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By Jan G. H. du Preez, C. Viviers, B. J. A. M. van Brecht, H. E. Rohwer, Nicole M. Sumter

"At the basis of metal ion separation lies some particularly metal ion specific chemical property which lends itself towards exploitation. This could be in the form of an anionic complex or a neutral chelate complex. In the former a cationic centre with a particularly high affinity for the complex will have to be designed. In the latter case a stereospecific chelate ligand containing the correct symmetry and type of donor atoms will have to be designed. In both above cases the ""active centre"" can be entered in a from that it can function in different media of hydrophobicity, eg a precipitant, a resin or a solvent extractant. Recent results obtained in this laboratory will be used to illustrate how the above variables can be exploited to develop improved processes for the separation of base metal and platinum group metals.IntroductionThe separation of metal ions in hydrometallurgy can be performed broadly speaking with two major aims. Firstly the separation/removal of a certain group of metal ions, either as a means of preconcentration or as a removal from effluent as part of a purification process and, secondly the removal of a specific metal ion from an industrial stream in order to produce a specific metal in a pure form. This latter operation is by far the most difficult of the two and is becoming more so in the light of the fact that the world is moving in the direction of lower grade ores and increasing pollution. Such a process can be divided into three essential parts, firstly the molecular one in which an active centre is required to obtain specificity, secondly a matrix within which this active centre must function, i.e. as part of a resin or solvent extractant and thirdly the design of the total system to optimize the realization of the operation."

Jan 1, 1996

By Abou Saghafi

In order to investigate the design parameters of a future longwall in a thick coal seam a numerical model of gas emission from the goaf area was developed. A Longwall goaf was modelled as a collection of different size coal blocks. For each coal block the partial differential equation of gas flow was independently solved. In developing the flow equations, both pressure-driven and diffusion driven gas flow regimes were considered. The total gas emission rate was calculated by integrating the gas release from each individual coal block over the whole goaf area. The main output of the computer program are gas flowrate from goaf and residual content of caved coal in the goaf as a function of distance from the face. The model was applied to a longwall face driven in a thick seam where large volumes of coal in the roof were to be left behind the face. The gas contained in the coal was mainly CO, with a high desorption rate. Simulations were under- taken to quantify the effect of size of the caved coal on the flowrate from the goaf. The flow properties of coal, such as diffusivity, permeability and coal swelling due to gas adsorption, were directly measured on coal samples from the seam.

Jan 1, 1996

The Ocean Drilling Program is the largest international geoscience project in the world, and the state-of-the-art drill ship, the JOIDES Resolution, is permanently at sea. Each year there are six scientific cruises (Legs) which each last approximately two months. These legs are designed by geoscientists from the 19 countries that subscribe to ODP. Australia and Canada share ODP membership under the banner of the AUSCAN Consortium. The Australian Secretariat of the ODP is housed at the Department of Earth Sciences at James Cook University, along with the AUSCAN Consortium office. The Canadian Secretariat is presently based at the University of Toronto. Both secretariats have major research interests in the ore deposits, both ancient and modem, and so there is currently a major drive by the AUSCAN ODP Consortium to make available data and technological information to the minerals industry. This type of information includes data from drilling hydrothermal sites such as the hydrothermally active TAG black smoker complex on the Mid-Atlantic Ridge, drilled during Leg 158, and the Middle Valley sulphide deposit, on the northern Juan de Fuca Ridge, which was drilled during Leg 139.

Jan 1, 1996

By K. Osseo-Asare

"The molecular structural and solution chemical characteristics that underlie the surface activity of solvent extraction reagents are highlighted, with particular emphasis on the tendency towards reverse micelle and microemulsion formation. The physicochemical factors that lead to microemulsion-enhanced solvent extraction with chelating extractants are elucidated. Membrane-based contactor systems are described which are uniquely suited for enhanced solvent extraction with microemulsions. The possibility of combining solvent extraction with microemulsion-mediated materials synthesis is discussed. IntroductionThe discovery of new selective extractants has resulted in major breakthroughs which have helped to establish solvent extraction as a versatile separation technology (1-3). A complementary strategy towards new process development is to seek new ways of using the available reagents. This paper explores this second approach. From a molecular structural standpoint, an extractant may be viewed in terms of two components: a polar functional group and a hydrocarbon radical. In the conventional view of solvent extraction, this molecular structure serves two main purposes: The polar functional group provides the binding sites for complexation of metal ions, while the organic group is needed to render the resulting metal-extractant complex organic-soluble. But are these the only properties of the organic and the polar groups that are relevant to the solvent extraction process?In this paper, attention is directed to the fact that solvent extraction reagents possess the molecular structures of amphiphiIes; that is, they are characterized by the presence of spatially separated hydrophilic and hydrophobic groups on the same molecule. A case is made for the view that this amphiphilicity offers interesting opportunities to develop new separation processes which collectively may be described as enhanced solvent extraction (4-6)."

