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By Nobuaki Sato, Tetsuo Fukasawa, Akira Kirishima

To apply the fluoride volatility process for the treatment of fuel debris formed in the damaged nuclear reactors, study on the fluorination behavior of main constituents, such as fuel and cladding is essential. The mixture of uranium and zirconium oxides is formed under severe conditions such as high temperature and oxidizing atmospheres. In this paper, fluorination and volatilization behavior of uranium and zirconium oxides have been studied by TG-DTA method in the presence of fluorine. From the TG-DTA result of UO2 in F2 atmosphere, the weight gradually increased up to 7% at 350 oC followed by rapid weight decrease with exothermic peak showing the vaporization of uranium as UF6. ZrO2 showed similar fluorination behavior to that of UO2. However, fluorination of UO2-ZrO2 seemed to be suppressed with increasing ZrO2 amount. This may be caused by the formation of solid solution.

Jan 1, 2016

By Ayşe Ece Yıldızçelik, Mehmet Buğdaycı, Onuralp Yücel

ZrB2 and TiB2 are significant metal borides. They are being used in various industrial areas from space technology to nuclear industry owing to their physical properties such as high melting point, high thermal/electrical conductivity and low density. Present study was conducted in two main stages: self-propagating high-temperature synthesis (SHS) reactions and leaching. ZrO2, TiO2, B2O3 were used as starting material and Mg was used as a reductant to produce ZrB2-TiB2 powders via SHS. Therefore, it was aimed to determine production parameters, leaching conditions and comprehensive examination of final product features. The samples were characterized by using chemical analysis (AAS), XRD, XRF and SEM/EDS techniques.

Jan 1, 2015

By Gordon T. Austin

The combined production value of natural abrasives, which consist of tripoli, special silica stone, garnet, staurolite, and emery, increased in 1987. The increase was, in certain cases, because the materials were used in nonabrasive applications, such as the increased use of tripoli as a filler and special silica stone material as a special-purpose crushed stone. The increased use of garnet as a blasting media accounts for most of its growth. Production and sales of garnet were at a record-high level in 1987. [ ]

Jan 1, 1989

By Robert W. Hunt

(Cleveland meeting, October, 1912.) PERHAPS of all the scientific economic questions which have been claiming the attention of capitalists, metallurgists, manu-facturers, directors of public utilities, and the general public of America, during the last few years, none have been of more importance than the one relating to the wear and safety of steel rails. The discovery of the Bessemer process made possible modern railway development. In that growth, as has generally happened in all progressive movements, ill its department have not remained equally balanced. Iron rails permitted the construction of roadways for the passage of power-driven vehicles. In time the speed and weight of such carriages proved too much for the wearing-qualities of the rails, and the limit of railway capacity seemed to have been reached. Bessemer made his invention, which was soon perfected and developed, especially as related to steel rails, and thereby increased the limit of capacity, acid vastly greater railway progress was, made possible. The Siemens-Martin open-hearth process followed, and was later supplemented by the Thomas-Gilchrist basic improvement. For a time the Bessemer steel rails of commerce Were, more than equal to all that was asked of them, but this did not long continue, as evidenced by the records in our Transactions. Revolutionary changes occurred in the industrial world, and in no part of it more than in steel-rail manufacture. Great and powerful commercial combinations were made, whose financial resources made possible the supplanting of the then most efficient blast-furnaces, steel-works, mid mills, by others of theretofore unimagined capacity. Old traditions and practices of steel-making were wiped away, and, in too many cases, output was apparently the chief aim, with the result that much dissatisfaction with the wear and safety of rails was felt by railway officials, and the general public was concerned as to its safety when traveling. The climatic conditions of the winter

Dec 1, 1912

By Stanko Nikolic, Oscar Mendoza, Christian Pasten, Stuart Nicol, Ben Hogg

ISASMELT™ technology is based on the use of an elegant furnace system design which uses submerged lance technology to provide highly efficient mixing and reaction of feed materials in a molten slag bath. Within Peru the ISASMELT™ technology has been applied to the Southern Copper Ilo Smelter, part of Grupo Mexico. Southern Copper selected the ideal technology to meet their sulphur capture and particulate emissions requirements whilst minimising capital and operating costs. The commissioning of the ISASMELT™ in 2007 marked the modernisation of the primary smelting section of their smelter, with traditional batch converters still used for the secondary smelting stage of the copper production flowsheet.

