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By A Larsson, K Niiranen

The Palaeoproterozoic Leveäniemi iron oxide apatite (IOA) deposit of the so-called Kiruna type is currently mined by Luossavaara-Kiirunavaara AB (publ.), commonly known as LKAB. The mineralogy of iron oxides, ie magnetite, hematite, maghemite, and goethite is more complicated compared to the neighbouring and more famous IOA deposits of Kiirunavaara and Malmberget. Furthermore, the mineral chemistry of the iron oxides in the Leveäniemi deposit is also slightly different. Especially, the information about the deportment of titanium and vanadium in iron oxides and distribution in the deposit is essential since they can have an impact in the steelmaking process. For this study 50 samples were selected from exploration drill cores and investigated by optical microscopy, FE-SEM-EDS and EPMA at LKAB and the Geological Survey of Finland. Investigations revealed that magnetite is the predominant iron oxide mineral with secondary hematite being the second most abundant mineral. Primary hematite, maghemite, and goethite seem to be less abundant. It should be noted, however, that this investigation focused on magnetite which currently is the only mineral with economic value. Vanadium occurs as a substitution element in the crystal lattice of iron oxide minerals in the Leveäniemi deposit and not as discrete stochiometric vanadium minerals. In the investigated samples vanadium concentration in magnetite ranges from 0.12 to 0.32 wt per cent V2O3 with higher concentration in the southern part of the deposit. Contrary, titanium does not substitute for iron in the crystal lattice of magnetite or secondary hematite (less than 0.018 wt per cent TiO2). It either occurs as tiny inclusions of titanium oxide minerals or as exsolution lamellae of ilmenite in magnetite. The spatial distribution for titanium in the deposit, however, remains unknown. Furthermore, results of this study indicate that alteration of primary magnetite to secondary hematite has had no significant effect on the trace element chemistry of these minerals in the Leveäniemi deposit.

Nov 8, 2021

By J Caron, M Athayde, F Lavoie, R Joyce

Decarbonisation has become a major challenge for the global steelmaking industry, turning towards new technologies aimed at carbon footprint reduction, which on its own accounts for approximately 9 per cent global emissions. The iron and steel industry represents a ‘hard to abate’ sector, where much of efforts are currently being deployed into initiatives aiming to decarbonise the ironmaking through the use of green hydrogen, carbon capture utilisation and storage and state-of-the-art operation of current technologies, while little efforts being deployed to find carbon-efficient solution to iron ore burden preparation, where high-grade iron concentrate will increase in importance to ironmaking regardless of the chosen reduction route. Quebec Iron Ore (QIO), a subsidiary of Champion Iron Limited (Champion), produces high-grade hematite concentrate with one of the lowest carbon global footprints. Still, QIO is partnering with its clients to the development of burden solutions to minimise CO2 emission, in the seek for a decarbonised steel. In a strong technological partnership, Binding Solutions Limited (BSL) has developed a novel, coldbinding technology to provide a cleaner, more cost-effective alternative to induration. The technology allows miners and steel producers to reduce Capex significantly and reduce energy consumption and CO2 emissions by 90 per cent. QIO and BSL have partnered to adapt the disruptive cold binding technology developed by BSL to QIO’s concentrate to produce a high-quality low emissions iron ore agglomerate. This paper describes the efforts taken to further develop BSL’s cold binding technology and its application to QIO’s high-grade iron ore concentrate to produce a hematite cold bonded briquette (hCBB) showing comparable performances with high quality seaborne fired pellets.

Nov 8, 2021

By B Vorster, T Medhurst, A Huey

Roof conditions at Oaky North Mine can be prone to stress related damage and/or time dependent degradation. The ability to identify these areas prior to mining has proved challenging using traditional methods. To help alleviate this situation, a study was initiated to investigate methods for roof characterisation using geophysical logs. This involved the use of neutron log data to provide an indirect measure of the proportion of carbonaceous/micaceous laminae present in the immediate roof strata. Detailed analysis of the shale–porosity inter-relationships arising from this analysis provided a means to estimate the proportion of laminations for a given roof interval. This paper outlines the process and how it was used to improve the current GSR modelling and hazard mapping process.

