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By J. Gathje

Normal process development for pressure-preoxidation treatment of refractory gold ores starts with laboratory batch autoclave tests. That is followed by continuous autoclave pilot-plant testing to confirm the process options. This scheme will generally provide good information showing the effects of grind size, time and temperature. And it will indicate whether autoclave preoxidation will produce solids that are amenable to cyanidation for gold recovery. However, several test programs have shown that the cyanide-leaching responses of treated solids from the batch tests can differ considerably from those achieved by the continuous pilot-plant autoclave. It has become apparent that laboratory investigations should extended to include the use of a semicontinuous autoclave test procedure. Santa Fe Pacific Gold conducted several months of metallurgical investigations for a major refractory sulfide gold deposit. The project started with batch tests to investigate and optimize the primary variables, such as grind size, retention time and temperature. These tests were conducted using a representative whole ore composite.

Jan 1, 1995

By L. F. Zeiler

In the past, health concerns in coal mines have primarily centered on those elements which have been essentially inherent to the mining environment. These would include respirable coal mine dust, respirable crystalline silica, excessive noise levels, and diesel exhaust particulates. Commercially-available chemical products are prevalent on mine property. These potentially toxic materials are chemical formulations that can degrease, clean, and lubricate metal parts, separate coal from rock in float/sink operations, and aid in roof consolidation, among other uses. As the general public has become more aware of the hazards of chemical exposures, miners have likewise become more concerned about working with an ever-expanding variety of chemical products on the job. Often, product or chemical specific hazard communication training is inadequate or ineffective, and miners do not know exactly what the ingredients are in the products they handle, or the health hazards involved with their use or misuse. Currently, the Mine Safety and Health Administration (MSHA), by law, enforces 1972 Threshold Limit Values (TLV). MSHA is making preparations to adopt new personal exposure limits for enforcement. The values given throughout the article are 1994 TLV's and are not enforcement standards, but are used for discussion purposes. They reflect the current scientific thinking regarding personal exposure to these chemical agents. An overview of these products is presented, and the potential health hazards associated with their use are discussed. Controls needed to prevent overexposures, such as proper handling procedures and personal protective equipment, are covered. Methods used to collect and identify contaminants are presented.

Jan 1, 1995

By Martin L. Smith

Mine waste characterization and risk assessment currently focesses on water quality and largely ignores boththe charteristics of the wastes themselves and how wastes interact with the environment. Characterization of the parameters that control contamination of pore waters and their migration can quantitatively assess risk and remediation strategies in terms of cost effectiveness and risk reduction. Since mine waste characteristics are spatial, geostatistical methods should be used for characterization and assessment. A number of geostatistical methods are reviewed in terms of their application to mine waste sampling, modeling and risk assessment and management.

Jan 1, 1995

By Terry Mudder

Long-term anaerobic biochemical treatment for draindown of residual solutions is a cost-effective way to close a heap-leach pad. This article presents a laboratory evaluation of anaerobic biochemical treatment of cyanide heap-leach pad solutions. The traditional approach to heap-leach pad closure is to rinse the pads with multiple pore volumes of fresh or recycled treated water. The effluent from an initial rinse is often treated and recirculated until the solutions passed through the heap meet the appropriate numeric and narrative water quality standards. Column rinsing tests are completed during project planning to determine the number of pore volumes of fresh or recycled treated water required to rinse the pad to meet long-term closure requirements. A traditional closure plan generally includes provisions to sample the rinse effluent and rinsed solids (the Meteoric Water Mobility, Procedure or USEPA 1312) to verify that chemical requirements are being met.

Jan 1, 1995

By KNona C. Liddell

The time and spatial dependence of component and species concentrations during in situ uraninite leaching have been modeled using a reactive transport model based on partial equilibrium between reactive minerals and the solution. The flow field is represented by mixing cells in series. The effects of the H2O2, (NH4)2CO3, and NH4HCO3 component concentrations have been simulated, and results are presented for a one-dimensional flow field.

Jan 1, 1995

By Quast K. B

Samples of limestone and micaceous hematite have been ground in a laboratory batch mill using equal weights of either rods or balls. Values of the Schuhmann distribution modulus, a, have been shown to depend on grind time and do not remain constant as often reported. The linear reduction in a with grind time was attributed to a change in grinding mechanisms with time. The product sizing from ball milling limestone showed a bimodal distribution, but rod milling produced a unimodal size distribution. The product sizing from milling micaceous hematite was difficult to interpret due to the major influence of the shape factor on the transition from screen sizing to cyclosizing.

