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By W. H. Ode, F. H. Gibson, W. A. Selvig

The great expansion of production of aluminum for war purposes has aroused some concern regarding the available supply of carbon suitable for making carbon electrodes required in the electrolytic aluminum process. Approximately three-quarters of a pound of carbon electrode is consumed for each pound of aluminum produced. 5 Because of its small amount of impurities and its suitable physical characteristics, calcined petroleum coke is the standard material used by the aluminum industry for making electrodes As it may be necessary to use some substitute materials, the possibility of using coke made from coal has been considered. Besides this possible use, information concerning the source of low-ash coals is of general interest. Specifications of the aluminum industry for calcined petroleum coke suitable for the manufacture of electrodes are very stringent in regard to allowable impurities. In one such specification the maximum allowable ash is 1.0 percent; the maximum allowable content of iron (as Fe) is 0.06 percent and that of silicon (as Si) is 0.08 percent; the maximum for cal- cium (as Ca) and for sodium (as Na) is 0.12 percent for each, but the two combined may not exceed 0.12 percent; maximum allowable sulfur is 2.0 per- cent. The presence of barium, nickel, chromium, manganese, cobalt, or vanadium is objectionable, and only extremely small amounts are allowed. In regard to physical properties, the coke is required to be so thoroughly calcined that it has a real density of at least 2.02.

Nov 1, 1943

By Oliver Q. Leone

Three electrorefining cells were designed to investigate various factors associated with the electrorefining of reject - grade titanium sponge . Operation of the cells provided information on cell design as well as on how design and operating variables affected the quality of the titanium product . A sodium chloride - titanium chloride electrolyte was used , and the electrolyte chambers had capacities ranging from 400 to 3,500 pounds of molten salt . Major factors investigated were electrolyte composition , temperature and useful life , effect of various cathode shapes and materials of construction , methods for removing cathode deposits , effect of current density and cell potential , and the mechanics of deposit growth and crystal morphology . One of the cells was in intermittent operation over a 4 - year period and produced 2 tons of refined titanium . A product with a hardness of 80 or less Bhn (Brinell hardness number ) was consistently and easily obtained . Some metal with a hardness of less than 60 Bhn was produced . In one of the cells in which the electrolyte was held at operating temperature with an internal heater an ac input of 25 kw maintained 3,500 pounds of electrolyte at 850 ° C , but with an external heater 35 kw was required to maintain 400 pounds at 850° C.

Jan 1, 1964

By F. E. Block, Robert R. Brown, A. W. Henderson

The chlorination of Cr₂ 03 (chromic oxide ) in the presence of carbon with CC14 (carbon tetrachloride ) and COCl2 (phosgene ) chlorinating agents was investigated by employing the radioactive tracer carbon By tagging carbon mixed with Cr₂ 0з , the chlorination reaction was evaluated in terms of the competitive reaction of the elemental carbon and the carbon contained by the chlorinating agent . A unique gas - analysis train was used to separate the chlorination product gases ; CO , CO₂ , and COC12 . The C¹ activity of the gases was determined and used to calculate the reactivity of each source of carbon . Reactivities were determined for the temperature range from 600 ° to 900 ° C. The results of the investigation show that each source of carbon reacts significantly with the Cr2 03 and that the reactivity of each form of carbon depends on the reaction temperature , and each form is independent of the other . Radioisotope and gas - analysis techniques are discussed and a description of the experimental apparatus is given .

Jan 1, 1964

By D. B. Dow

The transportation of any commodity which is actually or potentially a source of fire or explosion, has been made safe, insofar as humanly possible, by rigid requirements as to inspection mechanical safety devices, and by printed labels. For the most part these precautions have been sufficient. This is evident when it is considered that in the thousands of instances in which commodities with a great fire risk have been transported, few disasters have occurred. This paper deals with the recent gasoline explosion which occurred at Memphis, Tennessee. At 7:50 a.m. January 24, 1921, vapors from a tan: car of gasoline became ignited and resulted in a blast that killed eleven people and badly injured nineteen others. Probably forty or fifty men, women, and children received slight injuries from falling debris or from burns. The explosion wrecked an oil plant, leveled a block of frame buildings, and broke window panes within a radius of five blocks.

Feb 1, 1921

By Robert M. Becker

This report (the second in a series of five) presents the mathematical development in extending the theory of sample reliability from a sample consisting of a fixed number of items to a sample consisting of a fixed amount of items. Examples of a fixed amount of items per sample are samples consisting of a fixed weight or a fixed volume of unequal size particles. The probability distribution functions (those here called the compound binomial and compound multinomial functions) are developed from fundamentals. Their distributions are generalized to include some measured characteristic of the items. Infinite population moments are derived from moment-generating functions, while finite population moments are developed from corresponding infinite population moments using the finite probability operator defined in part 1 of this series.