Nov 29, 2022

By W Zhu, J H. Zhao, H Ma

The permeability coefficient is an essential parameter for the study of seepage flow in fractured rock mass. This paper discusses the feasibility and application value of using readily available RQD (rock quality index) data to estimate mine water inflow and grouting quantity. Firstly, the influence of different fracture frequencies on permeability in a unit area was explored by combining numerical simulation and experiment, and the relationship between fracture frequencies and pressure and flow velocity at the monitoring point in fractured rock mass was obtained. Then, the stochastic function generation program was used to establish the flow analysis model in fractured rock mass to explore the relationship between flow velocity, pressure and analyse the universal law between fracture frequency and permeability. The concepts of fracture width and connectivity are introduced to modify the permeability calculation formula and grouting formula. Finally, based on the on-site grouting water control case study, the rock mass quality index is used to estimate the mine water inflow and the grouting quantity. The results show that it is feasible to estimate the fracture frequency and then calculate the permeability coefficient by RQD. The relationship between fracture frequency and RQD and the relationship between structure surface frequency and permeability follow an exponential function. The calculation results are in good agreement with the field monitoring results, which verifies the rationality of the calculation method. The relationship between the rock mass RQD index and the rock mass permeability established in this paper can be used to invert the mechanical parameters of the rock mass or to evaluate the permeability and safety of the rock mass, which is of great significance to the prediction of mine water inflow and the safety evaluation of water inrush disaster management.

Nov 29, 2022

By C Zhang, G Si, J Oh, X Zhu

The presence of rock joints has a huge impact on the strength, deformability, and permeability of fractured rock masses by providing surfaces of weakness on which further deformation are more prone to occur, and by serving as the major channels of water flow due to low matrix permeability. In earlier studies, water flow-through rock joints is often assumed as laminar flow between two ideal smooth parallel plates, and the well-known cubic law was derived and widely used to characterise the hydraulic behaviour of rock joints. However, natural rock fractures are irregular and of spatially varied aperture. Thus, the concept of equivalent hydraulic aperture was introduced to modify the cubic law. Numerous works have been conducted on the relation between hydraulic aperture and mechanical aperture incorporating various geometrical parameters. The surface roughness is one of the most sensitive factors for water flow-through rock joints. The aperture distributions are irregular in natural roughed fractures relative to the parallel plates. Barton et al (1985) and Olsson and Barton (2001) incorporated the joint roughness coefficient JRC in evaluating hydraulic aperture and proposed an empirical equation based on fluid flow tests. However, their equations do not conform to the dimensional consistency. Many other researchers (Zimmerman and Bodvarsson, 1996; Xiong et al, 2011; Li et al, 2019) considered aperture distributions in their equations. But the aperture distributions change during shear was always neglected. The contact of rock joints also has a significant impact on the hydro-mechanical behaviour of rock joint, since fluid tends to flow-through a rough joint along connected channels while bypassing the contact obstacles with tortuosity. Nonetheless, previous research mostly considered joint roughness or aperture changes based on 2D joint profiles, while the contact and tortuosity based on 3D surfaces were often overlooked. Only a few works have been made on quantifying the effect of contact area on flow behaviour (Walsh, 1981; Zimmerman et al, 1992; Zimmerman and Bodvarsson, 1996; Yeo, 2001), and mostly ignored contact area change induced by shearing and the associated impact on flow behaviour. Summarily, the quantification of fracture geometry effects on water flow in single rock joints still needs further investigation, especially when considering coupled shear-flow processes. This paper, therefore, aims to study the impacts of contact area and aperture distributions of the single rock joint on the flow behaviour. The evolutions of contact area and aperture distributions induced by shear are considered. Then, an improved model for estimating the hydraulic aperture with the mechanical aperture incorporating the above factors is developed. Finally, a series of shear and shear-flow tests are conducted on artificial joint samples and the model performance is verified by comparing against the results of experimental tests.

