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By T Mizuta, H Satoh, M Ogasawara, M Miyata, M Fukuyama

The Miocene Chichibu granitoids associated with the Chichibu skarn deposit are divided into North Body, South Body and Daikoku altered stock. Orebodies of the Chichibu skarn deposit are mainly distributed in the north-western part of the North Body and Daikoku altered stock. The North Body consists of magnetite-series granitoids ranging from tonalite to granodiorite and to monzogranite from the margins to the centre of the intrusion. The South Body consists of tonalite and granodiorite, and most of these rocks are also classified as magnetite-series granitoids. The Daikoku altered stock consists of a quartz diorite porphyry. The SiO2 contents of the granitic rocks of the North Body and South Body range from 61.6 to 70.7 wt per cent. During magmatic differentiation, Cu, As and Zn contents in fresh granitic rocks of the North Body and South Body increase with SiO2 content up to 63 wt per cent SiO2, and then progressively decrease with increasing SiO2 contents as SiO2 exceeds 65 wt per cent. Estimated pressure for the emplacement of the granitoids is about 0.5 kbars. Cathodoluminescence studies on quartz from those granitic rocks show that vapour rich two-phase fluid inclusions tend to occur in the core of quartz crystals, while halite-bearing poly-phase fluid inclusions occur in the margins of quartz crystals. The distribution of fluid inclusions suggests that fluid composition changed from low to high salinities during the growth of magmatic quartz crystals. Texture showing quartz crystals with an oval shape enclosed by radial aggregates of a mixture of fine-grained quartz, plagioclase and K-feldspar composing the groundmass of the monzogranite also suggests a pressure decrease during solidification of North Body. These findings show that high salinity fluids were present during magmatic differentiation and that Fe-Cu-Pb-Zn-Au-Ag skarn mineralisation of the Chichibu deposit was possibly associated with these high salinity fluids. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By D. Mohapatra

The possibility of using 2,2,4-trimethyl-1,3-pentanediol dissolved in tetrachloromethane as extractant for boron recovery is discussed. The parameters optimized for this purpose are contact time, boron concentration in the aqueous phase, extractant concentration, equilibrium pH and phase ratio. NaOH is used as stripping agent for boron recovery from the loaded organic phase. Boron extraction is found to be a slow process (equilibrium time 20 minutes) compared to boron stripping, which is reasonably fast (equilibrium time 5 min). Maximum boron extraction is possible at a broad pH range from 1.0 to 6.0. Using 1.0M extractant concentration, a 1:1 phase ratio (organic: aqueous) and two stages, ~99% boron extraction is achieved. More than 97% boron stripping is possible using 0.5M NaOH at a 1:1 (organic: aqueous) phase ratio in two stages. Overall, a 95.6% boron recovery was achieved. Loss of solvent into the aqueous phase and co-extraction of Ca, Na and K into the organic phase at higher equilibrium pH are two major concerns in his process.

Jan 1, 2008

By Rudy Rogers

When Gas hydrate formation rates have two steps: a nucleation induction step and an agglomeration step. Hydrate induction in distilled water is extremely slow because of lack of nucleating particles. Our laboratory found that synthetic anionic surfactants greatly improve both hydrate induction and agglomeration because the surfactant?s hydrophilic head absorbs water molecules and the hydrophobic tail absorbs hydrocarbon gas molecules, creating necessary nucleation sites. Vast hydrate deposits inhabit seafloors. What is the seafloor hydrate nucleating mechanism? We find that nano-particles of smectite clays (bentonite and nontronite) are hydrate-nucleating sites in sea-water-saturated, packed porous media, especially when trace quantities of anionic biosurfactants adsorb on the clay particles. Microbes and their bioproducts proliferate around seafloor gas hydrate accumulations. The seafloor microbe-mineral-hydrate synergy is explored in this paper. Keywords: gas hydrates, biosurfactants, crystal nucleation, smectites

Jan 1, 2008

By G Cormack

By designing comminution circuits for mineral liberation rather than the final recovery process and by using high mass pull gravity recovery, the concept of underground processing has become a reality. Gekko has found that many ores respond favourably to fine crushing with either high pressure grinding rolls or vertical shaft impactors which when combined with the InLine Pressure Jig gravity separator and coarse flotation results in a narrow, low-head, compact processing plant that can be sensibly fitted in existing underground openings. The focus on fine crushing reduces the power requirements of the plant to approximately 5 kWh/t for a capacity of up to 20 t/h run of mine ore feed. The use of water recycle systems places no extra load on the mineÆs normal water handling system. GekkoÆs underground processing plant, the æPythonÆ, has been designed to be towed down the decline or lowered down a shaft and is capable of being installed in sloping, non-linear drives for placement close to the working face. The overall benefit to mining companies of this concept has been estimated to be a significant operating cost-saving, lower cut-off grade and a significantly smaller environmental footprint.

