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By G Brooks

The control of phosphorus in steelmaking is one of the famous challenges of pyrometallurgy. It is well established that highly basic slags, the presence of FeO in the slag and lower temperatures (less than 1650°C) are favourable for phosphorous removal. The thermodynamics of this reaction have been extensively studied under laboratory conditions and the general trends confirmed through industrial trials. However, in general, phosphorus slag/metal distributions measured in industry are far from equilibrium and quite specific to the oxygen steelmaking technology being used. This variability was quantified by Urban, Weinberg and Cappel (2015), who found that the phosphorus partition ratio measured in plants varied with blowing practice, stirring intensity and even converter life. Some recent kinetic studies by Gu, Dogan and Coley (2017) have shown how the kinetics of these reactions vary with FeO content and dissolved sulfur at the droplet scale. A global kinetic model by Rout et al (2018) provides meaningful predictions of where dephosphorisation occurs in an industrial basic oxygen furnace (BOF) and some recent heat transfer modelling by Madhavan et al (2021, 2022) implies that temperature difference between droplets and slag has a role to play in explaining why equilibrium is not achieved. This paper will review the current state of knowledge and provide suggestions on predicting phosphorous removal for industrial operations and how greater removal could be achieved.

Jun 19, 2024

By T Perera, B Fan, S Thang, T Hsia

Minerals are valuable resources and critical elements for a broad range of biological and technological applications, including technological developments to improve energy efficiency and the global movement to promote a low-carbon economy. However, in order to extract these critical metals, large amounts of waste and toxic chemicals are generated, as well as the use of high energy and large amounts of water consumption. Froth flotation is one of the most commonly used processes to separate and collect high-value minerals, but it still has some limitations, including low flotation efficiency performances using existing collectors and other reagents. Therefore, there is an urgent need to design and develop new metal-specific collectors to more efficiently separate and recover valuable minerals and to allow bulk water recovery from flocculated tailings. In this research, we propose to use our newly designed and synthesised novel collectors derived from a type of vitamin E (α-tocopherol), a relatively inexpensive and non-toxic natural molecule. As a potential collector-building block, α-tocopherol has a long hydrophobic carbon chain that facilitates the attachment to air bubbles during the froth flotation process. In addition, the phenol group of this molecule can be easily modified to incorporate various functional groups for targeting different types of minerals. Furthermore, α-tocopherol can be converted into a monomer for polymerisation by the reversible addition-fragmentation chain-transfer (RAFT) process, which can provide us with polymer based-collectors with high precision control of molecular weight and architecture. So far, small-scale qualitative experiments on α-tocopherol-based collectors have been performed with good results, which indicates the feasibility of these compounds as novel collectors for improved froth flotation processes.

Aug 24, 2022

By J J. Hanhiniemi, M S. Powell

A ‘Variable Blend and Rates’ model is developed for SAG mills which extends upon the JKSimMet® Variable Rates Model. Similarly, a ‘Variable Blend Residence Constrained Perfect Mixing’ Ball Mill model is also introduced, also extending upon the existing JKSimMet® model. These models are used in conjunction with JKSimMet® while employing external technical programs. The technical model is then used to inform an economic model described elsewhere in Hanhiniemi and Powell (2022), which calculate operating and unit costs based on operating conditions, design, and ore characterisation. The SAG and ball mill models include constraints beyond those in the JKSimMet® models. The SAG model constraints include Size Specific Energy (SSE) verification, charge weight limit, and assessment of the impact of media to ore composition in the charge using the SAG Charge SSE Model developed in this paper. The ball mill model includes residence time, volumetric capacity, and SSE verification constraints. These models are applied to Cortez Gold Mine in the processing of two very different ore types and their blends; ‘Horse Canyon’ which is softer in coarser sizes and competent is fine sizes, and ‘Wenban’ which is competent at coarser sizes but softer in fine sizes than Horse Canyon. Horse Canyon also has a finer run-of-mine size distribution then Wenban. The application of the model at this site included undertaking five surveys at varying blends. The behaviours of the blends and individual components is then studied in the SABC circuit. A nonlinearity is observed with throughputs increasing with blending. The newly developed modelling approach captures these responses. Controlled blending based on ore competence-by-size and size distribution was implemented by the site, which then realised significant improvements in throughput without any capital cost (Ntiamoah et al, 2020). The modelling developed in this paper is then compared to existing practice, and the new method was found to provide improved fidelity and utility. A three-dimensional surface is then developed using the model describing the SAG mill throughput capacity at varying conditions (speed-filling) versus varying blend. The change in throughput as a function of only the changing charge composition is presented. The result is nonlinear, and explanations are provided to describe this behaviour.

