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By Z. Tang

A collaborative project was performed between NRC Institute for Fuel Cell Innovation and MagPower Systems Inc, to develop a cost effective fabrication process to manufacture the anode for magnesium-air fuel cell with improved performance. A novel fabrication process was developed, which resulted in a porous microstructure with increased surface area, instead of the traditional solid structure. This porous anode greatly increased power density in the magnesium-air power source. This fabrication process is very simple and cost effective. Especially, this process makes it convenient to incorporate different alloying additions, as well as hydrogen inhibitor and electrolyte management additive into the anode. The anode composition was designed so that micro galvanic cells were formed as current is drawn out of the fuel cell, and resulting increased dissolution rate of Mg. It is feasible to incorporate hydrogen inhibitor and electrolyte management additive into the porous anode, and the anode with some kinds of inhibitors exhibited improved electrochemical performance. This paper describes the microstructure and electrochemical performance of anodes with designated porous structure and alloying additions. Furthermore, quantitative kinetics analysis of the obtained I-V curves and electrochemical impedance spectroscopy were carried out to clarify the mechanism.

Jan 1, 2005

By J. Kulczycka

Poland in time of transition had been dealing with the remnants of the previous regime ? particularly in the field of environmental protection. The burden left was tremendous and there was a need for fast and effective tools for improving the environment. The idea of environmental protection had been supported by the introduction of a new environmental policy that underlined the importance of sustainable development in industry in the beginning of 1990s. This policy introduced high environmental fees and fines ? a concept not very popular in Europe in that time ? and good only for a country in transition to boost the protection of the environment. While this policy had its role to play, its role is now completed. It is time to move forward, especially when these environmental charges affect the international competitiveness of industries so much, and at the same time have virtually no influence on environmental protection investments any more.

Jan 1, 2005

By L. Boyd, A. Charland, G. Potts, D. Fragomeni, N. O. Lotter

"The Raglan orebody and concentrator has been the subject of study in Process Mineralogy at Falconbridge since 1998. (Lotter and Tuzun, 1998) The orebody is classified into three distinct textural groups, or end members. These are referred to as disseminated, net-textured, and Massive Sulphides, and differ in terms of mineral grain size, nickel grade, hardness, and mineral association. In this paper, it will be shown that the sampling and characterisation of each end member on an individual basis develops a higher-level understanding of the processing requirements and behaviour of the mixture of ore as presented to the mill.The end members have been used in robust prediction of recovery at various grind size p80 from laboratory scale High Confidence Flotation Tests. Weighted mean mixtures of the end members have been mathematically combined to determine impact of textural distribution on metallurgical performance as a function of grind size.The ore end members also vary in hardness and breakage mechanism and have been used to model throughput capability for existing, optimized and retrofit grinding circuits. This modeling has provided a range of expected throughputs as the relative proportions of each end member varies.Finally, the differing grinding requirement per end member has led to the development of grinding and flotation strategy that increases rougher flotation recovery and provides flowsheet options for a concentrator expansion. This leads to further understanding of the plant performance as a function of ore mixture."

Jan 1, 2005

By Shuangsuo Yang

Based on field observations and physical modeling of simulated materials, the dynamic equilibrium principle on the whole interaction process between the surrounding rocks and support of large deformation roadways in coal mines has been developed. It explains the methods of forming the bolted strata and its changing load capacity with deformation. It also points out the factors and conditions for forming the bolted strata as follows: (1) many entries in coal mines are subject to large deformation. During their service life, it goes through the following process, elastic > plastic > fiacture > broken > loosening, etc. During this dynamic process, the mechanisms of supporting structure are changing and therefore the interaction between support and rocks experiences a process of dynamic equilibrium. Furthermore, the required supporting force for stabilizing the surrounding rocks shows overall decreasing trend; (2) the bolted strata is a special supporting structure consisting of bolt, rock skin protection devices and rock strata within the bolted horizon. As deformation increases, the supporting structure of the broken strata within the bolted horizon experiences a process of periodic change, from equilibrium > not equilibrium > equilibrium. Corresponding to this change, the supporting capacity of the bolted strata also fluctuates and gradually decreases; (3) under the bolted strata, the stability of a large deformation roadway is dynamic and step-wise; and (4) the formation of bolted strata, especially bolted broken strata depends on the existence of compressive force. Supporting the bolted strata is not constrained by the quality of the surrounding rocks. It has broad range of application.

