1989 and 1990. The combustion o ii fu1s released 175 mt/yr in the same years. The manufacturing, use, and disposal of products containing mercury accounted fix the release of 1,037 mt of mercury in 1989 and 938 mt in 1990. The manufacture of chlorine and caustic soda was a major source of recycled mercury, but it was all reused within the industry. Recovery from all waste products accounted for 36% of reported consumption in 1989 and 42% in 1990. The losses from manufacturing and end use have been declining, whereas mercury emitted from combustion sources has not been strictly regulated and will likely become the largest source of mercury releases to the environment.

Jan 1, 1994

By Tatsuo Inoue, Marnoru Mizuno, Toru Matsuoka, Kenichiro Abe

"The distribution of particle reinforcements and the residual stresses in metal matrix composite are simulated by considering the motion of particles and the solidification of matrix associated with temperature variation in the course of centrifugal casting process. In the analysis, a heat conduction equation including heat generation due to latent heat and also mechanical work as well as heat input from successively accumulated element on the air/metal boundary is solved by the finite element technique. After the movement of particles subjected to the centrifugal force and drag are analyzed, the residual stresses are elucidated by using a unified constitutive equation which can describe the behavior both in liquid and solid states. Results of the simulation are compared with the experimental data, and the validity and utility of the procedure is confirmed.IntroductionProcess simulation of metal matrix composite (MMC) is required to determine the mechanical properties of the materials and the efficient process and conditions of the fabrication. Properties of bonding matrix with reinforcements in the course of the processing, for example, affects the strength of the composite, while the final costs of the productions depends on the efficiency of fabrication. Therefore, the simulation of processing of MMC is prerequisite in order to clarify the mechanism to fabricate the material which has been expected to maintain high mechanical properties and the cost performance.Some techniques of processing MMC[l] have been developed so far. Among them, the centrifugal casting technique [2-5] has many attractive characteristics as processing of the MMC: The centrifugal casting technique makes the reinforcements such as particles or short fibers to be distributed in the radial direction by the centrifugal force acting on reinforcements due to the difference in density between reinforcements and matrix. Since the distribution of reinforcements affect the mechanical properties of MMC, the composite with functionally gradient mechanical properties can be provided by the centrifugal casting technique."

Jan 1, 1994

By A. Durnan

Barrick Goldstrike Mines Inc. (Goldstrike) operates a six circuit (train) pressure oxidation plant for the pretreatment of gold bearing sulfide ores. The property is located 27 miles north of Carlin, Nevada. Since the commissioning and start-up of the first circuit in 1990 until the present total plant availabilities have exceeded 90%. The discussion that follows will detail the maintenance practices employed to consistently achieve this goal.

Jan 1, 1994

By Joseph C. Milbourne

The selection of a suitable nitrate removal process depends on a variety of site-specific chemical and environmental issues. The dominant technologies for nitrate removal include biological denitrification and continuous countercurrent ion exchange. The decision to apply either of these technologies, or both together, depends on the nature of the waste water to be treated. Factors that affect the selection of the biological system include the feed composition and feed temperature. Ion exchange nitrate removal systems are less sensitive to the feed composition but require disposal or destruction of the concentrated pregnant eluate. The paper discusses Tetra's continuous countercurrent ion exchange technology (CCIXTM) and fixed film biological reactor, Denite°. The treatment of the ion exchange pregnant eluant is also discussed.

Jan 1, 1994

By K. A. McDonald

This paper will describe the experiences of Hibernia Holdings, Inc. in constructing a mineral processing facility in Mexico. It will attempt to set forth a guideline on what companies attempting to operate in Mexico can expect and what actions they can take. Ownership laws, import/export laws, labor laws, security, transportation and operating experiences will be discussed.

Jan 1, 1994

By Steven Wright

The reduction of a slag produced 6om the recycling of lead batteries was studied in a kilogram scale laboratory investigation by reacting with graphite at temperatures of 1180 and 1200°C. Simultaneous reduction of PbO, Fe203, Sb203 and As203 occurred with the Sb and As reporting to the metal while the lead content in the slag was above 2 wt%. The Sb and As distributions between metal and slag were strongly affected by temperature and slag oxidation state. The rates of reduction of PbO and Sb203 increased with increasing slag basicity and temperature and decreased as the PbO content in the slag decreased. The reduction rate of PbO from these slags was similar to other industrial lead slags at the same CaO/SiO2 ratio and temperature. The implications of the behavioural similarities of the antimonous slags during reduction with carbonaceous reductants and other lead slags are briefly discussed.

