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By Courtney A. Young

Cyanide is a critically important chemical to the mining and metallurgical industry. It has a strong affinity for metals making it favorable as an agent for metal finishing and treatment as well as a lixiviant for metal leaching, particularly gold. These technologies are environmentally sound but, because cyanide is very toxic, safeguards are required to prevent accidental spills and treat effluents before being discharged. Various methods of cyanide remediation by separation and destruction for cyanide management purposes are therefore reviewed. The methods have been broadly categorized as physical, -adsorption. complexation and oxidation methods including photolysis and other advanced-oxidation processes. Reaction mechanisms for these methods are presented throughout this paper, Finally, the methods are compared in regards to their effectiveness in treating various cyanide species: free cyanide, thiocyanate, weak-acid dissociables, and strong-acid dissociables.

Jan 1, 1998

By H. Y. Sohn, S. PalDey

"A new chemical synthesis process for the preparation of intermetallic compounds has been developed. It involves the vapor-phase reduction of mixtures of constituent metal chlorides by magnesium vapor to produce intermetallic compounds in the form of fine powder. The advantages of the process include (a) the use of inexpensive raw materials, (b) low reaction temperatures, and (c) products in the form of fine particles. Titanium and nickel aluminides were prepared by this method. The effect of AlCl/TiCl3 partial pressure ratio on the formation of different titanium aluminides was studied. A two-phase mixture containing 80 mol % of TiAl and 20 mol % of TiA13 formed at an AlC13/TiC13 ratio of 10. The amount of TiA13 was maximized to 72 mol% at an AlC13/TiC13 ratio of 16. The maximum conversion of the limiting chloride TiCl3 was 94 % . In the case of nickel aluminides, NiAI, NiAl3, and Ni2Al3 were formed by reducing mixtures of NiC12 and A1Cl3 vapors. The effect of the partial pressure ratios AlCl3/NiC12 and Mg/NiC12 on the formation of nickel aluminides was studied. The maximum content of NiAl obtained was 98 mol % . At the AlC13/NiC12 ratio of 19, a two-phase mixture of 17 mol% of NiAl and 83 mol% of NiA13 was produced. The product particles were very fine in the size range of 0.05 to 0.2 µm.A. IntroductionIntermetallic compounds are attracting much attention [1]. Titanium and nickel aluminides have attracted a great deal of attention from the aerospace as well as automobile industries because of their potential for high-temperature application (e.g., low density, good oxidation resistance, and high-temperature strength retention [2, 3]). Gamma TiAl and two-phase (TiAl and Ti3Al) alloys [4] are used for gas turbine engine rotational components as well as automobile exhaust valves. TiAl3 is one of the most extensively investigated aluminum-rich intermetallics. Nickel aluminides are attractive because of their low densities, relatively high melting point and good high-temperature strength properties. For example, Ni3Al shows increasing rather than decreasing yield strength with increasing temperature [5]."

Jan 1, 1998

By K. K. Bhattacharyya, S. Bhattacharya, S. Dey

Coal batch flotation tests were conducted both with and without collector and with one- and two-stage additions of frother. The recovery of combustibles and the flotation rate constant were found to be higher with two-stage frother addition, both with and without collector.

Jan 1, 1998

By Constance Holmes

President Lien presented Mrs. Holmes with the first of speaker appreciation gifts presented by his firm Amax Coal West, Inc. These were books by Rand-McNally entitled The Executive Golfer Guide. Following the coffee break, Clark Moseley presented the first annual Institute Safety Achievement Awards for the safest mines in the eight member state region. The awards were based on: 1. Total man-hours 2. Total number of lost time accidents 3. Incidence rate 4. Number of S&S violations 5. Description of safety program 6. Safety awards received 7. Health and safety training efforts 8. Safety Policies 9. Does the operation take employee suggestions and implement them? 10. Letter(s) of commendation from agencies individuals The awards were judged by the senior/graduate level class of Mine Safety & Health at the Colorado School of Mines under the supervision of professor Edward Hollop. The two handsome traveling trophies were awarded to and accepted by: Surface: Big Sky Mine. Colstrip, Montana Gordon Brannon, Manager of Safety Underground: Skyline Mine, Scofield, Utah Dave Hales. Safety Supervisor and Doug Johnson, General Production [ ]

