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By Peng Fan

Liquid phase tends to migrate from an aggregate of solid particles immersed in a liquid phase into another aggregate composed of the same solid particles and liquid but with smaller particle sizes and/or lower volume fraction of the liquid phase. This type of liquid migration in a two phase system can be attributed to the driving force for the system to decrease its total interfacial energy. With liquid migration pressure as a convenient measure for the total interfacial energy of a solid-liquid two-phase system, liquid migration can be attributed to the existence of liquid migration pressure gradient in the two-phase system. The kinetics of liquid migration is of great practical importance for many industrial processes, one of which is the liquid phase sintering of functionally graded WC-Co composite materials. During liquid phase sintering, WC-Co composite forms a typical solid-liquid two-phase system where solid particles of WC are immersed in liquid Co. For a sample composed of two layers of WC-Co with the same Co content but different WC particle size, Co gradient will be formed during liquid phase sintering; while for a sample composed of two layers of WC-Co with the same WC particle size but different Co content, the Co gradient will be eliminated during liquid phase sintering. The formation and elimination of Co gradient are controlled by the liquid migration pressure gradient. This paper describes a numerical simulation of the kinetic process of the formation and elimination of cobalt gradient.

Jan 1, 2006

By Rob Thomas

Main gate roof control during longwall retreat is subject to a significant increase in horizontal stress and risk. The implementation and management of an appropriate roof support design is as a result, an imperative requirement for any longwall mine and must in addition to the likely consequences of a roof fall, also consider the variables of the geotechnical environment, associated support costs and practicalities. This paper will therefore summarise a number of recent advances in main gate roof control in the Australian coal industry. Points considered include; (i) the ?Longwall Acceleration? concept, (ii) macro-scale horizontal stress notching, (iii) micro-scale horizontal stress notching, (iv) bedded versus laminated roof types and (v) the type of cable reinforcement used.

Jan 1, 2006

By R. Frim, S. D. Ukeles

The present U.S. production of bromine is from inland brines located in Arkansas and Michigan. The most concentrated domestic brines (up to 5,000 ppm bromide) are situated in Arkansas. Less concentrated brines (about 2,500 ppm bromide) are located in Michigan. The amount of bromine sold or used in the United States came from three companies operating in Arkansas and Michigan. Arkansas, with its six plants, was the leading U.S. state in bromine production. Bromine being the leading mineral commodity valuewise produced in the state. The Michigan bromine production was a byproduct of magnesium compounds production.

Jan 1, 2006

By D C. Ibana

The use of electrostatic fields to effect phase dispersion and agitation in solvent extraction (SX) has demonstrated many advantages over conventional mechanical methods and is therefore a very real alternative. Despite this, an industrial application of the technique is yet to be developed. Here, the several variations of the technique that have been proposed are reviewed, the state-of-the-art assessed and key limitations to a commercial application outlined.

Jan 1, 2006

By M. B. Greyver

The results of laboratory tests on iron precipitation from non-decopperized nickel anolyte are discussed. The parameters (pH, oxygen consumption and stirring speed) for iron precipitation from the anolyte, using the oxygen in the air, were determined. In the experiments conducted under optimized conditions, the residual concentration of iron in the anolyte after precipitation was 0.7-2.7 mg/L, and the copper and nickel losses to the solid phase were 0.05-0.07% and 0.05-0.16%, respectively. The filtration ability of the iron slurry obtained was 2 to 5 times higher as compared to that after chlorine oxidation and oxyhydrolysis. The leaching of the non-ferrous metals from the iron cake made using the separate nickel anolyte purification process was possible by dissolution in sulphuric acid. It was established that after cobalt precipitation from the copper- and iron-depleted anolyte, the precipitates obtained had lower ratios of Fe:Co and Ni:Co.

