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By P. J. Brereton-Stiles, C. J. Hockaday, I. J. Barker, M. S. Rennie

This paper reports on studies that have been done on the electrical conduction in silicon, ferro silicon, and charge chrome furnaces. A system has been developed that can distinguish between normal resistive conduction and arcing, and this was used to quantify in particular the relative amount of arcing that takes place in these furnaces. It was found that silicon and ferro silicon behave similarly and exhibit a relatively large amount of arcing. Charge chrome on the other hand exhibits considerably less arcing, and the extent of this arcing is highly correlated with the tapping of the furnace. The arcing measurements can also be used online in the control of the furnace, both for the electrodes and electrical circuit, and for the raw materials.

Jan 1, 2007

By T. Lindstad, S. Gaal, S. Hansen, S. Prytz

The SINTEF SiO-reactivity test, developed by Tuset and Raaness in the 1970?s, is a recognised method of characterising the ?reactivity? of carbonaceous reactants, used in the ferrosilicon and silicon metal industries. Recently, the test has been updated, which has resulted in the development of an extended and improved SINTEF SiO reactivity test. This has included updating the test reactor, control system, data-logging, handling and preparation of carbonaceous materials to be tested and measurement procedure. The scientific basis has been re-assessed, resulting in a new interpretation of the test results. The repeatability of the test has improved significantly, especially through system automation. In the ?old? test, the kinetics of the reaction: SiO(g) + 2C(s) = SiC(s) + CO(g) for a specific carbonaceous material was characterised solely by the ?R10? parameter, the volume of SiO(g) which passes un-reacted through the coke-bed as the concentration of CO in the outlet gas decreases from 18 to 10%. As both the kinetics and obtainable conversion of SiO to SiC for a reductant is of importance to the ferroalloy producer, the new SINTEF SiO reactivity test ranks carbon materials both according to degree of conversion and reaction rate. From research carried out on the test in the past couple of years at SINTEF and NTNU, it has also become clear that some of the reactions taking place in the test reactor are more complex than previously assumed. As an example, it was previously assumed that the condensation reaction of SiO gas in the condensation chamber of the test reactor can be described as: 2 SiO(g) = Si(l,s) + SiO2(s). However, it has been established that the side-reaction: CO(g) + 2Si(l) = SiC(s) + SiO(g) causes approximately 10% of the total volume of CO to react to SiC and SiO2 in the condensation chamber. This means that some back-reaction i.e., the reverse SiO-generator reaction 3SiO(g) + CO(g) = 2SiO2 + SiC also takes place in the condensation chamber. In the new SINTEF test, the %CO versus time curves are therefore corrected in order to describe the effect of the reaction between SiO(g) and C(s) studied i.e., SiO(g) + 2C(s) = SiC(s) + CO(g). A correction-formula for this purpose is presented.

Jan 1, 2007

By A. V. Tarasov

There are still a number of copper smelters in the world using the roasting and smelting process flow diagram for treating sulphide raw materials. The technical, economic and environmental performance indicators of such operations are inferior to the respective indicators of advanced processes. First of all with respect to copper and sulphur recovery: 95% and 75% as compared with 98% and over 90%, respectively. Based on the studies of the single-stage smelting process to produce white metal and blister copper conducted during recent years an analysis of the feasibility of roastingsmelting technology improvement was carried out in the Gintsvetmet Institute to substantially increase the copper and sulphur recoveries. On the basis of this analysis, it was proposed to modernize the technology and equipment within the framework of the existing process flow-sheet. The proposed modernization implies an increase in the roasting temperature; higher desulphurization degree in the process of roasting; a number of modifications in the roaster design depending on the particular conditions of a given operation; addition of lime flux to the feed charge to roasting; and transition to combined calcium-silicate smelting slags. The metallurgical and energy computations made have indicated that the proposed modifications of the technology will improve the copper and sulphur recovery up to 98% and 90%, respectively. The required capital investments have been estimated using as an example a particular copper smelter, the payback period determined taking into consideration additional output, fuel saving and a reduction in fines for sulphur emissions. For comparison, the capital cost of a smelter modernization is given for change-over to basically new autogenous Ausmelt, Outokumpu and V anyukov smelting technologies.