Jan 1, 2008

By Marco A. S. Aguiar, Luis G. S. Sobral, Vânia Mori, Paulo A. Medeiros da Silva

"Copper occurs in the crust of the earth, predominantly, as sulphides. Among the copper sulphide minerals, the chalcopyrite is the most abundant and the most refractory to the conventional oxidative processes. This work aims at developing an electrolytic process for treating a copper sulphides flotation concentrate, more precisely chalcopyrite (CuFeS2) and bornite (Cu5FeS4) in the percentages of 70 and 30%, respectively.This paper presents a low-cost operational electroleaching process for treating copper sulphides flotation concentrates, with a high chalcopyrite content. This research practical work aims at improving the copper extraction from that sulphide mineral, in a relatively short time with low-operating cost taking into consideration the influence of a cationic surfactant. The electrolyte of the electrolytic reaction system was a 2,0 mol.L-1 NaCl solution containing CTAB, a cationic surfactant. The electroleaching system contains one DSATM (dimensionally stable anode) anode and two nickel or copper foams (threedimension electrodes. During the electroleaching process the chloride ions are oxidized to chlorine at the anode surface, which in contact with the aqueous phase generate enough hypochlorite ions to oxidize chalcopyrite.The copper ions released from the chemical oxidation process are reduced at the cathode surface as metallic copper."

Jan 1, 2008

By R. Chen

Most tunnels built in Sydney encounter similar ground situations; they penetrate either the Hawkesbury Sandstone or the shales that lie beneath the city. Tunnels in these materials are generally sup-ported by rock bolts in combination with a shotcrete lining. A method of analysis is presented to improve our understanding of the long term behaviour of fiber reinforced shotcrete (FRS) materials and the tunnel support systems. A finite element method SAFEA (Semi-analytical FE Analysis) is developed to model the combined creep behaviour of a shotcrete lining and the Hawkesbury Sandstone. To model the time-dependent creep behaviour, the bulk modulus and shear modulus of the materials are represented by logarithmic functions in time. A Laplace transform is then applied to these functions of time and the solution of the problem found from a finite element analysis. Tablot?s method is then used to invert the transformed values and find the solution in real time. The time dependent creep deflection of the numerical tunnel models reflects the interaction of the shotcrete lining and rock which have different creep parameters.

Jan 1, 2008

By C. W. Siyasiya

Process and steel chemistry differences in hot rolled Al-killed low carbon strip steel between the hot charge route (HCR) as practised in a compact strip production (CSP) plant and the conventional cold charge route (CCR) have been studied. This was done with reference to differences in reheating practice, hot rolling practice and steel chemistry through emphasis on the effects of solubility and reprecipitation of AlN in the two process/product combinations and its effect on ferrite grain size development. An earlier modelling study on the evolution of the austenite grain size in both of the above hot rolling processes has also now been extended to include an estimate of the possible effects of retained strain after the last finishing pass on the ferrite grain size. As part of this study the equilibrium solubility trends of AlN in a number of boron-free low carbon Al-killed strip steels with low and high sulphur content from the two respective processes was investigated by the thermoelectric power (TEP) technique and differences in the effects through the derived solubility equation of Log[Al][N]=2.6?9710/T at typical slab reheating temperatures was demonstrated. Ferrite grain size modelling using the significantly lower Ar3 transformation temperatures generally found in hot rolled low carbon strip steel produced in the CSP plant using the HCR compared well to the larger grain size produced in the conventional CCR strip rolling plant. Keywords: austenite grain size modelling; thermoelectric power(TEP); compact strip production (CSP); cold charge route (CCR);ferrite grain size

