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By Krystyna Raszka, Jerzy Iskra

The paper presents results of spectrophotometric investigations concerning the adsorption of sodium oleate on silicon carbide in the presence of the cations of multivalent metals, applying the ATR IR technique with computer-aidedprocessing of the spectrum. The analysis of these spectra indicates the occurance of distinct OH and COOH bands in the pH range in which the hydroxy complexes of metals of the type MeOH+ and MeOH++ reach in the respective cases the highest concentration in the solution. The correlation of these results with those of flotation, measurements of the zeta potential confirms the proposed mechanism of activation of the flotation of silicon carbide, applying sodium oleate as a collector, the collection taking place over the adsorption of hydroxy complexes of the type MeOH+ and MeOH++

Jan 1, 1995

By P. J. Brown, R. W. Nice

The Thalanga Copper-Lead-Zinc Concentrator in Northern Queensland was commissioned in early 1990. The design of a flotation process for the sequential production of separate copper, lead, and zinc concentrates has always been a most formidable mineral processing challenge. In 1988-1989 during the process design phase, sized fractions of various samples were subjected to quantitative and qualitative mineral analyses. These analytical techniques are collectively known as modal analysis. Modal analysis aided in the selection of key process treatment parameters for the initial laboratory testwork on the Thalanga ore. The work also guided the flowsheet development and quantified the mineralogically imposed limitations on the separation process. This paper describes in general terms how these modal techniques were used to guide the program of laboratory flotation testwork which constituted the flowsheet design phase of this project. During these design studies, the primary grind and regrind requirements were deduced and the basic flowsheet configuration selected. Recent operating plant performance data are to illustrate the value of modal methods in addressing complex metallurgical separation problems.

Jan 1, 1995

By Jim Truman

Appalachian coal mines include operations in eastern Kentucky, Maryland, Pennsylvania, Virginia and West Virginia. During 1994, they produced a total of about 342.5 Mt (377.6 million st) of bituminous coal. This figure represents 37% of the total production from the United States. This region contains nearly all of the nation's coking coal reserves and high-quality compliance steam coal that will be in demand after the turn of the century as utilities comply with phase two of the 1990 Clean Air Act Amendment. Figure 1 shows the location of the study area and the general regions that supply various coal types. Data for the study reviewed here were compiled and interpreted from Mine Safety and Health Administration (MSHA) production reports, Federal Energy Regulatory Commission 423 reports, King's Export database and additional data from the US Department of Energy's (DOE) Energy Information Administration (EIA). Table I is an overview of the total production from Appalachia and the delivered tonnage to various sales categories.

Jan 1, 1995

The epizonal Ag-Pb-Zn vein deposit at San Bartolome is characterised by a base-metal sulphide assemblage containing the spectacular development of interpenetrating, bladed networks of pyrrhotite which have been replaced by marcasite and pyrite. A similar assemblage displaying the same crystal habits and textures are also a diagnostic feature of the Sn and Sn- Ag deposits of Bolivia. On this basis, it is reasonable to conclude that both deposits were formed from fluids of similar nature and origin. Although no economic accumulation of Sn is known in San Bartolomr, further comparison of the geologic setting, age, mineralogy, fluid inclusion data and magmatic association of this deposit with the Bolivian systems has highlighted additional similarities consistent with a hypothesis that more extensive Sn mineralisation might exist in the San Bartolomd area.

Jan 1, 1995

By Gregor Mori

Niobium electrolysis has been performed in a NaCl-KCl-NaF-NbCls electrolyte. By means of electrolytic .refining the average valency of the niobium ions was determined as well as the crystallization behaviour. In electrowinning runs the influence of the main parameters such as temperature, RF (mole ratio F/Nb), chemical prereduction, niobium content of the melt and current density has been determined with respect to low specific energy consumption and high purity of the deposit.