Nov 29, 2022

By Y K. Leong

Iron ore tailings typically containing 40 to 50 per cent Fe can be beneficiated to iron ore products containing 54 to 60 per cent Fe. The impurities are comprised of clay, quartz, cristabolite and TiO2. Goethite and hematite are also present. At high concentrations of 55–60 wt% solids, the tailings displayed high yield stress and viscosity and cannot be pumped over long distances. Composite additives comprising of NaOH, phosphate-based additives and sodium metasilicate are found to reduce the viscosity and yield stress very significantly by a few orders of magnitude. The yield stress of 100 Pa can be reduced to almost zero. At this state, dilution of the tailings with its process water to 40 per cent solids causes the coarse and high-density iron ore particles to separate from the colloidal fractions located in the supernatant after a few minutes of sedimentation. Separation by decantation produces a sediment with an Fe content of 54 per cent from tailings with 47 per cent Fe. Another tailings sample with 48 per cent Fe was beneficiated to greater than 57 per cent Fe using NaOH-metasilicate-polyphosphate additives and employing an additional washing step. The use of other composite additives, NaOH and polyphosphates, increased beneficiated product Fe content to greater than 60 per cent from the same tailings. With the current iron ore spot price of more than US$180 per tonne, the cost of this treatment process even including a desalination step, if necessary, is relatively insignificant. This study has given tailings an economic value that should be exploited as soon as possible.

Nov 8, 2021

By R Carstens, L Munsamy, L Prinsloo, C Huang, C Zhang, R Liang, I Canbulat

With recent advances in machine learning, data-based automated decision-making has been proven successful with promising outcomes in many industries. Its application in the mining sector can be ground-breaking; particularly the data-driven analytics that can support decision-making in the mine and consequently enhance mine safety, efficiency and sustainability. However, the current data science applications in the mining industry are mostly noncomprehensive, especially inadequate in evaluations, thus often requiring further study to be potentially beneficial to operations. Furthermore, it was found that existing literature paid limited attention to understanding the role of such techniques. Hence, in this paper we aim to build an end-to-end machine learning powered data-driven framework for intelligent geo-hazard analytics to support decision-making for underground mining data management, where multiple types of data are managed in an integrated database to support the unified machine-learning model. Here we present the framework as data-driven workflow processes, including data gathering, data preparation, data processing and data presentation. In addition, we present an application scenario of the proposed framework, where falls of ground (FoG) is managed with the historical FoG investigation reports, related panel hazard ratings, compliance data and rock mass characteristics. A demonstration can be dynamic forecasting of high-risk areas for FoG based on both spatial and temporal factors, including a 3D data visualisation. Such a scenario shows the potential of the proposed framework to establish connections among various data fields across a diverse category of data. Furthermore, the results offer important insights for ground instability management and can potentially optimise the underground operation flow.

Nov 29, 2022

By E Bouchard March, F Lavoie, B Legare, K Bourassa

Quebec Iron Ore (QIO), a subsidiary of Champion Iron Limited (Champion), completed the restart of the Bloom Lake iron ore mine located in the heart of the Labrador Trough region of Northern Quebec, Canada in February 2018. Prior to its restart, the concentrator flow sheet underwent major upgrades which brought the iron recovery to the highest of all Labrador Trough operations. After two profitable years of production, QIO, supported by Soutex, started to look at technologies to improve its current performance and integrate into its expansion project flow sheet. From the lessons learned while optimising Phase 1, the addition of a scavenger-cleaner processing stage was identified as an improvement opportunity to increase recovery, produce a higher-grade product, and further improve the stability of concentrate quality. In 2019, the NI-43101 feasibility study for the Phase 2 expansion, aiming to double the production of high-grade iron ore concentrate, was published. Based on the metallurgical test work, the hydraulic classifier was selected to perform the scavenger-cleaning duty for its well-established performance and known behaviour at the cleaning step in the Phase 1 plant. To validate laboratory results, a pilot scavenger-cleaning hydraulic classifier was installed in Phase 1. Although the hydraulic classifier was selected for the feasibility study, metallurgical test work performed with the REFLUX® classifier showed interesting potential. It was thus decided to also install a pilot RC300 Reflux classifier at the scavenger-cleaning stage in Phase 1. Despite their apparent great similarities, the metallurgical performance was significantly different, and many dozens of sampling campaigns highlighted the different performance of both pieces of equipment considering the feed material particle size. This article presents the pilot plant results in terms of recovery, selectivity and stability for both the Reflux classifier and the hydraulic classifier operated in a scavenger-cleaner stage at the Bloom Lake iron ore concentrator.