Sep 30, 2022

By Alexandre Gonçalves Andrade, Crisley Dellaqua Pacheco, Gabriel Miranda Teixeira, Aline Maria Santoro Nasaré, Tatiane Ferreira Alvarenga

Diffuse emissions are that directly related to particulate matter suspended from civil structures, materials disposed in conveyor belts carried out by wind, stack e reclaimers operations and that one where dust collectors are not able to act correctly. Vale implemented in the last years a unique system capable to measure this kind of dust, called RAMPs (Dust Monitoring Automatic Network), which creates an analytical net in Tubarao industrial site, located in Vitória, ES. In order to prevent diffuse emissions in Tubarao’s pellets stockyard, it was proposed and developed a predictive model based on operational and climate variables available on the site, using big data and advanced analytics tools. The models developed shows to be adherent to the real emissions rates measured by the RAMPs and proved to be an efficient tool to predict emissions over the internal target with 4 hours of precedence.

Oct 1, 2019

By Priscilla Messias Pereira, Wellington Bonelar dos Santos, Alex Dalapicola Veronez, Maurício do Santos Rocha Junior, Leandro Resinentti Zanon

The pelletizing process allows inputs to be added to the mixture resulting in better control of the physical, chemical and metallurgical characteristics desired by the pellet. Anthracite is incorporated as input of the pellets as an alternative form of fuel, making the burning more homogeneous, "from the inside out", benefiting the physical resistance of the burned pellets and aiming to reduce the cost of natural gas during the stage of hardening. However, the amount of anthracite should not exceed an optimum value, which may cause an adverse effect on the physical quality of the pellets. Hence, it is very important an accurate control of the coal dosage. Based on that, the present study presents the implementation of a control using advanced control system that applies, using linear regression of historical data, the optimum relationship between anthracite and ore (respecting the physical quality of the pellets during processing in pelletizing furnaces). After the implementation of this control, it was possible to adjust the anthracite dosage automatically, measured in percentage of fixed carbon in the mixture, when the process is able, thus reducing the specific consumption of natural gas.

Oct 1, 2019

By Miguel Araújo Vasconcelos Filho, Ulisses Tetti

In order to determine the influence of the number of increments of the sinter sample on the variability of the chemical composition obtained in Sinter Plant production, a variographic study was carried out. It was performed with two series of samples. The first series was composed of 40 samples with a 6-second interval, with the objective of obtaining the so-called minimum practical error, resulting from the extraction processes of the sample of the conveyor belt and preparation and analysis in the laboratory and the second series composed of 60 samples with a range of 4 minutes, which points to the sample selection error. The results obtained showed that the minimization of the sample selection error occurs for increments spaced in 15 minutes, being in agreement with ISO 3082, but with significantly better results than those currently practiced for intervals between 1hour increments. It was then decided on the suitability of the sampler to allow hourly increments to be collected and on a second opportunity to install a sampling tower with primary and secondary samplers to collect increments every 15 minutes including sample size reduction.

Oct 1, 2019

By Olivier Lacroix, Dubé Mathieu, Guylaine Laforest

The reduction behavior of iron ore pellets in gas-based DR shaft processes has been studied at COREM since the late 80s. At that time, a new DR characterization test called COREM R180 was developped in collaboration with ArcelorMittal Mines Canada (former Quebec Cartier Mining) and ArcelorMittal Long Products Canada (former ISPAT Sidbec Inc.). This paper describes COREM’s approach to improve its understanding of the relations between iron ore pellet microstructure and pellet quality. The differences between the DR90 and the R180 tests are discussed. The evolution of the microstructure during reduction of both tests is also described. The reduction steps during the two tests are put forward as an important factor impacting the microstructural changes as well as the test results.

Oct 1, 2019

By Luiz Afonso Andrade, Pablo Amâncio de Freitas, Ana Patrícia Andrade Jaccard, Eduardo Cezar Ribeiro, Ana Christina Pitard Lima, Rodrigo Ribeiro de Souza

A análise dos carvões em mistura é de suma importância para redução dos custos e controle de qualidade de uma coqueria, esse trabalho trata da influência da cominuição comum de carvões de diferentes ranks, assim como suas implicações no processo de amostragem e consequentes desvios nas análises. O processo de produção da mistura de carvões na Ternium Brasil possuía um desvio não rastreado entre matéria volátil resultante da amostragem automática da mistura de carvões e a matéria volátil esperada pelo resultado da média ponderada dos carvões individuais no recebimento, para tal foram estudadas todas as etapas do processo de produção da mistura de carvões desde a variação dos carvões em pilha, escoamento em silos e na etapa anterior e posterior a britagem. Os dados foram comparados e foi feito um plano de ação para redução do desvio.