Jan 1, 1995

By John F. Papp

Based on a review of historical domestic and international chromium metal production capacity, production, consumption, trade, and trade literature, world annual chromium metal production capacity in 1995 was estimated to have been 38,300 metric tons, a drop from 43,500 tons in 1994. World chromium metal production and consumption were estimated, on average from 1984 through 1992, to have been 21,000 tons per year. U.S. consumption was estimated, on average over the same time period, to have been 6,200 tons per year. The major world chromium metal producers between 1984 and 1995 were China, France, Germany, Japan, Russia, United Kingdom, and United States. From 1984 through 1992, world trade averaged 8,400 tons per year. Germany and the United States accounted for over 75 percent of imports on average during the same time period. U.S. chromium metal import value rose from under $1 per kg before 1964 to over $6 per kg in 1993. Over the same time period, prices rose from about $4 per kg to about $10 per kg. Chemical specifications have become more stringent. Detailed chromium metal trade, prices, value, chromium metal chemical specification, and production capacity by country are reported. A shift in trade patterns was anticipated as Japan exits production and displaces Germany as the second largest importer and as Russia increases its role in world trade.

Jan 1, 1995

By Charles W. Perdue

This U.S. Bureau of Mines report considers, from a psychological perspective, the perceptual process by which miners recognize and respond to mining hazards. It proposes that if the hazard recognition skills of miners can be improved, mining accidents may be reduced to a significant degree. Prior studies of hazard perception in mining are considered, as are relevant studies from investigations of military target identification, pilot and gunnery officer training, transportation safety, automobile operator behavior, research into sensory functioning and visual information processing. A general model of perception is introduced, and selected concepts from the psychology of perception that are applicable to the detection of mining hazards are reviewed. Hazard recognition is discussed as a function of the perceptual cues available to the miner as well as the cognitive resources and strategies employed by the miner. The development of expertise in responding to hazards is related to individual differences in the experience, aptitude, and personality of the worker. Potential applications to miner safety and training are presented.

Jan 1, 1995

By Y. C. Guan

The dissolution behavior of silver and copper form their elemental states and Ag/Cu alloys in ammoniacal solutions has been studied using rotating disc electrodes. The variables studied included concentration of ammonia, oxygen partial pressure and rotating speed of the disc. The results have been interpreted in terms of the mixed potential theory. The effect of local current resistance on the overall current has also been examined as a part of the governing theory of the dissolution. It was observed that the dissolution potential and the rate of dissolution were very much affected by the composition of the alloys.

Jan 1, 1995

By Osvaldo A. Bascur

The implementation of continuous quality improvement is the confluence of Total Quality Management, People Empowerment, Performance Indicators and Information Engineering. The supporting information technologies allow a mineral processor to narrow the gap between management business objectives and the process control level. One of the most important contributors is the user friendliness and flexibility of the personal computer in a client/server environment. This synergistic combination when used for real time performance monitoring translates into production cost savings, improved communications and enhanced decision support. Other savings come from reduced time to collect data and perform tedious calculations, act quickly with fresh new data, generate and validate data to be used by others. This paper presents an integrated view of plant management. The selection of the proper tools for continuous quality improvement are described. The process of selecting critical performance monitoring indices for improved plant performance are discussed. The importance of a well balanced technological improvement, personnel empowerment, total quality management and organizational assets are stressed.

Jan 1, 1995

By Corbett GJ, Leach TM

ABSTRAC'T' Although hosted within an Ordovician magmatic arc, the Peak Hill high sulphidation system displays features typical of younger Pacific Rim high sulphidation epithermal gold deposits. Regional NW trending transfer structures are inferred to localise the magmatic source at their intersection of the NS trending arc. Fluids have migrated from the magmatic source along NW structures and thence exploited permeable horizons, which have become silicified. Alteration displays typical zonation from silicification through assemblages characterised by alunite, pyrophyllite and kaolinite and is followed by breccia/fracture controlled sulphide and gold deposition. Sinistral rotation on the NS arc has dilated NW trending fractures to produce the WNW to EW dilational fractures which host the higher grade ore. Mineral assemblages are typical of formation distal to the magmatic source in an epithermal environment. The combination of alteration and mineralisation zonation with structure provide fluid vectors which target a magmatic source to the SE of Peak Hill.

Jan 1, 1995

By Evan O. Jones

Processes involving distillation under reduced pressure were developed at the Pacific Northwest Laboratory several years ago to recover spent acid solutions generated during the manufacture of nuclear fuel for the N-Reactor at the Hanford site. Following construction and testing of a pilot-plant, the technology was licensed to Viatec Recovery Systems, Inc. for commercialization. The technology developed included specialized distillation and rectification of volatile acids, removal of water and/or volatile acid from sulfuric acid, and precipitation of salts. A key feature of the Waste Acid Detoxification and Reclamation (WADR) technology is the development and use of advanced thermoplastic and fluoropolymer materials of construction in all critical process equipment. The technology was then expanded to include crystallization to recover metal salts for possible reuse. Economic and environmental advantages of the procedures include recovery of acids for reuse, simplification or elimination of the disposal of waste solutions, and possible recovery of metals. Industries expected to benefit from such applications include galvanizing, electroplating, sand leaching and any where metals are cleaned in acid solutions. Currently a modular system has been assembled for recovery of several different spent acid solutions.