Jan 1, 2005

By Mutombo Nombe, Avimanyu Das, Rick Honaker

Enhanced gravity separators (EGS) provide a more efficient separation than froth flotation when cleaning coal in the 150 x 25 µm particle size range. To improve the performance of an EGS unit, air bubbles were injected into the feed stream in an attempt to decrease the apparent density of the coal particles due to the formation of bubble-coal particle agglomerates. Air injection had a significant impact on operating characteristics and separation performance. Coal recovery was increased by 10 to 20 absolute percentage points while a 2 percentage point drop in the minimum product ash content was also achieved.

Jan 1, 2005

By M. Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

Jan 1, 2005

In this paper, the use of electrochemical AC impedance spectroscopy (EIS) for in-situ diagnosis of high temperature PEM fuel cells is described. EIS was performed on single cell hardware, built in-house, using a fuel cell test station modified to operate up to 120°C and 30 psig. Electrode kinetics, membrane resistance, porous-layer and mass transport impedance of MEAs, assembled in-house, were measured at various current densities for the purpose of validating the test station and cell hardware, and for optimizing MEA and flow-field designs. The effect of temperature and humidity on the various impedances was investigated. Impedances obtained at lower and higher temperatures were compared to obtain insight into the issue of water management in operating fuel cells.

Jan 1, 2005

Level measurement of underground orepasses is important. Orepasses are not only utilised to funnel ore to the shaft skip loading station but also as silos for storing of ore in order to smooth out ore flow in a shaft system. Safety and operational efficiency are also improved as proper orepass level measurement could prevent overfilling of tipping areas. A study was therefore commenced to determine alternative technologies available as well as identifying practical installations across the Anglo American plc Group. From an instrumentation perspective an orepass system is an extremely difficult environment to take measurements in. Factors like dust, vapour, interference, bridging, wear and physical installation have to be taken into account. The study discusses time-of-flight (ultrasonics, radar and laser) measurement techniques followed by other possible solutions. These solutions included strain gauge measurement, the æjumping monkeyÆ technique, radiotomography, fibre optics and very long baseline interferometry (VLBI). Finally, various South African suppliers have been approached in order to determine instrumentation that is available for orepass level measurement in the marketplace. These recommendations were verified, where possible, by visiting the claimed installations.

Jan 1, 2005

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By Misra M., P. Grimes, Chen. S.

The combustion of petroleum products produces emissions which contain oxides of nitrogen (NOx), hydrocarbons (HC), and particulate matter (PM) which have adverse health and environmental effects. In recent years there has been increasing interest in the use of water-fie1 emulsions as a substitute for conventional fuels. Emulsified fuels are emulsions of water in fuel, which are typically made of 10 to 20 percent of water mired with certain additives and fuel. Studies have shown that the emulsified diesel can significantly reduce the emissions of NO, PM and car- bon monoxide and increase the fuel efficiency. In order to produce a stable diesel emulsion, the development of an effective surfactant additive is critical. The stability of diesel emulsions is influenced by many factors, including size distribution of the droplets, the viscosity of the continuous phase, the physical properties of the interfacial film, and temperature. This paper describes a method to produce emulsified diesel and combustion results obtained from various tests. It has been found that the diesel emulsion made with this additive package was stable during the test, and the emissions were lower in NO, CO, and PM compared to the baseline diesel.

Jan 1, 2005

By André C. Zingano

The domino effect in a violent pillar collapse occurs due to the redistribution of stress in the remaining pillars near the collapse, and this stress transfer occurs in the immediate and main roofs. The remaining pillars do not have enough load capacity to support this overstress and also fail, and the domino effect propagates further to the entire panel. The domino effect does not occur only due to low load capacity of the pillars, but also the roof rock mass quality, because the stress is transferred by the roof. In high competent roof without discontinuity (fault), like massive sandstone seam, the deformation of the roof is the cause of pillar collapse extension and propagation. Depending on how close it is approaching the collapse limit; the immediate and main roofs behave differently. When it is close to the collapse limit roof convergence and pillars compression occur. Conversely when it is far from the collapse limit divergence and pillars decompression occur. This is called the arc-effect. This paper studies this behavior of the roof (immediate and main roofs) using numerical modeling to simulate the roof deformation and stress distribution in the roof and pillars. This simulation represents the progression of pillar collapse and shows the zone of convergence and divergence of the roof, and also the effect of this behavior on pillar confinement. Two-dimensional plain strain model was applied to simulate the arc-effect. The simulation results were compared to those of the instrumentation that was installed before the collapse. Keywords: pillar collapse, room and pillar, numerical modeling