Jan 1, 2008

Ceremonies for the induction of four mining industry pioneers into the National Mining Hall of Fame will be held Saturday, Sept. 13, 2008 at the Charles F. Barber Pavilion of the Museum Convention Center in Leadville, CO. This will be the 21st Annual National Mining Museum and Induction Banquet. The four inductees are Lew Eklund, 76, Carrie Jane Billings Everson (1843-1914), ?Colonel? William C. Greene (1851-1911) and Arthur L. Hawkesworth (1860-1905). Lew Eklund founded Eklund Drilling that is now based in Elko, NV. He invented many designs that play a major role in today?s mining industry. His Cyclo Blower and various sampling devices he designed helped to revolutionize gold deposit exploration by allowing mining companies to effectively sample microscopic gold. Carrie Jane Billings Everson discovered and proved a method for bulk oil flotation concentration of mineral ores, the precursor to modern froth flotation methods of minerals concentration. She patented her process in 1886. In the early 1890s, coworkers built and operated demonstration plants incorporating her bulk oil flotation process. ?Colonel? William C. Greene was responsible for the development of the great copper mining properties of Cananea, Mexico. In seven years, he went from ragged cattleman and adventurer to the greatest captain of industry the borderlands have ever seen. Arthur L. Hawkesworth was a master mechanic for Anaconda Copper. He invented the detachable drill bit. His invention generated tremendous savings for the mining industry in time, in dollars and in safer operating conditions underground. His bit?s long lasting contribution to improved mine economics is immeasurable. The 21st Annual National Mining Museum and Induction Banquet will begin with an open house and reception at 5:30 p.m. followed by the dinner and program at 7 p.m. The inductions will bring to 201 the number of mining ?greats? whose engraved photographs and biographical sketches are installed in the National Mining Hall of Fame.

Jan 1, 2008

By Henk van Muijen

To create a feasible plan to extract marine minerals there are a significant number of factors that must be analyzed. Most of these are known from conventional mining types. The following issues are the most relevant factors that have to be considered for mining a deep sea reserve economically: Sufficient reliable geological, physiographic data to create a proven reserve and mineral resources, Environmental Conditions, Geological & Geotechnical Study, Mining and ancillary equipment selection (design) and suitability, Environmental Conditions, Initial Transportation (seafloor to surface), Locations for stockpiling & processing, Processing, Power requirements, Land (Seafloor) ownership, Government, Economic Climate, Waste Handling, Methods of obtaining information and Post-Mining Activities.

Jan 1, 2008

By Bart Hogeweg

The development of deep sea mineral deposits creates a new horizon for the mining industry. In a field where mining technology meets deep-water offshore engineering, new challenges are faced to come to the successful exploitation of these deposits. With the absence of proven technology for the mining of these minerals, a ?technological green field? is entered. IHC Merwede (IHC), a global market leader in the dredging and wet mining industry, is on the frontline of these developments. MTI Holland, IHC Merwede?s research and development company, has undertaken a number research efforts focused on the successful development of technology for the mining of deep sea minerals. This paper highlights a number of these efforts and illustrates IHC?s continued dedication for the research and development of technology to enable the commercial mining of deep sea minerals.

Jan 1, 2008

By Alan D. Fisher

Amtrak made a decision to replace an aging bascule bridge with a vertical lift bridge for their crossing of the Thames River in New London, Connecticut. The new lift bridge occupies the same alignment and shares the same foundations as the bascule span. During construction the deep foundation caisson supporting the bascule span settled and tilted. Investigation into possible reasons revealed interesting historical facts, both of the construction of the innovative open well caisson foundations and of the state-of-the-art in tremie concrete placing methods in use at the turn of the century. This paper describes both of these topics.

Jan 1, 2008

By M. Olper

The change in regulations and the strong attention to the environment have suggested some changes in the traditional processes for the recycling of lead acid batteries. Engitec Technologies, marketing the Integrated CX® System, is continuously updating and improving its technology to fulfil the technical, economical and ecological requirements coming from the market and from the environmental authorities. In this paper Engitec Technologies will present the latest technical innovations introduced in the Integrated CX® System.

Jan 1, 2008

By Gungor Tuncer, Ali Kahriman, Abdulkadir Karadogan, Umit Ozer, Ertugrul Kaya, Kagan Ozdemir

The results of bench blasting on quarries, have important influences on the performance of subsequent mining activities such as loading, hauling, crushing, grinding etc., and the total costs of that mine. Drilling and blasting is an important step in mine producing chain and its results such as fragmentation, muckpile shape and looseness, dilution, damage and rock softening effect the efficiency of downstream processes. Within the scope of this study, the three different hydraulic excavators’ working performances have been studied considering the particle size distribution after bench lasting at a quarry in Istanbul Turkey. Five shots have been realized on the quarry and average particle size of muckpile after each shot were assessed by digital image analysis method. Bucket loading times have been measured by stopwatch study after five shots. Excavator bucket loading times were also estimated by bucket loading time estimation formula which was published in ISEE 2007 Conference, Ozdemir et al. 2007. Estimated and measured times have been statistically analyzed and the accuracy rate of formula has been determined for five events.

