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A wide range of models are available to computer process simulators that require a large number of parameters which often are physical measurements, coefficients, calibration factors and functional forms. This makes it intuitively difficult in the majority of cases, to tune the parameters in order to simulate a circuit in agreement with experimental results. Unit calibrators operating on the principle of least squares minimisation of the difference between predicted and observed plant data, are relatively successful when the parameters are unconstrained and independent of each other. In the case of constrained parameters, a set of carefully chosen transforms is presented which map the unconstrained variables being minimised into the constrained parameters required for the model. This technique has been used successfully with the Powell minimisation algorithm and it may also be applied to other unconstrained minimisation methods. Necessary model characteristics are discussed to enable these transforms to be applied to interdependent model parameters such as points of a graph. Examples of the calibration of several unit models using these transforms are presented. KEYWORDS: Calibration, optimisation, transforms, process simulation.

Jan 1, 1993

By Y. H. Tang, H. Y. Zhang

"Tailings from lead-zinc mine contain plenty of dolomite and low-grade fine-grained barite, which is difficult to enrich by mineral processing. Since the density of barite and dolomite has some differences due to the fine dissemination size in a complex sedimentary, the gravity separation tests were conducted with no results obtained. The magnetic separation was conducted to remove the magnetic gangues, and the results were not satisfactory because of the gangue minerals such as limonite and others were low in content. The results of floatation tests showed that the mineral separation of barite and dolomite is quite difficult because that they have similar mineral floatability. Experimental research shows that the good results can be obtained by “desulfurizationbarite floatation” processing with the new depressant TS. The barite concentrate containing BaSO4 91.27%, BaSO4recovery is 70.25% when sodium dodecyl sulfonate serves as a collector and TS as the depressant.INTRODUCTIONBarite is an important mineral material. Often associated with other minerals, it usually needs to be separated by mineral processing in order to meet the application requirements. The main barite beneficiation methods include hand sorting, gravity separation, floatation, magnetic separation, acid leaching, etc. Usually barite associated with oxide ore such as fluorite dolomite, quartz ore etc. are also associated with sulfide ore such as pyrite, sphalerite and galena. The separation between barite and sulfide ore (such as pyrite) is easy. On the other hand, the separation between barite and oxide ore (such as dolomite and fluorite) is very difficult. There are quite a lot of reports on the separation between barite with fluorite dolomite however the separation between barite and dolomite is seldom discussed.The ore properties are quite complex attributable to mineral assemblage containing a large amounts of dolomite. As the density of barite and dolomite has some differences, gravity separation between them is usually easy. The gravity separation tests were conducted with no results obtained due to the fine dissemination size in a complex sedimentary. The magnetic separation was conducted to remove the magnetic gangues, and the results are not satisfactory as the gangue minerals such as limonite and others were low in content. Due to the fine dissemination and intimate association of minerals, and barite and dolomite contain the same group ions of Ba2+, Ca2+ and Mg2+, the results of flotation tests showed that the mineral separation between barite and dolomite by flotation means problematic. Previous studies have been conducted by several institutions but none to date has come up with a satisfactory process in dealing with the deposit. This may be attributable to: high cost of reagents; unsatisfactory performance. Therefore, the key to the flotation separation of barite and dolomite is the application of selective inhibitors. Based on previous test observations and years of extensive research experience in barite processing technology, with the new depressant TS has selectivity inhibition on dolomite developed and used, good results can be obtained by “desulfurization-barite flotation”, which allows barite in the lead-zinc tailings to a comprehensive recovery."

Jan 1, 2018

By M. L. Clark

Advances in the recovery of gold from heap leaching are being made daily, but of all the systems vital to the maximum recovery of gold from a leach pile, none is more important than the methods used to construct the pile in preparation for the leaching operation. The technology described in this paper illustrates the latest systems developed to minimize compaction in the pile during its construction and reduce the cost of placement of ore on the pile. The Florida Canyon Mine of Pegasus is evaluated in detail to show reasons for its high degree of success to date.