Nov 8, 2021

By E J. Y Koh, G J. McLachlan, E Amini, N Beaton

Preconcentration greatly reduces the ore mass input to the processing plant while upgrading the grade. One of the commonly used methods of preconcentration is optical sorting. These methods rely on optical sensors which classify the material stream into “accept-reject” streams. Currently, it is common to use near infrared (NIR) or colour cameras to classify streams based on reflectance or colour thresholds set by experts. The imaging is done through line-scan sensors where the material is scanned on a belt or a chute. Then, a separation apparatus like a diverter gate or air jet is controlled to separate the streams according to the classification made by the algorithm. Separation efficiency is dependent on the classification algorithm. Existing classification algorithms rely on low-level feature discrimination like observing individual pixel values for reflectance or colour hues. This limits discrimination between minerals with low contrast in colour. Human experts perform mineral segmentation using texture, colour distribution and shape, but it is difficult to translate these visual rules to mathematical thresholds. Deep learning methods like Convolutional Neural Networks (CNNs) provide high-level feature discrimination similar to a human expert. Instead of relying on pre-defined features, the CNNs learn complex features from the dataset. CNNs can construct a hierarchy of features based on pixel clusters to learn texture, shapes, and colour spectrums of the mineral grain surface to provide better separation. In this study, a state-of-the-art deep learning instance segmentation method is used to outline boundaries and classify grains from the background (mineral segmentation). The algorithm is trained on images collected from a flotation feed of a gold deposit, where the gold is mechanically locked inside pyrite. This method can process on-line video inputs at 5 frames per second to provide a live grade. The proposed method is inexpensive as it only uses a camera and a desktop computer.

Nov 10, 2020

By Raymond Sandiford, Kenneth Xu, Taehyun Moon

Tunnel approach structures situated in slow moving earth flows are subjected to significant earth pressures. The authors have developed a system, utilizing collapsible concrete columns, that limits such loading. The system uses an array of collapsible concrete columns in front of the structure to absorb downslope movement and limit-imposed loads. This concept has been modelled using 3D FEM analyses and a rudimental lab test. For implementation, the collapsible columns would be prefabricated in strengths to mimic the soil strength profile. This concept has merit, and analytical results demonstrate that collapsible columns are a viable means to limit loading.

Jun 23, 2024

By E. H. BURROUCHS

This bulletin is the third of the series of yearly petroleum bibliographies being published by the Bureau of Mines. The two preceding, Bulletin 149 and Bulletin 165, were for the years 1915 and 1916, respectively. In arranging the references the same general scheme has been followed, but as in those bulletins, several changes and additions have been made in the classifica.tion, the more important being in the classes " Development and production " and "Refining and refineries." German periodicals for 1917 were not procurable and references to articles in those and in other foreign journals that were not available have been credited to the sources from which they were procured.

Jan 1, 1920

By E. H. Burroughs

This bulletin is the fourth in the series of petroleum bibliographies being published by the Bureau of Mines, the three preceding, Bulletins 149, 165, and 180, being compilations for the years 1915, 1916, and 1917, respectively. In this bulletin the same general plan has been followed in arranging the references, but a few changes and additions have been made in the classification, the more important changes being in the classes "Geology and Origin" and "Refining and Refineries." Dl1'ring the year German periodicals were not available, and, as in the bibliography for 1917, references to articles in foreign journals that were not available have been taken' from other sources and credit given to those sources.

