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By Robert W. Bartlett, Keith A. Prisbrey

"Natural biooxidation of shallow, refractory ore heaps, relying on gaseous oxygen diffusion from the heap surface is attractive because of its simplicity and potential low cost, especially without using a lined pad, which is possible if percolation of leachate through the heap is avoided. In this case, the excess oxidation enthalpy must be removed by water evaporation from within the wet ore heap, and the rising water vapor flux within it will impede the downward oxygen flux. An analysis of this process shows that for typical values of pyrite grades and limited temperature increases in the ore heap, the oxidation rate and penetration into the heap is reduced to values between about 30 percent and 50 percent of those obtained when leachate percolation occurs and water evaporation is not a significant mechanism of heat removal.IntroductionHeap biooxidation of refractory gold ores, needed as a pretreatment step to liberate the gold for subsequent extraction by leaching, requires large amounts of oxygen for the normal amounts of sulfide minerals that are typically present, one to two percent pyrite and/or arsenopyrite.The importance and potential limitations of oxygen transport into commercial ore heaps, which are much larger than encountered with column tests of ore and with pilot heaps, has been recognized111 • Commercial ore heaps using radial stacking conveyors are typically about nine meters high and may be 100 meters or more in lateral dimension. Three oxygen transport mechanisms have been identified and analyzed: ( 1) natural convection, which arises from an increase in buoyancy caused by the temperature rise and gas composition changes associated with the exothermic oxidation of the sulfide minerals within the ore heap, (2) forced air ventilation, using low pressure fans and air distribution pipes within the heap, and (3) diffusion of oxygen in the gas-filled void spaces within the ore heap driven by the oxygen concentration gradient from the surface of the heap to the mineral oxidation loci within it."

Jan 1, 1997

By M. Arenas

A corrosion study of a bonded NdFeB permanent magnet materials alloyed with titanium carbide additions has been undertaken. The materials were produced by rapid solidification by melt spinning. Commercial epoxy was used as a bonding medium. The corrosion results were compared with those of a near stoichometric unalloyed NdFeB. Anodic polarization and potentiostatic techniques in 0.9 M Na2SO4 solutions were used to characterize corrosion behavior. It was found that the addition of 6 a10 Tic resulted in superior corrosion resistance, as indicated by lower corrosion currents and less iron dissolution at fixed potential.

Jan 1, 1997

The importance of orebody definition and optimisation in project development cannot be overstated. Inappropriate orebody definition is the single most important reason for project under performance and/or failure. Without the firm foundation of good orebody definition, the structure of a project cannot be assembled reliably. Many factors need to be considered in the process of orebody definition. These factors are well summed up in paragraph 123 of The Institute's Code and Guidelines for Assessment and Valuation of Mineral Assets and Mineral Securities (Valmin Code). The factors range from the initial geological data through assaying, geotechnical and hydrogeological factors to mining and metallurgical considerations. There are other factors which also need to be considered including marketing and environmental factors. This paper briefly reviews some of these factors and their impact on project development. Three examples are presented where one or more of these factors have had significant impact on the development of the Project.

Jan 1, 1997

By E. V. Konopleva, H. J. McQueen

"The isothermal bainite transformation kinetics of low- and medium-carbon alloy steels after hot deformation and the rmocycling treatment (TC) has been studied by the magneto - metric method. Deformation was produced by rolling at 800°C-1000°C. TC included three cycles of rapid (30°C/s) electro-heating up to 900°C-1000°C followed by quenching.Hot deformation retards bainite transformation in the lower part of bainite range (<400°C) and accelerates it in the upper part (>400°C). The effect is greater for higher strain and lower deformation temperature. Deformation also diminishes the overall bainite fraction below 400°C and increases the completeness of reaction above 400°C.Thermocycling provides more uniform ultrafine austenite grains with average size of 3 µm -4 µm compared to 12 µm -14 µm after conventional heating. The transformation rate after TC was almost the same as after conventional heating in low-carbon steel but was faster in medium-carbon with no change in the completeness of reaction. The degree of acceleration increased with rise of transformation temperature.There are a number of factors which are responsible for a change in bainite transformation kinetics in austenite deformed at high temperatures or subjected to TC. One of the most important factors is the refinement of structure, another one is structural and chemical inhomogenity of austenite due to deformation or to rapid heating. To estimate the contribution of these factors, ?-transformation was studied after different austenitizing conditions (low-temperature heating at 850°C- 950°C; high-temperature heating at 1100°C; step treatment – austenitizing at 1100°C, then cooling to 950°C-850°C). The results obtained make it possible to conclude that the structural and chemical inhomogeneity of austenite activate the bainite reaction while the grain refinement retards it. Intensity of the effect produced by each factor depends strongly on the steel composition."

