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By Bora Derin

This study is a collection of both newly published and/or presented works on impurity capacity predictions in molten melts which were carried out by Derinetal. Some sulfide capacity prediction results of iron oxide containing ternary silicate melts and industrial lead and copper slags using the Reddy-Blander model and some impurity capacity predictions of multicomponent oxide and salt melts obtained using a Artificial Neural Network Approach are discussed.

Mar 1, 2017

By Laura Angeles, Martin Reyes, Ivan Reyes, Miguel Perez, Francisco Patiño, Mizraim Flores, Elia Palacios

Chemical and mineralogical characterization of a sulphide ore from the mining district of Zimapan, Hidalgo, Mexico, was performed in order to obtain accurate information on the composition of the ore to optimize the subsequent flotation process. A combination of techniques was used: Scanning Electron Microscopy (SEM) with Energy Dispersive Spectrometer (EDS), X-ray diffractometry (XRD), Inductively Coupled Plasma (ICP) and Fourier transform infrared spectroscopy (FTIR). The SEM mapping confirmed the presence of the elements: Ca, Si, Fe, K, S, Al, Zn, Mg and Mn. The XRD analysis suggests that the ore matrix is calcite; additional species found were wollastonite, johannsenite, and pyrite, among other impurities. The FTIR analysis performed for the aqua regia insoluble showed the presence of calcium oxide, copper oxide and silicon oxide. The results for the ICP analysis were:13.31% S, 2.55% Fe, 0.46% Zn, 0.03% Cu, 0.06% Pb, 0.07% Mn, 0.09% As, 0.01% Sb and 0.08 grton-1 Ag.

Mar 1, 2017

By Chengyi Ding, Xuewei Lv, Senwei Xuan, Jie Qiu, Yun Chen, Kai Tang

Isothermal reduction kinetics of CF2 by 30% CO and 70% N2 at 1123, 1173 and 1223 K was investigated by TGA in this study. The reduction rate analysis indicated that reduction of CF2 comprises three stages during the whole reduction process, Apparent activation energy of samples CF2 reduction is 34.37 kJ/mol. The ln-ln analysis implied the reduction of CF2 was expressed initially by a 2D subsequently by 3D shrinking layer reaction.

Mar 1, 2017

By Donggen Fang, Liu Xuan, Jilai Xue

SiO2 and Al2O3 in the metallurgical slag of nickel laterite ore have great recycling values. In this work, Si and Al were extracted from the slag in NaOH based molten salts through alkali roasting and water leaching process for preparing zeolite materials. The extraction ratio of SiO2 increases with increased temperature and appropriately prolonged time, and more than 80% SiO2 can be recycled from the slag after roasting at 550°C. Si and Al from the slag are in the filtered liquor for producing zeolite materials, while Mg, Ca, Fe and other impurities remain in the leached residues. Adding Na2CO3 into the alkalin-slag roasting process can reduce the amount of pure NaOH used with minor decrease in extraction ratio of SiO2, while make better separation of Ca to avoid it getting into the filtered liquor. Adding Al2O3 into the alkalin roasting process can replace part of more expensive NaAlO2 addition that is required for preparing zeotite material, which may bring out a minor decrease in extraction ratio of SiO2 due to formation of NaAlSiO 4 in the filtered residues. Quality X zeolite and 4A zeolite materials can be made from the starting liquor containing Si and Al recycled from the laterite nickel slag through alkali roasting and water leaching process.

Mar 1, 2018

By Mostafa Maazouz, Jeff Blackwood, Mauricio Gordillo, Sang Hoon Lee, Micah Ledoux, Liang Zhang

To meet rising requirements for the low-damage ultra-fine process with the focused ion beam (FIB) in the materials science and semiconductor industry, the advanced ion column and corresponding advanced applications as a solution are developed and demonstrated. Novel high-speed high kV milling, low kV cleaning and imaging capabilities have enabled the creation of impeccable ultra-thin structures such as TEM samples and nanometer scale structures. Minimizing Ga+ induced sample damage is achieved through the optimized final cleaning at 500 eV ion landing energy with the new ion optics, which utilizes close control of the ion dose, beam incidence angle, spot size, pattern algorithm and imaging performance. Newly introduced process solutions achieve the improved process throughput. Initial demonstration is performed on the latest 14 and 10 nm scale FinFET device. Validation of the thinnest <0.8 nm thick ion damage layer on the <7 nm thick lamella structure was confirmed through TEM analysis.