Jan 1, 1998

By A. Dale Wunderlich

With the price of precious metals at an 18-year low, every ounce of metal produced is important. The theft of metals from mining and refining sites can mean the diffrence between profit and loss for many mining companies. Low metal prices do not reduce the potential for the theft of precious metals. History has shown that the price of gold has little to do with the desire for employees to steal precious or base metals. There is actually evidence that the theft of precious metals increases when the price of this commodity goes down. Several of the major precious metal thefts in the past year took place at silver mines when the price of silver was less than 16 cents/g ($5/oz). How does the lowest gold price in 18 years affect the need for security at precious metals properties? There is no short answer to this question. One reason is because the exposure to theft of precious metals is unique to each property. This makes it important that each property be evaluated individually. More than 95% of all precious metals thefts can be attributed to those working at the mine site. So preventing employee theft is the primary concern. One consideration is the location of the property. Gold selling at any price is still an attractive commodity in countries where the employees are making between US$400 and US$600 a month. It is not uncommon for employees at mines in countries where low wages are the norm to consider the value of a gram or two of gold to be a significant amount of money. A gram or two of gold a day may not seem like much. But if 15 employees steal two grams a day, that equates to a significant amount of money during a year. The type of property where the precious metals product is being recovered is also important. For example, a property with a gravity circuit is more likely to suffer from the theft of gold product than a property where all gold is finely disseminated and the only gold seen in the ore body is through a microscope. Gravity circuits increase an operation's exposure to theft because the grinding circuit that is associated with a gravity circuit often becomes a giant concentrator. Areas such as the bottom of grinding-mill pump boxes, cyclone-feed-pump clean out traps and the sumps often become locations where precious metals concentrate (Figs. 1 and 2). Muck concentrations in these locations can be as high as 25% to 40% of gold or silver. Not long ago, muck was removed from a barren-solution sump at a Merrill Crowe circuit that had concentrated to more than 40% gold. At a milling site in the Pacific Rim, residents of the community adjacent to the mine learned about the value of the concentrates in the sump under the ball mill and committed an armed rob¬bery. While several of their co-conspirators held the em¬ployees at bay with machetes, the others emptied the contents of the sump into buckets and removed it from the site. Armed robbery is not as common as employee theft. However, while this article was being written, an armed robbery occurred at a gold property in Central America. Armed perpetrators took as hostages the night shift employees at a process plant and used cutting torches that were on site to cut into the high-security and gold-storage areas. The perpetrators then stole a company vehicle to remove the stolen gold buttons and sludge from the site. Unfortunately, this type of activity goes on regularly. But managements of most mining companies are reluctant to discuss theft scenarios. So information pertaining to the theft of precious metals seldom becomes a newsworthy item. An audit conducted at a mine site with a gravity circuit recommended that the gravity recovery area be shut down until adequate protection could be provided. Although it was not connected with the audit, it was necessary to shut down the gravity area for a pro¬longed period because of problems with the gravity table. In the two months that followed, gold production at the site increased by about 31 kg/month (1,000 oz/month). It is difficult to attribute all of this increase to the theft of concentrates. But there was a good chance that at least part of the increase was due to the fact that concentrates were being stolen from the gravity area.

Jan 1, 1998

By Daniel K. Kim

The charge for the copper refinery is a mixture of anodes produced at San Manuel from BHP source concentrate and copper purchased from external sources. Control of unwanted impurities in the tankhouse - is very important and beneficial. Currently available removal/recovery technologies were reviewed for the control of bismuth and antimony levels in the electrolyte. Recent studies have focused on solvent extraction (SX) technology and generated successful results for the removal and subsequent recovery of bismuth and antimony. The SX system employs the reagent, ACORGA SBX-50, in conjunction with a patented high chloride stripping system. The latter enables recycle of the eluant, avoiding the high costs associated with conventional systems, such as regeneration of resin. Concerns over potential transfer of organics and chloride ion to the electrolyte were readily addressed, solved and demonstrated using conventional, established technology. This paper describes the benefits of electrolyte purification, the flexibility afforded by the SX system, the operational practices necessary for maintaining adequate control of bismuth and antimony impurities in the electrorefining environment and possibilities for future development /exploitation of the Zeneca SX system at the San Manuel refinery.