Jan 1, 2006

By S. Di Muzio

Sulphate Reducing Bacteria (SRB) are hetero-trophic anaerobic micro-organisms that can be used to remove sulphates and heavy metals from Acid Mine Drainage (AMD), heavy metal-bearing streams with high iron and sulphate contents and low pH, generated by sulphur bio-oxidation in abandoned mine districts. After the preliminary chemical precipitation of iron with carbonate stones (I step, chemical precipitation) SRB can be used to reduce sulphates to sulphurs then favouring heavy metal removal as sulphur precipitates (II step, biologically mediated precipitation). In this work the experimental results of heavy metal and sulphate removal from column tests were reported. Sulphate and heavy metal abatement in fixed bed column was performed using chemically pre-treated samples of synthetic AMD. Attenuation of toxic effects of treated samples was also ascertained by toxicological tests of germination and radical growth with Lepidium sativum.

Jan 1, 2006

By T Berryman

The Fimiston reserve is being depleted at the rate of one million ounces per year; most of which is processed by the Fimiston plant, with the remainder being stockpiled. As for most other large open cut mines around the world, Fimiston has an excellent dispatch and tracking system. Reconciliation is used to determine how the various models used in mine planning (such as a reserve, budget and schedule models) are tracking against production. It is also used to gauge the performance of grade control estimation against production; however, analysing the results of this can be complicated and, at times, misleading. The reconciliation process involves adjusting the monthly production data to equal the mill reported tonnes and grade, plus the change in stockpiles. This adjusted number is then compared to the grade control reported tonnes and grade, the scheduled model (monthly planning model) tonnes and grade and against budget (Reserve) tonnes and grade. This paper includes explanations of all assumptions made in the reconciliation process, including the end of month closing stocks balance, the application of adjustment factors to the dispatch data to create a new balanced set of production data and the monthly sign off to comply with the Sarbanes-Oxley requirements of the North American owners. The reserve is reconciled by proved and probable classification. This tool is used to assess the robustness of the classification scheme utilised and identify any reconciliation issues as they arise. Within the Fimiston deposit there are still issues that are clouded by the assumptions made concerning the scale of observation, poor data support and the mining of the narrow lode areas of the deposit. The declared ore mined (DOM) number (which is defined in the paper) can be significantly affected by these assumptions, and these need to be clearly stated and understood when looking at the reconciliation data. The DOM tonnes and grade is a good indicator of real mine performance as it adjusts mined tonnes and grade to take into account the milled tonnes and grade each month, and prevents cumulative errors from building up in mine predicted dispatch numbers or end of period stockpiles. This number allows monthly monitoring of the mine to mill performance and allows valid comparisons to be made back to budgets and reserves over a period of time. KCGM uses three month rolling averages to monitor performance against reserve and budget models. This ensures that monthly distortions in the figures due to stockpiling issues or over mining in a particular period do not lead to false conclusions. Reconciliation performance over a longer period (12 - 18 months) is used to adjust reserve models should significant variance be observed. By closely monitoring the reconciliation performance at the Fimiston operation, fine tuning of all aspects of the grade estimation process from reserve through to grade control can be made. This allows the most accurate data to be used when planning from reserve data for the Life of Mine Plan through to grade control data for short-term mill feed.

Jan 1, 2006

By Beatriz Ramírez

Xanthates are anionic collectors normally used in flotation devices to modify the hydrophobic surface of sulphide minerals. Xanthates are heteropolar compounds and in aqueous media they dissociate into ionic xanthate and alkali-metal ions; nevertheless their behaviour is not well understood yet. This work characterises the six reactions describing the decomposition of the ionic xanthate in aqueous media by analysing the set of spectra from a UV- Spectrophotometer. Results show the effect of pH on the stability of certain compounds which can be useful to explain the relationships among xanthates and the hidrophobicity of some surfaces (or ions dissolved).

Jan 1, 2006

By Klaus Pöllath

This paper describes mitigating measures and the design of compensation grouting which will be executed from deep shafts of the Amsterdam North/South Metro line project. Due to the specific conditions for TBM-tunnelling in Amsterdam (historical buildings on pile foundations near the tunnel and soft soils with high groundwater levels) tunnel construction necessitates mitigating measures, such as compensation grouting or soil freezing. Züblin developed a special shaft construction method for critical distances to buildings. For the compensation grouting Züblin developed a new software tool, called SOFIA, which controls and visualizes and thus optimizes the entire injection process. This tool significantly increases the efficiency of the injection works while reducing the geotechnical risks.