Jan 1, 1997

By P O. Koons, R J. Norris, S C. Cox

&nbsp;The Southern Alps is an active oblique collisional zone which has a characteristic wedge-shaped geometry above a low-angle ductile shear zone. The Main Divide region is a relatively low strain zone above this ductile shear zone, and is _deforming principally along steeply dipping strike-slip faults. Extensional fractures are common at a high angle to the regional structural trend. These steeply dipping structures act as conduits for gold-bearing fluids from depth, and small mesothermal gold deposits have formed at several structural levels including the near-surface region. Gold has also been deposited in a meteoricmetamorphic fluid mixing zone near a conductive thermal anomaly on the western slopes of the mountains. These various gold deposits and their well-constrained structural and tectonic settings can be used as analogues for larger, deeper-eroded mesothermal gold deposits in the Mesozoic Otago Schist belt. High level Miocene veins in NW Otago have formed beneath the main divide of the initiating Southern Alps. Late metamorphic gold-bearing veins formed as fluid escaped from the ductile-deforming crustal root beneath Mesozoic mountains. &nbsp;

Jan 1, 1997

By K. C. Liddell

"Cu/Ni multilayers exhibiting giant magnetoresistance were deposited from a single electrolyte under stepped potentiostatic control. To enable transport measurements to be made without remounting the multilayer film, we developed a novel method that involved plating on a thin metallic basal layer atop a rigid non-conducting Si substrate. Rotating ring-disk electrode techniques were used to monitor the composition and thickness of individual plated layers. Transmission electron microscopy confirmed that the interfaces between adjacent layers were sharp and that the structure of the layers was uniform throughout the film. Atomic force microscopy images indicated that the film's surface was smooth and free of defects.ELECTRODEPOSITION OF THIN MULTILAYER MAGNETIC MATERIALSI. IntroductionElectrodeposition of compositionally modulated films will in all likelihood continue to be used to produce the read heads for stored magnetic data. However, the next generation of head materials will require both improved sensitivity and reduced film thickness. Certain multi layers consisting of thin alternating ferromagnetic and nonmagnetic layers exhibit giant magneto resistance and consequently are promising candidates for read head applications. We have successfully made multilayer films with giant magnetoresistance that have total thicknesses as low as 25 nm, approximately 120 times thinner than the thinnest similar films reported in the literature. This paper describes early results from our work on electrodeposition and characterization of Cu/Ni multilayers, a model system with enhanced magnetic and mechanical properties, including the GMR effect. The structure and composition of the multilayers were determined using TEM, AFM, and electrochemical methods, and their magnetoresistance was measured by the standard four-probe technique. A novel method developed in this work enabled the transport properties of the ultrathin films to be measured reliably without the need to dissolve the cathode or handle the films. To provide a context for these results, short accounts of other work on giant magnetoresistance and multilayer electrodeposition are also included."

