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Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By I. Dimitrov, S. R. McCutcheon

"Industrial-grade limestone is found in both the Lower Silurian La Vieille Formation and Upper Silurian LaPlante Formation of the Chaleurs Group in northern New Brunswick. Currently, between 150 000 and 200 000 tonnes of limestone are produced per year from the proximal facies of the LaPlante Formation at the Sormany quarry of Elmtree Resources Ltd., located west of Bathurst.The proximal facies of the LaPlante Formation was deposited on the margins of tectonically uplifted Ordovician terranes. This facies comprises stromatoporoidal-algal bindstone intercalated with wackestone, packstone, and floatstone in variable proportions. The distal facies comprises calcareous shale and minor limestone deposited deeper offshore.Folding and faulting related to Middle Devonian Acadian tectonism have caused an increase in the apparent thickness of the limestone sequences, especially adjacent to the regional Rocky Brook-Millstream fault. Structural and stratigraphic observations indicate that some of the limestone bodies in the area have been tectonically displaced from their site of deposition.A variety of prospecting techniques was used to locate new limestone resources, including geological mapping, airborne and ground electromagnetic surveys, and satellite remote sensing. Clastic rock units above and below the LaPlante Formation have distinctive properties that help to trace the intervening limestone along strike. Because of water-saturated glacial cover, thick vegetation, and the small size of targets, airborne geophysical methods did not prove effective in delineating limestone beds, but aeromagnetic surveys helped map the underlying clastic unit. The remote-sensing data and especially high-resolution digital elevation models helped in identification of karst topography related to limestone."

Jan 1, 2007

By I. V. Kojo

Continuous development of technologies has been self-explanatory for Outokumpu Technology's engineers for decades. The aim in the development has always been the improvement of profitability of the copper production but also the sustainability of the processing i.e. high copper recovery, low external fossil based energy utilization, high emission captures and of course low operation and investment costs. Outokumpu Technology's long-term view of the development is a change towards continuous processes and elimination of number of unit operations in smelting i.e. elimination of possible sources of emissions. Outokumpu blister smelting processes i.e. Outokumpu Direct-to-Blister Flash Smelting and Kennecott-Outokumpu Flash Converting have shown excellent operational results during the years of operation and it is expected that soon more than 10 % of the world primary copper is produced by these technologies. The paper will give some background of this development trend.

Jan 1, 2007

By N. Dahata

Earlier research has indicated that an addition of titanium master alloy to aluminum alloys, results in improved fillability, grain refinement and finer pores. B206 alloy differs from other alloys used in automotive industry, with lower titanium level. This paper examines the effect of alloy chemistry (copper and titanium levels) and grain refinement (A1-5`)oTi- 1%B grain refiner) on grain size, microstructure and microporosity in B206 aluminum alloy. In this study, characterization of grain size, microstructure and microporosity was carried out using light optical microscopy (LOM) and scanning electron microscopy (SEM). Results have shown that the addition of 0.05 wt % titanium resulted in grain refinement of B206 alloy. With an increase in titanium to 0.25 wt further grain refinement, much reduced pore size and uniform distribution of pores resulted. These results suggest that B206 with proper addition of titanium has a promise as an alloy for automotive casting.

Jan 1, 2007

By T. Stauffer, B. McGunegle, A. Adu-Acheampong

The Fairmount Minerals, Inc., Maiden Rock underground sand mine historically delivered air to ventilate diesel-powered equipment at its working faces through high-resistance, 15-inch-diameter PVC distribution lines. In support of plans for expanded production, three new, low-resistance ventilation design alternatives were analyzed. The study determined that adequate ventilation for expanded production was possible with various commercially-available, high-volume/low-pressure fans combined with a systematic layout of control structures. The recommended re-design was implemented in 2001, resulting in a significant increase in flow volumes and a noticeable improvement in the mine environment.