Jan 1, 1988

By B. S. Ignasiak, Dennis Carson

"Laboratory study of the behaviour• of binary coal blends shows that coke strength is more closely dependent on the distribution of ""reactive"" oxygen in the parent coals than on their proximate, elemental or petrographic compositions, and it also appears possible to qualitatively predict coke strength from information about reactive oxygen. Proceeding from this recognition, experiments were carried out to test the possibility of preparing metallurgical cokes from binary blends in which non-caking hvb coal was substantially freed of reactive oxygen by prior heat t1•eatment under controlled conditions. The results indicate that such blends can yield surprisingly strong cokes and that coke strength may be amenable to further improvements by modifying the size distribution of the pre-heated component and the rate at which it is charred."

Jan 1, 1976

By T. J. Driscoll

In this Bureau of Mines investigation, the electrochemical polarization behavior of Fe and Fe-1BCr has been characterized in rigorously controlled 1[N] H2S04 solutions stirred with oxygen or an inert gas. Samples that under-went various levels of corrosion or passivation were examined using Auger electron spectroscopy (AES) and ion sputtering. Passivation of iron occurred at a potential of approximately 0.6 volt (1) in poorly stirred, oxygen-saturated solutions for forward polarization (scanning from cathodic to anodic potentials); (2) in pH-adjusted (increased), well-stirred, oxygen-saturated solutions for forward polarization; and (3) in well~ and poorly stirred, oxygen-and helium-saturated solutions for reverse polarization. Passivation of Fe-18Cr occurred at a potential of approximately -0.1 volt in helium-, nitrogen-, and oxygen-saturated solutions for all cases of forward polarization and most cases of reverse polarization. Elemental depth profiles obtained from AES sputtering measurements indicated that films or adsorbed species were present on iron samples in solution subjected to open-circuit, active, and transpassive corrosion, cathodic reduction, and passivation. This conclusion was reached by considering the distribution of the solution species, primarily sulfur, in the films, which were composed primarily of iron and oxygen. Sulfur was present throughout the films on actively corroding samples, in the outer regions of films of passive and transpassive samples, and on the film surfaces of open-circuit and cathodically reduced samples. For Fe-18Cr, sulfur was found on the surfaces of films on passive samples only, indicating that only the passive samples had films on their surfaces in solution. The films on electropolished and passive Fe-1BCr samples had the largest chromium concentrations, estimated to be approximately 45 at. pct, with less chromium in films of cathodically reduced, active, and open-circuit samples, in that order.

Jan 1, 1979

The effectiveness of three different types of longwall chock under the three different types of geological conditions worked recently is outlined. Some provisional analyses of the variation of chock load under the shale roof con- dition are briefly discussed and some problems and solutions of gateway and road- head support outlined.

Jan 1, 1974

By B. Das, V. Hucka

In light of the present energy crisis, coal appears now as the only reliable source of energy. The production of coal is expected to regain a rising trend after the latest slump. Aside from the competitive price with natural gas and oil, the other retarder of coal production is its environmental pollution effect. Gasification of coal has been advanced as the partial solution to the energy-ecology crisis. All the Advantages In situ gasification of coal may be considered a further step in this direction. It carries all the advantages of normal coal gasification as a stable source of energy; it is clean to handle and nonpolluting of the environment. It partially and sometimes fully does away with mining, makes uneconomical low grade coal and lignites economical and places some formerly unworkable seams within the scope of modern technology. The seams posing problems for mining due to tectonic disturbances may be converted into gas in situ. Low grade coals, such as lignites, which otherwise would be left in nature as uneconomic wealth, may be exploited by underground or in situ gasification. Thus, in situ gasification is likely to increase the exploitable reserves of coal and may reduce the cost of production. An additional merit of this method is that coal substance never reaches the surface and there is no problem of cinder disposal.