Jan 1, 1994

By T. J. Fenner

Research conducted in South African mines has demonstrated the benefit of ground penetrating radar for the detection of geologic features and hazards. This is crucial for safety and production considerations in underground mines that are as much as 4 kilometers deep. This paper describes a new ground penetrating radar system designed specifically for high quality data acquisition, in the harsh conditions of deep underground environments, for use by operators with minimal geophysical experience. Design criteria included automated functions, intrinsic safety, light weight and minimal power requirements. Data is processed on the ground surface by geoscientists using a PC.

Jan 1, 1994

By Bhattacharyya A. K

A strata parameter is introduced to include the deformation characteristics of the undermined strata in the prediction of subsidence movement. By using the strata parameter and mining factors as parameters, a nomogram for predicting the maximu

Jan 1, 1994

By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By William E. Hill

The blasting program at the Valdez Creek Placer Mine must deal with challenging situations throughout the year. During the short summer, extreme water conditions must be confronted, while the winter months present problems of a different nature, where the overburden freezes to a depth of up to 18 feet. These obstacles require techniques borrowed from hardrock blasting combined with creative experimentation to overcome.

Jan 1, 1994

The types of risk to mining projects using environmental protection as justification are examined. In Australia, Governments, whether Federal or State, enforce environmental legislation. The way they do This has an impact on the risk to a project. This is discussed and examples are taken from the Northern Territory uranium industry. Special reference is made to mine closures where the roles are not yet entrenched.