Jan 1, 2007

By N. J. Alderman, D. J. Clowes, N. I. Heywood

The effects were studied of the presence of comminuted flint on the rheological characteristics of chalk slurry pumped through a 92-km long pipeline from Kensworth Quarry to Rugby Cement Works in the UK, and their impact on the pipe flow conditions. Flow curves were measured for 63different chalk slurry samples; these were described by the Bingham plastic model. In addition to observing trends in the yield stress parameter and plastic viscosity in the model with variations in both flint concentration and dispersant additive, use was also made of slurry viscosity values at a reference shear rate of 60 s-1for the pipe flow. It was found that chalk slurry viscosity decreases with increasing flint content up to 10% by weight for a given additive concentration, and increases with increasing additive concentration from 0.7 to 1.0%, for a given flint content. The pipeline flow regimes were identified using the critical value of the Bingham Reynolds number for laminar flow breakdown. For Bench 11 (quarry bottom) chalk slurries, it was observed that all sections of the pipeline operate in the turbulent flow regime for the nine different formulations and for the three pipe diameters used along the pipeline. However, this was not always the case for Bench 1(quarry top) slurries. It was therefore recommended that chalk slurries prepared from Bench 1 should not be used because of the strong likelihood that laminar flow conditions will occur owing to the presence of higher clay concentrations within this bench. This, in turn, will lead to an unsafe operation of the pipeline because of the potential for coarse particle settling. Likewise, blending of chalk from Bench 1 with the lower benches such as Bench 11 could be problematic and this requires further experimentation.

Jan 1, 2007

By R. Worrall

The global mining industry has been proactive over the last decade in finding ways to embrace the concept of sustainability. However, legacy mine sites (which include abandoned derelict and orphan mine sites) across the world continue to present issues for the global mining community, governments, local communities and NGOs. Unfortunately there has been much less academic focus on this area of mining and sustainability. This paper seeks to address how principles of sustainable development can be used to guide the development of processes for addressing post mining landuse issues for legacy mining areas. This is being done using a case study area located near Ipswich, in southeast Queensland, Australia. This area has a 160 year history of coal mining, and was one of Queensland?s crucial early industries. Mining in the area ceased in 2003 leaving a degraded landscape covering an area in excess of two thousand hectares adjacent to one of the fastest growing urban areas in Australia. A sustainability criteria and indicators framework for post-mining landuse on legacy mined land, developed from current best practice used for measuring sustainability across a range of industries is being developed. A review of current best practice suggests the framework should: (1) consider in equal measure environmental, social and economic factors; (2) have a minimum number of indicators which should be easy to identify and measure; (3) must have indicators with a meaningful output; and overall, the framework must consider particular requirements of the site being investigated. Application of the framework to the case study area is an ongoing aspect of this research, and the results will be evaluated through the use of expert stakeholders.

Jan 1, 2007

By C. Cortés

Flotation is a highly interactive process where a change or disturbance in any part of the circuit results in different final grades and recoveries. This high variability of the circuit metallurgical performance complicates the diagnosis of the scavenger stage at the end of the line, as copper losses in the final tailings are erratic and not totally a consequence of problems in the scavenger section. The assessment of the scavenger performance requires a more elaborated procedure than that used for others stages of the circuit. This communication describes the application of an approach that combines results of laboratory flotation tests with those of surveys performed at the plant. The approach is based on running surveys in one of the circuit lines to collect samples for determining grade vs. recovery curves for total mass and size-by-size fractions. Full mineralogical and liberation analyses are also considered on some samples of the feed and tailings streams selected to have a range of feed grades. A separate sample of the feed is used to run laboratory flotation tests to determine optimum flotation time. Two additional pieces of information are the effect of operating variables on recovery, determined through a test program based on design of experiment techniques, and operational data on every cell in the line gathered by visual observation. The application of this approach to one of the scavenger lines at Los Colorados concentrator (Minera Escondida, BHP Billiton) is demonstrated.