Mar 1, 2017

By Shusen Cheng, Dongdong Zhou

The high temperature distribution in ironmaking and steelmaking industry is very important to control the smelting process. Although equipment is available to measure the temperature in the smelting process, in general it could just measure one certain point or only at discrete times. The real time temperature distribution in ironmaking and steelmaking is important because it could reflect reaction information and help to control the operation parameters. In this paper, a new method to detect the temperature distribution in ironmaking and steelmaking through the application of digital imaging system based on the color CCD was studied. In addition, the two-color method and partial least square method were used in the calculation model to improve the accuracy. The results agreed well with the measured temperature.

Mar 1, 2017

By I. Moscoso, R. Padilla, M. C. Ruiz

Antimony and arsenic are impurities in copper concentrates found normally as stibnite (Sb2S3), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4). When copper concentrates contain appreciable amounts of As and Sb, they must be removed before smelting to avoid environmental pollution. Oxidizing volatilization roasting at 500–700 °C has been used to eliminate these impurities. However, only a fraction of Sb volatilizes in those conditions; thus, a more effective process to eliminate antimony from concentrates is needed. In this study, the chloridizing roasting of Sb2S3 using CaCl2–O2 was investigated to remove the antimony from concentrates. XRD analysis of calcines indicated that the overall reaction could be written as: Sb2S3 þ3CaCl2 þ6O2 ¼ 2SbCl3 þ3CaSO4 Temperature and oxygen partial pressure have a significant effect on the rate of reaction. An estimated conversion of about 90% was obtained at 750 °C, 5.4% oxygen in 20 min. High oxygen concentrations arrest the advance of the reaction forming various antimony oxides including Sb6O13, Ca5Sb5O17 and Sb2O4.

Mar 1, 2017

By Vahid Javaheri, David Porter, Tun Tun Nyo

A field emission scanning electron microscope equipped with EBSD has been employed to evaluate the role of 0.013 wt% Nb on the evolution of the microstructure and texture of a novel thermomechanically processed low-alloy, medium-carbon steel. Specimens were subjected to hot-rolling with a total reduction of 80%, four passes in the recrystallization regime and four passes below the non-recrystallization temperature. Immediately after rolling, the strips were quenched to 420 °C and subsequently cooled slowly in a furnace to simulate strip coiling with transformation of austenite to bainite. The results showed that Nb microalloying results in a finer microstructure with a sharper texture when compared to an identical steel but without Nb. In addition, analysis of the retained austenite texture indicated that the main bcc texture components are the product transformed brass and copper components in the parent austenite.

Mar 1, 2018

By HeeDong Lee, Owen Reedy, Lawrence Matson, Naidu Seetala, Thomas Key

Spark Plasma Sintering (SPS) consolidated ZrB2+SiC composites using nano-powders (around 40 nm) showed smaller grains compared to those using micron size powders and segregation of SiC into islands is minimal but with higher oxidation of ZrB2 to form ZrO2 in nano-composites. Argon-gas purging prior to SPS consolidation at around 2000 °C and 40 MPa of ZrB2+20vol.%SiC nano-powders was used to minimize the oxidation and obtain fine granules with high densification. The densification of the Argon-gas purged nano-composites is higher compared to those consolidated without Argon gas purging. The EDX analysis showed a strong reduction in the oxygen peak for the Argon gas purged composites. The XRD spectra also support this observation with less ZrO2 phase composition in Argon gas purged composites. The Vickers micro-hardness showed slightly lower values for Argon gas purged composites though they have higher densification.

Mar 1, 2017

By Juárez T. Julio Cesar, Mendez R. Eliecer, Reyes P. Martín, Flores G. Mizraim Uriel, Teja R. Aislinn Michelle, Hernández C. Leticia, Reyes D. Iván Alejandro

The present study shows the characterization of a zinc concentrate collected at Hidalgo, Mexico, in order to identify its mineralogical species and to propose a leaching methodology for silver recovery. The results obtained by X-Ray Diffraction (XRD) show Sphalerite (ZnS) as the mineralogical matrix and silver into the specie proustite (Ag3AsS3). The techniques of Scanning Electron Microscopy-Energy Dispersive Microanalysis (SEM-EDS) and Polarized Optical Microscopy (POM) identified the presence of sulfides of Fe, Cu, Pb and Zn, in addition to silicates and feldspar. The proposed dissolution method of Ag(I) was carried out with [S2O3 2−] = 0.5 M and [NaOH] = 0.1 M to regulate the medium at pH = 9 for 12 h at 298 K. Oxidation of the concentrate was favored by injection of O2 to a partial pressure of 1 atm. Monitoring of the reaction was carried out by reading the [Ag] and [As] by AAS.