Jan 1, 1964

By W. W. Odell

The results of the 1921 cooperative experiments conducted by the U. S. Bureau of Mines and the University of North Dakota at the University mining substation plent at Hebron , North Dakota , pointed clearly to certain definite dep ficiencies in the schemes hitherto developed for benefiting and utilizing lignite . First The apparatus used in the carbonizing process or used to produce carbonized lignite suitable for briquetting is too costly , that is , the cost per ton day of residue made is too high . Second - The depreciation of the carbonizing appara tus is too high . Third The carbonizing apparatus can not be operated intermittently without seriously damaging it and impairing its efficiency of performance . Fourth Too little attention has been given to the possibility of using at least a certain percentage of the carbonized lignite directly in suitable stoves and furnaces without briquetting or other treatment . Accordingly , consideration was given to the design of an oven that could be built at a mine without the importation of highly skilled and specially trained construction men , erected at a low first cost , readily kept in a state of repair , operated at a rela tively high capacity and put into operation or shut down at will without seriously damaging the brickwork . The need of such an oven was appreciated also by the University of North Dakota and a cooperative agreement was made to build and operate such an oven during the summer of 1921.

Feb 1, 1923

By H. R. Babitzke, H. Kato, R. E. Siemens, G. Asai

The purpose of this investigation was to develop a wide variety of columbium and tantalum alloys and to determine their suitability for use at elevated temperatures . Sixty - nine columbium and tantalum alloys were investigated . For this study , columbium was alloyed with two or more of the following : nium, tungsten , vanadium , titanium, and zirconium . Tantalum was alloyed with vanadium or hafnium, or hafnium and carbon . The fabricability was determined by an arbitrary procedure . Hardness measurements , elevated - temperature tensile properties , and oxidation- resistance studies were made . Of the alloys studied , Cb - 15 Hf - 5W, Cb - 15Hf - 5W- 10Ti , Cb - 15Hf - 10W- 10Ti , Cb - 10V - 5W, Ta - 30V , and Ta - 20 to 33Hf exhibited excellent high - temperature properties . These alloys were not only easy to fabricate , but they also had good oxidation resistance and excellent high- temperature strength .

Jan 1, 1964

By Henry E. Blake

Defluorination studies on refractory fluoride - bearing compounds and minerals , particularly on partly defluorinated residues from high - temperature pyrohydrolysis , required a dependable and reasonably accurate analyticalcontrol method for the analysis of fluorine . The difficulty in liberating fluorine from the fluorides of metallic elements such as aluminum, zirconium , and rare earths by steam- distillation can be largely overcome if the distillation is made from a sulfuric - phosphoric acid solution of a sodium carbonate fusion of the sample material and if the distillation temperature is maintained at about 155 ° C. The data presented in this paper show that liberation of fluorine by this method is more complete and proceeds more rapidly than by usual distillations from perchloric or sulfuric acid alone or a mixture of phosphoric and perchloric acids . Fluorine in amounts ranging up to about 140 mg can be recovered by collecting only about 300 ml of distillate . Determination of fluoride in the distillate is made by the usual thorium nitrate titration .

Jan 1, 1963

By Elton L. Litchfield, Milton L. Weiss

Studies were made on the projectile impact sensitivity of explosives by subjecting explosive samples to the impact of metal projectiles fired from a 0.50- caliber gun . The projectiles , in the form of right cylinders , made plane surface to plane surface contact with the explosives . Pressures in the explosive were investigated with an expendable pressure transducer in some instances . The physical model of the projectile - explosive interaction describes , in principle , the duration of the peak shock pressure in terms of the projectile and explosive geometry and the steady- state penetration of the explosive . Of the explosives studied , liquid hydrogen- solid oxygen and liquid oxygen - solid or liquid hydrocarbon fuel were the most shock sensitive ( requiring an initiating shock of about 1.0 kb or 987 atmospheres pressure ) ; cast TNT was the least sensitive ( requiring an initiating shock of more than 110 kb pressure ) . Measurements of pressure in the explosive showed some moderate space resolution by the transducer and gave pressure distributions in agreement with expectations from the model of the shock processes . The appearance of the recovered projectiles and the calculated initiation shock pressures suggest that the solid explosives were initiated directly to high- order detonation , whereas the liquid explosives were probably initiated to low- order detonation-- with a subsequent , later transition to high- order detonation .

Jan 1, 1965

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Representation of actual oil yields from sections of the Green River formation oil shales by two types of drill - cutting samples was evaluated . Average oil yields of single sets of mud cuttings from hydraulic rotary drilling in Colorado and gas cuttings from pneumatic rotary drilling in Utah were compared statistically with yields of core samples taken from adjacent holes . Oil yields from gas cuttings were identical to oil yields of core samples . Mud cuttings appeared to represent a section of the formation conservatively , the deficiencies increasing with increasing richness of sample . Because a large amount of the oil - yield data currently available for the Green River formation is based on mud- cutting samples , development of a valid correction method by additional testing is needed .

