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By Hong Ouyang

A unified computational model has been developed for the Bridgman growth processes of B-NiAI and CdTe crystals. To handle the geometrical and physical complexities, a two-level approach has been developed. At the gtobatlevel, conjugate heat transfer, phase change dynamics, and variable material properties along with the realistic geometries and thermal boundary conditions are accounted for inside the entire crystal growth system. Refined calculations are then made within the ampoule, with the boundary conditions supplied by the global simulations. This model can optimize the use of computational source, help understand solidification behaviors, and improve designs of crystal growth system.

Jan 1, 1996

By Norbert L. Piret

From the copper smelter operation a various outputs are to exert negative impacts on the environment. Particularly, emissions like SO2 and dusts, solid wastes like contaminated gypsum and arsenic sludge, effluents and heated cooling water are generated. Most countries have sitipulated an environmental legislation to provide the framework for an efficient environmental management. As part of the planning activities for x major greenfield copper smelter, the Following elaborations are required and were drawn up. -The Environmental Impact Assessment which is the first step of environmental management and mandatory for every new project. - The Environmental Monitoring Plan, which describes the monitoring procedures for the main impacts identified and assessed. -The Environmental Management Plan, which deals with the minimization of environmental impacts, and the methods of its implementation.

Jan 1, 1996

By A. Davis

Pit lake chemistry depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock versus oxidizable sulfide content, and the alkalinity of recharging ground water. In this paper, we assess the geochemistry of 11 existing pit lakes, ranging from the acidic Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington Pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits with the long-term pit lake chemistry lying on a geochemical continuum between end members consisting of influent calcium bicarbonate ground water, and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1996

By L. R. Nelson

The efficiency and cost-effectiveness of the aluminothermic reduction process in the production of ferro-alloys and 'pure' metals depends strongly on appropriate balancing of the process energy required. Insufficient energy results in a poor metal yield, while over-supply can result in excessive fuming and possibly even ejection of the reactor contents in a potentially dangerous 'thermite bomb' reaction. This situation becomes even more critical when the suitability of limited quantities of oxide from new sources must be evaluated, dictating smaller-scale testwork. The resulting higher relative heat losses from the system complicates control of the energy balance, and usually requires the addition of thermal boosters or reactant preheating in order to sustain an autothermic process. This often detracts from the quality of the metal product, and adds to the hazards of batch aluminothermic- reduction testing. The development of a small-scale method (producing less than 2,5 kg of metal) for the plasma-assisted aluminothermic reduction of chromium oxide that overcomes such difficulties is described. The technique involves the use of a sealed 50 kVA plasma-arc furnace to provide controlled electrical ignition and supplementary energy to the reactants contained in a water-cooled copper crucible. The application of the method to the evaluation of the aluminothermic production of pure chromium metal from a unique chromic oxide source is reported.

Jan 1, 1996

By Takeshi Tanaka, Shinya Ono, Tsuyoshi Kato, Masaji Kato, Yuusaku Tominaga

The knowledge of the macroscopic characteristics of a ventilation network is of fundamental importance for taking counter- measures to increase air quantity in-specified branches, such as those corresponding to working faces at advancing entries or longwall panels. Because the ventilation characteristics are inherent properties of each mine, it takes a long time for an engineer to accumulate experience on how a specific regulator may affect the air quantity in a specific branch of a mine with a complicated ventilation system. A computer-simulation training system, based on the macroscopic ventilation characteristics, is presented in this paper. When a trainee selects a specific condition from five regulator option (closed, almost closed, slightly open, half open, open), the change in air quantity for a network branch is indicated by the color allocated to the ratio of the new air quantity to the old or planned air volume. After the ventilation simulation, the colors in the specified branches are defined by using the fuzzy set theory. The trainee continues practicing the selection of closed/open conditions for different regulators until each of the specified branches is displayed in good state of airflow. The ventilation net- work of the Horonai coal mine is used as an example of the training system to control air quantities in six working faces with 33 regulators.