Jan 1, 2007

By I J. Holland

Located in North West Queensland, XstrataÆs Mount Isa Copper Operations (MICO) is one of the largest underground mines in Australia with annual production exceeding six million tonnes of ore with average copper grades of three per cent. As at 30 June 2006, the Ore Reserve inventory totalled 87 Mt, with annual diamond drilling planned at >40 000 m in order to convert existing resources and test and define exploration targets. The role of the geology department within MICO is to collect, interpret and communicate relevant geological information to ensure the optimal extraction of ore. Routine underground inspections across multiple ore sources are undertaken and the information derived is then distributed to a range of professionals, operational personnel and management. The information is a æreal-timeÆ geological view for the stakeholders. Ongoing data collection and interpretation has developed a strong geological input to all mine planning processes within MICO. This has created strong synergies between mine planning professionals and a throughput benefit has been seen all the way to the concentrator. The MICO geological framework also provides avenues for a geological focus away from short-term production requirements, and as a result significant orebody scale observations and patterns have been realised that have led to an increase in the accuracy of geological and resource models. This has provided practical benefits for short-term scheduling and production, whilst enabling the realisation of long-term benefits that have a strong potential to increase the volume and value of the MICO resource. This paper will discuss the various mine geology contributions at MICO and illustrate some examples where mine geological input from graduate level has added significant value to the MICO business.

Jan 1, 2007

In June, 1,334 underground construction and tunneling professionals gathered in Toronto, Ontario for the 2007 Rapid Excavation and Tunneling Conference (RETC). This biennial event, sponsored by SME, is one of the global underground construction industry?s major events. And this year?s RETC was the first one that included the new Underground Construction Association. [ ] (UCA) of SME. In addition, the conference?s exhibit attracted 125 equipment and service providers. The next Rapid Excavation and Tunneling Conference is set for June 14-17, 2009 at Caesar?s Palace, Las Vegas, NV.

Jan 1, 2007

With the increased variability of today's large-scale mining operations, consistent flotation performance is important to improving and sustaining overall recovery through the circuit. The Newcrest Telfer Mine has implemented advanced process control technology to obtain stable level operation and consistent mass pull in the copper rougher and scavenger flotation circuits. The final result has been an overall reduction in variability, which impacts on both copper and gold recovery. This paper describes the methodology and implementation of the improvements in control at the Newcrest Telfer Mine as being an essential part of the business for minerals processing.

Jan 1, 2007

By D. M. Bastidas

The reduction of copper sulfide and copper oxides originated during artificial tarnishing of copper was studied using potentiodynamic potential/current density experiments. Six copper surface treatments were considered: mechanical polishing; indoor exposure for 7 days; chemical etching in 1.6 M nitric acid; chemical etching and heating at 160°C; and chemical etching and dipping in a 9x10-4 M or 0.9 M potassium sulfide (1(25) solution at 70°C. Cuprite (Cu20) and chalcocite (Cu2S) were the main compounds formed. A linear relationship with the square root of the scan rate (v) was obtained by plotting the potentiodynamic potential/current density for the tarnish dissolution processes. A relationship between potential and current density cathodic peaks was not obtained, according to Müller's model, showing a proportionality factor with the dimensions of a resistance.