Aug 24, 2022

By K Mayank, A N. Mainza, I Govender, M Narasimha, A Mittal

In mineral processing industries grinding is the most energy-consuming process. A tumbling mill is an essential grinding equipment widely used for particle size reduction. Power consumption, impact forces and trajectory paths are critical parameters for characterising a tumbling mill to determine grinding efficiency. The effect of lifters and mill speed plays a vital role in such parameters. However, most of the studies ignore the impact of the lifter and do not investigate the effect of slurry dynamics on charge motion. The focus of the present work is to prepare a computational model that can accurately predict the complex multi-phase dynamics of charge particles, air and slurry inside the mill using a model that couples computational fluid dynamics (CFD) and the discrete element method (DEM). The details of impact forces with lifter profiles and mill speed variations will be refined even further using the CFD-DEM coupling approach. The slurry-air free surface is modelled using the volume of fluid (VOF) method, and the charge motion is modelled using the DEM. The phases are coupled using the interface momentum exchange between the charge and the fluid slurry. The coupled model is validated against experimental results from the positron-emitting particle tracking (PEPT) data. The validated model compares the effect of slurry content on charge dynamics with the dry DEM model. The presence of slurry is observed to dampen the tangential and shear contact forces.

Aug 24, 2022

By F Weir, B Estrada

The impact of seismic loading on open pit slope stability in Australia is often only considered where the slopes are located adjacent to tailings facilities or other major infrastructure. The debate regarding application of seismic loading in open pit design in Australia is usually founded on limited reporting on significant damage of open pit operations during earthquakes, the common perception that earthquakes do not occur in Australia or that they are unlikely to occur during the mine life of the mine. It is frequently overlooked that pit slopes that have withstood strong earthquakes in highly active seismic regions are often designed under strict seismic guidelines. This paper discusses the factors that impact earthquake performance of open mine slopes. These factors include topography, slope geometry, rock material and mass properties, water management and intrinsic pit design. Further, the paper presents insights into the characteristics of earthquake activity in Australia such as magnitude distribution, earthquake depths, areas prone of earthquake activity and general seismic hazard that are relevant to pit design. Guidelines are provided on the conditions and circumstances under which earthquake design in open pit mining should be considered. In addition, this paper provides recommendation on the applicable methods for assessment of the impacts of earthquake loading on pit slope stability.

Jun 22, 2022

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

By F Diaz, G Hovestadt, B Friedrich, D Latacz, M Sommerfeld

The metallurgical sector significantly contributes to the global carbon footprint and encounters the challenge of developing more sustainable production methods. This study introduces novel approaches aimed at reducing CO2 emissions within the industrial sector, some of which have been developed up to the demonstration scale. In two case studies, urban waste from the agricultural sector (corn, olives, coconut etc) and waste electrical or electronic equipment (WEEE) recycling residues (shredder light fractions (SLF)) were subjected to thermal treatment. The resulting materials were then used as substitutes for conventional fossil-based reducing agents in both the copper and ferroalloy industries. Furthermore, hydrogen was employed at different scales to assess its efficacy as a reducing agent for recovering metal oxides from fayalitic copper slags. Our findings reveal promising prospects and defined specific challenges for the integration of these alternative reducing agents in the industry. The synergistic use of pyrolysed SLF, bio-coke, and hydrogen presents a viable pathway to significantly diminish CO2 emissions while simultaneously improving the sustainability of the metallurgical sector.

