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By I. Gaballah

Decontamination of synthetic solutions of PbC12 containing 10, 100 and 1000 ppm of lead, using chemically treated barks had been studied. The percentage of !cad cations' removal from solutions depends upon the pH and the initial concentration. About 99 % of the initial lead content can be removed at pH of about 3.5, 5.5 and 6.5 for initial concentrations of 10, 100 and 1000 ppm respectively. The maximum retention capacity of the treated bark is about 83 mg of lead per gram of modified bark. Bark loaded with lead had been analyzed by Infra Red spectroscopy. It seems that lead reacts with hydroxyl groups of the phenolic constituents of the bark. On the other hand, the removal of a lead cation by the bark leads to the release of two H+. This seems to show that the removal of lead could be interpreted as an ion exchange with hydrogen belonging to the hydroxyl groups of the modified bark.

Jan 1, 1994

By Philip M. E Thomas

For over sixty years man has struggled to defeat the natural swamp lands known as the Florida Everglades as demand for land to support the burgeoning population growth in the state continued almost unchecked. Over the past ten years there has been a growing awareness that this land development could wipe out a whole ecosystem in a very short time unless steps were taken to reverse the trends. In 1991, a state law called the Marjory Stoneman Douglas Everglades Protection Act was enacted giving power to the South Florida Water Management Board to condemn certain lands for conversion to manmade swamp lands, designed to filter polluting run-off water from the agricultural lands around Lake Ockeechobee.

Jan 1, 1994

This work describes preliminary laboratory testwork to study the relative leaching response to cyanidation and thiourea leaching of an oxidised low grade gold ore. The potential of an alternative lixiviant like thiourea to commercial processing of mine dumps is discussed by specific reference to selected case histories. It would appear that on the basis of the available published information, there could well be a case advanced for the acid thiourea leaching of sulphide concentrate tailings being subjected

Jan 1, 1994

By J. E. Sallee

An experimental study has been conducted on the level of arsenic contamination in samples of zinc oxide when the zinc oxide is contacted with gas mixtures containing As4O6(g). This contamination has been determined as a function of A4O6 saturation pressure, temperature, zinc oxide sample surface area, impurities, and oxygen level in the gas mixture. The results indicated a rather clean separation can be achieved between condensed zinc oxide and gaseous arsenic oxide as long as attention is given to temperature control, and the final zinc oxide surface area. For a 300°C operation temperature and an AqOg saturation pressure of 0.38 TORR (or 0.05% As406 by volume), the contamination level is expected to be approximately 100 ppm. This suggests that arsenical dusts can be treated in the HRD flame reactor process and a reasonable purity zinc oxideproduct produced. The results also show no evidence of zinc arsenite or zinc arsenate formation.

Jan 1, 1994

By Deepak Gupta, R. Kageyamat, J. W. Evans

"In electromagnetic casting, a liquid metal pool is partly supported by electromagnetic forces resulting from the interaction between induced currents and an alternating magnetic field. Stability of the metal surface is of paramount importance if the cast ingot is to be free from surface defects. Prior work by Garnier and Moreau had suggested that the magnetic field has no influence on the surface stability, but a more complete analysis at Berkeley suggested that surface perturbations are destabilized by the magnetic field once a critical magnetic field is exceeded. More recently we have employed a modified version of the software SOLA to compute the behaviour of a melt surface in the presence of an alternating field. The computed results support the theoretical analysis in predicting an unstable surface. Experimental work is now in progress to examine the stability of a mercury pool in the presence of an alternating field. Introduction and Previous InvestigationsElectromagnetic casting (EMC) is a technique widely employed in the aluminum industry to produce ingot for subsequent rolling. It is a ""continuous"" casting technique (illustrated in Fig. 1) producing ingots several meters high (and perhaps 1m by 2m in horizontal dimensions) at a casting speed of one or two mm. per second. The technology has gained acceptance because the metal is solidified without contact with a mold. Consequently the surface finish of the ingot is usually smooth and the ingot can be fed directly to rolling without machining, the surface (""scalping""). Scalping is necessary with alternative technologies (e.g., DC casting) where a mold is used. Consequently any disturbances that result in surface imperfections of EMC ingot are a serious matter. One type of imperfection is waviness on the surface of the ingot; a line drawn along the crest of a wave would run horizontally around the ingot. This imperfection may be caused by waves on the surface of the metal pool. As the waves reach the solidification line at the periphery of the metal they cause alternate outward and inward bowing of the meniscus at that point with attendant small (but significant) changes in ingot width. Elimination of building vibrations and similar disturbances minimize the occurrence of these surface waves but it is interesting to speculate whether there are disturbances of the metal pool that arise from the electromagnetic forces supporting the liquid metal. These forces are generated by the interaction of currents induced in the melt and the magnetic field produced by the current imposed on the inductor surrounding the melt. The present investigation has been concerned with whether the alternating magnetic field destabilizes the melt surface."