Jan 1, 1963

By G. C. Reed, J. A. Herdlick

The Blackbird district, Lemhi County, Idaho, has long been recognized as a potential source of cobalt and copper. Exploration of the early discoveries in the area was largely discouraged by the comparatively low grade and small size of the known ore bodies, the slight demand for cobalt, and the lack of adequate roads throughout the region. Recent advances in the field of alloy metallurgy culminated in a steadily expanding demand for cobalt. This demand was finally accentuated to critical proportions in 1940 by worldwide rearmament programs and by the threatened disruption of foreign imports by submarine warfare.

Feb 1, 1947

By A. J. Kraemer, O. C. Blade

This report on the properties of commercial motor fuels sold in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee of the Cooperative Research Council (C.R.C. ) and the Bureau of Mines of the United States Department of the Interior . The first report contained data on motor gasolines sold during the winter of 1935-364 . Further reports on motor gasolines sold during the succeeding summers and winters to the summer of 1941 have been issued . No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942 . The present report presents analytical data for 1,120 samples , representing the products of approximately 88 companies . As in previous surveys , these companies include both large and small suppliers . In addition, the Pacific coast is represented by data averaged by the Pacific Coast Technical Group before being submitted and are published exactly as they were received . Conforming to previous surveys , the data cover three groups of samplesregular - price , premium - price , and third - grade gasolines and each group has been averaged separately. The number of samples , items and brands comprising each group, exclusive of those of the Pacific coast, are as follows : Regular price , 641 samples , 250 items , and 64 brands ; premium price , 439 samples , 222 items , and 68 brands ; third - grade gasoline , 50 samples , 50 items and 19 brands .

Jun 1, 1943

By E. Morrice

The Bureau of Mines investigated methods for beneficiating platinumgroup metal ores from the Stillwater Complex , Montana , as part of its program to increase the supply of critical and strategic minerals and metals from domestic resources . This report presents results of a 5- day continuous campaign employing a pilot flotation mill to recover sulfide concentrate containing platinum- palladium values from anorthositic ore . A mercaptobenzothiazole - sulfuric acid reagent suite was used . The pilot flotation mill was operated at an average feed rate of 106 lb/ hr of ore . A rougher concentrate containing 8.5 pct of the feed was prepared ; it assayed 1.1 oz /ton Pt and 3.5 oz / ton Pd . Recovery of platinum and palladium were 91 and 87 pct , respectively .

Jan 1, 1965

By E. D. Gordner

U. S. Bureau of Mines

Jan 1, 1923

By R. L. Grant

During the last decade or more , experimental research on commercial detonators used for initiating the detonation of dynamite and other high explosives has led to important improvements . Developments , especially in the United States , have been directed toward improvement in the construction of detonators to make them safer to manufacture and use . More suitable and safer initiating charges also have been found . Although for many years mercury fulminate was unrivaled as the initiating charge for dynamite , during the last decade it has been replaced to a large extent by less sensitive , more efficient, and cheaper combinations of ignition , priming , and base charges . Commercial detonators were once of relatively simple construction and almost universally identical . Today they are technically complex, with special nodifications for particular uses ; they have developed along different lines n various countries and even among the several manufacturers within any one country .

Apr 1, 1943

By E. W. GOODWIN, V. F. Parry, J. B. Goodman, L. D. Schmidt, J. D. Davis, A. C. Fieldner, W. S. Landers, J. L. ELDER

The Heliopore process is essentially an arrangement that uses the waste heat in the exhaust gas of an internal - combustion engine to carbonize coal (noncaking ) or lignite . The gases distilled from the coal furnish fuel for the internal - combustion engine , which drives an electric generator . Thus the main products of the plant are electricity and char . A flow diagram illustrating the principles of operation of the Heliopore process is given in figure 1. The primary equipment consists of a carbonizing retort , gas cooling and scrubbing equipment, a gas storage holder, and an engine to burn the gaseous carbonization products . Coal is charged into the top of the retort while the hot gases from the engine travel upward through special ducts in the retort countercurrent to the coal flow . The hot gases never come into direct contact with the coal . Char is discharged at the bottom of the retort and hot gases at the top . The gaseous products resulting from carbonization of the coal are drawn off by an exhauster through the condensing and scrubbing equipment to take out tar and liquor , then to a gas holder , and finally are burned in a gas engine . The gas engine drives an electric generator and the engine exhaust gases are returned to the retort to carbonize coal . The entire process was intended to be continuous and self - sustaining, and to use coal as the only fuel . The plant may be said to be a large - scale pilot plant in that , although it is of full commercial size , its main purpose is to provide data for the design of others of its type . The installation tested had a daily throughput of about 4 tons of coal . Figures 2 , 3 , and 4 picture some details of the plant and equipment used in the experimental testing . Further details of the equipment and engineering drawings of the castings are shown in figures 8 to 22 in the Appendix .