Jan 1, 2006

By Steve Kral

The mining industry in northern Ontario is known mostly for its huge nickel deposits. Inco’s and Falconbridge’s nickel mines in the Sudbury Basin are the best known. And with nickel prices being what they are, interest in the region continues. And how. Inco and Falconbridge want to merge. Teck Cominco wants Inco, but without Falconbridge. Xstrata made a hostile bid for Falconbridge, which Falconbridge rejected. And, in June, Phelps Dodge trumped them all when it made an approximately US$40-billion friendly offer for Inco and Falconbridge in a two-part deal.

Jan 1, 2006

By M. Hopf

The use of water-cooled copper components as sidewall elements of submerged arc furnaces and other pyrometallurgical applications has become increasingly common. The high cooling efficiency of copper has made it possible to increase the service life of furnace refractories when compared to conventional refractory linings. However, even the self-healing effect of ?freezing? worn areas of the lining does not necessarily protect the copper coolers against wear or corrosion completely. In order to avoid furnace explosions, various methods have been used to monitor the wear of coolers. Unfortunately, these have not been able consistently to identify localized wear. Thos Begbie (South African) and SAVEWAY (German) jointly developed technology to embed a line sensor into the copper cooler during the casting process. This system allows an exhaustive monitoring of the copper cooler. A SAVELINE sensor is placed inside the copper-cooling panel between the water-cooling passage and the hot face of the panel. The sensor follows the meandering shape of the cooling water channels. In the first instance, the sensor provides analogue information as the thickness of the copper reduces. Secondly, this wear signal will be confirmed by a signal of interruption if the sensor is washed away. Because of the structure of the sensor, a self-diagnosis is possible and indications can be confirmed (double proofed).Subsequent to the manufacture of some test pieces, coolers for a large submerged arc furnace were manufactured. The sensorized coolers have been installed at the intermittent surface (slag line) where the largest amount of corrosion has been encountered. The system has been operating since December 2005 in what is considered one of the largest submerged arc furnaces in South Africa. Keywords: Pyrometallurgy, furnace, copper coolers, freeze lining, monitoring, Saveway

Jan 1, 2006

Jan 1, 2006

By George Kayesa

[ ] A multiple-bench slope failure occurred at Letlhakane mine on 14th July 2005. No injuries or damage to equipment was suffered and mining production was not affected. Slope failure was preceded by the precursors of tension crack formation, crack widening and extension as well as slope monitoring targets movement. It was predicted that slope failure was imminent using the Geomos slope monitoring system, though the timing was not certain. The area to be affected by the slope failure was also known before hand as was the slope failure mode. As a result, measures were taken to avoid exposing personnel and mining equipment to the slope failure risk. This paper discusses how the prediction of the slope failure of 14th July 2005 using the Geomos slope monitoring system resulted into avoiding potentially fatal injury, damage to mining equipment and loss of mining production.

Jan 1, 2006

By B Lavin, R Sanford

This paper examines the application of Lean Manufacturing in a mining environment, based on experience within the Rio Tinto entities: Rio Tinto Aluminium, Northparkes Mines and Hunter Valley Operations. The three applications have tested the flexibility of the Lean methodology. Within Rio Tinto, Rio Tinto Aluminium was the first group to introduce Lean. The rollout began in late 2004. It was introduced firstly at Boyne Smelters, Gladstone, as a model site with the initial application in the Carbon Bake Furnace area. It was later extended to other sites including the Weipa Bauxite Mine. LeanÆs successful application within Rio Tinto Aluminium was in part responsible for its recent adoption by other Australian-based Rio Tinto business units including Northparkes Mines, a copper mining operation in Central New South Wales, and Hunter Valley Operations, a group of four coal mines in the Hunter Valley region of New South Wales. Lean is also being adopted by Rio Tinto Iron Ore. Rio Tinto Aluminium introduced Lean Manufacturing to complement an existing Six Sigma business improvement program and to achieve continuous improvement activities at a workplace level. Lean provides a similar level of rigour and discipline to Six Sigma but its application is everyday and for everyone, everywhere in the workplace. It is a valuable management tool. In a short time, Lean has achieved good and sometimes spectacular results improving productivity and efficiency at all sites, including our mining site. Within Rio Tinto Aluminium, it has also had beneficial impacts on our ability to develop and retain employees.