Mar 1, 2017

By Beatryz C. Mendes, Márcio Sampaio S. Moreira, Rita de C. S. S. Alvarenga, Juliano Correa

Over the last decades, modern technology to build wood structures have been substantially developed. Building solutions for floor systems of wood-concrete mixed T-beams with wood web and concrete flange stand out among these technologies. This work describes an experimental investigation of the performance of bond connectors made of round steel bars for wood-concrete mixed elements. Symmetric three-member specimens were built. The middle member was made of concrete and the other two were made of wood. The first kind of connector consisted of steel bar designed as straight pins with head, normally driven through the wood. The second kind consisted of arc-shaped connectors directly embedded into the wood or bonded using epoxy adhesive. The specimens were then tested in compression. The compressive strength and the force-displacement curve were obtained, in order to evaluate the failure mode and obtain the stiffness in the ultimate (Ku) and serviceability (Ks) limit states. The stiffness values were calculated in the interval corresponding to the secant straight line between, respectively, 10–40 and 10–70% of the ultimate strength. The obtained results indicate high strength and ductile failure mode for all of the cases. Bond stiffness gains were verified when using the arch-shaped connectors.

Mar 1, 2017

By Ruilin Yang

Explosive blasting is a widely used method for rock breaking, recognized for its energy efficiency and cost-effectiveness. Despite its advantages, the efficiency of blast energy can vary significantly between different blasts. This paper introduces a new blast efficiency index to assess the energy efficiency of rock blasting, incorporating factors such as explosive consumption, the energy required for fragment surface generation (based on fragment size distribution), and the strength reduction of rock fragments due to blasting. Several examples presented in this paper demonstrate the calculation of the blast efficiency index using data from the literature. The findings indicate that blasting may be the most efficient method for rock breaking compared with direct mechanical techniques of rock breaking used for excavation. On the other hand, blasting is much less efficient compared with the controlled fracturing, such as the cleavage and fracture toughness testing, which highlights the significant potential to further enhance the efficiency of explosive energy usage for rock fragmentation during blasting. The proposed blast efficiency index can be integrated with advanced blast modeling techniques to optimize blast designs, thereby increasing the effective utilization of explosive energy for rock fragmentation and fragment strength reduction.

Jan 26, 2026

By Jaime Herrero, Santiago Gómez, Pablo Segarra, José Ángel Sanchidrián

This paper presents a mathematical model for the study of the 2D movement of blast bench faces based on the high-speed video analysis of three blasts at El Aljibe quarry (Spain) recorded at 2,000 frames per second. In these blasts, a set of bags of 0.75 × 0.75 m were placed in front of a selected blasthole defining a reference plane in which to study the kinematics of the movement. The burdens range from 3.86 m to 5.54 m, with a bench height of 12–13 m. An affine transformation system was calculated to convert coordinates from the video images into actual spatial coordinates. The problem is established from a multi-objective minimization approach in order to simultaneously optimize two defined objectives: trajectory fitting using Total Least Squares regression, and time–displacement regression using Ordinary Least Squares. Muti-objective minimization formulation produces Pareto plots of non-dominated solutions, i.e., optimal combinations of initial velocities and response times, (i.e. time between detonation and the onset of bench face motion). From the Pareto frontier, the most balanced solution is selected. Blast response time lasts only a few milliseconds and appears so brief at the frame rate used that it is difficult to detect visually. In this context, the bi-objective optimization-based approach proves to be a more robust tool than frame-by frame survey for quantifying such a rapid event while also maintaining a strong performance in the trajectory fitting task. Root Mean Square Error (RMSE) for the two minimizations average 0.22 m and 0.13 m, respectively. The initial velocities obtained range from 4 to 17 m/s, and the response times 0.7 ms to 21.7 ms. An analytical model is also presented for predicting fragments initial velocity and response time as functions of blast geometry and rock mass properties, explaining approximately 87% of the total variability.

