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By Jin Liu

In the early 1990?s, Inco successfully installed two new flash furnaces as part of their SO2abatement project to reduce SO2 emissions from the Copper Cliff Smelter by 60%. The flash furnace off-gas is cooled and cleaned through two new Monsanto Dynawave gas cleaning systems that replaced the traditional venturi scrubbing system. It was discovered that the flash furnace production capacity is often limited by the capacity of the gas cleaning system. The key task is to eliminate pressure drop from the system. The froth column is responsible for by far the largest pressure drop in the gas cleaning system. Initially, the column was fitted with 22 plates. In 1994, both #1 and #2 froth columns were modified by reducing the number of plates in each column from 22 to 18 and increasing the interplate spacing on lower plates. With increasing demand for more throughput in the flash furnaces, further modifications on the froth columns were made in 2005. This paper describes these modifications and results together with some fundamental analysis of the froth column characteristics.

Jan 1, 2006

By F. Ferella

In this paper several leaching tests were per-formed to optimize the leaching section of a hydrometallurgical process for the recycling of alkaline and zinc-carbon batteries. Zinc and manganese oxides were dissolved by an acidic-reductive leaching using sulphuric acid and oxalic acid as reductant. Leaching tests were developed according to a full factorial design. The operational variables were pulp percentage, sulphuric acid concentration, temperature and oxalic acid concentration. Additional tests were performed to evaluate the precipitation rate of Mn and Zn oxalates. Finally a hydrometallurgical process were proposed for the recycling of alkaline and zinc-carbon batteries, in which Zn and MnO2 are recovered from purified solution by electrowinning: Zn is recovered as metallic compound, while Mn can be recovered as electrolytic manganese dioxide (EMD), but recovery of further manganese compounds is possible with simple process changes.

Jan 1, 2006

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By Sheng-hai Yang

The ultrafine, monodispersed, spherical cobalt powder has been fabricated by reducing cobalt hydroxide with glycol. It were investigated that the effect of NaOH concentration on the reaction rate and the effects of the concentration of cobalt hydroxide and surfactant on the morphology and particle size. The particles were characterized by the X-ray diffraction(XRD), scanning electron microscope(SEM), laser diffraction particle size analyzer and BET specific surface analyzer respectively. The XRD shows that the cobalt powders exist mostly in face centered cubic (fcc) structure, a little in simple hexagonal. The cobalt powders prepared at Co(OH)2150g/L, NaOH 40 g/L and surfactant 30g/L, its average particle size, specific surface area and cobalt content, were 0.88µm, 2.705m2/g. and more than 99.5% respectively.

Jan 1, 2006

By H. R. Shakeri, R. Mayer, M. J. Worswick, A. Rahem

The current focus of research and development in transportation industry is to use lightweight materials such as aluminium alloys for more structural components. In this regard, maintaining safety of the passenger and vehicle is the most important; therefore crashworthiness of components made of lightweight materials must be evaluated prior to sizable application of these materials. The focus of the present study is to understand failure and damage mechanisms during the axial crushing of aluminium tubes made of A1Mg3.5Mn alloy of 2 and 3.5 mm thickness. Due mainly to complexity of the crushed tubes, a microstructural approach is considered. In this study optical, stereo as well as scanning electron microscopy techniques have been used to study damage and failure mechanisms in these types of tubes, which are essential energy absorbing components in passenger vehicles.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Gregory Poole

With access to the World Wide Web, many resources are readily available for improving claim reports. With a little time spent on line, a more thorough report can be created. Claimants will accept the conclusions of a report more readily when they can view support information on their own computer, particularly when the support information is not just from blasting related web sites. Some suggested resources are discussed including aerial pictures, local tax maps, topographical maps and home repair web sites. This paper provides suggestions for tracking down support information on the web and information on how to properly reference this information. Case studies of several claim investigations are presented. These are some examples of how a little time spent online provided clear and convincing evidence to support the conclusions of the investigation.

Jan 1, 2006

By Rauf Hurman Eric

The high temperature liquid miscibility gap in the Ag-Ag2S pseudobinary portion of the Ag-S system has been redetermined by very carefully conducted equilibration-quenching experiments. Samples were contained in evacuated and sealed silica capsules. The stratified liquid phase compositions were obtained by chemical analysis. The miscibility gap extends from 14 to 32.3 atomic percent at the monotectic temperature of 906°C and closes at around 1320°C.Thermodynamic properties of the liquid solutions, including the limiting activity coefficient of sulfur in molten silver were expressed analytically by using the sub-regular solution model which proved to be in excellent agreement with the experimental findings.

Jan 1, 2006

By John O. Marsden

The past fifteen years have seen a number of important developments in copper hydrometallurgy, including the commercial application of biological heap leaching of secondary (chalcocite-dominant) copper ores, the commercial demonstration of chalcopyrite concentrate leaching technology using pressure leaching and biological processes, and the application of novel configurations of solution extraction circuits. Significant emphasis is now being placed on the development of effective stockpile leaching practices for primary ores (chalcopyrite and bornite-dominant mineralization). Some of these developments have been highly successful, and will pave the way for further development and commercialization. Others have been less successful. These developments are reviewed in the context of the metal price cycle and trends for the future are identified.