Jan 1, 2007

The development of 3D multi-parametric models facilitate the provision of resource information well in advance of the mining face. Using the model, one can evaluate mining areas not only for grade and tonnage predictions but also for predictions of rock mass quality. Blast design and milling requirements can be derived from the rock mass quality predictions. This information can be used for overall mine planning and evaluation, costing, production optimization and slope design. This allows the full range of mining activities and costs to be interconnected, thereby lowering costs and improving efficiencies through the application of the multi-parametric model. Feasibility studies for new projects require an expected budget expenditure estimate to within 5% of actual costs. This level of accuracy is expected by mining companies and investors but cannot be achieved without a sound knowledge of the rock mass variability. By developing a 3D multi-parametric model as part of the feasibility study and using the same geological model exploration boreholes, a significantly better understanding of the rock mass conditions can be obtained. This rock mass information can be used for equipment selection, economic pit layouts, processing plant design, underground mining layouts and support requirements, to name but a few design parameters that depend on rock mass conditions. The initiative at Anglo Platinums, Potgietersrust Platinum Ltd.?s (PPRust) operation, has delivered significant results showing improvements across the mine to mill value chain. These include increased loading rates, reduced electricity and crushing consumables, as well as higher plant throughput. The ore reserve model has gained international acceptance as an invaluable tool for a mining operation. Certainly most financial organizations will not invest in a mining project that does not have an ore reserve model. There is the potential for multi-parametric models to be recognized as vital tools in the mining process, as is the case with ore reserve models.

Jan 1, 2007

By M. Sanchez

In the last decades, the Chilean copper mining and metallurgical industry have had to modify their technological processes to meet the environmental regulations implemented by the Chilean government, and also to support the pressure of the public opinion. Thus, air quality standards for sulfur dioxide and particulate matter (primary and secondary), plans for reducing emission of arsenic by the Chilean copper smelters, effluents discharge limits, among others regulations were applied by the environmental agency. Additionally, agreements on cleaner production were carried out by mining sector and government. Now, a draft law on mine closure, and another on environmental mining wastes (abandoned mines) are being discussed by the authorities and the mining sector. In the context, production and environmental impacts in different ways to produce copper in the Chilean mining industry are reviewed and regulatory tendencies as well as abatement technologies today used are exposed and discussed in this presentation. Pyro, hydro and electrometallurgical processes employed and their current effluent and contaminants are presented showing various alternatives of treatment in the copper industry. An update of regulations established in Chile vis a vis copper production, with an especial attention to mine closure are also presented.

Jan 1, 2007

By C. G. Anderson

With demand and prices for copper and gold at near record high levels, coupled with a lack of readily treated orebodies, the emergence of environmentally sound hydrometallurgical treatment of enargite concentrates has become a priority. This paper will outline the application the industrially proven technologies of low pressure and temperature NSC (Nitrogen Species Catalyzed) pressure leaching and ASL (Alkaline Sulfide Leaching) for the recovery of copper and gold from enargite. Copper can be recovered as cathode metal or as a clean concentrate suitable for smelting. Gold is recovered by smelting, conventional cyanidation or alkaline sulfide hydrometallurgy. Coupled with this is the effective precipitation and stabilization of arsenic as scorodite and ferrihydrite.

Jan 1, 2007

Where space is limited, as it is throughout most of the northeastern United States, new construction either takes place high above street level, or below it. In Lower Manhattan, NY both kinds of expansion can be found in abundance. That is good news for the nearly 200 attendees at the George A. Fox Conference, presented by the Underground Construction Association (UCA) of SME at the Graduate Center, City University of New York, on Jan. 30. Among the many projects taking place in Lower Manhattan?s massive trans-formation process, are expansions to the city?s vast underground network of subways and other tunnels. ?New Yorkers either live on the ground or below it,? said keynote speaker Charles J. Maikish while explaining how an attempt to build above street level walkways never caught on in the city. Maikish is the executive director of the Lower Manhattan Construction Command Center. His job is to oversee the $22 billion project that will transform the island by 2010. From the construction of Freedom Tower at the site of the fallen World Trade Center buildings, to the expansion of the Second Avenue Subway, the extension of the East Side Access, No. 7 line, the new trans-Hudson line and numerous waterway tunnel expansions, including City Water Tunnel No. 3, the task Maikish is charged with is a huge one. He is primarily responsible for coordinating the scheduling and staging of the overall rebuilding plan, along with the day-to-day coordination of construction work down-town. He places particular focus on mitigating impacts on the environment and mobility, maintaining and improving access and alleviating congestion of any kind related to construction. At the time of the Fox Conference, there were 59 projects under way in Manhattan. All of those projects need things like concrete and steel delivered to sites in very tight working environments. And some need the equipment in even tighter spaces. ?This is not just about the recovery of Lower Manhat-tan (from the 2001 terrorist attacks) but this is a plan to restore it and to maintain its integrity,? said Maikish. ?I think that is the appropriate response to the terrorist attacks.? When Freedom Tower is completed, it will stand 541 m (1,776 ft) about the skyline. That will be a strong statement to the world about America?s strength. But it is the work that takes place much lower that was of interest to the conference attendees. On this respect, Maikish said Manhattan?s efforts below ground aim to provide relief to the city?s street level congestion and to make sure Manhattan ? already essential to the economy of the United States and the world ? stays current by upgrading the existing telecommunications and technological network while also allowing room for growth in that area.