Jan 26, 2026

By Jorge Cardenas, David Martinez

Blasting-induced vibrations can be predicted with high precision, allowing for the optimization of sequence design, delay timing, and charge configurations to minimize their indirect impact on rock masses. This optimization leads to a reduction in peak particle velocity (PPV) and dominant frequency at monitoring points. However, a crucial aspect of slope safety is estimating the degree to which vibrations influence stability through numerical modeling of the dynamic response. Slope stability is closely linked to rock mass strength, the predominant failure mechanism based on discontinuity orientation relative to the slope face, and the pre-existing stability conditions before dynamic alterations occur. Blocks, wedges, and planar failures tend to slide under lower vibration levels and are more susceptible to resonance, particularly in fractured and low-strength rock masses. To evaluate the interaction between rock mass and vibrations, photogrammetry and artificial intelligence were employed to identify discontinuity families at vibration monitoring sites. This data facilitated the development of artificial discontinuity networks (DFN), which replicated a discontinuous medium within a numerical finite element model. The input signal was recorded at the slope base using triaxial geophones and incorporated into a discontinuous numerical model. The output signal was estimated through finite element analysis and subsequently compared with geophone measurements taken at the same location. Based on real-world output signals, damping parameters and the model’s natural frequency were adjusted to align both frequency spectra. Using the calibrated parameters, vibration records from various blasting projects at different distances were applied as input signals until slope failure was induced, thereby defining maximum allowable vibration limits in terms of PPV and frequency at the monitoring point. This approach provided a framework for optimizing sequence designs, charge configurations, and delay timings to enhance slope safety and prevent failure due to blasting-induced vibrations.

Jan 26, 2026

By Joe Atalla, Leojenen Etulle, Jesse Desrochers, Joseph Mukendi Kabuya, Remi Proulx, Ruilin Yang

The Mont-Wright mine is Canada's largest open-pit iron ore mine with multiple open pits in operation. It is operated by ArcelorMittal Mining Canada in the northeast of the province of Quebec, near the town of Fermont. Fragmentation of rocks with explosives generates vibrations and gas expansion that damage intact rocks, affect existing crack networks, reduce the shear strength of discontinuities and the quality of the rock mass of the highwalls. The efficiency of its blasting operations is challenged by the need to optimize production and manage the risk of mine slope instability caused by vibrations from successive blasts. This paper presents a Multiple Seed Waveform (MSW) vibration model that was established at the mine for this purpose. Near-field signature hole blast vibration monitoring was conducted in multiple areas to establish site characterization as input to the blast vibration modeling at the highwalls of the site. The vibration attenuation laws were established and the effects of different blasthole diameters, shifting frequencies and presplit design were evaluated. Based on the results obtained from the near-field blast vibration monitoring, the calibrated MSW vibration model was used to select blast design parameters to control blast vibration while maximizing productivity of blasts at Mont-Wright mine.

Jan 26, 2026

By Kahmmelly Mathildes Pimenta Coelho, Felipe Dantas, Jaine Ribeiro de Souza, Augusto Ferraz, Carlos Roberto Campos Junior, Davi Bastos Martins de Oliveira

The Carajás Iron Mine, recognized as the largest iron ore province in the world, is notable for its continuous efforts to improve operational efficiency and safety. In response to these objectives, a QA/QC (Quality Assurance and Quality Control) Program was implemented and integrated with Blastscout Probe technology to optimize drilling and blasting processes. The program supports the standardization of operational parameters, the execution of regular audits, and real-time data analysis, facilitating precise and timely adjustments. The implementation led to significant improvements, including an 80% increase in operational compliance, a 49% reduction in drilling depth deviations, and a 30% enhancement in Jaspelite fragmentation. This study presents the methodology employed, the outcomes obtained, and the positive impacts observed in both operational performance and environmental management.

Jan 26, 2026

By Juan Pablo Henríquez, Sebastian Lozano, Constanza Soto, Gonzalo Segura, Carlos Torres, Danko Morales

The Atacama Kozan underground mine, located in Tierra Amarilla, Atacama, Chile, was facing over-excavation and slow progress in drift construction, issues associated with the use of traditional explosive, ANFO. The presence of water in the blast holes required as well the use of cartridged emulsions, which extended loading times and increased operators’ effort. With loading times ranging around 76 minutes and lower advanced rate, Enaex Underground proposed the use of a pumpable emulsion-type explosive to optimize blasting, enhance safety, and streamline the operational process. This explosive is loading into the blasting holes using an UBT equipment (Unidad Bombeable para Túneles in spanish). This equipment allows mechanized loading, adaptation to small and medium diameter boreholes, ensuring compatibility with varying drilling profiles, integration with Atacama Kozan’s operational equipment and improvement in environmental and occupational conditions, with a measurable reduction in contaminant emissions and worker exposure risks. The implementation of this emulsion-based explosive allows an increase in productivity in drift development. A notable effective advance rate of 95% to 96% was achieved, alongside a reduction in overbreak in 7%, and a decrease in loading time to 40 minutes. Additionally, there was a 40% occurrence of drilling half cast, contributing to contour drift quality. The operation also benefited from a cleaner and safer working environment, enhancing operator ergonomics and reducing the need for jetanol and compressed air.