Jan 1, 1998

The importance of factoring mining dilution into the estimation of ore reserves in an open pit mine is discussed. An example that relates the issue of mining dilution to the size of the smallest volumes that can be mined selectively is given. The relationship between the size of the selective mining units (SMUs) and the variance of their average grade is presented. The concept of variance reduction and its use in factoring mining dilution into geostatistical ore reserve estimation is described. An approach to estimate a variance reduction factor by way of conditional simulation is introduced.

Jan 1, 1998

By Mostafa Benzaazoua, Bruno Bussière, Jean Lelièvre

De nombreuses opérations mimères exploitent et traitent des minerais sulfurés pour concentrer des métaux precieux (Au, Ag ... ) OU des métaux de base (Cu, Pb, Zn ... ), laissant en fin de parcours des tonnages considérables de résidus plus ou moins générateurs de drainage minier acide (DMA) selon leur contenu en sulfures. De nos jours, Jes restrictions en matière de protection de l'environnement obligent Jes opérateurs miniers a trouver Jes solutions Jes plus efficaces pour préserver Jes sites environnants de la pollution due a l'oxydation des sulfures. Cette oxydation cause une acidification accrue du milieu et une mise en solution des metaux toxiques. L'utilisation des recouvrements multicouches est l'une des solutions Jes plus efficaces pour limiter la pollution liée au DMA mais entraine des coilts de construction qui sont souvent considérés par l'industrie miniere comme prohibitifs. Une façon de rendre cette technologie applicable, d'un point de vue économique, est de désulfurer Jes résidus à l'usine de traitement et d'utiliser la fraction inerte comme composante d'un recouvrernent multicouche. Cette opération de desulfuration peut etre réalisée par flottation non sélective des résidus dans le but d'obtenir d'une part un faible volume de concentré de sulfures qui devra être géré convenablement et d'autre part un rejet non générateur d'acide.

Jan 1, 1998

By Herbert Pöllmann

The mineralogical and chemical compositions of various waste materials undergo different reactions when treated thermally The heavy metal contents can be bound to stable phases. These minerals are called reservoir minerals. The main property of these minerals is the stability in their geochemical surrounding containing the heavy metal cations and anions. Examples for these minerals are apatites, spinels, garnets, perovskites and also water containing minerals like ettringites, metal-metal-hydroxi salts, jarosites and zeolites. When the chemical compositions of different wastes are mixed according to the compositions of the new formed minerals, a probable reuse of these wastes can be obtained. The use of waste incineration ashes for the production of cementitious binders and the use of flue gas desulfurization products for cement additives are shown. Also the transformation of highly contaminated materials into stable reservoir mineral assemblages are shown including the study of stabilization and immobilization techniques.

Jan 1, 1998

By Jose R. Parga

In mining operations, cyanidation is the ,predominant method by which gold and silver are recovered from their ores and it is recognized that cyanide consumption can be a major factor that contributes to the operating costs for such operations. Also after extraction and recovery of precious metals a certain amount of cyanide is delivered to the tailings pond and must be considered with respect is environmental problems due to the toxicity of cyanides. In this regard, the Air-Sparged Hydrocyclone (ASH) has been used as a reactor for the treatment of cyanide solutions in two ways; first for cyanide recovery by acidulation using the Mexican modification of the Mills-Crowe process and second for cyanide destruction by oxidation with the use of chlorine dioxide (ClO2). In both cases, excellent performance can be achieved using the high capacity ASH system.

Jan 1, 1998

By Pierre Gy

"Abstract - This paper deals with industrial complexes such as: (1) a mine producing metal-bearing ore and a furnace(s)/converter(s) where the ore is melted into metal, either directly, or after a mineralurgical concentration; and (2) quarries producing the raw materials required for the manufacturing of cement and the kilns to which they are fed.Each mine or quarry operation results from the exploitation of a mineral deposit. This deposit is never homogeneous. The raw materials which are extracted from the mine/quarry can never be safely fed to a "process" such as a cement kiln or a metal smelter, because the devices involved lack the flexibility required to absorb a very inhomogeneous feed. Furnaces and kilns are known to be very sensitive, sometimes dangerously so, with regard to deviations from a certain ideal feed composition.The purpose of this paper is to present the conditions required to optimize the operation of such a complex, so as to maximize the production, the quality of the product, as well as the profit generated. Two key operations are involved: sampling (to know accurately the materials being dealt with) and bed-blending (to achieve the desired degree of homogeneity). The theories of sampling and bedblending have been developed by the author and presented in various books (Gy, 1992, 1998)."