Jan 1, 1996

By Maurice Bottiau

The recent evolution of the piling market clearly shows a growing demand for screw piles with soil displacement. The recently developed Omega Screw pile ful-fill these new expectations, combining the advantages of vibration-free systems and the behaviour of a displacement pile. The paper describes recent experience and new applications with this very promissing pile. Full-scale load tests were carried out in different countries as U.K. or Sweden. A very attractive and innovative piled embankment is also described, using geogrids in order to transfer the loads from the superstructure to non-reinforced Omega-piles.

Jan 1, 1996

By Stephen A. Rholl

Computer software has been developed which uses fast Fourier Transform (FFT) techniques to analyze the frequency spectrum associated with peaks in ground vibration time histories. The procedure consists of filtering the FFT of a time history into individual frequency components.

Jan 1, 1996

By Robert C. Pease

Siskon Gold has started gold production at the San Juan deposit in northern California. The mine is located about 27 km (17 miles) north of Nevada City, CA (Fig. 1). It is scheduled to be-come the largest underground gold mine in California. It is situated in the western foothills of the Sierra Nevada Mountains in the Mother Lode gold belt. The property consists of 8 km2 (2,000 acres) of patented land. It is situated in a topographically high area known as San Juan Ridge, which is 213 m (700 ft) above and between the Middle Yuba and South Yuba rivers. The elevation is between 790 and 914 m (2,600 and 3,000ft) above sea level. Annual precipitation averages 1,346mm (53 in.). Most of that falls between November and April.

Jan 1, 1996

To provide accurate navigation and control of continuous mining systems.

Jan 1, 1996

By Jim Daley

This case history discusses a pre-split test conducted at BHP Mineralss Navajo Mine in Fruitland, New Mexico. The test was an extension of earlier pre-split testing conducted by Virgil Stachura of the U.S. Bureau of Mines in conjunction with Navajo Mine and WESCO Inc. which tested low-density product in 10.625 diameter holes.

Jan 1, 1996

By M. B. Cortie

The historical development of materials engineering in the mining industry Is briefly reviewed, and some of the factors currently influencing the industry in South Africa are discussed. Material usages in various parts of the mining operation are surveyed. The predominant mechanisms in the degradation of materials in mines are wear, corrosion, and fatigue. The issue of corrosion-abrasion Is considered, but it Is concluded that abrasive wear predominates in most rock-handling and comminution applications and that, in general, little economic benefit Is to be gained in those applications by the use of existing corrosion-resistant alloys. However, alloys with a measure of corrosion resistance find profitable application elsewhere in the mining environment. The use of other engineering materials such as polymers, ceramics, al1l1inium, and various ferrous alloys may be economically viable in a variety of niche situations. Identification of the most cost-effective material in each case calls for a systematic approach and some patience.

Jan 1, 1996

By Hall S, Upton D

WMC Resources Ltd nickel operations have expanded significantly over the last three years. Production capacity has increased at mine/concentrate, smelting and refinery processes to such an extent that WMC now ranks within the top three or four producers of nickel metal in all forms. The stainless steel industry remains the dominant user of nickel. WMC's forecast is for stainless steel production to grow at 2.8 per cent per annum off of the 1995 peak, with much slower growth in the short-term as the stainless steel inventory overhang unwinds, followed by a return to higher trend growth rates. WMC's forecast for the long-term growth in demand for primary nickel is three per cent per annum off the 1995 peak; again, slower growth in the short-term before a return to higher long-term trend rates. This projection is towards the optimistic end of the range of industry experts. It equates to a requirement for new primary nickel of 25 000 to 30 000 tonnes of annual capacity each year.

Jan 1, 1996

By Hye-Sung Kim, Dong-Wha Kum, Gyeungho Kim

"Mechanical alloying is an effective way to finely distribute inert dispersoids in AI-TM (TM is a transition metal element) systems. It is considered that high melting point aluminides are formed by precipitation from the supersaturated aluminum matrix. The analysis is based on the fact that much higher content of TM than the solubility limit can be dissolved in alpha aluminum during the high energy ball milling. Nonetheless, the role of undissolved TM particles affecting the formation of aluminides is not suitably considered. In this paper, authors present experimental observation on the formation of Ab3Ti particles from mechanically alloyed AI-Ti alloys in the hyper-peritectic region. This study showed that, in the mechanically alloyed AI-20wt%Ti specimen, intermediate phase of cubic Ab3Ti and tetragonal AIz4Tis formed at 300 - 400°C and 400 - 500°C, respectively, before the MA-state reaches to the global equilibrium at higher temperatures. The formation behavior of Lh- Ab3Ti is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiating the formation of Ab3Ti phase during annealing.IntroductionInterest in the hyper-peritectic AI-Ti alloys is based on industrial demand for high-modulus and high-temperature aluminum alloys. Earlier works on hyper-peritectic AI-Ti alloys with 4 to 12wt%Ti show that these alloys are strong at ambient temperature and maintain high strength above 300°C when titanium-trialuminide (e.g., Ab3Ti) is finely distributed in the aluminum matrix [1,2]. High melting point and high stiffness with low density of AbTi make the AI-Ti alloys strong with greater thermal stability while keeping weight savings as much as possible. Titanium in aluminum shares other merits of transition metal additions because Ti solubility in Al is low (i.e., 1.l5wt%Ti at 665°C and virtually zero below 400°C), and fine dispersion of Ab3Ti particles is readily accomplished and resists grain coarsening effectively."