Jan 8, 1973

By Mark D. Hannington

Drilling of the active Trans-Atlantic Geotraverse (TAG) deposit during ODP Leg 158 indicated that the size of the mound-stockwork complex is approximately 3.9 million tonnes, including 2.7 million tonnes of massive and semi-massive sulfide (ca. 2% Cu) at the seafloor and 1.2 million tonnes of mineralized breccias (ca. 1% Cu) in a subseafloor stockwork. Quartz-pyrite veining in the stockwork zone extends from about 40 meters below seafloor (mbsf) to a depth of 95 mbsf. Siliceous wallrock breccias in the lower part of the stockwork grade abruptly into chloritized basalt breccias at the margins of the mineralized zone, and massive sulfides at the flanks of the deposit onlap relatively unaltered, partially hematized basalts. The pipe-like dimensions of the stockwork zone do not exceed the diameter of the sulfide mound. Comparisons with samples collected during earlier dive series confirm that the vent complexes at the surface of the mound are not representative of the bulk composition of the deposit. Dramatic vertical zonation of metals within the mound suggests that a long history of hydrothermal reworking has effectively stripped the constituents that are soluble at lower temperatures from the massive sulfides and concentrated them at the top of the deposit through a process of zone refining.

Jan 1, 1998

By Tracy Jarrett

In 14-karat gold alloys, as in 10-karat gold alloys,3 the addition of such metals as zinc, nickel, copper and silver produces a wide range of physical and chemical proper-ties such as color, hardness, corrosion resist-ance and melting points. These important factors made gold alloys desirable in the optical work and for jewelry. In 14-karat gold alloys, as well as in 10-karat or 12-karat, it is possible to have two golds of the same color, one of which will corrode more than the other, although it may be harder. Some of these alloys have been investigated by F. E. Carter,1 E. M. Wise,5 and L. Sterner Rainer.4 In this group of alloys the gold content of 58.3 per cent (14-karat) was held constant, while the copper varied from 36 to 24 per cent. The balance of the alloy consisted of one, two, or three of the metals silver, zinc, and nickel. All the alloys were melted in an induction furnace and cast into an ingot that meas-ured 3 by 1/4 by 3/4 in. The method of determining the melting points, color deter-minations and acid test have been discussed in previous papers by the author.2,3 It is necessary to use small test bars (Fig. r). The tensile bars were annealed at 1300°F. for 20 min. and then air-cooled. There being a very marked drop when the yield point was reached, "the drop of the beam" method was used in determining the yield point.

Jan 1, 1940

By E. N. Durussel

"The Fox Mine has been producing copper/ zinc ore since 1970 at a rate of approximately one million tons per year, and until 1978all production was derived from longhole open stopes. In June 1978, a trial stope using bighole mining methods was started to eliminate the development of two sublevels between 400 level and surface. The trial proved to be successful, and bighole mining is now an accepted mining method for both stopes and pillars at Fox Mine.When production blasting was started in the first stope, the biggest problem encountered was the production of large amounts of sulphur dioxide gas as a result of secondary sulphide dust explosions. This gas generation resulted in lost production time and caused minor damage to underground installations to the blast level, and to the headframe. Sulphur dioxide generation has been noted in secondary drawpoint blasts and, on rare occasions, in drift rounds.This paper discusses the occurrence of the sulphur blasts and the practices and precautions used to prevent their reoccurrence at Fox Mine.IntroductionThe Fox minesite is located 30 miles southwest of Lynn Lake, Manitoba. With production startup in 1970, Fox Mine is owned and operated by Sherritt Gordon Mines Limited.The Fox orebody occurs as a large lenticular zone of semi-massive sulphides approximately 1,500 feet long and 15 to 100 feet wide running east and west. Dipping 70 degrees to the north, the orebody tends to bottom out at the 3200-foot level and reaches to within 15 feet of surface."