Jan 1, 1995

By W. M. Hart

The current Automatic Data Acquisition system developed by some support manufacturers makes it possible to continuously monitor and record changes in leg pressure and advancing ram stroke in every shield, and shearer position at any moment during the mining operation. In order to effectively use the massive data obtained from this system for improving production and maintenance managements as well as providing better roof control at a longwall face, the research currently conducted jointly by West Virginia University and Cyprus-Amax Coal Co. attempts to develop a Longwall Management System for mine operators. The LMS software package runs on a MS Windows NT environment and consists of four sub-systems: (1) Data Interpretation and Analysis; (2) Production Management; (3) Maintenance Management; and (4) Ground Control. This paper presents the details of each sub-system.

Jan 1, 1995

Discovery 2000 is basically about data, its collection, management, assessment and dissemination. A major focus of Discovery 2000 is the collection of new geoscientific data. However, the Department is already a major source of data on the geology and mineral resources of New South Wales. These existing data when combined with the new data, will greatly enhance the knowledge of and information on the geology and the mineral development potential of New South Wales. This paper discusses some of the existing datasets and outlines how they can be accessed. It also gives an insight into the Department's strategy for data and information technology management.

Jan 1, 1995

By J. H. Daniel

Dust-related respiratory disease remains the major health concern in mining, and health agencies are proposing more stringent standards. The U.S. Bureau of Mines (USBM) is investigating techniques to continuously monitor respirable dust in real-time during the coal or ore extraction process. Continuous monitoring will allow mine operators to evaluate hazardous dust concentrations and adjust the operations to produce less dust. Mine instrumentation applications include machine-mounted and hand-held monitors, personal monitors, and area/environmental monitors. Six dust detection methods have been considered to meet application requirements. These are: light-scattering instruments, a smoke-particle detection technique, correlation of pressure drop across the collection filter with amount of dust deposited, the Tapered-Element Oscillating Microbalance (TEOM) instrument, a method that relates the amount of dust collected on a filter with the vibration of the filter, and beta attenuation measurement of dust. Studies to date have identified the TEOM instrument and the technique of correlating the amount of dust collected with the vibration ofthe filter as having the most promise for success. Development of the machine-mounted monitor is the highest research priority. The application options and progress to date in developing continuous monitoring instrumentation are presented.

Jan 1, 1995

By O. E. Omotoso

This study is part of an ongoing investigation to understand the mechanism of stabilization/solidification of hazardous chromium wastes in ordinary Portland cement (OPC). Tricalcium silicate (C3S*),a major component of OPC is mixed with reagent grade Cr(lll) and Cr(VI) solutions, to simulate complex cementiCr waste systems. Scanning electron microscopy (SEM) and energy disperse spectrometry (EDS) were employed to provide microstructural and chemical information. Transmission electron microscopy (TEMlEDS), apart from complimenting the SEM, was used to probe the distribution of Cr in the hydration products of C3S and to provide crystallographic information. 29Si MAS NMR (magic angle spinning - nuclear magnetic resonance) Was used to characterize the influence of Cr on the hydrated silicate structure.

Jan 1, 1995

By J. A. Brierley

A biooxidation-heap pretreatment process was field tested to evaluate enhancing gold recovery from a preg-robbing sulfidic carbonaceous ore. Newmont Gold Company&apos;s Gold Quarry sulfidic carbonaceous ore was inoculated with an iron-grown culture of Thiobacillus ferrooxidans to form a 495 ton test heap. Biooxidation was conducted for a period of 100 days. The most active period of biooxidation occurred during the first 40 days of pretreatment? About 35 to 40% of the sulfide was oxidized. The extent of biooxidation was considered good as the ore particle size was relatively large 58% >1?9 cm (&apos;/< inch). The larger particle size ore limited the extent of bacterial activity. The field test demonstrated the ability to conduct biooxidation in a small pilot test heap. Thiourea was evaluated for extraction of gold from the biooxidized preg-robbing ore.