Jan 1, 2007

By I. S. Laitinen

Outokumpu Technology has recently introduced new technology in both copper electrorefining and electrowinning. This technology includes, among other things, a new permanent cathode (Outokumpu Permanent Cathode) and new busbar technology (Outokumpu Double Contact System). The new technology has already been tested in commercial scale cells. To get a better understanding of the busbar system a multiphysical simulation model of the electrowinning and electrorefining cells was developed. A mathematical model of electrical conduction and heat transfer in a copper electrolysis cell was developed from partial differential equations. The model was expanded to a cell group including seven electrolysis cells connected electrically in series. The model was solved numerically using the finite element method (FEM). Using the model, different intercell busbar systems were simulated. Typical electrical disturbances, like loose contacts between cathodes and the main busbar and short circuits between electrodes, were included in the simulation. The results of the simulation runs with conclusions are presented in this paper.

Jan 1, 2007

By Georgene Renner, William R. Yernberg, William Gleason

American Commercial (ACI) offers a selection of ground control solutions. Beginning with steel liner plates installed in the Gratiot Avenue sewer system in Detroit, MI 1920, ACI is one of the leading designers and manufacturers of underground steel supports in North America. ACI is also a leader in fire-proofing underground structures with its Promat Fire Protection Boards. The sandwich panels have been used in many new and retrofit tunnel and underground construction projects worldwide. Ease of installation and replacement, cost effectiveness and superior performance have made this product line the premier choice of owners and designers for structural protection, fire-life safety requirements and architectural finish needs.

Jan 1, 2007

By K. Adam

The sustainable management of solid wastes, including the wastes emanating from portable batteries, consists one of the main objectives of the current EU Environment Framework Programme. Overall reduction in the quantity and volume of disposed wastes, elimination of dangerous species within the waste streams and wastes recycling comprise specific targets of this policy. Within this framework a Greek funded research project entitled ?Development of an Integrated Alternative System for the Environmentally compatible Management of Used Batteries and Accumulators - DIASBAT?, was recently completed by a research team consisting of major Greek Battery producers and retailers, Research Organisations, Universities and Environmental Consultants. The aim of the project was the development of an Efficient Alternative Management System for spent portable Batteries and Accumulators, (B&A), in compliance with the prevailing EU and national environmental legislation, taking advantage of the state-of the art technology. The present article summarises the research carried out within the DIASBAT project in order to review and develop a set of sustainability indicators for the assessment of the effectiveness of Spent Portable Batteries Management Systems (SPBMS). Based on the European experience and practice, various indicators were initially examined regarding the performance evaluation of SPBMS. Specifically, the indicators used in European studies conducted to assess the environmental, social and economic impacts of the recently issued Batteries Directive 2006/66/EC, as well as the indicators used by European Collection and Recycling Organisations (CROs) to assess the performance of SBPMS across Europe were presented and analyzed. Additionally, the set of indicators used within DIASBAT to assess the effectiveness of alternative Spent Portable Batteries Collection Schemes developed within the project, are presented. The experimental collection networks of the DIASBAT project included schools, selected retail stores and a pilot network set up by the Greek Institute of Geology and Mineral Exploration (IGME). From the evaluation of the various indicators, it was deduced that in order to assess an Integrated Spent Portable Batteries Alternative Management System, a multi criteria analysis approach is required. Within the general principles of sustainable development, there is a need for different qualitative and quantitative indicators to be combined, taking into consideration critical parameters such as: annual portable batteries collection rates, compliance with the targets set up by the prevailing European and national legislation, economic performance of the System - and finally social criteria - environmental sensitization according to age, gender, economic prosperity, educational level etc.