Jan 1, 1996

Continuing with the effort of providing new and more effective exploration methods to the mining industry, where direct methods (drilling, cross-cutting, etc.) are not applicable, either for logistical or environmental reasons or because they are costly and sometimes ineffective, we present here a new seismic technique based on full wave recording of 3-D channel waves generated within the coal seam across a longwall. In the past two years we reported the application on In-Seam High Resolution Seismic Reflection (ISHRSR) and In-Seam Seismic Tomography (ISST) to map non-coal inclusions that disrupt the coal seam continuity. In the present paper we present a 3-D In-Seam Seismic Tomography (3-DTSST) method using 3-D channel waves recorded by three component high resolution geophones. The method allows to distinguish longitudinal and transversal components of the channel waves, similar to the spheroidal and toroidal modes for the free oscillations of the earth. The recording of these waves allows a more complete analysis of the free modal vibrations of channel waves, permitting a more complete inversion of the structure of the coal seam through which they travel. The full wave analysis provides additional insights of the detailed coal structure for larger, distances than for the ones previously reported using the one dimensional method. The refinement of the inversion software is also a contribution towards the better definition of the coal seam geometry and structures disturbing them such as sandstone channels, sandstone rolls, partings, mine voids, faults, fractures, etc. The method is illustrated with three case studies where subsequent mining revealed the virtues and limitations. The first example deals with the problem of mapping mine works in one side of a longwall panel which geometry is well known, to verify its applicability to map old mine works. The second example deals with a sandstone body that partially scoured the coal seam withing a longwall panel. The third shows an application of the method to map roof conditions in a longwall panel where this problem critically affected production scheduling and costs

Jan 1, 1996

By C. G. Anderson

The treatment of materials for the recovery of the precious metals imposes many processing and environmental challenges. Sunshine Mining and Refining Company has developed hydrometallurgical technology for recovery of values from refractory precious metal materials. At Sunshine, the industrial focus of these processes has been for the direct recovery of silver without cyanidation. However, recent work has indicated that these technologies can provide a means for treating complex, refractory gold concentrates. This will be the focus of this paper. The practice of pretreating ores and concentrates to make them more amenable to cyanidation is becoming more common. Several pretreatment options for sulfide concentrates containing gold include roasting, bio-leaching, direct pressure oxidation and nitrogen species catalyzed pressure oxidation. The industrial use of nitrogen species catalyzed pressure oxidation has been limited to the Sunshine refinery where its focus has been for the treatment of silver concentrates. Much of the reluctance, outside of Sunshine, to use this type of technology may be based on the perception that high costs are associated with using nitrogen species (e.g. nitric acid, sodium nitrite) to leach. Also, the use of nitrogen species catalyzed pressure oxidation on an industrial scale is unfamiliar to most metallurgical professionals. A summary of pressure leaching processes which utilize nitrogen species as a catalyst is presented in Tables 1 and 2.

Jan 1, 1996

By John W. Padan

The 1982 United Nations Convention on the Law of the Sea contains major provisions that U.S. negotiators have sought for over two decades. The internationally recognized right to the mineral resources of a broad continental margin is of potentially enormous future importance to the United States. Although water depths reach 10,000 feet in some of the deeper areas of the margin, technology is rapidly making those depths economically accessible. In 1997, production in the Gulf of Mexico will reach a world record water depth of 5400 feet. Of perhaps even greater importance to the oil and gas industry is the broadly acknowledged right for tanker transport of oil to take place throughout all parts of the world's oceans.