Jan 1, 2007

By B. L. Eggers

This study investigates the application of computed order tracking with subsequent rotation domain averaging and statistical analysis, to the drag gearbox of a dragline used in a mining environment. Computed order tracking is a fault detection method developed to deal with the varying speed conditions often found in industry and has been proven effective in laboratory conditions. Its application to real situations, however, requires some adjustment to deal with issues such as inadequate speed data and the fact that the drag gear rotates in two directions. This provides a unique opportunity to observe the performance of the order tracking method in a bi-directional rotating environment, allowing an investigation of the relationships between the results obtained from each operating direction. A monitoring station was set up aboard the dragline and data was captured twice daily for a period spanning approximately one year. The data captured consisted of accelerometer and proximity sensor data. The key on the shaft triggers the proximity sensors, allowing speed and direction to be measured. The measured speed is interpolated by using various speed interpolation techniques. Then the interpolated speed is used to complete the order tracking procedure that resamples the vibration data with reference to the speed. The results indicate that computed order tracking can be successfully employed in real environments. Furthermore it is shown that the rotation direction that opens the gear-tooth crack gives a better indication of incipient failure. It is therefore important not to disregard either direction when monitoring rotating machinery of this kind.

Jan 1, 2007

By F. F. Peng

The raw-coal feeding system and the upward medium current flow in a dense-medium vessel (DMV) are, in addition to the residence time of particles in the separator, important factors for efficient coarse particle separation. The feed material from a raw coal screen and/or pre-wet screen merge with the major volume of circulating medium as push medium, guided by an adjustable submergence baffle plate deep fed into the separator for effective separation. The remaining volume of the circulating medium enters from the purge and drain hoppers at the bottom of the DMV. This generates a gentle upward medium current flow in the separator, which prevents dense medium stratification/settling and merges as part of the push medium. A two-dimensional, two-phase model developed using computational fluid dynamics (CFD) is used to describe the flow pattern and evaluate the function of the dip plate for understanding the mechanisms of particle separation in the separator. The particle movement in the DMV is also tracked to investigate the major operating parameters affecting the separation performance of the DMV. The simulation results of the DMV separation performance are validated by in-plant test data.

Jan 1, 2007

By C. Van Rhee

In dredging practice sand is eroded at very high flow velocities using water jets. The existing pick-up functions overestimate erosion. By taking the permeability into account conventional pick-up functions can be made suitable for high velocity erosion. This can be achieved by modifying the critical Shields parameter. The procedure is demonstrated using the pick-up function of Van Rijn. The theory is compared with experiments and agreement is good.

Jan 1, 2007

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By H. Salamanca

HighService has developed different equipment using wireless technology and machine vision systems that were specially designed to allow 1) the online determination of the SAG mills liner's service life, 2) the automatic detection of a missing dipper tooth in mineral extraction shovels, 3) the reduction of accident risk potential in the mineral transportation within the mine, and 4) the reduction of collision risk potential between shovels and wheel dozers during mineral extraction. For the development of all these systems at HighService, extensive research has been done in radio frequency and image processing fields. The integration of both technologies with the expert knowledge of the company on the typical harsh environment conditions of the mining industry has led to the development of heavy duty equipment that tolerate the extreme mechanical requirements of SAG mills and electrical mining shovels.

Jan 1, 2007

By Abdel Rahman, M. Khaled, Abo Makarem

There are four large limestone quarries, located nearby Cairo metropolitan. Drilling and blasting operations are used to extract limestone for the cement industries. In these quarries, the blast vibration should be kept below a certain limit. One of these quarries is Tourah Portland Cement Company (TPCC) limestone quarry which, lies near important and historical large caves, within Tourah Mountain. Therefore, control of blast vibration level becomes very critical.

Jan 1, 2007

By R. Abel

During the last eight years, the Ventanas electrolytic refinery has been improving its results by applying a series of new operational practices, such as the reduction of electrode spacing from 115 mm to 105 mm., raising the current density to 305 A/m2, modification in the operators shifts to about 70% of the workers, reducing the pulling cycles by two hours, and the erection of a new anode preparation machine. These improvements allowed an increase in the refinery capacity from 323,000 to 382,000 metric tons of electrolytic copper per year. In the same period it has obtained certification under the ISO 9001:2000 and ISO 14001:2004 standards. All of these developments have been achieved using conventional technology with copper starting sheets. The continuous improvement that is covered in this paper has allowed Ventanas to optimize its production, costs, and operational results. For the next years, it is planned to follow the same tendency, bringing the productivity of the plant to higher levels.