Jan 26, 2026

By Luis Huaroc, Jorge Cardenas, José Salvador

One of the current challenges in mining is managing increasingly competent rock conditions within the mine-to-plant value chain, particularly when working with marginal ore grades. This study presents a case from a Peruvian open-pit operation where the mine plan projected a significant increase in rock hardness, as measured by the Axb index (parameters derived from the JK drop weight test). In response, the Drill and Blast Technical Team made efforts to increase the powder factor by reducing drill spacing and increasing the explosive charge, employing high-energy explosives (3,090 kJ/kg). However, this adjustment presented a challenge in achieving the fragmentation required to meet the target throughput of 97,500 tons/day, resulting in a shortfall of approximately 8.7% under the base case scenario. To overcome this technical challenge, the use of locally engineered ultra high-energy explosives was proposed, offering adjustable energy levels ranging from 3,210 to 3,570 kJ/kg. This solution enhanced ore blending strategies, calibrated to specific Axb ranges. The results also suggest that microfractures generated by the energetic blasting designs contributed significantly to downstream improvements. These outcomes demonstrate the value of a fully integrated mine-to-plant strategy, aligning blasting parameters with downstream processing performance to maximize operational efficiency. This solution led to a 10% increase in process plant efficiency, a 16% reduction in specific energy consumption during primary crushing, and a 13% reduction in the SAG mill. Additionally, shovel productivity rose by 18%, and the dig rate improved by up to 35%. Keywords: fragmentation, blending, high-energy explosive, power factor, microfractures, specific energy consumption and Axb model.

Jan 26, 2026

By Iván Aguirre Palacios, Jean Guiroux Toro, Eduardo Valdés Guerra

Currently, mining operations seek to be competitive in the market. To achieve this, one of the relevant factors is to maintain and improve the productivity of the extractive processes, mainly the loading from the point of opening of the mineral bodies. To do this, many techniques suggest reducing production costs, with the first opening of your free-face up raises. However, there are different ways to carry out these open-face raises up opening processes, where the balance of costs and construction time must be well planned to meet production plans. Operationally, there are different techniques for its construction, the most common being Blind-Hole up Raises and those with drilling with current production equipment that operates mining operations. This study shows a methodology and the results of the implementation of access stack drilling with production drilling rigs for a maximum height of 15 m with electronic detonators in production blasting. Within the methodology used, Qa/Qc processes were considered in cargoes with explosives, instrumentation for monitoring (vibrations), VOD registration, among others. As a result, of a total of 12 raises up blasts, construction time was reduced by 45% and the cost of drilling and blasting (P&V) was reduced by 50%, for up raises with a maximum height of 15 meters. Regarding the efficiency of the heights, this was 97% compared to the planned drilling design.

Jan 26, 2026

By Orica Peru, Pedro Lozada

Proper management of exclusion zones in blasting operations is essential to ensure safety without compromising operational efficiency. In Peru, mining regulations establish minimum exclusion distances specifically for personnel (500-meter radius / 1,640 feet), but do not define clear technical criteria for equipment. As a result, conservative distances such as 200 meters (656 feet) are often applied, negatively impacting productivity. This study proposes a technical-scientific methodology to reduce equipment exclusion zones, based on the use of advanced technologies such as drones, high-resolution cameras, and specialized software tools. The solutions used allow video recordings of blasts to be transformed into dynamic data through artificial intelligence and computer vision, as well as execute probabilistic simulations of the flyrock phenomenon using Monte Carlo algorithms and physical models calibrated to real operating conditions. Technological integration enabled the simulation of real operational scenarios, considering variations in critical blasting parameters that directly affect flyrock generation, such as drill diameter, explosive density, linear charge, and stemming height. Additionally, the Terrock methodology was incorporated, allowing the behavior of the rock mass to be included as a variable in risk assessment, improving analysis accuracy under different rock hardness conditions. The methodology was applied in four phases: diagnosis of the current design (15 blasts), modeling, validation of the calibrated model (6 blasts), and subsequent operational implementation. As a result, it was determined that the exclusion radius can be safely reduced from 656 to 492 feet (200 to 150 meters), maintaining as the main restriction the use of stemming lengths greater than 5.0 m. This optimization has the potential to generate tangible benefits, with estimated monthly savings exceeding USD 50,000, associated with reduced evacuation times, lower fuel consumption, less equipment wear, and increased productivity in drilling and hauling activities. The comprehensive approach presented here highlights the transformative potential of digital technologies applied to blast management, contributing to safer and more efficient mining operations.

Jan 26, 2026