Jan 1, 2007

The Skorpion process comprises three processing steps-atmospheric leaching in sulfuric acid, zinc solvent extraction and electrowinning to produce special high grade zinc. The major mode of impurity transfer was attributed to crud runs in the solvent extraction circuit. Crud may be described as a heterogeneous, partly inorganic, partly organic mass of material which accumulates predominantly at the interface between organic and aqueous solutions. The paper describes the root causes of the crud formation in the solvent extraction circuit and optimization strategies which are being followed to prevent impurity excursions in electrowinning. Keywords: zinc oxide, solvent extraction, crud formation, colloidal silica.

Jan 1, 2007

Geostatistical conditional simulation is a method to assess variability and risk in mineral deposits and the tool has wide potential applications in the iron ore industry. Correct reproduction of multivariate relationships is important in iron ore simulation, especially between Fe and impurities such as Al2O3, SiO2 and P. The turning bands simulation method, using a full model of coregionalisation for multiple attributes, is the main multivariate conditional simulation algorithm used in the Western Australian iron ore industry. This paper discusses the results of a more recent approach using minimum/maximum autocorrelation factors (MAF) to transform and decorrelate the multivariate data prior to independent sequential Gaussian simulation (SGS). MAF-SGS results are compared to those of the turning bands approach in the Yandicoogina channel iron ore deposit (CID), and both methods performed well in simulating Fe, SiO2, Al2O3 and P distributions. Extensive checking of simulations showed that both approaches could reproduce multivariate statistics and spatial continuity of the original conditioning data. Both approaches reproduced the histograms and variography of input sample composites. While the MAF-SGS approach requires additional transformations when compared with the single normal scores transformation required for the turning bands method, MAF requires only that the direct semivariograms be modelled. In contrast, using turning bands with multiple attributes requires modelling a full linear model of coregionalisation, which can be difficult to model because of the need to ensure the model is positive semi-definite. Turning bands may be preferred if there are a modest number of correlated variables allowing construction of a linear model of coregionalisation that adequately models the multivariate behaviour. MAF-SGS is preferable for larger numbers of correlated variables. Both MAF-SGS and turning bands methods performed well in conditional simulation of correlated variables at Yandicoogina.

Jan 1, 2007

By Louis J. Cabri, Donald Hoy

"Samples with contrasting gold mineralization were studied quantitatively prior to metallurgical tests. The AD samples are coarser-grained and characterized by abundant Sb minerals (jamesonite, berthierite, stibnite). The finer-grained MW sample has abundant pyrite and pyrrhotite, with arsenopyrite and galena next in abundance. A large number of gold mineral particles were determined by SEM investigation of hydroseparation concentrates, ranging from 150 to 597 per sample. The grain-size distribution of the gold minerals shows evidence of bimodal grain-size distributions (volume %), with the coarse fraction being most significant in sample MW-1 (maximum ECD=308µm). The coarsest gold minerals in the AD samples range from 139µm to 281µm ECD.The deportment of gold minerals is as electrum, aurostibite, native gold, and a possible new mineral (AuNiSb4). Gold also occurs in nisbite. The gold minerals are dominated by electrum in three samples and aurostibite is next in abundance. The major gold minerals are probably representative of three stages of gold mineralization. The first stage is represented by electrum, which is partly to completely replaced by Sb-rich mineralization forming aurostibite, and the last stage is native gold, often occurring as rims on one or the other earlier gold mineral. The gold minerals are strongly associated with sulphides in the AD samples (55 to 60 vol.%). At the grind used for the hydroseparation the liberated gold mineral quantity (volume %) is also significant, ranging from 65% for sample MW-1 to 30 to 37% for the AD samples.INTRODUCTIONThe Clarence Stream deposit is located 70 km south-southwest of Fredericton and 25 km northnorthwest of St. George, south-western New Brunswick, near the international boundary with Maine (Fig. 1)."