Jan 1, 2008

By M I. Pownceby, W J. Bruckard

A South African chromite sample was subjected to characterisation and physical beneficiation testwork in order to assess its suitability to produce an upgraded chromite product with a silica level of <1 per cent SiO2 and a chromite level of >46 per cent Cr2O3. Chemical analysis by XRF indicated that the bulk material had a Cr2O3 content of 40.5 per cent w/w and a SiO2 content of 7.5 per cent w/w. Combined XRF analysis with sizing data showed that the majority (~70 per cent) of the siliceous material was present in the +600 ¦m fraction while ~70 per cent of the Cr2O3 was in the -600 ¦m fraction. Qualitative mineral phase analysis by XRD indicated that the sample mineralogy was dominated by ferrian-magnesiochromite spinel ([Fe,Mg]Cr2O4) and aluminium-chromite spinel (Fe[Al,Cr]2O4), with enstatite (Mg2Si2O6), haematite (Fe2O3) and anorthite (CaAl2Si2O8) as minor phases. SEM and EMP characterisation showed that the silica was mainly present in discrete enstatite grains but lesser amounts were also present as the high silica phases plagioclase and enstatite on the edge of grains. Wet gravity separation performed on sized fractions (-600+106 ¦m size range) from the -2.0 mm (primary) ore as well as the ore that had been crushed to pass 0.6 mm (secondary) showed that stage crushing of the -2 mm +600 ¦m fraction followed by wet gravity separation upgraded the Cr2O3 grade at 70 per cent Cr2O3 recovery from ~44 per cent Cr2O3 in the primary material to 46 per cent Cr2O3 (the target grade specification) in the secondary sample. It also showed that the stage crushing of this +600 ¦m fraction at a cut-off level of one per cent SiO2 increased the cumulative Cr2O3 recovery from ~50 per cent in the primary material to ~63 per cent in the secondary sample in the same size range of -600+106 ¦m. The extent to which additional crushing could lead to improved chromite recoveries at the required chromite and silica grade target specifications was not determined. This experience demonstrates that prior to processing test work being conducted, a thorough understanding of the chemistry and mineralogy of the test sample promotes efficient and targeted processing research.

Jan 1, 2008

By H. K. Lin

The effect of metallic iron fines on froth flotation of a sulfide ore was examined by comparing the flotation results with and without iron fines present in the flotation feed. Mild steel and ceramic laboratory ball mills were used to grind 600 g sulfide ore charges. The mild steel ball mill generated approximately 4.6 g of iron fines (0.8% of the ore charge mass) when grinding to a product size of 80% passing 200 mesh (75 mm). When a low dosage of a weak xanthate collector was used in flotation, the impact of the iron fines on sulfide flotation was marked. Higher dosages of stronger xanthate collectors rendered the impact of the iron fines much less significant. Consumption of the collectors by the powdery iron fines is believed to cause the differences observed in the flotation results. A galvanic effect on flotation was not evident in this study. The impact of the iron fines on silicates depression was also examined.

Jan 1, 2008

By R Lastra

Applied mineralogy involves conducting investigations on ores, minerals and materials to solve problems encountered in mining, metallurgy, processing, industrial minerals, environment, health and other fields. The investigations are performed to determine the mineral behaviours during processing by using every mineral and ore characterisation technique and appropriate instruments. As the field is young, new techniques and instruments are still being developed. This paper attempts to convey the scope of the field by:describing the capabilities of the respective research instruments for determining mineral characteristics, summarising investigations of gold as an example of applied mineralogy studies of precious metals, andpresenting a case history where applied mineralogists worked closely with mineral processing engineers on a base metal ore and mill products to help the engineers optimise their processes for maximum recoveries.