Jan 1, 1995

By James J. Gusek

Passive-treatment systems that mitigate acid-rock drainage (ARD) from coal mines have operating since the mid-1980s. Large systems at metal mines are being contemplated. A 95L/sec (1500-gpm) capacity system is planned this year at an underground lead mine in Missouri. Mine, process and environmental managers need to understand how and why passive-treatment systems work. They must understand what operational limitations to expect, as well as the economics of construction and operation compared to the alternatives, like lime precipitation. Wetlands have been recognized as nature's method of improving water quality. Contaminant reductions can occur through the precipitation of metal hydroxides, sulfides and carbonates and pH adjustments. Local conditions, oxidation state and water and soil chemistries dictate whether these natural reactions will occur under oxidizing (aerobic) or reducing (anaerobic) conditions.

Jan 1, 1995

By E. Topuz, M. J. McPherson, J. Banik

This paper summarizes the analyses of ventilation layouts for mines that experience both spontaneous combustion. The major focus is placed on the longwall coal mine layouts used in several countries. Each of the different layouts is modeled in the form of a ventilation network. The gob of a longwall panel is the most critical location for the occurrence of spontaneous combustion. Airflow leakage paths inside the gob are simulated by using a simplified grid-like network. Computer simulations with this model indicates that the W-system of ventilation is most effective in minimizing air leakage into the gob. Homer, the U-system of ventilation, with pressure balancing behind the face support line, is also found promising for longwall panels. The magnitude of air leakage into the gob is observed to change with the advance or retreat of bee, thus requiring appropriate balancing of pressure to maintain the leakage at a minimum.

Jan 1, 1995

By L. C. Atkinson, E. A. Azrag, T. M. Hanna

The results of using a simple analytical solution and a relatively complex numerical model to estimate ground water inflow to an open pit mine are compared. The analytical solution assumes lateral, radial flow to a fully penetrating pit in an idealized confined aquifer, whereas the numerical model simulates fully three-dimensional flow to a partially penetrating pit from a water table aquifer. The latter is a more realistic simulation of the problem, but the former method is significantly easier to use. Comparison of the results obtained with the two methods for some typical hydrogeologic conditions encountered in mining yields ratios between them in the range of 0.2 to 0.6. These values can be used as a coefficient in the Pit Flow analytical solution to produce reasonable estimates of in-flow even when there are significant differences from the idealized conditions implicit in its application.

Jan 1, 1995

By D. A. Rhys, M. Sieb, M. A. Prefontaine, C. L. Swanson, S. R. Frostad, H. Q. Smit

"Gold-silver mineralization at Red Mountain (1992 resource of 2.5 million tonnes grading 12.8 g/t Au and 38.1 g/t Ag) occurs within several discrete zones within a folded sequence of Middle to Late Triassic Triassic sedimentary rocks, Early Jurassic volcaniclastic and pyroclastic rocks, and Early Jurassic intrusions. Three phases of Early Jurassic sills and stocks collectively comprise the Golds/ide intrusions: (1) irregular bodies of medium-grained hornblende monzodiorite (Hillside porphyry); (2) hornblende-biotite + quartz porphyritic monzodiorite to quartz monzodiorite (Golds/ide porphyry; U-Pb zircon ages of 197.1 + 1.9 Ma); and (3) biotite porphyritic hornblende monzodiorite sills (Biotite porphyry). Contact breccias and igneous breccia dikes are common features of the Golds/ide intrusions. Chemical similarities and equivalent ages of volcanic rocks and intrusions, and the presence of intrusive clasts in volcanic rocks suggest that the intrusions are feeders to overlying volcanic units.Hydrothermal alteration affects all pre-Tertiary rocks on Red Mountain, including all phases of the Golds/ide intrusions. Several shallow-dipping alteration zones are developed sequentially above a propylitic quartz stockwork/molybdenum zone. These include: (1) sericite-quartz-pyrite alteration (pyrite-dominant alteration); (2) chlorite-K-feldspar-sericite-titanite alteration with disseminated and vein pyrrhotite (pyrrhotite-dominant alteration); and (3) brown to black tourmaline veins and K-feldspar-pyrite-titanite-actinolite alteration. Anomalous gold(> 0.3 g/t) mineralization is developed at the transition from the pyrite to the pyrrhotite dominant alteration over a > 1 km2 area. Within this anomalous zone, high-grade (3 g/t to 20 g/t Au) gold-silver mineralization occurs in 5 m to 29 m thick, semi-tabular pyrite + pyrrhotite stockworks with intense sericitic alteration and surrounding disseminated sphalerite + pyrrhotite.Stratigraphic, spatial and geochronologic relations and alteration zoning indicate that mineralization formed in a subvolcanic environment at the top of the Golds/ide intrusions and at the base of the Early Jurassic volcanic pile. The Golds/ide porphyry is interpreted to be the mineralizing intrusion. The alteration zoning, molybdenum-copper mineralized quartz stockworks, extensive Ksilicate and tourmaline alteration, and the relationship with a hypabyssal porphyritic intrusion show similarities to many porphyry systems."