Jan 1, 1994

By Brian Lightfoot

Ausmelt Technology uses a furnace/slag/lance system in a way analogous to the way a chemical engineer would use a mixed reactor. The technology is sufficiently versatile to treat materials under a very wide range of temperature and chemical conditions. At one extreme the system has been operated at temperatures high enough and oxygen potentials low enough to make iron. At the other extreme it has been operated of temperatures as low as 800°C and oxygen potentials high enough to cupel lead from silver. This versatility permits the treatment of a great variety of wastes including asbestos, mixed organic\heavy metal wastes, incinerator ash smelter residues, waste water treatment sludges, organochlorine compounds and many others.

Jan 1, 1994

By H. E. Frimmel

Abstract - Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morpho­logical characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively , estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry . Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infiltration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in turn, was deter­ mined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid:rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

By Moore A. J, Evans R

Blast vibration control and assessment techniques have been developed which supplement traditional charge mass scaling methods. The improved techniques, which can be used to predict air and ground vibration levels at the planning stage, and to assist in the control of blasting operations, have reduced the level of operating risk concerning blast vibration. In addition to such factors as charge mass, distance and blast vibration levels, these additional techniques take account of orientation of the blasting face, topographic shielding, wavefront reinforcement, and meteorological conditions. They have assisted in compliance with specified blast vibration levels for environmental licence and mining lease conditions, the reduction of blast vibration nuisance to residents in the area surrounding a mine, and control of building and rock structure response in adjacent areas on the mine lease area.

Jan 1, 1994

By P. T. Velu

Solubility of metal oxides in the molten salt electrblytes is an important parameter in the electrochemical processing of metals and alloys. The efficiency of an electrochemical process primarily depends on the quantity of metal oxide present in the electrolyte in the dissolved form and its thermodynamic properties. The activity of CeO2 was calculated using the free energy of fusion of CeO2,{ AG°m, CeO2. The AGOm,CeO2 }was deduced from the values of enthalpy, heat of fusion and melting point of Ce02. The activity coefficients of CeO2 as a function of temperature and melt composition were calculated. The thermodynamic data such as integral molar enthalpy, entropy and Gibbs energy of formation were calculated as a function of composition and temperature.

Jan 1, 1994

By X. Nie

A new one-step process was developed to completely eliminate iron and directly obtain pure Ni, Co, and Cu chloride catholyte from nickel rich matte by low temperature (400 0c) chlorination roasting of Ni, Co, and Cu with HCl and leaching with water (PH 7). The effects of roasting temperature, time, oxygen potential and HCI addition and leaching temperature, pH, H2S04 addition and residue sulphur on the recovery of metals and purity of leaching solution were investigated. More than 99 % of Ni and Co and 95 % of Cu in the matte was directly extracted into the solution while 99.995 % of Fe remained in the residue. The iron concentration in the leaching solution was less than 3.6 X 10-5 mol/L.

Jan 1, 1994

High sulphur volcanic-hosted hydrothermal environments are favourable geological environments for gold mineralisation. Numerous world-class gold deposits including Pueblo Viejo (Dominican Republic), Goldfield (Nevada), EI Indio (Chile), and Wa

Jan 1, 1994

By J. W. A. Morris

To investigate the use of centrifugal fields in fused salt electrowinning cells, a high temperature rig has been designed, constructed and commissioned. Initially, the cell has been applied to the fused salt electrowinning of zinc. Current efficiencies of 93% have been obtained for inter electrode gaps as small as 8mm for 70mm diameter electrodes rotating at 100rpm. The construction of a semi-rigorous physical model has shown the potential exists to extend the use of centrifugal fields to the electrowinning of light metals.