Jan 1, 1994

By Harold R. Kokal, Madhu G. Ranade

A metallurgical/flux is a substance that is added to combine with gangue (unwanted minerals) during ore smelting, with impurities in a molten metal, or with other additives in metal refining processes to form a slag that can be separated from the metal. Because slags are immiscible with the metallic melt and are of lower density, a separation of the slag and metal occurs if the viscosity and surface tension are of the proper values. The chemistries of slags are adjusted to provide the proper melting point, viscosity, surface tension, conductivity, specific heat, density, or chemical properties to effect the desired task. In addition to absorbing impurities from the metal, the purposes of the slag are to thermally insulate the metal bath, protect the molten metal from the atmosphere, and control the chemical potential of the system. Several excellent references on slags and metallurgical fluxes are available (Boynton, 1980, Lankford, Jr., et al., 1985, Turkdogan, 1983, Rosenqvist, 1974, Fine and Gaskell, 1984). The function of the slag might vary at different stages within a process prior to final melting. For example, the slag composition and behavior will change as materials descend in the iron blast furnace, or as they melt in the early stages of formation of steel- making slags. Selection of the chemistry for a slag might be influenced by factors outside the primary function as when blast furnace slags are used to make cement, rock wool insulation, or fertilizer supplements. Sometimes slags contain a sufficient amount of valuable recoverable elements to be sold as raw materials for other processes. Fluxes are often referred to as acid, basic, or neutral. Acid fluxes are those that generally form acids in water and bases are those that would generally form bases in water. Typical acid fluxes are silica, alumina, and phosphorus, although alumina can function as either an acid or base. Typical basic fluxes are lime and magnesia. Fluorspar, or calcium fluoride, is a neutral substance because it can be viewed as the reaction product of a base and an acid. The degree of acidity (ratio of acids to bases) or basicity (ratio of bases to acids) is often specified to characterize the slag chemistry for a particular system. The system might also be referred to as acid or basic depending on the choice of slag, for example, basic steelmaking uses slags with more bases (lime and magnesia) than acids (silica and alumina). Many forms of minerals and compounds have been used as fluxes depending on the process requirements, availability, costs, requirements for recycling of intermediate products, and environmental concerns. Because slags are most often mixtures of oxides and silicates, fluxes are usually oxides, carbonates (which decompose to oxides) and silicates. Slags comprising phosphates, borates, sulfides, carbides, or halides have also been used (Rosenqvist, 1974, Moore, 1981, Szekely et al., 1989). In ironmaking and steelmaking, some acidic components are sometimes added. In nonferrous processes slags and fluxes are acidic with silica as the primary component, and although the use of basic flux such as limestone or lime is not extensive, some amount is used to modify slag properties and some refining slags are lime based. The production of iron is accomplished by smelting of ores, pellets, and sinter in blast furnaces with subsequent refining of molten iron and scrap in oxygen-blown processes. The electric furnace is used to make steel, stainless steels, ferroalloys, and special alloys, whereas ferromanganese is often made in blast furnaces. Fluxes are used in all of these processes, and either limestone or lime is the major flux component with some dolomite, dolomitic lime, silica, alumina, and fluorspar being used. In ironmaking, the flux is added either by direct charging or through sinter and fluxed pellets. In steel refining by the basic oxygen process, flux is added as lime and dolomitic lime that are either charged as lumps or injected as fines. Some small amount of limestone is sometimes used. Fluorspar is often added as lumps or mixed with other fine materials in briquettes. Alumina is sometimes added to blast furnaces either by direct charging of sized lumps or through sinter. Typical acid fluxes are sand, gravel, quartz rock, used silica brick, or raw siliceous ore (Lankford, Jr., et al., 1985). Olivine, which is a magnesium-silicate mineral, has been added to iron blast furnaces to enhance removal of alkalis (Lankford, Jr., et al., 1985). Alumina in the form of bauxite, aluminiferous clay, and recycled alumina brick has been used as flux. Alumina can function amphoterically as either an acid or base, for example it can form aluminum silicate in high silica slags or calcium aluminate in lime-bearing slags (Lankford, Jr., et al., 1985). Limestone (calcium carbonate) and dolomite (magnesium-calcium carbonate), or fluxstones as they are sometimes called (Boynton, 1980), and their calcined forms, lime and dolomitic lime are the major basic fluxes. In the latter cases, the carbonates are de- composed in a kiln-type process to drive off carbon dioxide that might otherwise interfere with the subsequent smelting or refining process or require expensive forms of energy to effect the decomposition (e.g., by combustion of coke in the iron blast furnace). Limestone is considerably less expensive than lime because it is not calcined; however, lime is far more difficult to handle and reacts readily with water. Dolomite and dolomitic lime are used for their magnesia content. Fluorspar is a neutral flux often used as an additive in steel- making slags to improve fluidity, but it has also been used in combination with lime as a primary slag in electroslag refining (Duckworth and Hoyle, 1969). Fluorspar is available in several grades, with the lowest grade often used for steelmaking. When the price of fluorspar has risen, substitutes including aluminum smelting dross, borax, manganese ore, titania, iron oxides, silica sand, and

Jan 1, 1994

By T. N. Moore, E. M. De Souza

Because jackleg rock drills are a potential source of hand vibration exposure, they can effectively produce Hand Arm Vibration (HAV) Syndrome in their operators. This will affect operator efficiency and mine productivity. As a result, a significant amount of work has focused on redesigning rock drill handles using new materials to minimize hand-transmitted vibration. In previous work developed by the authors (1991), a detailed study was undertaken to determine the effectiveness of using elastomer covered handles in place of the standard steel design. The results indicated that, for an elastomer-based handle design, the overall acceleration level experienced by the hand can be reduced by as much as a factor of three, relative to the steel handle. It was also shown that this reduction takes place predominantly in the frequency range above 500 Hz. This paper presents an investigation of the long-term effectiveness of an elastomer-cushioned handle under different conditions underground. In this study, sponsored by the Mining Industry Research Organization of Canada (MIROC), a number of cushioned handles were quantitatively and qualitatively tested in five operating mines. The vibration testing program has indicated that the cushioned handle can reduce overall vibration levels by as much as a factor of three. The qualitative assessment program of the cushioned handles by the drill operators has indicated some degree of preference for the cushioned handles over the steel handles, if certain design modifications are performed. This research program indicated that cushioned handles have the potential to become the dominant method with regard to vibration reduction and operator performance.

Jan 1, 1994

Studies of Theological effects in grinding hold promise for improving this energy-intensive process. Six surveys of the Hellyer ball mill were conducted. The stream and sizing data from these surveys were balanced by JKMbal to compare the mill

Jan 1, 1994