Jan 1, 1995

By M. D. Carter

The availability of environmentally acceptable and reliable energy sources is an important issue for Federal, State, and local planners. A cooperative program by the U.S. Geological Survey, State geological surveys, and the U.S. Bureau of Mines has developed a national GIS-based systematic effort to collect, analyze, and depict data characterizing the relationship between restrictions to mining and the potential development of the Nation's coal resources. Land use/environmental and technologic/geologic restrictions are identified within selected 1:24,000-scale, 130-to 150-sq-km 7.5-min quadrangles and applied as overlays to maps of coal-bed thickness, depth, and mined-out areas. Tonnages of original, mined and lost-in-mining, remaining, restricted, and available resources are calculated. Resultant data files are transferred to the Bureau of Mines for recoverability and cost analysis.

Jan 1, 1995

By Sibson RH

The gold province of Otago occupies an area of upwarped basement, the Otago Schist, comprising predominantly quartzofeldspathic and volcanogenic metasediments. This assemblage is the product of collisional tectonic deformation and associated metamorphism, mainly to lower greenschist facies, during the Rangitata Orogeny (200-100 Ma). Historically this region has produced 240 tonnes of gold, 4% (10 t.) of which was from the mining of Cretaceous gold- quartz mineralised vein systems. Auriferous vein systems in the Otago Schist are mainly hosted within NW trending normal fault-fracture arrays, however NW trending reverse fault-hosted vein systems also occur. We propose that the Late Cretaceous-mid Tertiary Otago Schist structure represents a regional anticlinorium containing flexural folds of at least two wavelengths. The anticlinorium structure has been quantified by determining variations in angular discordance between schistosity and the Otago Peneplain, a Late Cretaceous-mid Tertiary erosion surface covering most of the Otago district. A structural model for the evolution of the post-collisional anticlinorium requires the cooling surficial zone (carapace) of a retrograding metamorphic belt to behave as an elastic lid. Erosion of topographic load on the carapace drove isostatic uplift, which was greatest in the tectonically thickened core of the orogen. In this way differential uplift produced flexural deformation in the elastic carapace, expressed as a large scale arching of the orogenic belt. Flexure created tangential longitudinal strains in the outer-arc, leading to extension and the formation of mineralised normal faults. These structures are separated by a neutral surface from shortening and associated mineralised reverse faults in the inner-arc. Our structural model predicts that the distribution of auriferous lodes should be localised about zones of maximum flexural curvature, where the tangential longitudinal strains are highest. As a result, NW-SE hinge regions separating schistosity dip domains in the Otago gold province may have new found significance as potential exploration targets.