Jan 1, 2008

By Jeong-Soo, Joon Soo Kim, Rajesh Kumar, Sohn, Jin-Young Lee

"Liquid-liquid extraction (LLE) studies of tetravalent platinum from acidic chloride solutions have been carried out with Alamine 336 as an extractant diluted in kerosene. The title metal shows the inverse behavior at higher acid concentrations. Plot of log D vs. log [Acid], mol.L-1 gave a straight line with a negative slope of 0.8±0.03 indicating the exchange of one mole of hydrogen ions for every mole of platinum(IV) extracted into the organic phase. Extraction of platinum(IV) increases with increase of extractant concentration. The plot of log D vs. log [Extractant], mol.L-1 is linear with slope 1±0.3, indicating the association of one mole of extractant with the extracted metal species. The plot between metal distributions to aqueous to organic phases is 1.3±0.01; it indicates monomeric species was formed in organic phase. Stripping of metal from the loaded organic (LO) with mineral acids such as hydrochloric, sulphuric, nitric acids and bases like ammonia, hydrogen peroxide and sodium hydroxide are studied. The results indicated that hydrochloric acid and sodium hydroxide are the better stripping agents when compared with other acids and bases. Increase of temperature decreases the percentage extraction of metal indicating the process is endothermic. Regeneration and recycling capacity of Alamine 336 and extraction behavior of associated elements such as aluminium(III), magnesium(II), cobalt(II), iron(III) and nickel(II) were studied.IntroductionThe demand for platinum group metals (PGM’s) has risen in the last five years expected to keep in rising. Right now, the demand is already beyond the supply. The primary use of PGM’s today is in the automotive industry. Catalytic converters used in the PGM’s process to reduce greenhouse gases. Because of the current demand to reduce the green house effect the expected need for platinum is here stay. Country’s now advancing in the use of car production also are phasing increasing the needs for this metal. Chemical processing also use it, too. These industries account for more than 50% of all platinum production. Jewelry is other primary use of this precious metal whose value is much greater than gold. Other uses include computer data storage, scientific developments, fuel cell technology and in the glass manufacturing processes."

Jan 1, 2008

By Braden Lusk, Kyle Perry

Recent events and MSHA actions have resulted in discussion and reevaluation of the practice of sealing abandoned coal mine workings. In the past, MSHA has approved alternative seals based on a pass/fail system that required minimal engineering. Disasters involving fatalities led MSHA to impose higher seal pressure requirements based on research and experiments. Impending new MSHA seal regulations will force manufacturers and industry to obtain a high level of engineering expertise. The expertise necessary is in the field of blast resistant design, which is not easily accessible due to the limited number of experienced individuals within the mining industry.

Jan 1, 2008

By Brett Campbell

The San Vicente to 2nd Aqueduct Pipeline?Tunnel project is a raw water conveyance tunnel linking the San Vicente Reservoir (SVR) to the 2nd Aqueduct Pipeline via Rancho Penasquitos Pressure Control Facility (RPPCF). This 58,230 lf long tunnel will be 8.5? final ID, and has four points of construction access. The job is classified into 6 Reaches of tunnel, identified by the dominant geology within the reach. This paper will focus on Reach 3, specifically the measures necessary to drill and blast a 550 lineal foot section of granitic rock tunnel immediately in front of an open face digger shield.

Jan 1, 2008

By M Fahey, A B. Fourie

Over the past ten years, the mining industry has witnessed the introduction of a new and innovative mine filling technique known as paste fill, which consists of placing full stream tailings with small amounts of binder and water into underground stopes. Paste fill has benefits over traditional backfill methods, such as higher solids contents than hydraulic fill and easier transportation than rock fill. From a geotechnical perspective, the behaviour of very fine material in a fully saturated state can be complex, particularly when binder is added. Previously, there has been no rigorous solution to understanding the paste fill deposition process, resulting in uncertainty regarding critical aspects such as barricade load calculations. This uncertainty has the obvious consequences of potential barricade failures (including at least 12 over the past four years), and for many operations attempts to deal with this uncertainty has led to excessively conservative filling schedules, restricting production. This paper presents an application of Minefill-2D, the first rigorous model capable of representing the paste fill deposition process. The model couples the processes of material accretion, consolidation and cement hydration to calculate the distribution of stress around a stope (including the total stress applied to barricade structures) during filling. Minefill-2D is a finite element numerical program, which has been verified using laboratory element tests, centrifuge tests and in situ measurements (Helinski, 2008). The authors present a sensitivity analysis, carried out using the model, to demonstrate some of the critical and less critical aspects relating to paste backfill deposition. The results of this sensitivity analysis are used to devise a fill management strategy that can be utilised to minimise the risk of barricade failures and maximise fill rates where appropriate.

Jan 1, 2008