Jan 1, 2006

By Cevat Serdar Kucukkaragoz

The kinetics of prereduction of Chromite by carbon was studied under argon atmosphere at temperatures between 1000°C and 1300°C . The compacted and agglomerated specimens were reacted by using a TGA system. The mixing characteristics and the degree of compaction of the chromite and coke particles were the main parameters influencing the reduction kinetics. The reduction rate increased with temperature reaching to 81% reduction at 1300°C. The metallization started as the metallic nucleation around the particles which was first observed at 1100°C. The particles were surrounded by the metallic phase at approximately 40 % reduction obtained at 1200°C. At 1300°C, the reduction proceeded with a high rate during initial stages and with a low rate at final stages. The reduction was found to proceed in the sequence of Fe3+to Fe2+, Fe2+ to Fe(metal) and Cr3+to Cr(metal) with the formation of carbides.

Jan 1, 2006

By V. A. Bryukvin

It has been found that by superimposing symmetric alternating current over the process, the rate of nickel and cobalt leaching from metallized products with copper sulfate solutions increases by a factor of 1.5 to 2.0 and the apparent activation energy of the process investigated is reduced from 12 down to 6.6 kcal/mole. It appears especially attractive to use alternating current for anodic dissolution (oxidation) of metallic scrap of refractory metals and their alloys in ammonia electrolytes permits production of high-grade commercial products in the form of respective ammonium salts using a short and virtually reagent-free process flowsheet. Similar approaches can be applied also for electrochemical processing of nickel and copper scrap in sulfuric acid media with subsequent recovery of pure sulfate salts or electrolytic processing. Electrochemical technology for recycling of tungsten-cobalt (WC 15) and tungsten-rhenium (WR 20) alloys has been also investigated. In the former case, anodic oxidation of carbide alloy was carried out in nitric acid electrolyte with production of pure tungstic acid. The research conducted has indicated that the physicochemical effect of alternating current results in a lower activation energy of electrode reactions due to changes in the mechanisms of the electrode reactions themselves.

Jan 1, 2006

By W. L. Jacobsen, T. L. Dyer

Cortez Gold Mines is completing a Feasibility Study for a new open pit gold mine in north central NV. The production schedule calls for a peak in material movement. This schedule is based on current operational efficiencies and equipment parameters observed at the company’s existing open pit operation. To mitigate risks of over/under predicting production, simulation modeling was used to validate the loading and haulage requirements during the peak production period. The advantage of simulation is the ability to provide a realistic model of a mining operation based on scheduled, and unscheduled random events during the period under analysis.

Jan 1, 2006

By Charles Vaught

This paper discusses the fact that US coal mining organisations are losing the knowledge they need in order to be able to respond to emergencies. The authors note that knowledge management provides a useful perspective from which to view the problem, but that the debate about what constitutes knowledge should be broadened to include a debate about what constitutes management. It is argued here that knowledge is actually shared knowing distributed across group members; that such knowledge can be managed by cultivating it; and that narrative is the medium through which this may be done. The paper then examines NIOSH research that has attempted to use such an alternative knowledge management approach to help potential mine emergency responders better deal with the predicaments they are likely to encounter on-site.

Jan 1, 2006

By J Cahill, M Lee

Leinster Nickel Operations, located in Western Australia, consists of an underground and three open pit mines in relatively adverse ground conditions. This paper reviews our ground control practices in the open pits, covering aspects of ground support, wall control and monitoring. These methods have been effective in allowing mining operations to continue beneath unstable slopes. In particular, the use of Groundprobe?s Slope Stability Radar has enabled the Harmony Open Pit to safely operate for months following indication of failure from traditional methods. This case study highlights the benefits of investing in appropriate slope stability monitoring systems.

Jan 1, 2006

By Giovanni A. Bonita

The new Embassy of the Peoples Republic of China in the United States (Chinese Embassy) is located in the Embassy Row portion of Northwest Washington DC. The 475,000 ft2 (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. The structure approaches the property line on all sides, and is immediately adjacent to several foreign embassies and a secure U.S. Federal Building. A vertical soil nail wall was used as the primary support of excavation (SOE) system for the project. The soil nail wall was irregularly shaped, benched in areas, and reached total heights up to 98 feet (29.9 m). The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Tight excavation requirements were defined for the project due to the location of the building relative to the property line, requiring fairly precise wall positions and shotcrete tolerances. Design challenges included soft soil conditions, inside wall corners, underground utilities, and seismic impacts from blasting. The paper will focus on the design, construction, and performance of the soil nail SOE system, as well as touch on the logistical and political factors that influenced the design. The paper also notes the Value Engineering and communication approaches that were generated during construction. These efforts resulted in a significant improvement in the quality control and quality assurance exhibited on site, expedited the schedule, and led to significant cost savings to the contractors, engineer, and owner.