Jan 1, 1995

By G. Q. Liu

"The application of oxygen-enriched cyanidation to three Canadian gold ore samples has been investigated. The results showed that the use of oxygen can improve gold dissolution kinetics, reduce grinding time, and lower cyanide and lime consumptions. To obtain the same gold extraction, the required cyanide leaching time was reduced from 48 hours in slurry containing 8 ppm O2 to 12 - 24 hours in 20 ppm O2 slurry. Reagent consumptions were reduced by 23 - 37% for cyanide and by 35 - 54% for lime. There was little advantage to further increasing the dissolved oxygen to 32 ppm from 20 ppm. Gold extraction from the +200 mesh fraction improved 4 - 14% in oxygen-enriched slurry. A general kinetic model derived from the cyanidation of three ore samples can be described by the following equation: <equation>where E is the gold extraction (%) at time t (hours), EI is the ultimate gold extraction (%) , and &apos;P and k are constants depending on cyanide concentration, level of dissolved oxygen, and the characteristics of the ore samples. Comparative studies of conventional carbon adsorption and carbon adsorption in oxygen-enriched slurry have also demonstrated that oxygen enrichment resulted in more favourable conditions for gold adsorption."

Jan 1, 1995

By O. Guyot, A. Broussaud, J. Björkman, P. Söderman, P. O. Samskog

Model-Based Expert Control systems (MBEC) are on-line supervisory dynamic optimization systems which combine the ability of a phenomenological model to generate a large amount of information about the state of the process and predict its evolution, with the flexibility of a rules-based approach to take plant constraints into account and apply a complex control strategy. For its new concentrator started in 1995 in Kiruna (Sweden), LKAB has implemented a progressive grinding flowsheet with closed-circuit autogenous grinding followed by closed-circuit pebble grinding with ore pebbles. The standard for instrumentation in this new plant is very high. The control hardware consists of a Distributed Control System (DCS) through which the operators interact with the plant, supplemented by a site-level Management Information System (MIS). A state-of-the-art MBEC system was imbedded in the MIS by the authors before plant start-up. It consists of several modeling and expertise software modules: a phenomenological process model and a Kalman filter estimate continuously the state of the process, an optimizer calculates an optimum feedrate, while rules-based modules establish production targets and key process set-points. The decision to install the MBEC system as an integral part of the new plant before start-up illustrates the current maturity of the technology, i.e., enough know-how was accumulated through former projects to design and develop the system to a large extent without accessing the plant. The feasibility and the power of dynamic optimization systems were previously demonstrated in Kiruna pre-existing concentrator by the authors. First, a MBEC system was installed on the three existing pebble mill circuits, providing both an increase in quality (stabilised size distribution) and a 10% increase in capacity. An on-line expert control system with limited modeling capabilities was also installed in the existing flotation plant, with the aim of stabilizing phosphorous content in the concentrate and optimizing collector additions. Both objectives have been achieved.

Jan 1, 1995

By Robert B. Parsons

"The last edition of Tax Notes expressed concern about two proposed tax changes in Finance Minister Paul Martin&apos;s 1995 budget that could have detrimental effects on Canada&apos;s mining industry. This month, Tax Notes expands on these concerns. This article is based on a paper that the author presented at ClM &apos;95 in HalifaxIntroductionOn a global basis, there are more investment opportunities in the mining industry today than at any other time in history. Countries in Central and South America, Eastern Europe, the CIS, Central Asia, and Asia are competing aggressively to attract investment to all sectors of their domestic mining industries. Today, the demand for investment dollars exceeds the amount of dollars that are available for investment in mining. It is not surprising, then, that the established mineral producing nations are witnessing a decline in spending on exploration and development on their home turf, and an increase in spending in developing countries. In the context of a developed country such as Canada, there are two manifestations of the problem of declining investment: (I) Foreign investors are allocating more of their capital budgets to new opportunities in developing countries; and (2) Canadian juniors and seniors are spending proportionately more abroad. This shift in global spending patterns is the source of some concern for the future of Canada&apos;s mining industry, particularly because it is widely believed that the current rate of discovery of ore reserves in this country is too low to replenish depleting reserves.""Government bashing"" has always been a popular pastime in Canada. Invariably, this pastime has focussed, at !east in part, on taxation. In view of the intense competition that Canada faces on the global mining scene, it is important that the role of taxation in the decision-making process be kept in perspective. This paper seeks to put the role of taxation into perspective."