Jan 1, 1996

By C. Lupi

Electric arc furnace dust generated during the production of steels is regarded as hazardous waste because of the presence of leachable elements such as Cr, Pb, Cd .... Different processes are available according to the management policy chosen by the steelmaker: disposal. recycle and/or recovery. The feasibility of an hydrometallurgical Zn recovery process on fumes generated during the pyrometallurgical treatment of EAF dust has been investigated. The recovery of metallic iron, chromium and nickel as molten metal provides fumes very rich in zinc oxide ( 63.1% ) and poor in zinc ferrite. This secondary dust is still an hazardous waste and represents the raw material for the recovery of Zn and Pb. The waste material is first leached in 1.5 M sulphuric acid at 30°C to provide a Zn, Fe and Mn rich aqueous solution and a Pb and Ca sulphate rich sludge. The iron is eliminated by precipitation because is harmful to the following electrowinning process. The ftltered and purified leached solution is acidified in order to obtain good electrowinning conditions. A pure cathodic deposit of zinc is then produced in an electrolytic cell at laboratory scale.

Jan 1, 1996

By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By F. W. Petersen

The Conference Minerals & Materials '96 was held in Somerset West, South Africa, from 31st July to 2nd August, 1996. It was organized by the Universities of Stellenbosch and Cape Town, the Cape Technikon, and the Western Cape Branch of The South African institute of Mining and Metallurgy (SAIMM). The three-day Conference was attended by 180 delegates, representing countries such as Australia, South Africa, United Kingdom, Finland, Sweden, Germany, Poland, Zambia, and Zimbabwe. The programme and associated exhibition were well organized, and each of the delegates received two volumes of proceedings containing the 77 papers presented at the Conference.

Jan 1, 1996

By T. K. Mukherjee

The importance of the processing of secondary resources such as solid industrial wastes and liquid effuents as well as byroducts for the recovery of the associated metal values hardly needs any elaboration. Such processing contributes in no small measure.towards the augmentation of the availability and the supply position of resources. As an added benefit, it leads to a reduction in environmental pollution caused by the undesirable waste materials. As some typical examples of secondary resources in the Indian scenario, mention' can be made of spent catalysts, metal/alloy scrap, ash, consumed batteries, flue dust, slag, sludge and slime, pickling solutions, spent acids; plating rinse solutions, spent etchants, waste water from synthetic fibre manufacture and from tanneries etc. These wastes constitute a source of a variety of non ferrous metals. In the processing of secondary resources like these, the techniques of hydrometallurgy such as solvent extraction play a pivotal role. This paper outlines the efforts made to use solvent extraction to recover (1) base metals such as copper, zinc, nickel and cobalt from a number of secondary resources like cake, and sludge(2) refractory metals like molybdenum and vanadium from sulphidic, byproducts and spent catalyst and (3:) nuclear metal like uranium from phosphoric acid. In the case of base metals, process flowsheet involving the use of acidic extractants such as DEHPA and PC88A have been optimised. The problem of iron removal from the leach liquor, "which influences the metal recovery process significantly, has drawn a special emphasis. hi the case of refractory metals, basic extractants .like Alamine 336 has been pressed into service to produce kilogramme. quantities of pure salts of molybdenum and vanadium, Finally, the paper gives a brief account of plant experience in recovering uranium from phosphoric acid, using 'a solvent system comosed of DEHPA and TOPO.

Jan 1, 1996

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Thomas M. Barczak

With the development of the shield support, the primary requirement for successful ground control in longwall mining is to provide stable gate road and bleeder entries. Wood cribbing has been the dominant form of secondary support. However, the cost and limited availability of timber, along with the poor performance of softwood crib supports, has forced western U.S. mines to explore the utilization of other support systems. The recent success of cable bolts has engendered much interest from western operators. Several innovative freestanding support systems have been developed recently including: (1) "The Can"' support by Burrell Mining Products International, Inc., (2) Hercules and Link-N-Lock wood cribs and Propsetter by Strata Products (USA) Inc., (3) Variable Yielding Crib and Power Crib supports by Mountainland Support Systems, (4) the Confined Core Crib developed by Southern Utah Fuels Corporation; and (5) the MEGA prop by MBK Hydraulik. This paper assesses design considerations and compares the performance and application of these alternative secondary support systems.