Jan 1, 1996

By Thomas Fenner

Surface and underground mining operations are often hindered by unknown tunnels and slopes and the precise locations of adjacent workings. Mine safety and planning are adversely affected especially in previously undermined areas where historical records are incomplete or nonexistent. The results of several ground penetrating radar (GPR) studies for the detection of known mine tunnels in underground coal, salt and gold mines are presented. A case study to locate unknown, abandoned mine workings at a surface gold mine successfully located all workings to a depth of 11 m (36 ft).

Jan 1, 1996

By Funsho K. Ojebuoboh

With several “green” applications on the horizon, bismuth has become an even more important minor metal in the smelting and refining of lead. Smelters with a complex sulphide feed invariably deal with bismuth. Its behavior during the smelting of lead in conventional sinter-blast furnace operation is discussed. Because it readily deports to the lead phase during the refining of lead, its separation from refined lead remained unsatisfactory in early lead production. When commercial requirements of bismuth in lead became more stringent early this century, the procedure where by calcium and magnesium is used todebismuthise lead was developed. The present conduct of this 1936 process, the Kroll-Betterton process, is discussed with emphasis on operational improvements.

Jan 1, 1996

By J Lyall Workman, Peter N. Calder

Large hole rotary drilling is one of the most common methods of producing blastholes in open pit mining. Large hole drilling generally refers to diameters from 9 to 17 inch (229 to 432 mm), however a considerable amount of rotary drilling is done in diameters from 6½ to 9 inch (165 to 229 mm). These smaller diameters are especially prevalent in gold mining and quarrying.

Jan 1, 1996

Jan 1, 1996

By Animesh Jha, Catherine Davey

"Carbothermic reduction and nitridation reactions using synthetic kaolinite mineral were investigated for the formation of silicon based nitrogen ceramics. The temperature dependence of the reaction rate and its effect on phases formed are reported. The effect of the reactivity of carbon on the kinetics of formation of AIN and ShN4 is discussed. Using the standard Gibbs free energy values for the formation of nitrides and oxides of aluminium and silicon, a log po2 verses I/T diagram is constructed. The experimental data results are discussed and compared with the predicted phase equilibria. We also report the influence of sub-oxide gaseous species on the microstructure of the ceramic phases produced.IntroductionSynthetic kaolinite is a clay containing alumina, silica and water of crystallisation, and has a chemical formula 3(Al2O 3.2SiO2.2H2O). This mineral is relatively inexpensive and, is therefore an ideal candidate for use in the production of ceramic powder mixtures for example silicon nitride and aluminium nitride for composite material formation, When the mineral is heated, the water of crystallisation from the crystal lattice is lost via the 3(Al2O 3.2SiO2.2H2O) = 3(Al2O3.2SiO2) + 6H2O reaction. It has been shown [1·2j that on further heating to 1673K, the anhydrous kaolinite decomposes to a mixture of mulllte and silica, 3(Al2O3.2SiO2) = 3Al2O 3.2SiO2 + 4SiO2 which is consistent with the alumina-silica phase diagram, shown in figure 1.The binary alumina-silica phase diagram has a well-defined sub-eutectic immiscibility dome and this characteristic dernixing behaviour is reflected in the thermal decomposition of anhydrous kaolinite consequently the microstructural features resemble the spinodal decomposition process. It is well established that the spinodal decomposition process raises the nucleation frequency due to their low free energy barrier, (?G). The small magnitude of this barrier consequently promotes the evolution of a very fine microstructure. The process of spinodal decomposition is therefore expected to be influential during the reduction-nitridation of kaolinite minerals."

Jan 1, 1996

By J. C. Yingling, R. J. Sweigard, S. T. Mickleborough

The geostatistical technique of conditional simulation is applied to measure the uncertainty inherent in the factor-of-safety (FS) predictions for soil slopes in which there is an incomplete knowledge of the spatial distribution of soil properties. A case study that considers a natural clay slope in Canada is presented. The sequential-indicator simulation technique was used as a means of generating a series of spatial maps of the soil properties at the site. These maps approximate random draws from the conditional probability density function that characterizes existing uncertainty in the spatial distribution. FS determinations were made for each simulated map using the simplified-Janbu approach. In using this approach, computations are performed using a new computer program that can operate on irregular spatial profiles of soil properties specified on a discrete grid. A unique capability of this approach is the ability to generate the FS distribution conditional to the type, position and value of existing site-characterization measurements. This capability should reduce uncertainty in FS predictions.

Jan 1, 1996

By E. R. Torak

Custom Coals, International has installed and is presently testing a 225 kg/hr. (500 lb/hr.) micronized-magnetite, fine-coal cleaning circuit at PETC's Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program's High Efficiency Preparation Subprogram. The project includes design, construction and testing of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense-medium cycloning of the 300 by 30 micron feed coal using three different size micronized-magnetite mediums, and medium recovery circuits using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

Jan 1, 1996

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996