Jan 1, 1994

By Robert L. Cheek, Sid McIlveen

Sodium sulfate is an important industrial chemical. As recently as ten years ago it was produced and consumed in the United States in quantities exceeding 1 Mtpy. Since then, both its production and use have declined; however, approximately half the production still comes from natural sources. [Fig. 1] illustrates the history of production of natural sodium sulfate in the United States. Production of natural sodium sulfate from various types of deposits is the main source of this chemical in Canada and Mexico, and probably in Argentina, Chile, Iran, Spain, and the Russian Republics. MINERALOGY AND PHYSICAL PROPERTIES Sodium sulfate is widespread in occurrence and is a common constituent of many mineral waters, as well as seawater. Atmospheric precipitation contains sulfate; it is one of the major dissolved constituents of rain and snow (Davis and Dewiest, 1966). Many of the saline lakes throughout the world contain varying amounts of sodium sulfate. Because sodium is usually the dominant cation, some workers make an anionic distinction, referring to lakes containing predominantly sulfate as bitter lakes and those containing predominantly carbonate as alkali or soda lakes (Bateman, 1950). Sodium sulfate in its natural form is found in two principal minerals, mirabilite and thenardite. Mirabilite, the hydrous form, is commonly called Glauber's salt. It was discovered by the German chemist, J.R. Glauber (1603-1668), who derived its name from the Latin, sal mirabile, meaning wonderful salt. Thenardite, the anhydrous variety, was named for the French chemist, Louis Jacques Thenard (1777-1857) of the University of Paris (Mitchell, 1979). The largest quantities occur in the form of mirabilite. Sodium sulfate is found in varying degrees of purity, from theoretically pure efflorescent crystals of mirabilite to combinations and admixtures of other salts and impurities. It is a common constituent of some brines; from this source much is extracted commercially. Sodium sulfate also is found in compounds, such as the minerals glauberite, the double salt of anhydrous sodium and calcium sulfate, bloedite, the hydrous double-salt of sodium sulfate and magnesium sulfate, and burkeite, the anhydrous double-salt of sodium carbonate and sodium sulfate. Over 40 minerals contain sodium sulfate in varying proportions; many are of special interest because of their frequent occurrence. Table 1 lists some sodium-sulfate bearing minerals. The reader is referred to other publications (Cole, 1926, Dana, 1932, Grabau, 1920, and Dietrich, 1969) for descriptions of these minerals. Only mirabilite and thenardite will be described herein. Mirabilite Na$04.10H20, contains 55.9% water of crystallization. It is noted for its efflorescence or spontaneous loss of water. On dehydration it changes to the anhydrous form, Na2S0,. Mirabilite is an opaque to colorless, water-soluble mineral that tastes first cool, then slightly bitter. It has a specific gravity of 1.48. It frequently forms as efflorescent, needlelike monoclinic crystals, but generally is found in the massive form. Thenardite, the anhydrous mineral, Na2S04, contains 43.68% Na20 and 56.32% SO3. It ranges from colorless to white and may be tinted shades of gray or brown. It is a water soluble mineral with a slightly salty taste. Its specific gravity (2.67) and hardness (2.5 to 3) exceed those of mirabilite. It commonly occurs in the massive form without visible crystals. Its crystals are frequently tabular pyramids of the orthorhombic system. Sodium sulfate also occurs as a heptahydrate, containing seven molecules of water, but this is unstable and has not been found in the natural environment. The solubility of sodium sulfate has an important effect on the crystallization of the salt in nature, as well as in its production. Its solubility in water generally increases as a nonlinear function of temperature. Below 1.2°C, ice and mirabilite form. As the temperature is increased above O°C, increasing amounts of sodium sulfate become soluble. At 32.4°C, a transition point on the solubility curve is reached, as the decahydrate melts in its own water of crystallization and the anhydrous form crystallizes. With in- creasing temperatures, solubility decreases somewhat. The presence of other dissolved salts changes the transition temperature and solubility characteristics of sodium sulfate.

Jan 1, 1994

Actual observations of rockburst damage, together with some theoretical considerations, strongly suggest that conventional approaches to the design of tunnel support are inappropriate where there is a significant seismic risk. The present widely used support systems, which are based on stiff, fully grouted re-bars, are inadequate where rock displacement velocities exceed 1 m/s. It is shown by means of a simple conceptual model that yielding of the support elements is essential to ensure their survival when they are subject to the high strain rates typical of severe rockbursts. The model proposes that the total load in the element is an impulsive tensile force imposed and sustained by a single 'tributary' block ejected from the tunnel wall. The stability of the system is determined from a comparison of the kinetic energy developed by the block with the energy of deformation absorbed by a grouted steel tendon. A novel test procedure was developed for the validation of this approach, and for an examination of the energy-absorbing capacity of stiff and yielding tendons. The results of an initial series of tests showed that the recently developed cone-bolt is an effective yielding device. It absorbs twenty times more impulsive-load energy than is consumed by the complete fracture of grouted re-bar of equivalent strength, and it remains totally unscathed. Importantly, the results demonstrate that the ejection model is not merely an explanatory concept, but can be used as a representative and valid design method.