Jan 1, 2005

By Y. He

Early research showed that the separation of particles based upon their density was not possible in steadily rising air streams. The terminal velocities of moving spheres are determined by their aerodynamic characteristics. This prevents particle separation by density in standard air classifiers. Passive pulsing air classifiers have accelerated airflow in certain regions, which achieves density-dominant separation. Numerical simulation of airflow within passive pulsing air classifiers was done to estimate airflow patterns near a damper. Analysis of those results shows the significant acceleration of the airflow above the damper. Laboratory trial separations have shown that passive pulsing classifiers are superior to standard air classifiers. Keywords: pulsing airflow, passive, simulation of airflow models, acceleration effect, density

Jan 1, 2005

By J. Huisman

With the introduction of ever-stricter environmental operating guidelines, capital expenditure restrictions and operational budget cutbacks, the biological method of SO2 removal becomes more and more attractive. Biological treatment of dilute flue gases is a more cost effective technology in comparison to conventional sodium hydroxide scrubbing. Although the investment costs for sodium hydroxide scrubbing is lower, the operational costs are significantly higher. In addition, the end product of the biological installation is sulfur instead of sodium sulfate; and no further wastewater treatment of the bleed from the biological installation is required since heavy metals are removed simultaneously. Another option for the treatment of SO2 containing gas at a sulfuric acid plant is the production of extra sulfuric acid of the discharged SO2 by applying an additional converter. Comparing biological treatment with this option shows much lower investment costs for the biological installation. Sulfur is produced which can be converted to sulfuric acid, so the bio-route will be more cost-effective than an additional converter. In principle, the biotechnological gas cleaning system is an integration of an absorber with a wastewater treatment facility. In the absorber, the SO2 containing gas is brought into contact with the washing water. The effluent absorber liquid contains a mixture of sulfite and sulfate that is converted into elemental sulfur. This conversion takes place in an integrated system; first, the sulfite/sulfate mixture is converted anaerobically into sulfide; secondly, the sulfide is converted aerobically into elemental sulfur. Subsequently the sulfur is separated and the water is returned to the absorber. Due to the buffer capacity of the washing water, removal efficiencies over 98% are possible. In addition to SO2 removal, it is possible to convert for example other bleeds streams such as scrubber acid or weak acid to sulfur in the same SO2 installation. Recent evaluations concluded that biological desulphurization of flue gases is not only economically attractive in comparison to convention sodium hydroxide scrubbing but also in comparison to gypsum producing systems and even seawater scrubbers. This paper describes the technological and economical viability of biological flue gas desulphurization.

Jan 1, 2005

Large areas of ground are permanently supported on coal pillars, both in extensive old workings and current drivages in active mining operations. Continued growth of civil infrastructure is resulting in more surface development above old bord and pillar mines and an increased need for mine development beneath existing surface structures and features. The result is a greater likelihood of conflict between miners, developers and regulatory bodies. However, over the last 40 years there has also been significant improvement in the general level of understanding of pillar behaviour and stability, both in Australia and overseas. This paper examines some of the issues to be considered when undermining surface structures or undertaking surface development above old workings. The Factor of Safety (FoS) methodology widely employed for the assessment of pillar stability is reviewed, including the key geometrical, geological and statistical concepts associated with the probability of pillar failure; local and international experiences are examined and significant parameters isolated. Common concerns are addressed in the context of actual practical experience, utilising a risk management approach. Recent advances in methods for the assessment of pillar stability are put forward, along with criteria for arriving at rational design outcomes.

Jan 1, 2005

By C. Musingwini

In the past ten to fifteen years, many organizations have applied business process re-engineering (BPR) to significantly improve their business competitiveness or stave off closures. The mining industry in Southern Africa is no exception and documented examples can be drawn from South Africa. Although the concept is superficially simple, its application has been marked by a high failure rate of about 70 per cent because it has been generally misunderstood. Shabanie mine, a chrysotile asbestos fibre producer in Zimbabwe took cognisance of this fact by cautiously embarking on a modular BPR programme in October of 2002. A year was used as a complete cycle or module for re-evaluation of the programme. Shabanie mine adopted BPR as part of management efforts to remain competitive amid serious threats to operational viability. These threats included hyper-inflation driven rising production costs, a declining world asbestos market and a possibility that Russia could take over the shrinking world asbestos market by dumping low-priced asbestos fibre. The only competitive advantage that the mine had was the high quality of its long-fibre chrysotile asbestos. The major BPR thrust was therefore to redesign processes for improved productivity and ultimately achieve a lower cost per ton of final asbestos fibre product. In addition, corporate culture change and cost-saving were also factored into the programme. This paper discusses the implementation experience of the BPR programme at the mine. The main BPR beneficial highlights are improved productivity, sizeable cost-savings, positive corporate culture change and identification of secondary projects. One of the lessons learnt from this programme is that mining companies will have to deal with the HIV/AIDS pandemic if they are to sustain high levels of productivity into the future.