Dec 1, 1943

By D. J. Stoops, H. Kato, M. D. Carver

The effects of impurity elements silicon , aluminum, copper , nitrogen , and manganese , at 50 to 300 ppm, on properties of the zirconium alloy Zircaloy 2 were investigated . Variations in microstructure , mechanical properties , and corrosion behavior in some inorganic acid and salt solutions were observed with variations in level of impurity element . Corrodents were solutions of sulfuric acid , phosphoric acid , copper chloride , and iron chloride . Silicon was found to modify annealed microstructures by spheroidizing and dispersion of secondphase material throughout grains . Silicon or manganese improved ultimate and yield strength of the alloy without loss in ductility . All five elements affected corrosion rates of the alloy , the effect being generally different for each element .

Jan 1, 1964

By D. Harrington

Examination of numberous disasters , such as fires or explosions , and the evidence at coroner's inquests following such disasters in several States , have shown the writer how frequently men in charge of the operation and safety of mines have forgotten, or have failed to learn , details of safe mining practices , After securing a position of trust as superintendent , or a certificate of competency to act as shot -firer , fire boss , or mine foreman, some men seem to have felt it unnecessary to keep safety principles in mind , or to keep abreast of current progress in safety ; they have concentrated on getting out maximum tonnage at minimum cost . • In coroner's inquests , the testimony after disasters has shown that firebosses , foreman , and coal -mine superintendents are noticeably lacking in knowledge of the provisions of the State mining law relating to fans or doors , frequency of crosscuts , nature of stoppings necessary , electrical equipment , records of daily mine examinations , quantity of air required , or splitting and overcasting .

Jul 1, 1922

By W. P. Haynes, A. J. Youngblood, J. J. Demeter

Synthesis of high - Btu gas , using the Fischer - Tropsch reaction was investigated in a tube - wall reactor of 2 - inch steel . The catalyst was carbonexpanded iron ( CEI ) , formed on the walls of a steel reactor by exposing the reactor to 1H₂ + 100 synthesis gas under certain conditions . Advantages to be gained from successful development of the CEI - coated tube- wall reactor are elimination of catalyst plant and catalyst handling and charging operations , high- temperature operation , and a relatively low- cost , reactor -heat recovery system . In one test ( TW- 8 ) in which the reactor was filled with CEI , the reactor was operated for 1,910 hours before the test was stopped because of excessive pressure drop caused by carbon deposition . The pressure drop was satisfactory for 1,000 hours of operation at an hourly space velocity of 300 , but it increased rapidly at space velocities of 600 and 1,000 . When operated at a space velocity of 300 , with a ratio of 1 to 1 recycle at 534 ° C , a conversion of 72 percent of the 3H + 100 synthesis gas was achieved . The product gas had a heating value of about 610 Btu per cubic foot and could be suitably upgraded to 900 - Btu gas by subsequent use of a nickel catalyst . CEI did not operate effectively as a film catalyst under conditions of generation tried in this study . Generally , operation of the 2 - inch reactor with CEI catalyst was unsatisfactory because of poor reproducibility of the activation step and poor temperature control resulting in high- operating temperatures and eventual plugging of the reactor . Tests using CEI in fixed , packed beds suggest that the most likely application for CEI in producing high - Btu gas would be a moving - bed reactor , where sufficient bed movement and heat removal are provided to prevent plugging .

Jan 1, 1964

By R. J. Leary, W. M. Mahan, F. X. Tartaron

A new type of apparatus for prerefining molten blast furnace iron and to reduce the cost of subsequent steelmaking consists of a funnel - shaped device lined with firebrick into which a horizontal stream of molten pig iron is directed tangentially at the top . The rotary motion thus induced causes the stream to flatten itself upon the wall and flow in a spiral path to the outlet ; thus , the device was termed " vortex cone .' Oxygen and other refining agents are impinged upon the flowing metal in the cone where reaction is facilitated by the large metal surface exposed and the turbulent flow pattern . Experiments with water in 1 - foot - diameter funnels provided an idealization of the flow patterns to be expected with molten iron . A brick - lined reactor 3 feet in diameter was built for desiliconizing molten pig iron in lots of 1 to 2 tons . At flow rates of 0.3 to 0.5 ton min - 1 (430 to 720 tons per day ) this apparatus was 64- to 90 - pct effective in desiliconization with oxygen efficiencies of 19 to 41 pct . Detailed experiments to develop basic engineering data are underway , and adaptation of this principle to other reactions and reactants is planned .

Jan 1, 1964