Jun 19, 2024

By M A. Rhamdhani, K Avarmaa, A Putera, J Chen, G Brooks

Silicon-based photovoltaic cells are currently the most dominant types applied to convert solar energy to electricity. In solar-grade silicon (SG-Si), the control of boron (B) and phosphorus (P) is very critical. Generally, these elements are difficult to remove into acceptable sub-ppm levels from lower grade Si. This study investigates slag treatment as a process for Si refining, focusing on the behaviour of P and B. The experiments were conducted by equilibrating Si-B-P alloys with 43 wt per cent SiO2 – 47 wt per cent CaO – 10 wt per cent Al2O3 slag under inert atmosphere at 1500°C. Different crucible materials were used (Al2O3, SiO2 and MgO), which determined the primary saturation phase for the system and modified the final slag composition accordingly. The samples were equilibrated and analysed with microanalysis techniques (EPMA (electron probe microanalysis) and LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometry)). New standards were prepared and applied in the LA-ICP-MS analyses. Experimental results show that silver is essentially fully dissolved in silicon, as well as most phosphorus with LP ( = wt per cent P in slag/wt per cent P in Si) between 0.1–0.3. The distribution coefficient of boron was measured to be between 1 and 2. The crucible material used had an influence on the phase compositions and slight influence on the distribution coefficients of boron and phosphorus. The experimental results provided new accurate data when considering applicability of slag treatment as a technique for Si refining and Si PV cell recycling.

Jun 19, 2024

By D Bruce

OZ Minerals’ Carrapateena mine is a Sublevel cave mine located in South Australia, approximately 160 km north of the regional centre of Port Augusta. Carrapateena commenced underground development in 2016, with production commencing in 2019 and ramping up to 4.25 Mtpa by December 2020. In pursuit of continual improvement, the Carrapateena mining team sought to identify how it could better interrogate its current productivity levels and its drivers (root causes). During this process the team were confronted by a disconcerting number of different opinions (which often conflicted) on our actual productivity performance which led to a need for review. Although reliable data and a well-designed time utilisation model (TUM) existed, it was still unclear what actions needed to be put in place to improve productivity. This was for the following reasons: • Data sources were disparate unless significant effort was applied to compile them. • Data sources were not available in a format that could be easily viewed or analysed. • General understanding of the data which was collected and how it could be used was poor. • Process of regularly analysing performance and forming tangible actions to improve was lacking rigour. A project was then started with the goal to fix the areas stated above. An initial requirements gathering exercise was undertaken to identify key data sources for site which returned a staggering 42 known systems which were then shortlisted to the key systems that contained operational data and could generate tangible improvements when analysed. This paper discusses the approach to selecting the OZ Minerals Insights Hub as the chosen platform, and the effort and collaboration between cross-functional departments that was involved in transforming the data so it could be displayed in a useful way. The data sources identified included a fleet management system, two planning databases, a control system historian, and a mobile fleet machine data system. New processes were also introduced to digitally capture daily commentary; this was achieved utilising SharePoint Forms. Data pipelines were then developed in the Insights Hub platform to automate the ingestion and transformation of the raw mining data into curated data models for end user consumption. Tableau dashboard packages have been created to support facilitation of short interval control, daily review meetings, and weekly review meetings as well as data analysis of key equipment and locations. These dashboards visualise the mining data models in a form that provides the user a clear picture of what has occurred, why it has occurred, and where to focus improvement efforts. This has resulted in a team which is more accountable, more equipped to assess the root cause of performance, and more regularly able to make data driven decisions. The next step? To build this out from Mine to Mill and create a data indexing tool which will drive self-service reporting, a data agnostic platform and predictive tools that help our people continue to be one step in front.

Mar 29, 2023

By D L. Head

Critical risk management (CRM) has become one of the latest safety buzz terms in mining. Everyone seems to be doing it, everyone seems to know about it, yet we are still having fatalities in our industry from well understood hazards such as mobile equipment amongst others.