Jan 1, 1997

By S. M. Jarrett, W. B. Schmidt

Within the last year, the Nation has been shocked by two major tunneling disasters. Almost exactly a year ago 17 men died in the San Fernando Tunnel in an explosion attributed to gas. A few months later another 21 men died in an explosion laid to the same cause at Port Huron, Michigan. The analysis of the causes of these accidents is still continuing. While it appears that they differ substantially from each other in their specifics, they share the common trait that, like most industrial accidents, they might well have been prevented. Gas explosions in tunneling are neither new nor particularly unusual. Forty years ago, Assistant Director Jarrett was hired as a safety engineer on the Hetch Hetchy Aqueduct in California after an explosion that killed 12 men. Prior to 1946, in California alone, the Bureau of Mines had recorded 27 gas explosions incidental to hard rock mining and tunneling. The purpose of this paper is to review the status of the principal regulations affecting tunneling and to indicate some ways in which safer and more healthful conditions can be obtained. The Bureau of Mines was established by an Act of Congress of May 16, 1910. Since that time the Bureau has been making investigations and compiling and publishing health and safety data relating to mining and to tunneling. If any benefit is to come from an anaylsis of tunneling accidents, it must be the knowledge needed to prevent their repetition. The Bureau of Mines has also had informal discussions with the Department of Labor regarding the possibility of the Bureau&apos;s assuming that agency&apos;s responsibility for tunnel inspections.

Jan 1, 1997

By Rod Samuels, Rupert Allen, Thomas Harper

"Viceroy Resource Corporation of Vancouver, B.C., has recently developed and brought into production the Brewery Creek Mine, an open-pit heap leach gold mine, located 55km east of Dawson City in Yukon, Canada. Mineable reserves are 15.2 million tonnes of ore grading 1.45 grams/tonne, containing 22 tonnes (707,315 oz) of gold. Ore processing employs the heap leach technology using run-of-mine ore. Highlights of 1996 activity included construction of a 158,000 m2 of leach pad, placing 1.9 million tonnes of ore at a grade of 1. 46 gpt to the leach pad, construction and successful commissioning of the ADR plant, and pouring of the first gold bar on November 15th.Permitting of this mine has drawn significant attention because of the innovated heap leach technology; although this technology has been proven in other jurisdictions, it has not been used at such extreme northern sites where winter temperatures routinely reach -45°C for extended periods.ABSTRACT ONLY"

Jan 1, 1997

By G. L. Finfinger, F. E. McCall, A. A. Campoli, M. D. Zuber

Injecting pressurized water into a coalbed prior to mining reduces mining-generated respirable dust. Because of economic and geological barriers, water infusion for longwall dust control in the United States is now limited to the Pocahontas No. 3 Coalbed in Virginia. Water is pumped into the coalbed through underground boreholes that are drilled horizontally from the headgate toward the tailgate side of retreat longwall panels. This paper theorizes that the barriers to widespread utilization of water infusion for longwall dust control could be overcome by long-duration, low-pressure water infusion through vertical gob-gas boreholes. Currently, 43% of the 72 longwall mines in the United States employ vertical gob-gas boreholes. Computer coalbed-reservoir simulation suggests that one vertical surface borehole could infuse the same longwall panel area as four horizontal boreholes in the current water-infusion system for longwall dust control in the Pocahontas No. 3 Coalbed.

Jan 1, 1997

Cyanide is a significant contributor to the cost of producing gold. Any reduction in cyanide consumption that is achieved through more reliable measurement, and/or more efficient management of cyanide dosing rates, can produce a significant financial saving to the mine operation.

Jan 1, 1997

By C. A. Pickles, D. K. Xia

"In the last few decades, microwave energy has been widely employed in food processing, rubber and plastics curing, and in ceramic sintering. Recently, the application of micro waves as an energy source in extractive metallurgy has received considerable attention from a number of researchers. During the period from the mid-1960s to about 1988, the majority of the research was focussed on the behaviour of materials in microwave radiation. These research activities will continue to be important, since fundamental data on the interaction of microwaves with materials are vital for the successful application of the technology. Since1990, a number of potential applications of microwave processing have been investigated.These include: pretreatment of ores and concentrates, leaching, reduction, preheating of refractories, heating of slags and waste treatment. In this paper, the interaction of micro -waves with materials of interest in extractive metallurgy are reviewed and potential applications are discussed.IntroductionMicrowaves were first used in 1946 for the heating of materials, shortly after radar equipment was invented during the second world war. It was evident that microwaves were very effective for heating water and the technology was quickly adopted for drying and cooking. Since the introduction of the first microwave oven by Raytheon in 1952, many millions of domestic microwave ovens have been sold annually (National Research Council,1994; Atomic Energy of Canada and Voss Associates Engineering, 1990).In extractive metallurgy, microwaves are in the early stages of development (National Research Council, 1994; Atomic Energy of Canada and Voss Associates, 1990; McGill and Walkiewicz, 1987; Bradhurst and Worner, 1990;Peng et al., 1993). However, there are several reasons for the growing interest in the use of this technology in the field of metals extraction. These include the following potential advantages of microwaves: (1) rapid and selective heating of materials; (2) reactions can be catalyzed because the heating occurs on a molecular or atomic level; (3) clean and controllable energy source; (4) the gas volume is reduced and the atmosphere can be controlled as there are no gaseous combustion products; (5) the material is heated internally in comparison to external heating with conventional methods; (6)the temperature of the refractory can be minimized; and (7) the working environment is improved."