Jan 1, 2006

By Frank Lucca

This study is based on a six month study performed for Lee County, Florida. The study was based on blasting for land development and how this type of blasting affects structures. The study is investigates peak particle velocities and the relationship to other environmental and manmade forces that affect structures. The study also explores the effect of geology on blast vibration. After completion in Lee County, the study was then continued in the quarry environment in Vermont and extremely tight blasting environment of New York City. Charge diameters were 127mm (5 inches) or less.

Jan 1, 2006

By Frank E. Chase

During the past quarter century, coal mine geologists have evolved from providing a qualitative description of drill core and coal reserves into quantitative geotechnical specialists who bridge the gap between geology and engineering. In the late 1970?s and early 1980?s, hazard prediction mapping was in its infancy. At best, hazard maps identified rudimentary structures and conditions such as stream valley locations, sandstone/shale transition zones, and lineaments. A ?technical disconnect? had existed between geologists and mining engineers as each profession operated largely independent of each other. Engineers did not readily integrate geology and geologic conditions, with the exception of coal thickness, into mine planning. Geologists were relied upon for reserve estimates and did not participate in mine planning or design. The employment and market slump of the 1980?s and 1990?s combined with mining more challenging reserves mandated that this gap be bridged and forced geologists to learn to speak more ?numerically? to engineers so they could be understood. The purpose of this paper is to describe the procedures and thought processes used by coal mine geologists when determining various mineability and reserve extraction feasibility issues. The paper will also address underground geologic hazard mapping and prediction techniques. To achieve these objectives, the opinions and experiences of leading coal mine geologists, geotechnical and strata control specialists across the United States were solicited.

Jan 1, 2006

By Mohamed Ourriban, Yongjun Peng, Qi Liu, Denis Cotnoir

"In the flotation of fine particles, there are two difficulties in general: low recovery of valuable minerals and high recovery of gangue minerals. The low recovery of fine valuable minerals is attributed to low bubble-particle collision and attachment efficiencies, while high recovery of fine gangue minerals is attributed to mechanical entrainment through water films between gas bubbles. Over the last five years COREM has been actively developing fine particle flotation techniques with the objective of improving fine particle flotation separation efficiencies.The fine particle flotation techniques with both generation of micro bubbles and enlargement of sizes of fine particles have been developed to increase bubble-particle collision efficiency. For oxidized fine sulphide minerals, both physical and chemical techniques have been developed to modify the hydrophilic surfaces and therefore increase bubble-particle attachment efficiency. To reduce mechanical entrainment of fine gangue minerals, a new approach, polymeric depression and flocculation, has been developed. By selecting the high molecular weight polymeric depressants to make fine gangue minerals hydrophilic and also enlarge their sizes, entrainment can be minimized. By combining these techniques, we are able to improve both flotation recovery and selectivity in some fine ore flotation systems.INTRODUCTIONWith depleting mineral resources and their declining grades, ores leaving grinding circuit for froth flotation are becoming increasingly finer to achieve mineral liberation. Together with the increasing demand for minerals, ever-increasing tonnages of fines are being produced. Therefore, flotation of fine particles is an immense challenge to be tackled by researchers all over the world today."

Jan 1, 2006

With the advent of COAG reforms in the late 1990s requiring full commercial return from æpublic infrastructureÆ, and the tightening regulatory compliance for any project that involves the development or modification of any natural resource, it has become increasingly difficult for the private sector to contemplate development and/or ownership of new large-scale water supply infrastructure. The hurdles that must be overcome often seem insurmountable even before a detailed understanding of the project challenges can be developed. Australia has prospered over the last 50 years in an environment where regional development, including mining, has been encouraged by high commodity prices, a well-trained and available labour force and abundant spare capacity in the necessary infrastructure, in particular rail, power and water. Unless future infrastructure is created in advance of, or closely following, demand, this prosperity may be in jeopardy. This paper presents a snapshot of todayÆs project development challenges, and with reference to some recent case histories, argues that owing to their unique background, culture and status, water utility government owned corporations (GOCs) are well-suited to fulfilling the demand for new water infrastructure.

Jan 1, 2006

By Michael S. Moats

As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the likelihood of anode passivation intensifies. To improve the industry?s understanding of the passivation phenomena, the role of anode composition was evaluated. While previous studies have focused on studying one impurity element at a time, this study was conducted using forty-four commercial electrorefining anode samples supplied by ten copper companies The passivation response of each sample was evaluated under accelerated galvanostatic conditions in synthetic copper electrowinning electrolyte at 65°C. This information allows for correlations between composition and passivation tendencies over a wide range of impurity elements and concentrations. It was found that selenium, tellurium, silver, lead and nickel accelerated passivation. It appeared that oxygen accelerated passivation when increased from 500 to 1500 ppm, but further increases did not have an effect. Arsenic was the only impurity found that inhibited passivation.

Jan 1, 2006