Jan 1, 2007

The U.S. Bureau of Mines (USBM) was established in the public interest to conclude inquiries and scientific and technologic investigations on mining and the preparation, treatment, and utilization of mineral substances; to promote health and safety in the mineral industries; to conserve material resources and prevent their waste; to further economic development; to increaseee efficiency in the mining, metallurgical, quarrying, and other mineral industries; and to inquire into the economic conditions affecting those industries. The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the U.S. Bureau of Mines to "disseminate information concerning these subjects in such manner as will best carry out the purposes of this Act." In accordance with this directive, USBM reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminars; in reference books; and in other non-USBM publications. The number of these reports, the wide range of subjects they cover, and the variety of mediums in which they appear make this kind of list both necessary and valuable. This edition describes reports and articles published during calendar years 1992 and 1993. It supplements the 50-year list of Bureau publications from July 1, 1910, to January 1, 19602; and these 5-year lists of publications and articles: from January 1, 1965, to December 31, 1969\ from January 1, 1970, to December 31,19745, from January 1, 1975, to December 31, 19796, from January 1, 1980, to December 31,19847, and from January 1, 1985, to December 31, 19898?.

Jan 1, 2007

By S M. Arndt, D Tyler, F Reusch

Although significant advances have been made in understanding the mechanics of pit slopes, numerical modelling hasnÆt significantly impacted on the reliability of the design process. It is well known that legacy modelling approaches donÆt simulate large slopes well. In recent times, the emergence of very large finite element (FE) models with more than ten million degrees of freedom and the ability to simulate a large number of discrete structures, has allowed a step change in the simulation precision for slopes. The model size allows global and local effects to be realistically simulated in one model for the first time and the process can be better integrated into normal open pit slope engineering processes. Some examples of simulation of very large open pits are shown that demonstrate the challenges and some recent advances in modelling large slope behaviour. Significant limitations in the current measurement and observation regimes of open pits have been identified.

Jan 1, 2007

By L. Ou

This paper reports on research on leaching pyrite in a germ-free system. The effects of mineral particle size, pulp potential and various oxidation agents on pyrite leaching were studied. The results indicated that a smaller mineral particle size leads to a higher leaching rate of pyrite. The optimum results were obtained with a mineral particle size of -0.037 mm. The pulp potential reflected the leaching process and an increasing pulp potential improved pyrite leaching. The leaching rate rapidly increased with the addition of oxidation agents such as Fe3+ and H2O2. However, the precipitate generated by ferric ion coated the surface of the pyrite and prevented further leaching.

Jan 1, 2007

By R M. Briggs, I E. Smith, P M. Black, A B, R L. Brathwaite, J L. Mauk

The Hauraki Volcanic Region of the North Island developed between 18 and 1.9 Ma. Initial andesitic volcanism from 18 to 12 Ma was followed by 12 to 1.9 Ma volcanic activity that included rhyolitic, dacitic, andesitic, and basaltic compositions, with a gradual migration of activity to the SSE. Early andesitic volcanism evolved over the course of 8 m.y. to more silicic compositions; this trend was reset and repeated by post-10 Ma andesitic volcanism. Early and later andesites are otherwise remarkably similar in trace element composition. Rhyolites have the most diverse compositions, suggesting a major role for crustal input in their formation.

Jan 1, 2007

By Jack Magtoto, Lysa Voight, Tom Martin, John Forero

SUMMARY Commitment by all parties to partnering goals established early in the contract aided Affholder, Inc. in constructing 2,360m (7,700') of soft ground tunnel in Rancho Cordova, CA. Despite two zones of known contamination, encountering a zone of loose cobbles and boulders in a matrix of flowing sand, some perched water tables and a flooded tunnel after 2 upstream safety plugs failed, the Contractor finished the work 33 days early and only 1.91% over his original bid.

Jan 1, 2007