Jan 1, 1921

By Albert H. Fay

Through the hearty cooperation of the State coal-mine inspectors, the bureau is able to present in this paper a a complete statement of the coal-mine fatalities occurring throughout the United States during the calendar year 1919. The reports received from the inspectors for the year just closed show a reduction of 10.58 per cent in coal-mine fatalities as compared. with 1918, while in 1918 the reduction was 4.3 per cent from 1917 figures. The total number killed was 2,307 in 1919 and 2,580 in 1918, a reduction of 273. There was a decrease of 128, or 25 per cent, in fa tali ties resulting from mine cars and locomotives, and a decrease of 198, or 15 per cent, in the fa tali ties due to fall of coal or rock. Surface accidents show a decline of about 25 per cent as compared with the previous year. There were, however, increases in accidents due to gas and dust explosions and also explosives. There occurred during the year nine disasters in which five or more men were killed, representing a total of 201 fatalities. The worst disaster of the year was the one occurring at the Baltimore Tunnel No. 2, Wilkes-Barre, Pa., resulting from the explosion or burning of a number of kegs of powder, by which 92 lives were lost. This disaster emphasizes the need for stricter regulations relating to hauling men and explosives into the mine at the same time. The question of whether electricity was responsible or not does not affect the consideration of the various dangers which arise in underground transportation and handling of explosiveB. At best the handling and hauling of explo.sives is hazardous and such being the case, no one, other than the necessary attendants, should be permitted to ride in cars or cages transporting explosives. As a result of this disaster, the report b of the coroner's jury to the governor of Pennsylvania brings out some important dangers to be avoided in the use and transportation of explosives.

Jan 1, 1920

By S Padekar, C Tapia, D Likhachev, S Harlikar, D Sapkale

In the quest to access valuable critical minerals, humankind is expanding the frontier into extreme environments like space and deep-sea mining. These ambitious enterprises involve considerable costs and lengthy development cycles to ensure the robustness of mining systems in the face of the harshest conditions and unforeseen challenges. Unfortunately, obtaining information from these unexplored territories is complicated. Data is often scarce, incomplete or impossible to obtain until equipment is deployed, leaving engineers facing many uncertainties throughout the design, testing, production and preparation of such missions. Despite these challenges, these extreme environments operate under consistent physical and chemical principles that can be faithfully digitally replicated. However, unexplored areas and dynamic systems like weather and geology continue to carry uncertainties. While eliminating uncertainties remains elusive, Digital Twins offers a means of robust risk management tool. These virtual replicas can excel in simulating extreme conditions and unexpected events, helping optimise and validate mining system designs tailored for such hostile environments. This study takes inspiration from the Mars Science Laboratory (MSL) Curiosity Rover’s wheel damage rate to develop a Multiphysics Modelling and Virtual Motion Simulation (MMVMS) system. Using advanced Generative Design, this MMVMS system refines the MSL’s design, simulates component and system performance, and assesses the risk of premature damage while operating on Mars. Additionally, MMVMS integrates cutting-edge CAD design technologies from aerospace and manufacturing to realistically recreate the Martian environment and a detailed representation of MSL, allowing mobility verification and validation simulation to test different components in terms of materials, design, weight, power and, therefore, cost. The research highlights the precision of MMVMS in replicating extreme conditions, simulating and evaluating internal and external variables influencing the entire system (Rover) in real-time, and predicting movements, failures, and premature damage. This sophisticated Digital Twin technology, showcased in this research, holds promise not only for space missions but also to be adapted for terrestrial and deep-sea mining operations.

Sep 1, 2024

By K Grohs, A Satriawan, S R. Pearce

Martabe gold and silver mine is operated by PT Agincourt Resources (PTAR) and is situated in northern Sumatra and comprises several deposits in steep terrain, and in a tropical climate, that are required to be developed in the optimal sequence for the best possible Net Present Value (NPV) return on the project. In addition, the waste rock from excavations and tailings from processing is a by-product to be scheduled and used for a number of purposes identified as part of life-of-mine planning. These uses include construction of the current integrated tailings storage facility (TSF) as well as future engineering construction and waste disposal projects which includes plans for a program of in-pit backfilling. These plans need to be aligned to ensure the waste rock and tailings can be contained relative to the production rate. Given that the site will have multiple open pit voids upon cessation of mining activities opportunities for integration of in-pit disposal of mine waste have now been assessed with technical studies to review the practicality of the approach with respect to operational challenges and conformance with closure planning requirements. This includes assessment of disposal of waste rock, tailings (including consideration of filtered tailings) and co-disposal of waste rock and filtered tailings.