Jan 1, 2007

By Professor of Civil and Environmental Engineering Northwestern University, Mike Wladron, Gordon Revey

A unique judicial opportunity allowed measurement of the response of three cracks in residential structure to blasting for underground aggregate mining. Instrumented cracks were located in the interior basement CMU mortar and upstairs dry wall as well as exterior brickwork. The dynamic environment was unusual. Even though the blasting occurred some 490 m (1600 ft) away, excitation frequencies were unusually high and there were no apparent surface waves. In addition there was no air overpressure wave to produce secondary crack response. As is typical, long term environmental effects produced greater crack response than did the blast induced ground motions.

Jan 1, 2007

By H. Lagendijk, I. J. Reinecke

Mintek was contracted by Oriel Resources plc in 2004 to conduct a preliminary assessment study on smelting ferronickel from the large but relatively low grade Shevchenko nickel ore deposit in Kazakhstan. A detailed feasibility study (?DFS?) was awarded to Bateman BV following promising results from the preliminary assessment study (?PAS?) and small-scale pilot plant test work. As part of the DFS, a total of 450metric tons of ore was collected from three different locations in the deposit and shipped to Mintek. After sampling, the bulk sample was prepared for smelting. This comprised crushing, screening and calcining with each step done separately for the three different lots. The chemical composition of the ore from the deposit is relatively high in silica and therefore falls out of the MgO to SiO2 range that is normally processed by pyrometallurgical means to produce ferronickel. The main objective of the testwork was to demonstrate that a method could be found and successfully applied to smelt these siliceous ores and produce an acceptable nickel-containing alloy. A 2-m ID DC arc furnace was installed with a twin-cathode (electrode) configuration to replicate the proposed commercial-scale furnace and also incorporated an advanced design of water-cooled copper panels in the lower furnace sidewalls to withstand the aggressive nature of the high SiO2-containing slags. The reductant used was a high-volatile coal from Karaganda in Kazakhstan. The reductant addition was adjusted to achieve a 90% recovery of nickel. In the assessment of the process metallurgy, some deviation from equilibrium conditions was observed. This deviation is ascribed to the intermittent existence of a smelting bath partially covered with feed during the testwork. Optimization of smelting conditions should result in the metallurgy (slag metal equilibrium) being closer to the theoretical predictions and make the production of a 20% nickel alloy possible at 90% nickel recovery. The solution for the successful processing of these siliceous ores was found in the attainment of the necessary operational stability through the control of arc length, operating temperature, open-bath smelting conditions and flux additions of up to 10% dolime for the most siliceous of the three ore types. The test work carried out by Mintek provided the basis for the process flow sheet and engineering design of the DC arc smelting furnaces for the Shevchenko Nickel project.

Jan 1, 2007

By Graham W. Gibbs

The current state of knowledge concerning mesothelioma risk estimates is reviewed. Estimates of the risk of mesothelioma exist for the commercial asbestos fiber types chrysotile, amosite and crocidolite. Data also exist on which to assess risks for winchite (sodic tremolite) and anthophyllite asbestos. Uncertainty in estimates is primarily related to limitations in measurements of exposure. Differences in the dimensions of the various fiber types and of the same fiber types at different stages of processing add a further complication. Nevertheless, in practical terms, crocidolite presents the highest asbestos related mesothelioma risk. The risk associated with sodic tremolite (winchite) appears to be similar. In chrysotile miners and millers, the mesothelioma risk has been linked with exposure to asbestiform tremolite. Exposure to chrysotile in a pure form seems likely to present a very low if any risk of mesothelioma. While the majority of mesothelial tumors result from exposure to the asbestos minerals, there are other well established and suspected etiological agents. While a practical threshold seems to exist for exposure to chrysotile, it is unlikely to exist for the amphibole asbestos minerals, especially for crocidolite. To date there is no indication of an increased risk of mesothelioma resulting from non-commercial fiber exposure in the taconite industry. © 2007 Elsevier Inc. All rights reserved. Keywords: Mesothelioma; Amosite; Grunerite; Taconite; Crocidolite; Tremolite; Anthophyllite; Winchite; Risk estimation; Etiology

Jan 1, 2007