Jan 1, 1997

By R L. Keller

Hong Kong has some of the most restrictive practices regarding blasting than any place in the world. Regulations regarding vibration limitations are 1 in/sec for structures and 0.5 in/sec (or even less) for most utilities; with no recognition of frequency response or adjustment. The Hong Kong Geotechnical Engineering Office has one of the most conservative approaches and protective guidelines for pre-blast assessment of slopes subjected to blast vibration (SEE paper '96). The protective measures to control flyrock generally required by the Mines Division are additionally very stringent. It is not uncommon for the costs associated with protective measures or methods which must be employed to exceed the cost of the drilling and blasting itself - or to waiver blasting application unfeasible altogether. From these restrictions it can easily be imagined how blasting in this urban environment would be most challenging.

Jan 1, 1997

By R. F. Korcak

There exists a wide array of industrial byproducts that produce beneficial responses in the soil/ plant environment. These materials range from clean-coal-technology residues produced during the generation of electric power (particularly those high in gypsum) to mineral fines produced by the aggregates industry (i.e., sand, gravel and crushed stone). A number of these materials are examined in relation to potential nutritional interactions in soils and crops with emphasis on trace elements. The significance of utilizing these materials in agriculture as a component of sustainable agricultural systems are discussed.

Jan 1, 1997

By V. L. Stolyarova

The high-temperature Knudsen effusion method was used to study partial pressures of vapour species, activities of components and the Gibbs free energies in the DyF3-Dy2O3 system at the temperature (1357±5) K. Partial pressures of vapour species were obtained by the ion current comparison method, with the DyF3 partial vapour pressure over pure DyF3 as a standard. The equilibrium constant of the gaseous reaction DyF3 + DyOF = Dy2OF4 is evaluated. Thermodynamic data obtained are in a agreement with the available phase diagram of the DyF3-Dy2O3 system. Results of the present study illustrate the negative deviations from the ideal behaviour in the system.

Jan 1, 1997

By Croggon R

Passing a direct current through a jointed fine grained soft rock mass auses the movement of water by the process of electric-osmosis. There are other processes such as electrolysis which transport ions that interact with associated ions and can, in turn, be oxidised. This results in the dissolution products being transported towards the cathode electrode. In the cathode region the ferrous hydroxide is oxidised to ferric hydroxide %%ith consequent precipitation. The cracks and joints are current pathways, along which the ferric hydroxide is deposited. This deposition reinforces the joints and increases the shear strength. By adding calcium chloride to the anode, the rate of corrosion is increased with the concomitant increase of deposited ferric hydroxide along the joints. This, in turn, significantly increases the joint shear strength. The process is pervasive in that the current via the water paths travels through the crack and joint systems The result is that not only specific joints are reinforced but the cracks and mtciconnected voids are also reinforced.

Jan 1, 1997

"The pyrometallurgical method of recycling car batteries suffers from a potential for air pollution violations, which prompts the desire for a viable hydrometallurgicaJ alternative. Several Processes have been proposed, including leach-electrowinning routes using HBF4 and/or HzSiF6 based electrolytes, along with anodes of PbO2 on inert substrates.A study has been carried out to evaluate the proposed systems, with the intention of demonstrating a six month life of an electrolyte-anode combination. The work, which focused on the use of HzSiF6, has indicated that there was no acceptable anode, and has lead to the development of a technique to produce smooth, glassy, adherent coatings on graphite, and to the development of an anode composed of a series of copper cored graphite rods.The paper will present results on leaching and electrowinning experiments, as well as the description of a flowsheet for a pilot plant that will be used to produce one tone per day of refined lead from spent battery paste."