Aug 2, 2023

By T Y. Ko, Y S. Kang, S J. Park, J H. Hwang

The lunar subsurface, particularly the lava tubes formed by ancient volcanic activity, presents a promising environment for establishing safe and sustainable human habitats on the Moon. Tunnel Boring Machines (TBMs), widely used for excavating tunnels on Earth, offer a potential solution for developing these subsurface spaces. However, the unique lunar conditions, including extreme temperatures, high vacuum, radiation, and the extraordinary strength and abrasiveness of lunar rocks, necessitate significant adaptations to existing TBM technology. This study investigates the feasibility of utilising TBMs for lunar subsurface exploration and base construction, addressing the challenges posed by the harsh lunar environment. We review previous conceptual designs for lunar TBMs, highlighting their strengths and limitations in addressing these challenges. Additionally, we explore innovative excavation methods, such as microwave-assisted rock weakening and undercutting techniques, to enhance the efficiency and effectiveness of lunar TBM operations. By evaluating the geological characteristics of the lunar crust and analysing the potential of lava tubes as launching points for TBM operations, this study provides a comprehensive assessment of the technical requirements and operational considerations for lunar TBM implementation. The findings of this research contribute to the growing body of knowledge on lunar base development and pave the way for future human exploration and utilisation of the Moon’s subsurface resources.

Sep 1, 2024

By R Peiffer, L van Wyk

The Port of Port Hedland is the largest bulk export terminal in the world and is one of Australia’s most important pieces of economic infrastructure. BHP is the largest Port user to support the export of iron ore products from mines located within the Pilbara region of Western Australia (WA). BHP’s priority is the safety and well-being of its workforce and the communities where it operates. In a recent regulatory application to increase export capacity, BHP committed to the deployment of wind fences to reduce wind erosion from stockpiled ore. Wind erosion from stockpiles was identified through inverse modelling as the most significant dust source compared to other sources such as stackers, reclaimers, shiploaders and transfer stations. The primary cause of dust emissions from stockpiles is dust lift-off during high wind conditions. BHP proposed the installation of wind fences across its Port Hedland operations, targeted at reducing emissions from wind dependent sources, primarily stockpiles, by reducing the wind speed downwind of the wind fence. Modelling predicts that installation of the wind fence will significantly reduce emissions from stockpiles, particularly at BHP’s western operations (Finucane Island). To be effective in shielding stockyards and reducing wind speeds, the wind fences are located upwind and as close as practical to the open stockyards. BHP’s wind fence design incorporates learnings from other existing installations and has been tailored for Port Hedland’s cyclonic conditions. The wind fence will be higher than the stockpile height, with a mesh porosity of approximately 50 per cent. The mesh porosity allows some of the wind to pass through the mesh. This reduces the wind turbulence downstream of the wind fence, as opposed to a solid wind fence, which increases downwind turbulence, resulting in increased dust.

Sep 18, 2023

By B Bradák, D Asahina, S Saydam, S Akdag

Human exploration of Mars has been on the horizon of scientific goals for decades now, and as part of the objectives of human missions to various planets, one of the possible goals is opening new economic frontiers by the potential extraction and utilisation of resources, eg mining minerals and using surface regolith (Neukart, 2024). A comprehensive understanding of surface morphology, lithostratigraphy, basic structural geology, and civil engineering technology is essential to conduct mining operations for resource extraction on extraterrestrial planets. For instance, proper assessment of the risks associated with excavation and infrastructure construction under unique environments such as low gravity, surface irregularities, and the presence of regolith is fundamental. Such knowledge has been accumulated through satellite imagery and numerical topographic data using remote sensing technology, as well as seismic surveys by the on-site lander (Knapmeyer- Edrun et al, 2021; Banerdt et al, 2020; Giardini et al, 2020). Recent studies show that Marsquakes could be caused by the release of strain energy generated by the contraction of Mars. In particular, Marsquakes occur around the graben where many faults exist and form regularly spaced patterns. This implies that Marsquakes occur when the stress field of the Martian crust is an extension condition, and normal faults appear on the surface. In this study, we focus on so-called graben structures, one of Mars’s common tectonic structures (Plescia, 1991; Banerdt et al, 1992; Hoogenboom Hagen, 2014). The study aims to provide additional information about the tectonic environment during the formation of such features and, in addition, the internal mechanical-rheological structure of Mars, revealed by the geometrical pattern of faults modelled and simulated in a laboratory environment.