May 5, 2022

By B Small

CSA Mine, named after the nationalities of the mines first owners being Cornish, Scottish, Australian, is one of Australia’s deepest and highest-grade copper mines. A combination of the modified Avoca method and shrinking was a standard practice where production rings were fired against and bogged to waste fill. This method resulted in dilution and involved rehandling of waste material to refill the bogged stopes in the Western region and the QTS Central. The introduction of pre-charging blastholes using a wireless initiating system (WebGen™) has enabled CSA to design and fire stopes in reverse. This involves the use of a pre-charged Temporary Rib Pillar (TRP) against the waste fill material in a previously mined stope. The temporary pillar reduces dilution and improves conventional bogging as material is blasted towards the drawpoint rather than towards the waste fill material. Additional drill, prep and blast re-work is reduced or completely removed as rings can be charged prior to, in conjunction with, or after, charging of the slot. This is a safer practice as the charge crew spend no time working adjacent to a brow or open void. A TRP trial was conducted in the western orebody at CSA. The risk of exposure to a brow or open void while charging underground, and the bogger rehandling of waste material was successfully eliminated. Once reverse stoping was established in modified avoca stopes at CSA, two TRPs were implemented in challenging ground conditions in the QTS Central region. The TRPs were utilised in a retreating four-way intersection to extract a central diminishing pillar to close the level out. The ore recovered in this stope provided 5 per cent of CSA’s copper for the year. Without pre-charging with a wireless initiating system, two 5 m pillars totalling 6936 t of ore at 7 per cent either side of the stope would not have been recovered. CSA has implemented the practice of reverse stoping in modified avoca stopes using TRP for ten stopes since the successful trial. The development of additional blasting techniques enabled by precharging with wireless initiating systems is currently underway in the QTS North orebody at CSA Mine.

Mar 29, 2023

By E Wargem

The optimum mining of an orebody in an underground mining operation is fundamental to the mine’s ability to operate both sustainably and efficiently. The effective mining of an open stope or a cave is largely reliant on the recovery of the initial void created by conventional drilling and blasting. These initial voids are known by various names such as a Longhole Rise, Slot or Winze and can be mined either as a downhole or as an uphole. Regardless of the underground mining method, the process of the design and implementation of this initial void is largely uniform across many operations with various patterns of slot or winze designs used across these different operations. Diligent design, implementation and review strategies in drilling and blasting of these will facilitate cost-effective mining with minimal disruption to mine schedules and production targets. When an operation struggles in opening the initial void in underground mine blasting, it has a negative impact on productivity, mineral recovery, and the overall economics of mining. Near field blast vibration monitoring is a vital tool to use in analysing slot blasts and will provide additional feedback into the reconciliation part of the drill and blast process. It is one that is often overlooked in the mining industry in many operations due to many factors such as lack of skilled personnel, or a lack of required resources. The data obtained from near field blast vibration monitoring can be used to provide additional feedback into blast reviews and help in any drill and blast optimisation projects. This paper highlights key aspects of underground drill and blast reviews and the use of near field blast vibration monitoring for post blast analysis and shares learnings from various projects that the authors have been involved in within Australia and abroad.

Mar 29, 2023

By C J. Pitzer

The prevention of fatal risks is a key objective for the global resources industry, especially considering poor performance with regard to fatality rate reduction and the continued occurrence of mine disasters globally. However, the industry has a credible history, over several decades, of the development and deployment management systems to control potential Serious Injury, Fatal and Catastrophic (P-SIFC) risks. While these systems have had a significant impact on the thinking and approaches to the prevention of fatal risks, fatal accident rates have not shown the desired reduction. Recent fatal and serious injury events in Australia have led to the establishment of several enquiries to further identify improvements that could be considered. Globally, fatal accident rates remain stubbornly high or plateaued in many jurisdictions, and several catastrophic events have occurred, such as tailing dams disasters in Brazil and South Africa, and the recent coalmine disaster in Turkey. Apart from the apparent lack of progress, it is evident that the deployment of critical risk systems has introduced more bureaucracy, slower response systems and additional burdens on already overloaded middle and supervisory levels of management. Organisations are rarely able to effectively tap into the risk source of risk knowledge of the frontline worker and supervisor, for various reasons discussed in this paper. To establish a valid and valuable channel of critical risk information flow from the frontline employee, Debmarine Namibia instigated the development and deployment of a system called SafeSENTRY, where the focus is on the ‘dynamic identification of dynamic risks’. This paper outlines the system, the principles of the design, the range of risk metrics that can be derived from the observations of the frontline operators, and demonstrates how a range of posited shortcomings in critical risk management is addressed how features of the High Reliability Organization (HRO) have been developed.