Jan 1, 1994

By the courtesy of Metropolitana Milanese (Milan Underground), roost of the delegates visited on April 12, 1991 the tunnel of "PORTA VENEZIA" STATION of MILANO RAILWAY LINK. The "PORTA VENEZIA" STATION will be the most important in the link and it will he also the largest underground project of the whole railway transport network in Lomhardy. The particular conditions of the soil and the collocation of site in the center of Milano have required new technologies and the technical solution applied to this job is called "Cellular Arch Method" by its designer Prof. P. Lunardi. Our sincere thanks go to Prof. P. Lunardi and Eng. E.M. Pizzarotti of Rocksoil, Milano who have kindly furnished us a technical description of this method. Eng. Pizzarotti was the guide during the visit and gave all the technical explanations to the delegates. THE "VENEZIA" STATION IN THE 2PB SECTION OF THE RAILWAY LINK The excavation of cavities in loose ground, exceeding a certain dimension and at shallow depth, is not feasible using traditional methods: in fact it is not possible to consolidate the ground around the cavity in such a way that homogeneity and resistance is sufficiently guaranteed.

Jan 1, 1994

By L. Xu, R. Bhaskar

The trends in dust exposure levels and longwall production over the last 20 years were examined. The study was conducted for nine major underground coal mining states: Alabama, Colorado, Illinois, Kentucky, Ohio. Pennsylvania, Utah, Virginia and West Virginia. The dust exposure and shift production data were obtained from the Mine Safety and Health Administration (MSHA). Trends were identified and analyzed for the headgate, tailgate, jack setter and shearer operator positions. The relationships between average scam height and dust exposure levels as well as the percentage of dust samples exceeding the dust standard for the four occupations were examined. The concentration to production ratio, a better indicator of the success of dust control measures, was calculated for the 20-Year period. The data show that, in general, dust exposures over the last two decades hare decreased. However, it appears that much of the decrease was in states that had significantly high dust exposure levels (such as Alabama and Utah), while for states such as Virginia, West Virginia and Pennsylvania, the decrease was not as dramatic. Major reductions were made in the period starting in 1982, when a host of longwall dust control techniques was introduced. However, nearly 35% of jack setter and shearer operator dust exposures were still above 2 mg/m3 in 1990, with nearly 20% of tailgate operator exposures and 8% of headgate operator exposures being above the federal standard. The concentration/production ratio has shown a remarkable decrease since 1981. This indicates that long wall operators have been able to meet increased production as well as, to a large extent, control chest production at the face. An analysis of the relationship between average seam height and dust concentration for the years 1984 and 1990 shows that while in 1984, the dust concentration could be correlated to seam height, in 1990 the relationship was less definitive. This indicates that technological factors may be more important than seam height.