Jan 1, 1998

By Valery W, Morrell S, Loughlin P, O&apos

Traditionally, blasts in mining operations are designed to prepare the in situ rock mass for excavation and transport without much consideration being given to the downstream comminution processes. Blasting is in fact the first step in a chain

Jan 1, 1998

By He Guangyi, Han Zhilong

This paper introduces the new technology of deep-hole blasting with water-soil mixed stemming to exposed stonework. Nine aspects of advantages are drawn in the paper based on tests of different types of charge and stemming under the conditions of different geology, height of bench and diameter of drill.

Jan 1, 1998

By D. W. Collins

The uptake of gold from halide solutions by activated carbon has been investigated using various techniques. Halide systems typically exhibit combined adsorption-reduction type behavior. In an attempt to gain more information about the nature of these processes, samples of synthetic highly-oriented pyrolytic graphite (HOPG) were contacted with aqueous solutions of gold-iodide. HOPG represents a model structure for activated carbon comprising of basal- plane sites, edge sites, and various defect sites. Two basic instrumental methods were used to examine the uptake of gold by HOPG. The first was standard X-ray photoelectron spectroscopy (XPS). The other involved several scanning probe techniques. XPS clearly indicated a preferred uptake of gold at edge sites. However, iodine appeared to be distributed on both basal-plane and edge sites. At low iodine additions, tapping mode AFM showed that clusters were concentrated along steps and surface defects. At high iodine concentrations, the HOPG surface was uniformly covered by iodine.

Jan 1, 1998

By J. du Plooy

Mintek has implemented a training scheme that provides students with the experiential training requirement for the National Diplomas in Chemical Engineering and Extraction Metallurgy. This note describes the main features of the scheme and the course content, and our view of future developments in this area.

Jan 1, 1998

By Elhachmi Es-Sadiqi

"For over 40 years, CANMET has focused its research on value-added products and energy efficiency in the metals industry. The Efficient Metal Production Program is currently managed by Dr. Elhachmi Es-Sadiqi, and the Canadian steel industry is its main client — both directly and through international organizations such as the American Iron and Steel Institute (AISI) and the International Lead and Zinc Research Organization. AISI membership includes Canadian steel companies IPSCO, Dofasco, Stelco, Algoma Steel and Sidbec Dosco.Canada’s steel industry makes important contributions to the economy. The industry comprises 14 companies and employs 33 600 people in locations such as Sydney, Nova Scotia; Tracy, Quebec; Selkirk, Manitoba; Saskatoon, Saskatchewan; and Sault Ste. Marie, Ontario. With annual production at about 16 million tonnes, sales in 1995 totalled $11 billion, $3.8 billion of which was exported.Canada’s steel industry supplies the transportation, oil and gas, appliance, packaging and construction industries. It is at the forefront of new technology use and has a substantial support network to provide raw materials, equipment and service. Three main segments of the industry include flat-rolled products (e.g., plate and sheet steels), long products (e.g., concrete reinforcing bar and structural steel), and specialty and alloy steels (e.g., stainless steel and tool steels, in both long and flat products)."

Jan 1, 1998

Two key elements in the design of a pastefill or high density hackfill system are the preparation of the backfill material and its distribution underground. This paper examines these two areas. Owing to the essentially impervious nature of total mill tailings, preparation of pastefill and high density fill from current tailings involves a physical dewatering process. There are currently three methods available for this process: I. Vacuum or pressure filters. These represent the 'traditional' approach to the preparation of pastefill. 2. Paste production storage mechanism. This is a thickening/storage mechanism developed with the specific objective of producing paste/high density backfills. 3. Fluidization. This system utilises silos fitted with simple dewatering devices and nozzles. Recently developed by CANMET, it provides the simplest and most economical approach. This paper describes and compares the three preparation methods, from a practical and an economic point of view. Once the pastefill/high density fill has been prepared and binder added, the backfill must be distributed underground into the stopes. A fundamental factor in the design of a distribution system is the rheology of the material- No two materials will exhibit the same properties, and a sequence of rheological and related testing is required prior to the completion of the design of the underground distribution system. This paper covers the testwork normally required and discusses the fundamental design parameters of pastefill distribution systems. The final section of this paper summarises the use of pastefill at three mincsin Canada.