Jan 1, 1981

By E. F. Loiseau

IN a paper on the manufacture of artificial fuel, read at the Philadelphia meeting of February, 1878, I enumerated the difficulties which I had to overcome before succeeding in the mixing of coal-dust and clay, the compressing of the same mixture, and the water-proofing of the lumps. The drying of the lumps, after leaving the press, was the remaining difficulty, and it was expected that a plan devised by Dr. Charles M. Cresson, of Philadelphia, would enable us to dry the fuel as rapidly as it was moulded, and that a continuous production could in that way be obtained. The company was reorganized. The works were purchased by the new company at an assignee's sale, and the oven was modified, according to Dr. Cresson's plan. Anticipating a possible failure, I had prepared a plan by which I expected to be able to demonstrate that anthracite coal dust mixed with pitch, could be manufactured with our present machinery slightly modified ; so that after all, if we were compelled to give up the attempt to make fuel for domestic use, there was a possibility of succeeding in the manufacture of a good steam-fuel. The plan suggested by Dr. Cresson for drying the pressed lumps of coal-dust cemented with clay, did not work as well as we expected. It enabled us to dry more fuel than we did before, but it could not be made to dry more than one-half of the lumps produced by the press. The plan was abandoned, and I was authorized to experiment with coal-dust and coal-tar pitch. The cement which is used in Europe to conglomerate coal-dust is ,usually dry pitch, which is prepared by separating from the tar, at a temperature of 572° Fahrenheit, the volatile matters which it contains. Some manufacturers, however, employ crude tar, others, a rich tar, which has been cleared of 25 per cent. of its volatile substances, by heating it to 392° Fahrenheit. But with common tar very weak fuels are obtained, which do not burn well, and give out a strong smell and a great deal of smoke ; it is also necessary to subject them to a baking process, in order to solidify them, and to eliminate the more volatile of the materials contained. This operation of course requires a special plant, the cost of which increases sensibly the price of manufacture, without counting the products

Jan 1, 1880

By F. C. Appleyard

A couple of miles southwest of the town of Saltville in the western tip of Virginia is a little village called Plasterco. Gypsum has been produced in this area since about the year 1815, being originally found as small outcrops at the surface. Production in the early days was very small, and the use of the mineral was limited to that of "land plaster" or ground gypsum which was spread on the land to sweeten the soil. In the late 1800's, a small calcining plant was constructed and the production of gypsum plaster began. About this same time, the surface rock was depleted and it became necessary to begin underground mining operations in order to maintain a continuous supply of raw material. The United States Gypsum Company became interested in this property in 1909, and has operated there ever since, having enlarged the calcining mill and built a plant for the manufacture of gypsum wall-board in the middle 1920's. Production of gypsum continues from underground' mining operations, and the present mine at Plasterco is now about 1,000 feet below the surface, making it the deepest gypsum mine' in the world.

Jan 1, 1965

By Paul E. Richardson, Edwin E. Maust

Cyclic voltammetry and surface potential (photovoltage) measurements have been carried out on galena electrodes in sodium tetraborate solutions with added HC1 and NaOH to adjust the pH over the range 2 to 13. The first technique shows that the surface species formed on moderate anodic polarization and reduced on subsequent cathodic polarization are the same over the entire pH range. At anodic potentials, a soluble metal species and excess sulfur are formed; at cathodic potentials, sulfur is reduced to a soluble species. More importantly, excess surface sulfur is formed spontaneously under zero current conditions in alkaline solutions. This has been shown to occur on both polished surfaces and on virgin surfaces produced by in situ cleavage under the electrolyte. The photovoltage gives some insight into the charge and potential distribution at the galena surface. This is found to depend on past electrochemical history and the n- or p-type semiconducting character of the electrode and is interpreted in terms of changes in the surface stoichiometry that occur during reduction or oxidation. The effect of surface stoichiometry on subsequent xanthate interactions is discussed.