Jan 1, 2005

By M J. Schultz, R L. Rude, D M. Tomko

The US Mine Safety and Health Administration (MSHA) conducted compliance assistance diesel particulate matter (DPM) sampling throughout the underground metal and non-metal mining industry. Based on that sampling, MSHA identified mines that were having difficulty meeting the DPM limit. To provide further assistance, MSHA then visited approximately 60 of the mines that were experiencing difficulty complying with the DPM standard. As part of these visits, DPM exposures were measured and control technologies for DPM were observed and assessed. Controls consisted of ventilation, clean engines, environmental cabs, alternative fuels, diesel particulate filters (DPF) and work practices. The focus of the follow-up compliance assistance visits was to assess control effectiveness and to make recommendations to mines experiencing difficulty in meeting the DPM standard. At each mine visited, the ventilation controls were evaluated, engine emissions were determined for equipment in use, environmental cabs were examined, and operational practices were noted. Additionally, control technologies, including alternative fuels and DPF were evaluated in several mines. A comparison was made of mine and section airflow to equipment particulate indices. Based on engine emissions, horsepower and operating time, the contribution of individual engine emissions to total emissions was made. Environmental cab integrity, positive pressure and air filtration systems were checked and operational practices relating to DPM exposure were assessed. This paper summarises the preference and magnitudes of controls that were typically used or needed for successful control of DPM. Additionally, results of the assessments of alternative fuels (including bio-diesel and water emulsion fuels) and DPF are presented.

Jan 1, 2005

This paper summarises the current status of the mining sector in Poland in terms of vertical transport system safety. Selected results of research programs conducted at the AGH-UST relating to mine hoist system safety are reviewed. The conclusions support the notion that the costs of vertical transport systems can be reduced, while at the same time maintaining the required safety and reliability levels. Novel solutions: movable fender beams HWR, linings modar« and the integrated shock absorbers PHH for conveyance guiding systems fully confirm this hypothesis.

Jan 1, 2005

By Roger Holmberg, Donald Jonson

The Swedish Standard SS 460 48 66, “Vibration and shock - guidance levels for blasting induced vibration limits”, is based on more than 50 years of experience from blasting close to structures and tunnels. The Swedish Standard gives a method for calculation of guidance values for different types of buildings and ground condition under the building. This is done for every building and structure within a predetermined zone. The guidance levels are for the peak particle velocity monitored in vertical direction. The standard is valid for all kinds of blasting project (tunnelling, quarrying, mining etc.) The guidance levels neither take in to consideration discomfort for people inside the building or structure nor vibration sensitive equipment inside the structure. The paper also presents the Swedish Standard SS 02521 “Vibration and shock - Blast induced airborne shock wave - Guidance levels for buildings”.

Jan 1, 2005

By P Trout, B Macaulay

Ridgeway Gold Mine (RGM) is an underground sublevel caving (SLC) operation that is owned and managed by Newcrest Mining Limited (NML). Production drill and blast practices are critical to the success of the SLC method at RGM. SLC production ring precharging was introduced in November 2001 to enhance these practices and deliver safety, productivity and cost improvements. Current precharging practices require up to two rings to be loaded ahead of the ring to be blasted in each drawpoint. The explosive may be required to remain in the up-holes for periods of four weeks or more prior to blasting. During this æsleepÆ time it is subjected to repeated shock from the blasting ofadjacent rings and from rings in adjacent drawpoints. The project described in this paper was designed to gain an understanding of the factors affecting explosive performance in the precharging environment and to develop explosive products and operating practices that would meet RGMÆs requirements in terms ofsaf ety, reliability and blast outcomes. Several months oflaboratory and field testing were required to characterise the explosive and quantify the effect of post-loading blasting shock. These results were used to determine the most appropriate loading and sleep time criteria for RGMÆs precharging practices. In addition, the information is being used to guide the development of the next generation of emulsion explosives for use in underground precharging operations.

Jan 1, 2005

By Davis. B. R.

There are a number of hydrogen storage systems proposed for automotive applications. However, all of the current suggestions fall short of the DOE targets for storage density and volumetric density. The DOE has suggested that only through radically new ideas will a practical solution to hydrogen storage for automotive applications be realized. This paper provides some background in chemical hydrogen storage and discusses roadblocks to the implementation of some proposed technologies.

Jan 1, 2005