Jan 1, 1995

By Marco Olper

After two years of extensive research a new and innovative modification to the CX-EW process has been exploited. This process, called CX-EWS, avoids completely all the critical aspects of the previous process which affected the cost of the energy, of the chemicals and of The maintenance of the insoluble anodes. All these benefits reflect a saving of about 30% of The operating costs compared to the present traditional production and allow for a total operating costs of less than 6.5 cts/lb. lead (net of raw material cost). With this new technology it is allowed for the first time the treatment in the same plant facilities of both primary lead sulphide concentrate and spent batteries. The paper describes the technical and economical aspect of the new process with a feasibility study for 150,000 t/y spent battery facility throughput.

Jan 1, 1995

By Tim Avery, Steve Klein, Mark Schmoll

Tunnel boring machine (TBM) performance in hard rock is highly dependent on the geologic conditions, including the type of rock and hysical properties like the rock strength, hardness, and the spacing of the fractures. This paper examines TBM performance relative to the geologic conditions and rock mass properties at four recent TBM-bored tunnels in California.

Jan 1, 1995

By Carlie JC

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralization. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

By Dean J. Soderstrom

Soil and sands were contaminated with depleted uranium from weapons testing. This resulted in the formation of a complex mixture of uranium compounds. Characterization studies of the soil indicated the uranium was present as uranium metal, uranium oxides, silicon-bearing metallic uranium, and uranium silicates. A process was developed to selectively remove dense uranium compounds using gravity separation and a chemical extraction system to remove uranium which was not available for separation by gravity methods. Results from characterization studies and pilot scale testing are presented for background information. The primary purpose of this presentation is the report of the results achieved in the field application of the processes.

Jan 1, 1995

By P E. H Gregg, D Horne, R B. Stewart, N Bolan

The Tui mine site is situated on the NW flank of Mt. Te Aroha, at approximately 400 m altitude. During underground mining operations two lead-copper-zinc ore bodies were exploited and processed on site. The legacy of the mining operation is a barren dam containing over 100 000 mm of sulphide-rich tailings. The Tui mine site is arguably the worst case of environmental degradation resulting from past mining activity inNew Zealand. Although the impacted area (approximately 4 ha) is extremely small by international standards, acid mine drainage (AMD) emanating from the abandoned tailings dam and mine adits has severely contaminated local streams and prevented natural plant recolonisation of the site for more than 20 years. &nbsp; The suitability of the tailings as a potential plant growth medium was assessed with the end view of revegetating the tailings dam and alleviating AMD. This paper outlines characterisation work conducted on the tailings and summarises preliminary results from plant growth trials. The tailings contain up to 5% Fe, 1.15 % Pb, and 0.45% Cu in the form of sulphide minerals. The distribution of heavy metals, sulphate and total sulphur with depth indicates that the top 200 - 300 mm of the tailings have been extensively weathered since their deposition. The oxidation of sulphide minerals, particularly pyrite (FeS2 ) has reduced the pH of the tailings to nearly&nbsp;2 in places. Below 300 mm the sulphide minerals are largely unweathered and the theoretical acid generating potential of the tailings exceeds 170 Mg CaCO3/1000 Mg tailings at certain depths. Plant growth trials were conducted to study the effects of lime and organic matter addition on the establishment of vegetation on the Tui mine tailings. Several plant species were assessed including some cultivars bred for their tolerance of heavy metals.

Jan 1, 1995

By Jean Goldschmidt

Recycling of fine oxidized particles of non-ferrous metals usually cannot be carried out by pyrometallurgical methods. &apos;Hydrometallurgy provides an alternative technology to reintroduce? the resulting products as secondary raw materials into the industrial cycle, thereby saving resources and energy while keeping the environment a little cleaner. The paper summarizes the methods employed by Hydrometal to achieve these objectives and? stigmatizes the latest counterproductive international regulations which create ever more obstacles to environmentally sound recycling.

Jan 1, 1995