Oct 1, 2019

By Bi Zongyue, ZhangYongqing, NiuTao, Guo Aimin

Over the past twenty years, significant advances have been made in the field of microalloying steels and associated applications, among which one of the most successful application cases is development and application of heavy-gauge X80 coil with high temperature processing HTP practice used for China's Second West-East pipeline, the longest X80 pipe in the world. During this process, HTP design concept has been sucessfully applied to develop 18.4mm X80 coil with demanding low-temperature fracture toughness requirements. In the meanwhile, China's metallurgical workers have further optimized HTP design concept with the aid of powerful rolling mill and coiling equipment, and made it possible to develop 21.4mm X80 coil used for Russia-China East line. In the paper, we would simply review the development history of high-strength pipeline steels, and then give more priority to the fundamental points for sucessful development of 18.4mm X80 coil and SSAW pipe, which paved the way for subsequent development of 21.4mm X80 coil and SSAW pipe. Finally, we would present the test results of mass production and burst tests, and dispel the suspicion that SSAW pipes made of X80 coil are more qualified to resist ductile fracture.

Oct 1, 2019

By Dimas Henrique Barros Andrade, Roberto Abreu Alencar

O algaraviz é uma parte importante do sistema de sopro de um Alto-Forno, utilizado para direcionar o sopro e combustíveis injetados para a ventaneira, por conseguinte o interior do forno. O algaraviz consiste em uma caraça metálica revestida de material refratário com resistência ao calor e uma camada de isolante térmico entre o refratário e a carcaça. Falhas em serviço de algaravizes costumam a gerar grandes danos materiais, financeiros e com grande risco à vida dos operadores, por isso o controle e inspeção da integridade estrutural e térmica dos algaravizes é de suma importância. A inspeção nos algaravizes é realizada a fim de se detectar precocemente pontos quentes que são indicativos de falhas estruturais no algaraviz. Portanto este artigo foi feito um modelo numérico de transferência de calor, a fim de se averiguar as condições do algaraviz, de forma a verificar se o algaraviz em condições normais de operação mantem as condições térmicas. O modelo revelou resultados satisfatórios de forma que em comparação com resultados de inspeções em peças em operação se obteve um erro de cerca de 8%.

Oct 1, 2019

By Odair José Kirmse, Bruno das Chagas Bernardo, Simony Barboza, Vinícios Andreatta

Neste trabalho buscou-se avaliar o consumo de sucatas com elevador teor de enxofre, em carro torpedo, sem afetar a qualidade final do produto, objetivando a recirculação de um coproduto gerado internamente e aumento do rendimento de gusa distribuído para Aciaria. A sucata em questão é gerada a partir do beneficiamento da escória resultante do processo de raspagem após dessulfuração do ferro gusa em panela (KR) e do procedimento de limpeza dos carros torpedos. Foi avaliada a operacionalidade da adição, riscos envolvidos no processo e redução da geração com reaproveitamento direto no processo. Os resultados mostraram que existe viabilidade técnica e ganhos financeiros significativos

Oct 1, 2019

By Anand Kumar Agrawal, Kinzel Klaus Peter, Lorenzo Micheletti, Cristiano Castagnola, Horst Kappes, Andre Oliveira, Björn Rösner, Philippe Bermes

Blast furnaces are widely employed today for iron production all around the world, with a total production of around 1.2 billion tons per year. Its operating principle, which relies on usage of coke to reduce the ore, to ensure the permeability in the reaction vessel, to maintain its flexibility of operation and acceptability for varying qualities of iron ores. The blast furnace route is widely considered as the most economic and efficient route of iron production, however it is based on fossil energy carriers. The blast furnace route has undergone significant developments in terms of energy efficiency in the last decades, which led to a substantial reduction in the use of fossil reduction materials. Being an energy intensive process, competitiveness and cost saving in the blast furnace plant was always strongly related to the saving of energy and hence reduction of CO2 emissions. In addition to this, EU emissions trading system (EU ETS) as a cornerstone of the EU's policy in response to climate change has set new “challenges” for iron production in Europe. Paul Wurth has always been deeply involved in the development of energy saving technologies for blast furnaces. In the following a review of energy saving achievements developed in the last decades will be presented and the potential of available CO2 saving technologies will be summarized. Additionally, an outlook about the potential of future technologies, concepts and their impact on the blast furnace and the steel plant’s energy balance will be discussed. Finally, the replacement of carbon by hydrogen as reduction agent in the steel plant will be reviewed, with special focus on a comparison of costs and incentives.

Oct 1, 2019

By Danilo Gonçalves de Oliveira, Rogério Martins Pereira

Chatter is a widely studied vibration phenomenon that affects most cold mills around the world and its impact on these lines are tremendous: from productivity and quality losses to mechanical equipment damage. The investigation of its origins and how to minimize the occurrences and their impact on the equipment require special instrumentation and algorithms in order to have a detection of the vibrations as soon as they start. This paper presents three methods of identification of chatter on a Tandem Cold Mill and the actions to leave the vibration frequency range before its amplitude achieve catastrophic values.