Jan 1, 2006

By G. Mousavian, R. Bagheri, N. Dalili

Polypropylene (PP) and its composites have an increasing use in automobile and domestic industries. Since the published results on strain rate effect on yield behavior do not match, and there is a high attention paid for effect of nanometeric fillers on deformation behavior of composites, in this research the strain rate effect on yield behavior of PP and the effect of nanometeric fillers on deformation behavior of PP have been studied. Microscopic observations and tensile tests in different strain rates on neat PP samples and on samples filled with 5, 10 and 15 %wt have been used. A dramatic change in behavior for the modulus and post-yield slope curves when the strain rate is between 0.0433-0.05 s-1 has been observed. Microscopic observations on PP indicate a change in deformation mechanism from shear yield to crazing at the same strain rate that the change in behavior of curves occurs. It has been observed that in PP nanocomposites with higher amount of calcium carbonate, fracture in early stages of deformation occurs in lower strain rates. In other words for a fixed stain rate there is a critical filler percentage such that if the filler percentage is higher then early-stage fracture will occur. Similarly for a fixed filler percentage there is a critical strain rate and in higher strain rates early fracture will occur. The critical stain rate will decrease as the filler percentage increases and vice versa.

Jan 1, 2006

By Fumito Tanaka

The Converting Furnace (C-furnace) of the Mitsubishi process has solely provided opportunities for producing blister copper continuously from molten matte. Continuous converting originates from the proven technology for controlling the behavior of magnetite in lime-ferrite slag of the CaO-FeOX-Cu2O system. Recent improvements in the C-furnace operation have included the slag controls reflecting the impact of minor oxides on magnetite behavior. Although previous investigations focused on magnetite behavior, sulfur has also affected the C-furnace operation because it is of practical importance to avoid the precipitation of gypsum from lime-ferrite slag and the separation of matte from blister copper. This paper will quantify the behavior of sulfur in C-furnace with respect to the gypsum formation and matte separation, and discuss better controls for C-furnace operation.

Jan 1, 2006

By Clara María Lamus Molina

The following minerals found in the residual black sands from gold mining in El Bagre Antioquia (Colombia) were identified as having major economic interest: Ilmenite (FeTiO3), with an average of 49% of TiO2, frequently altered presenting crowns; lamellaes of rutile and alteration textures; titanomagnetite with up to 25% of TiO2; magnetite (Fe3O4) in individual grains or associated with others minerals as hematite and ferromagnesian silicates rutile (TiO2) with considerable quantities of Nb2O5(0.1-3.7%Wt); zircon (ZrSiO4) with 66%Wt of ZrO2 and monazite with an average of 63.43%Wt of REE, this frequently associated to xenotime and thorite forming textures as little drops. Analysis in EPMA and SEM/EDS showed percentages of minor elements and traces, thereby clearly establishing the applications of these minerals in diverse industries. Furthermore, a detailed granumetric study of the different minerals and textural relationships among them also allowed for establishing the basis for possible processing and exploitation.