Jan 1, 1976

W. G. MATTESON, Houston, Tex.-I think that Mr. Powers has given us some very valuable information on the Healdton field, which is of material interest in view of the fact that the Healdton field has passed Cushing in the point of production, and if not leading, stands second only to the new El Dorado field in the point of production of the oil-in this country. Mr. Powers says that the deepest producing sand at Healdton is 1860 ft. Within the last 3 or. 4 months they have drilled to 2700 ft. there and found a sand which is producing very high-grade oil, if I remember correctly, about 42 gravity. Another very important point brought out by Mr. Powers is the fact that the Pennsylvanian beds and the Permian beds are conformable according to his interpretation. He seems to have based his interpretation upon the gathering of a number of well logs and a very careful study of them, but it seems to me the information furnished by the, well logs is really insufficient to justify such an important conclusion. In the first place, the difficulty of interpreting the line of demarcation between the Permian "Red Beds" of Oklahoma and the top of the Pennsylvanian is apparent, for the reason that sometimes the uppermost Pennsylvanian formation has a reddish phase and the line of demarcation is not very sharp.

Jan 4, 1918

By C. J. Roos

Ground-engaging tools are used to prevent damage to the main components of earth-moving equipment. These tools consist of everything from shovel teeth to replaceable drill bits to dozer wear plates. The costs of these "consumable" items are increasing with the costs of raw materials. This project developed a tool to be used by Newmont Mining Corp. to predict the consumption of excavator teeth at a particular mine site. This paper presents the results of the Montana Tech research project in which an equation was developed to predict excavator teeth consumption based on production rates and rock properties.

Jan 1, 2010

The design of a sand pump is similar in principle to that of a water pump but differs in several areas. Results of experiments on sand pump performance have been summarized and values of design parameters quoted for optimum results. Typical performance data are also Included.

Jan 1, 1973

By Gao H

Based on the author's research and plant practice experience of the last decade, several technological approaches have been developed to increase the recovery of gold and silver associated with sulphides. This paper gives a general discussion of some technological problems encountered in this area in five aspects and introduces the different approaches employed in three typical mineral processing plants to increase recovery of associated gold and silver. On the basis of studying occurrence characteristics of gold and silver minerals in sulphide ores and of determining loss locations of gold and silver on flotation process, a remarkable improvement on the recovery of gold and silver in all these three plants was made by choosing proper grinding fineness, using combined collectors of good selectivity, properly decreasing the grade of main metal concentrates, making reasonable arrangement of the products of main metals, or a combination thereof.

Jan 1, 1993

[Trans. No. Place Date Vol. Page 1, Wilkes-Barre, Pa.* .... May, '71.. 1 3 2. Bethlehem, Pa Aug., '71.. 1 10 3 Troy, N. Y Nov.,'71.. 1 13 4. Philadelphia, Pa Feb., '72.. 1 17 6. New York, N. Y •.... May, '72.. 1 20 6. Pittsburgh, Pa..:.Oct., '72.. 1 25 7. Boston, Mass Feb., '73.. 1 28 8 Philadelphia, Pa.' May, '73.. 2 3 9. Easton, a Oct., '73.. 2 7 10. New York, N. Y Feb., '74.. 2 11 11. St. Louis, Mo.* May, '74.. 3 3 12. Hazleton. Pa Oct.. '74.. 38 13. New Haven, Conn Feb., '75.. 3 15 14. Dover, N. J.' May, '75.. 4 3 16. Cleveland, 0 Oct., '75.. 4 9] [ ]

Jan 1, 1925

By T. D. Jones

Describes the facilities in South Wales for routine control and research work on all the various aspects of the dust problem. Considers mining and medical research, inspection and control, education, and plans for the future.

Jan 1, 1947

By I. Iwasaki

Platinum group elements (PGE) are often found in arsenide and sulfarsenide minerals as inclusions in copper-nickel bearing gabbroic rocks. Major losses of platinum in flotation have been attributed to the poor recoveries of the arsenic minerals. Flotation characteristics of a synthetic nickel arsenide and arsenopyrite were studied through rest potential and oxidation rate determinations, surface analyses, and micro-and batch-flotation tests. The use of nitrogen during grinding and flotation together with copper activation improved the PGE recoveries from Duluth Complex ores. The flotation behaviors of the sulfarsenide minerals are still unresolved. The role that electrochemical interactions play among arsenides, sulfarsenides, sulfides and grinding media on their f10atabilities is discussed.

Jan 1, 1988