Oct 1, 2019

By Thomas Höfler, Michael Auinger, Bernhard Linder

Gas-fired pusher furnaces are commonly used to heat steel slabs before hot rolling. Temperatures well above 1000 °C combined with an oxidizing atmosphere containing H2O, CO2 and O2 result in rapid oxidation of most steel grades. The resulting oxide scale and the chemistry of the metal-scale-interface are major determining factors for the occurrence of hot rolling defects. To better understand these phenomena, lab-scale trials were performed with two different steel grades in an electric tube furnace in the temperature range 1000-1250 °C, using an atmosphere of about 20 % H2O, 7 % CO2 and 3 % O2. Humidification of the gas was achieved by evaporation, using a custom thermostat with standard laboratory glassware. The resulting samples were prepared metallographically, using cold mounting under vacuum with taper section angles, and analyzed using light microscopy and SEM/EDS. The scale structure of the Si alloyed steel was highly dependent on the oxidation temperature due to the formation of eutectic liquid phases of FeO, Fe2SiO4 and FeAl2O4. Below the eutectic temperature, the scale of the Si steel appeared to be made up of three distinct areas: The external scale consisting solely of Fe oxides, the internal scale containing Fe2SiO4 and FeAl2O4, and an internal oxidation zone with SiO2 and Al2O3 in a mostly plain Fe matrix. Comparisons of the experimental results with simulations of the internal oxidation showed good qualitative agreement.

Oct 1, 2019

By Marco Túlio Santiago Ferreira, Nilton Carlos Torquato, Washington Pirete da Silva

In 2005, with the significant reduction of iron content in the “Quadrilátero Ferrífero” reserves, Vale began the study of alternatives for the tailings disposal in other structures, that are not tailings dams. In 2011, after bench-scale and pilot-scale tests, it was defined to implement the project "Alternative methods for tailings disposal", including the construction of experimental drainage piles to get mineral and geotechnical process parameters for future projects. The result of this study shows that it is technically possible to replace traditional tailings disposal (dams), to dry stacking, with the proportion up to 20% of ultrafine tailings in the total tailings composition, however, this study is in evolution and the scale of the project / pile is being gradually increased to guarantee a good performance for the mineral and geotechnical process.

Oct 3, 2019

By Caio Henrique Vidigal

No processo siderúrgico de uma usina integrada são gerados diversos combustíveis como subprodutos, os quais são reutilizados internamente ou mesmo, comercializados. Na ArcelorMittal Tubarão, isso ocorre com o Alcatrão, um subproduto do processo de coqueificação do carvão. No Presente trabalho são descritas melhorias implantadas no Sistema de Carregamento de carretas para comercialização do produto na empresa. Essas melhorias visaram eliminar duas fragilidades do sistema original: o risco de transbordo devido dificuldade de visualização do nível da carreta e o risco de exposição do motorista/operador aos hidrocarbonetos presentes no alcatrão, em caso de deficiência do sistema de exaustão dos vapores gerados e da não utilização correta dos EPIs definidos para a atividade. Para tal, foram realizadas algumas adequações ao processo, com a instalação de uma cabine para operação remota do carregamento e para monitoração do nível das carretas, utilizando um sistema de visão termográfica.

Oct 30, 2017

By Marcelo Macedo Fialho

No processo produtivo de aço, as empresas buscam continuamente a redução do custo de produção. Isto pode ocorrer através de diversas formas, tendo como as principais, o ganho de rendimento, o aumento de produtividade, a redução do homem hora aplicado e a redução do custo de matéria prima. Objetivando reduzir o custo de produção integrado placa bobina, a ArcelorMittal Tubarão busca aumentar o percentual de placas enviadas diretamente do Lingotamento Contínuo de Placas para o Laminador de Tiras a Quente. Os ganhos se dão, em primeiro plano, através da redução da intervenção nas placas aumentando o rendimento de placa e exigindo menos mão de obra para o corte e escarfagem de placa e, em segundo plano, através do aumento da temperatura média de enfornamento, propiciando maior produtividade no laminador de tiras a quente e menor consumo de energia para realizar o pré-aquecimento da placa antes do processo de laminação. Somado a isto, a maior disponibilidade de placas no pátio do LTQ, aumenta a chance de laminação exigindo menos paradas do LTQ e aumentando a produção. Os ganhos estimados com o projeto, apenas no que diz respeito a redução de custo de condicionamento são de 6MUSD/ano.

Jul 30, 2018

By Mateus Costa Corona

A ArcelorMittal Tubarão busca continuamente aumentar a sua produtividade, com isso, é necessário que as áreas de apoio a produção acompanhem este crescimento e sejam capazes de processar todo o volume produzido, sem comprometer a produção, a qualidade dos produtos e os prazos de entrega para os clientes. Os conceitos lean foram aplicados ao processo da Área de Condicionamento de Placas, com foco no aumento da produtividade e redução do lead time de processamento das placas.

Oct 30, 2017