Jan 1, 1998

By Lock PR

The Silver Swan nickel mine is located at the Black Swan Nickel Project, 53 kin north east of Kalgoorlie, Western Australia. The Silver Swan orebody is a massive sulphide nickel deposit dipping 70¦ east with an average in situ grade of 14 per cent. Mining of the massive orebody is by Mechanised Ramp Cut and Fill (MRCF). A mining recovery of 98 per cent and minimising dilution are primary goals in extracting the high-grade ore. Placing a distinguishable marker bed (working platform) on rock fill was identified as a key method to achieving these goals. Gravel from a pit located onsite was considered the most suitable material for the marker beds. Research undertaken to design the marker beds using the gravel revealed conventional methods used in mining would not suffice, but that road stabilisation methods could be a viable alternative. Trials used a road recycler to mix cement and gravel in situ and several test beds were constructed on the surface to determine the final design. The trials attempted to replicate a marker bed's life cycle of construction and placement and mucking of ore from the marker bed.

Jan 1, 1998

By N. Gopalakrishnana, R. Beccard, S. Lourdudoss, R. Holz, M. Deschler

"Rapid growth of conducting and/or insulating InP, GaAs, Gao.47In0.53As, and GaAs0.6Po.4 on one or more of (001), (110), (111)A, (3ll)A and (3ll)B surfaces by Hydride Vapour Phase Epitaxy (HYPE) is demonstrated. The maximum growth rate of the binaries lies between 12 and 300 µm/hr and of the ternaries between 7 and 170 µm/hr. A simple model is developed to describe the influence of crystallographic orientation on temperature dependent growth rates. The growth rates predicted by the model is compared with the experimental values. Room temperature resistivity of insulating InP:Fe can be as high as 5xl09 ohm cm. Temperature dependent differential resistivity is also analysed. This feasibility of growing conducting and insulating layers rapidly on different orientations is very useful for electronic and optoelectronic devices.IntroductionRecently there is a renewed demand for very thick layers of III-V compound semiconductors for high performance electronic and optoelectronic devices [1]-[2]. Long wavelength high speed lasers that can be modulated up to 30 GHz necessitate epitaxial growth of semi-insulating (SI) layers [3]. There is also an increased interest on the growth of epitaxial layers on surfaces other than (001) surface. Epitaxial growth of these materials on such surfaces is of theoretical importance besides being technologically relevant. These demands led us to focus on the growth of conducting and insulating III-V compounds by Hydride Vapour Phase Epitaxy (HYPE). lnP, GaAs, Gao.471no.s3As on lnP and GaAso.6Po.4 on GaAs were grown as conducting materials using Low Pressure HYPE (LP-HYPE) on (001) 2° off substrates. Gao511no.49P on (001) GaAs substrate and lnP on lnP substrates of (001), (110), (l 11)A, (31l)A and (3 ll)B orientations were grown as semi-insulating materials using Atmospheric Pressure HYPE (AP-HYPE). In this report we present the growth aspects of these materials. We also present a simple model on the growth of InP on substrates of various orientations. The theoretically obtained temperature dependent growth rates are compared with the experimental values. Differential resistivities of semi-insulating lnP grown on substrates of various orientations as a function of temperature are also summarised."

Jan 1, 1998

By B Chappell

Backfill in the form of mine waste tailings has inherent problems associated with attaining adequate strengths upon placement. Fines are usually removed to ensure adequate drainage, which lowers the cohesive strength of the fill, leaving the fines to be placed in a tailings dam. Electro-drainage and electro-chemical grouting is examined to investigate its effects on densification and shear strength within a silty clay tailing having low permeability and shear strength. Two separate grouting mechanisms are observed for the iron and silica grouts used. Electroosmosis is associated with iron grout that deposits within the tailing matrix under a converging pH gradient, and increases the permeability of the tailing. This process initiates cation exchange and causes cementing of the granular contact points between the clays. Electro-phoresis causes sodium silicate solution to deposit silica grout in the voids of the tailings. The resultant effect of these mechanisms results in an increase in cohesion, leaving the void ratio of the iron grouted tailings as it was but significantly reducing the void ratio of the silica grouted tailings.

Jan 1, 1998