Jan 1, 1997

By Eggleton R. A, Taylor G

As the search for major orebodies continues, the regolith dominated areas of the Broken Hill region remain one of the major exploration frontiers. The past exploration philosophies emphasising bedrock related characteristics have been limited in their ability to effectively explore in the regolith dominated areas, that are a feature of most of the Broken Hill region (Figure 1). If mineral exploration is to be more effective across all of the Broken Hill region, particularly in the regolith dominated areas, an appreciation and increased understanding of the regolith and landscape features are a necessity. Ironically, there have been very few studies of the regional regolith and landscape features of this region. Owing to the previous lack of an established regolith-landform framework, this study initially concentrated on the general characterisation and variation in regolith types corresponding to the area of the Broken Hill Block, within NSW (Willis, 1989; Stevens, 1986). The approach has been to produce a regional regolith-landform map at 1:100 000 scale and conduct a complimentary program of regolith sampling and site descriptions. This was a basis to identify areas for more detailed regolith-landform mapping (1:25 000 scale) and for producing a regional stratigraphic framework and models for landscape and regolith evolution. This information can then be used to provide a basis for regional mineral exploration models and strategies. This paper highlights some of the regionally significant regolith-landform features and their general significance to mineral exploration. More detailed information on specific regolith-landform features and study sites may be found in Hill et al (1994; 1996; in press) and Hill (in prep).

Jan 1, 1997

By J. A. Herbst, A. E. Oblad, Y. C. Lo

The major cost in comminution is energy consumption, which can be as high as 50% of the operating cost. Improvements in plant operations have resulted in up to a 15% reduction in energy usage (kw-hr/t). These improvements have been made through the optimization of grinding efficiency and the use of expert model-based control systems. Optimization involves the determination of the levels of the critical-operating conditions that result in the most efficient breakage of ore in the mill. These optimal levels are identified through plant/laboratory test work and through computer simulation using advanced process models. Model-based expert control achieves the maximum performance from the grinding circuit by identifying the characteristics of the ore in the mill with an optimal on-line estimator. Using this information, the control system dynamically determines the operating point that will yield the optimal performance. Two industrial applications of grinding-circuit optimization and model-based control are presented to demonstrate the power of this new technology.

Jan 1, 1997

By J. A. Haggman

In a country richly endowed in mineral wealth, Climax Arimco Mining Corporation&apos;s (CAMC) Dinkidi porphyry Au?Cu deposit in Nueva Vizcaya province, Philippines, represents the most significant mineral discovery in the country in recent times. The deposit is located within a belt of young intrusive and volcanic rocks in the Sierra Madre mountain chain of north Luzon a region previously unassociated with porphyry-style mineralization. Since 1989, drilling of the Dinkidi deposit has outlined a resource of 124 million tonnes of 1.0 g/t gold and 0.41 % copper. Regional exploration throughout CAMC&apos;s 37,000 hectare FTAA has identified a further sixteen potential porphyry-related deposits. A new mining law was passed in March 1995 but prior to that CAMC had the first Financial and Technical Assistance Agreement (FTAA) granted by the Philippine government allowing 100% foreign ownership of mining projects.

Jan 1, 1997

By M. C. Ruiz

The leaching behavior of chalcopyrite concentrate in acidic CuC12-NaCI-O2 solutions was investigated. Experiments were conducted under continuos flow of oxygen at atmospheric pressures. The results indicated that among the variables temperature has the largest influence on the dissolution of chalcopyrite in this medium, and high copper extraction can only be obtained at temperatures near the boiling point of the solution. It was also found that the stirring speed did not influence appreciably the dissolution of chalcopyrite. An increase in the oxygen flow rate up to 0.1 1/min increased the copper extraction. The total chloride concentration affects the dissolution of chalcopyrite up to about 4 M. Copper extraction of 93 % was obtained in leaching chalcopyrite of size fraction -400 # Tyler at 105 OC in 2 hours.

Jan 1, 1997