Jan 1, 1995

By George S. Austin

Perlite is rhyolitic glass with 2 to 5 percent by weight (wt.%) bound water held within the silicic-glass structure. It is often distinguished by vitreous, pearly luster and concentric perlitic fractures ("onionskin"). Occurrences worldwide are associated with Tertiary to middle Quaternary volcanic rocks. Perlite is in silicic domes, plugs, laccoliths, flows, vitric tephra, chill margins of dikes and sills, and welded ash-flow tuffs. It is a hydrated volcanic glass formed through secondary alteration of obsidian by the incorporation of water into the glass/silica structure. Post-emplacement hydration (weathering) of cooled glasses by meteoric water is the principal alteration process, but some hydration by magmatic or meteoric water during or shortly after emplacement, or hydration by water exsolved during cooling may occur. Commercial "perlite" is any volcanic glass that expands or "pops" when heated quickly to plasticity while evolving steam and thus forming a lightweight, frothy material. The expansion temperature typically ranges from 1,100 to 1,500°F. An expanded volume increase of 10 to 40 times the original volume yields expanded densities of 1.5 to 11 pounds per cubic foot (lbs/ft3). Perlite is mined by eight companies at 10 operations in six western states. New Mexico accounts for more than 80% of the total tonnage mined. The rest comes from Arizona, California, Colorado, Idaho, and Nevada. In 1992, domestic production was 571,000 short tons (st), domestic apparent consumption was 591,000 st, and the value of crude perlite was $15.3 million. In 1991, with about the same production and price of crude perlite, the gross value for expanded perlite was $101.7 million. Perlite exports in 1992, primarily to Canada, are estimated an 30,000 st; and imports, from Greece, are an estimated 50,000 st. In 1992, 70 plants in 33 states expanded crude perlite. Construction uses of expanded perlite accounted for 66% of total domestic sales. Expanded perlite used as filter aid accounted for 15%. All other markets, including use as a filler and in agriculture, accounted for 19%. Leading states for expanding perlite, ranked by order of sales, were Mississippi, Pennsylvania, California, Illinois, and Georgia. Domestic perlite encounters transportation disadvantages in some areas of the eastern United States compared to perlite imported from Greece. However, western U.S. perlite exports to Canada offset this in large part, and net import reliance for perlite is about 3% of domestic consumption. Perlite grab samples were tested at the New Mexico Bureau of Mines and Minerals Resources (NMBMMR) for their basic suitability in horticulture, construction, filter aids, and fillers/extenders using Perlite Institute techniques modified by the NMBMMR. Most commercial perlite ranged from 2.5 to 3.0 wt.% bound water for all major types (classical, granular, and pumiceous). Expanded density varied widely, but the lowest density of 1.9 lbs/ft3 was for granular. Average brightness of expanded perlite was 47.6 to 69.3%. Nonexpansibles, commonly obsidian or "dead" perlite, ranged from 18 wt.% to less than 1 wt.%, with granular perlte generally the lowest. Compacted density was not related to either perlite type or nonexpansibles present. Sieve analyses of the -50+100 mesh product showed that, in general, pumiceous perlite produces more fines and classical and granular perlite average 60 to 80% -30+100 mesh after expansion. Samples were tested for crystalline silica that ranged from below the detection limit of 0.5 wt.% to nearly 0.2 wt.%, but most tested below 0.5 wt.%. Although quartz content can be lowered in the expanded product by the expansion process, producers can further lower crystalline silica in the product by mixing low-quartz crude with high-quartz perlite before expansion. Chemical analysis by x-ray fluorescence confirms the rhyolitic composition of perlite, but indicates that surface weathering may increase the concentration of some elements, such as potassium and calcium, by infilling cracks or fissures developed during or after perlite emplacement.

Jan 1, 1995

By Danny J. Van Roosendaal

An investigation was undertaken to determine hydrogeological effects of subsidence over a longwall coal mine in the Illinois Basin. At this mine, approximately 200 ft of bedrock overburden is overlain by up to 150 ft of glacial till and localized water-bearing glacial sediments within a buried bedrock valley that overlies the longwall panel. A finite-element mechanical model of the subsided longwall panel shows sufficient strain to enhance permeability throughout the bedrock portion of the overburden. However, examination of the actual surface subsidence profile indicates that the overburden deformation is localized in narrow zones at the panel edges. The aquifer units at the base of the glacial sediments are confined by glacial clays (above) and weathered shales (below). Elevated water levels were observed in the glacial aquifers during subsidence, which indicates that the clays and shales maintained confinement as the overburden subsided and deformed. A three-dimensional ground-water flow model was used to simulate the effects of subsidence on the hydrogeologic system and to estimate inflows into the mine. Longwall retreat was simulated by several model runs, each representing a new longwall face position. Simulated heads and mine inflows were calibrated with recorded water levels and observed inflow conditions by modifying the hydraulic conductivity of particular model layers. Model calibration indicates that the permeability of certain lithologies, such as plastic underclays and weathered shales, is not significantly enhanced by subsidence. A worst-case scenario was simulated by inserting a deeply incised, sandfilled valley into the model, which had only minimal impact on the simulated mine inflows.

Jan 1, 1995

By R. D. Irvine

Enhanced concern for protection of the environment and attendant actions by environmental regulatory authorities in support of this concern are influencing to varying degrees the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms. In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States.

Jan 1, 1995