Jan 1, 1994

By Karan S. Keith, Haydn H. Murray

The sorptive and impervious nature of clay materials was recognized long before modem technology allowed us to understand the physiochemistry of clays. In Cyprus, around 5000 BC, sorbent clays were used for fulling woolen cloth. One of the earliest recorded uses of clays as an impervious liner was more than 3200 years ago in the construction of a bitumen-sand-gravel-clay liner built along the embankment of the Tigris River at Assur. Today one of the most common applications for clay minerals in the environmental industry is for use as impermeable barriers to fluid transport. Clay minerals are fine in particle size and thus have large surface areas, which, as a result of intermolecular forces and ionic substitutions, make them excellent materials for both ion exchange and ion sorption. Therefore it was logical to consider certain clay materials for applications in the environmental industry, where they can act as physical and chemical traps for potential contaminants. Certain bentonites have historically been used as sealants for fluids (Grim, 1962), and other clays have been used as sorbents for both water and oil (Haden, Jr., 1972). Prior to the 1980s, disposal of the nation's municipal, commercial, chemical, and nuclear wastes was largely indiscriminate and poorly regulated. This created environmental pollution problems, especially with respect to groundwater contamination. Promulgation of federal regulations like the Resource Conservation and Recovery Act (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA - commonly known as Superfund) have forced a more careful and costly approach to waste disposal. The US Environmental Protection Agency (EPA) is the government body charged with enforcing and ensuring compliance with federal regulations governing toxic waste production, storage, and disposal. Widespread application of geotechnology to the design and construction of waste containment systems and to pollution remediation has become necessary due to such laws and because of increasing use of the subsurface environment for the disposal of hazardous wastes. In the United States nearly 1.8 kg of trash is disposed of per person per day, which amounts to nearly 181 Mt per year. This amount is more than double the waste produced in 1960, and these numbers are expected to continue to increase. Canada produces approximately 1.68 kg of waste per person per day. The EPA estimates that in the United States 64% of our garbage is landfilled, 18% recycled, and 18% incinerated. Even with continued increases in recycling and incineration efforts, the EPA projects that the United States will still need 82% of today's landfill capacity in the year 2000. Data on the exact number of landfills in the United States and Canada is conflicting in part because of changing definitions of what constitutes a landfill and because of inadequate record- keeping by some states and provinces. An estimate of the number of municipal solid waste (MSW) landfills in the United States in 1990 to 1991 ranged from 4 462 to 10 467 with an average estimate of 6 600. In Canada the number of MSW landfills reported varied from 5 493 in a 1982 survey to 1 766 reported in a 1991 National Solid Wastes Management Association (NSWMA) survey (Repa and Sheets, 1992b). A properly operated MSW landfill on average requires 1 hectare of land per year per 25 000 people (Coates, 198 1). In addition to MSW facilities, there are also waste disposal facilities needed for hazardous waste and low level and high level radioactive waste. In 1983, approximately 266 Mt of hazardous waste was generated in the United States, almost 50% of this by industrial production. About 68% of the hazardous waste generated in the United States and Canada and almost 50% generated in Europe are still landfilled (Egger, 1987). In 1985, approximately 51 000 m3 of commercially produced low level radioactive waste was disposed of in radioactive waste disposal sites across the United States (Jungling and Greeves, 1989). By 1987, the US defense program had produced approximately 10 000 t of high level nuclear waste. In addition, there were approximately 14 000 t of spent fuel assemblies from commercial nuclear power plants in temporary storage; the amount is expected to nearly triple by the year 2000. Presently most commercial spent fuel assemblies are stored in water-filled pools at nuclear power plants. Defense waste is stored on federal reservations in surface and underground steel tanks (Anon., 1987). Under federal law nearly all waste disposal and containment sites are required to have a liner or barrier and a cover system design that meets federal- or state-approved hydraulic conductivity requirements for the type of waste that the site will receive. When approved materials, necessary for constructing the waste containment structure, are not available on site, one of the most economical ways to meet these requirements is through the use of clay, soil/clay, or clay/geotextile materials. In a 1991 survey by NSWMA of its members and other select private sector facilities, 81% of the surveyed landfills had some type of liner system. About 75% of these liners were clay materials (either recompacted or natural). The remaining 30% were using flexible membrane liners as part of a liner system. Clay liner materials are most commonly used in the South, Midwest, West-central, and South-central regions of the United States. About 93% of the landfill facilities had closure plans, and of these 91 % were using clay materials in some way for the final cover material (Repa and Sheets, 1992a). Waste barriers and containment structures take several basic forms, and they are used in a variety of different applications: 1) cutoff walls, 2) soil or soil/clay-admix liners, 3) geosynthetic bentonite-clay/geotextile membranes, 4) radioactive waste containment barriers, and 5) synthetic geomembranes. This chapter will discuss the first four of these categories. The field of synthetic geomembranes, although a related topic, is beyond the scope of

Jan 1, 1994

By Gillies A. D S, Lee A. H

Water is an integral component of a mining operation. To-date water management has received a low profile in the overall management of mining operations. To cost effectively meet the requirements of government environmental legislation the man

Jan 1, 1994

By A. D. Davis

The disposal of spent ore from cyanide heap-leach processing facilities is of concern to the mining industry, regulatory agencies, and the public. Disposal of several hundred million tons of additional spent ore is planned in the western United States during the next decade, with increased amounts likely if gold prices rise. In the past decade, more than fifteen million tons of spent ore have been disposed of in the Black Hills. South Dakota's off-loading criterion for cyanide has been set by the state's Department of Environment and Natural Resources at 0.5 parts per million (ppm) as weak acid dissociable (WAD) cyanide. Nitrate off-loading limits vary for each mine in the state, depending on ore type and other factors. Nitrate concentrations in leachate from spent ore depositories could be caused by conversion from other nitrogen-containing species. One likely source of nitrate is residual explosives from blasting of ore. Previous work on the combustion products of nitrogen explosives has shown incomplete 3xidation (Johansson and Persson, 1970). Another likely nitrate source is degradation of cyanide to ammonia, followed by oxidation to nitrite and nitrate.

Jan 1, 1994

By L. F. Delgado

Environmental and cost pressures sparked renewed interest in gravity separation. Industrial sands in Mexico are generally processed by screening, desliming, and flotation. Gravity separation with spirals was evaluated as an alternative to flotation in order to lower operating costs and decrease water pollution. Outstanding operating results are obtained in glass and foundry sand operations, plus a more competitive position for Mexican producers due to lower operating costs. Coal fines, generally recovered by flotation, have the same cost and environmental advantages when processed with spirals.

Jan 1, 1994