Jan 1, 1996

By L. Petitnicolas

The experimental study of nitrogen absorption and its removal from a liquid Ni-20%Cr alloy at 1873 K has been undertaken, using an experimental, apparatus based on the Sieverts technique in order to determine the solubility of nitrogen in the alloy. as well as the kinetics of nitrogen transfer across the gas/melt interface. Experiments show that nitrogen solute equilibrium content can be calculated using the Sievens law. Measurements point out the nitrogen absorption reaction rate to be well described by first order kinetics, whereas experiments on nitrogen removal reveal that the rate is better expressed using a second order equation.

Jan 1, 1996

By Paterson M. R, Spencer P. A

Vitrokele technology is a resin process that can be applied in gold plants to reduce both capital and operating costs. The Vitrokele resin can be used for both precious metal recovery and for recovering free and combined cyanide from effluent streams. Vitrokele resin has been extensively tested at pilot plant level and is now applied successfully at a commercial heap leach facility in Zimbabwe where it is used in place of activated carbon for recovery of gold from pregnant leach solution. Significant capital cost savings were achieved by installation of a resin plant instead of a conventional carbon adsorption plant. Operation to-date has not seen any significant physical or chemical degradation of the resin either in terms of adsorption capacity/kinetics or physical appearance/size. This gold recovery process is equally applicable to slurry streams where it would be implemented in stirred tanks with interstage screens in a similar manner to a conventional carbon adsorption plant.

Jan 1, 1996

By Makoto Suzuki

After hot rolling, stainless steel strip is processed by the Hot Rolled Annealing and Pickling line (HAP) , where H2SO4 or mixed acid of HNO3 and HF is normally used. In the pickling bath, metal oxide accumulates in the form of sludge, which should be removed from the bath regularly. A new automatic continuous sludge disposal system has been introduced at Chiba Works of Kawasaki Steel Corporation to increase sludge removal efficiency and improve the working environment. The elements of the equipment are as follows. a. Ejectors in pickling bath: to carry the mixed acid into the circulation tank through the piping system. b. Sedimentation bath : to sediment sludge out of the bath. c. Skip conveyer : to convey a specified volume of sludge into a kneading for device for neutralizing. The sludge removal efficiency of this system is very high. and the volume of sludge accumulation in the pickling bath has substantially decreased.

Jan 1, 1996

By G. R. Dasari

New Austrian Tunnelling Method (NATM) has been analysed by Finite Element method in two and three dimensions by Strain Dependant Modified Cam Clay (SDMCC) Model. The effects of construction sequence, stiffness of shotcrete and time dependency of shotcrete on surface settlement magnitude due to the NATM have been studied. Settlements obtained in 2D analysis, as expected, found to be more than the observations. The surface settlements obtained in 3D analysis found to be about 3 times less than equivalent plane strain analysis. This is due to mobilisation of soil strength around the tunnel face and soil-tunnel lining interaction. About 40% settlements occurred due to excavation of face at the monitor section and 60% after the excavation crossed monitor the section.

Jan 1, 1996

By Y. C. Guan

In an attempt to replace the traditional cyanide process of extracting gold, a new technology using ammoniacal solutions has been developed. In this study, the electrochemical behavior of gold in ammoniacal solutions at temperatures above 100°C has been investigated. An electrochemical cell in an autoclave has been introduced to carry out this study. The system consists of a gold working electrode, a platinum counter electrode, and an external saturated calomel electrode (SCE) which is connected to the autoclave system through a Birch wood plug. Techniques used in this study included potentiodynamic polarization, galvanostatic polarization, cyclic voltammetry, and Tafel polarization. The electrochemical reaction mechanisms governing the dissolution process are presented.

Jan 1, 1996

By T Michael LeBlanc

Drill trajectory deviation is a recurring problem in vertical retreat stoping operations. As a result of this deviation, 60 kilogram (165 millimetre diameter) and 103 kilogram (302 millimetre diameter) explosive charges are routinely detonated beyond ore/waste contact zones. Consequently, there follows a reduction in finished stope wall stability and an increase in ore dilution.

Jan 1, 1996