Jan 1, 2006

By M. A. Aziz

The electrochemical performance of a series of carbon materials produced from coconut shells, which are very cheap and readily available in Bangladesh was investigated for their viability as anode materials in rechargeable lithium-ion batteries. X-ray diffraction technique was used to measure the interlayer spacing (d002) of the produced carbon materials. A number of half-cells were prepared with the produced carbon materials from coconut shell as working electrode and metallic lithium as counter electrode with 1MLiPF6 electrolyte in a mixture of ethylene carbonate and dimethyl carbonate. The discharge-charge profiles were measured for the different half-cells by using Arbin 24-channel Cyler. The value of interlayer spacing of the coconut-based carbon material was found to be 0.397 nm at 900°C, which is most suitable for lithium-ion insertion into the carbon structure without any expansion. The specific discharge capacity of carbon material from coconut shell heat treated to 900°C was found to be 1015.65 mAh/g. The coconut carbon material heat treated to 900°C delivered 335.22 mAh/g reversible capacity, which is comparable to the commercial carbon/graphite presently used in lithium-ion battery systems. The irreversible capacity loss and coulombic efficiency in 25th cycle of half-cell made with coconut carbon material were found to be 0.16% and 99.83% respectively. The carbon material produced from coconut shell can, therefore, be used as a potential anode for rechargeable lithium-ion batteries.

Jan 1, 2006

By Peter B. Lilly

Thank you, Syd, for the kind introduction and for inviting me to give the Keynote Address at this very prestigious gathering of some of the finest intellect and talent in the domestic and international coal industry. CONSOL Energy has been a part of this conference for its entire 24-year existence. We have presented 27 papers over that time. CONSOL employees have also been members of the planning committee for the conference, and we have been pleased to support the event both financially and with many participants. So I am honored to be here with all of you this morning, especially during such a positive period for coal. You can just feel the enthusiasm in this room for our industry, and for this conference. I can tell you, there?s also a lot of enthusiasm and excitement in CONSOL Energy?s boardroom. And our enthusiasm is mirrored on Wall Street. But there remains an ironic twist to all of this attention. Even when times are good, the coal industry seems to go largely unnoticed by the mainstream. Outside of West Virginia and other coal-producing regions, the industry still seems to lack influence and support, at least here in America. As an example, last month, an ABC News crew visited our Blacksville 2 Mine, near here, to do a feature story on increased employment in the coal industry.

Jan 1, 2006

By Jan E. Nesset, Colin Hardie, Peter Radziszewski, Donald P. Leroux

"The successful introduction of new high intensity stirred milling technologies (e.g. IsaMill, SMDetritor) to the mining industry in recent years prompted Noranda-Falconbridge to initiate a study comparing these technologies to the conventional technologies of ball milling and existing vertical stirred mills (e.g. VertiMill). The study was unique in that it utilized the same material (Brunswick Mine zinc cleaner regrind mill feed), the same sizing instrument (a Malvern laser difractometer) and sampling protocol, and media size and type (for the high intensity stirred mills). The paper compares the net energy efficiency (kWh/t) of the various technologies, their power intensity (kW/m3) and product size distribution spread (P80/P20). A key finding is that media size is critical to achieving optimal performance. As part of the performance comparison, an analysis of the four methods of power measurement was made (Prony brake, shaft torque, grinding chamber reaction torque, “no-load” correction) and followed-up with an experimental test procedure using three of these methods. The findings include divergent results for power measurements and some explanations based on the observations are proposed. The direct shaft torque and Prony brake calibration methods are shown to be the methods most suitable for stirred mills.INTRODUCTIONThe motivation for the investigation reported here was the lack of a suitable comparison within the available literature of relative grinding efficiency for the emerging crop of new industrial fine grinding technologies. Such comparisons are potentially fraught with inconsistency, from ore samples and grinding media used, to testing methodology, to size measurement techniques, to the power measurements themselves. The collaboration of the industrial suppliers (at the time MIM Technologies and Svedala, now Xstrada Technologies and Metso Minerals) and McGill University (P. Radsiszewski) were sought in order to ensure as valid a comparison as possible. The work was performed between October 2000 and November 2002, led by the mineral processing group at the Noranda Technology Centre (NTC) in Pointe-Claire, Quebec. The paper is presented in two sections; Part A considers the different power measurement methods and a comparison of the results for the SMDetritor (SMD) technology, while Part B reviews the grinding performance of the 5 technologies investigated using the selected performance criteria."

Jan 1, 2006