Sep 1, 2024

By C Zschiesche, alam, A Abadias Llamas, A K

An integrated experimental and thermodynamic modelling study of the phase equilibria in the FeOFeO1.5- SbO1.5-SiO2 system in equilibrium with liquid Sb and Sb-Ag metal has been undertaken to develop thermodynamic model of the Na-Si-Fe-O slag system with S-Sn-Sb-Pb-As minor elements based on the experimental investigation of the selected sub-systems. New experimental phase equilibria data at 575–1600°C were obtained for this system using high-temperature equilibration of synthetic mixtures with predetermined compositions in sealed silica ampoules, Fe3O4 basket in sealed silica ampoule, or Re foils, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. Experimental results on phase equilibria in the Fe-Sb-Si-O+Sb metal system obtained helped to produce initial set of model parameters in the slag. The primary phase fields of quartz/tridymite/cristobalite (SiO2), 2 high-SiO2 immiscible liquids, olivine (Fe2SiO4), wustite (FeO1+x), spinel (Fe3O4), schafarzikite (FeSb2O4) and valentinite/ senarmontite (Sb2O3) were identified in the binary Sb2O3-FeO, Sb2O3-SiO2 and ternary FeO-Sb2O3- SiO2 systems. Further refinement, particularly the distribution of excess Gibbs energy among the ‘FeO’-Sb2O3-SiO2 and ‘FeO1.5’-Sb2O3-SiO2 interactions, required the study at more oxidising conditions. Oxygen potential was increased using an inert metal (Ag) rather than using the gas flow due to the high volatility of Sb-containing gaseous species. Liquid Ag-Sb alloys with low concentrations of Sb of a few percent were used. At these conditions, the concentration of AgO0.5 in slag was below 1 mol per cent, which had a small effect on observed phase equilibria in the system. In addition, important information on the solubility of silver in slags is produced, which can be valuable when treating electronic recycling materials or primary silver-containing ores through the Pb process. Two main areas were addressed: the spinel-tridymite boundary (40–70 per cent SiO2 in slag) and spinel liquidus near 15 per cent SiO2 in slag. This allowed to deconvolute the separate contributions of the FeO-Sb2O3(-SiO2) and Fe2O3-Sb2O3(-SiO2) systems.

Jun 17, 2024

By M S. Tuohy

Poorly judged or under-appreciated change plays a role in many major accidents. In particular, operational changes related to continuous improvement, maintenance and introduction of new technology can lead to unintended safety (and other) consequences. This paper provides an overview of the role of management of change in preventing unwanted impacts on safety, community relationships and the environment. It draws on a range of incidents covering mining, minerals processing, refining and smelting where inadequately assessed or ineffectively implemented change led to significant safety, environmental or community consequences. The paper will also highlight cases of well-managed complex change and the underlying model of decision-making in place to make those decisions. All these examples are drawn from Atturra’s experience in response to accidents or working with sites to improve their management systems. The paper will report on the challenges of applying conventional risk assessment approaches to complex or technically significant change. These typically result in either onerous and lengthy change procedures that are prone to workarounds or poor implementation. Conversely, ‘light touch’ or efficiency driven change processes present the risk of intended consequences by failing to bring appropriate expertise to bear in decision-making. Such balances can be resolved by considering the designation of ‘technical authority’ with appropriate expertise to consider the change and deconflict any production, cost or schedule trade-offs. Finally, the paper will reflect on the key components of management of change systems in the context of major accidents, highlighting good practice in how they are implemented. This will consider the integration of existing corporate processes, risk management and organisational structures into management of change systems, not just the content of change forms and procedures.

Apr 16, 2024