Mar 29, 2023

By T Ladinig

Raise caving is a novel cave mining method, which has been proposed for mass mining at increasing mining depths in LKAB operations. The method makes use of the raise mining technology and an active stress management approach. For the implementation the method is split into two phases, namely a de-stressing phase and a production phase. In the de-stressing phase, a slot-pillar system is established. The purpose of slots is to provide stress shadows and the purpose of the large pillars is to control stress and seismicity. The production phase follows after the de-stressing phase. Required infrastructure in the production phase is developed delayed in stress shadows and bulk extraction takes place in de-stressed zones. Eventually the pillars crush and they are extracted in the production phase. A comprehensive research and development program has been launched to develop the raise caving method towards implementation. As part of this program a full-scale test site of raise caving will be conducted as well as raise caving operations are planned for depth extensions in LKAB mines. This paper discusses the design of raise caving operations in practice at the LKAB mines. In particular, the purpose of the paper is to focus on requirements for the development and design of a raise caving operation. The development of raise caving is discussed from a systems engineering perspective as well as from a management perspective. The functional requirements in the destressing and production phase are outlined and discussed in the paper. The discussion is on basis of the main elements of the raise caving system, such as slots, stopes, pillars and infrastructure. Critical rock engineering design requirements in the de-stressing and production phase are highlighted and dependencies between individual main elements are identified. The analyses show that pillars are especially important for the success of the mining method. Overall, the analyses show that raise caving is a complex system and that its development demands a multidisciplinary approach.

Mar 29, 2023

By C M. Stewart

Lithium battery electric powered vehicles and machines (BEVs) continue to gain traction inunderground mining use, with predictions they will dominate the underground light and heavy vehicle fleets for some mines within the next decade. There are clear advantages for ventilation systems through reduced heat output and the elimination of harmful exhaust gases and diesel particulates. However, the risks and effects of BEV fire emergencies for underground personnel and ventilationsystems are still largely in the early stages of analysis and understanding. This paper conducts an industry review of a selection of lithium battery fire incidents and research.A research paper review on lihthium fire behaviour, intensity and toxicity will be analysed and comparisons made with equivalent diesel machinery fires for context. Guidelines for mine firemodelling parameters will be offered to assist in predicting the behaviour, heat and emissions from BEV fires, and recommendations and conclusions will be drawn on the specific hazards of lithium battery fires compared to conventional diesel powered machines.

Oct 12, 2022

By A Kite

Frontline leaders play a critical role in the safe and productive operations of Australia’s mining, resources and heavy industries. These leaders set the workplace culture, especially during night shifts and weekends, by providing team direction and encouragement, providing access to resources, fulfilling statutory requirements, enacting and reinforcing risk management systems, setting the standards on shift and acting as the primary conduit of communications between senior leaders and team members.

May 5, 2022

By M Ireland

Extensive use of diesel-powered mobile equipment in modern mines for materials handling, such as load-haul-dump machines, constitute a significant source of heat, exhaust gases and diesel particulate matter. Provision of sufficient quantities of fresh, cool air are required to remove such atmospheric contaminants from the environment for miners, particularly at depths where ventilation constraints and associated operating costs have an increasingly adverse impact. An alternative solution to diesel equipment to combat economic, environmental, social and health challenges, are battery electric vehicles (BEV), with the potential to expand production and substantially reduce ventilation and cooling demand, subsequently reducing operating costs. In this context, this paper focuses on the introduction of a battery electric loader to a diesel fleet at one of the deepest underground mines in Australia, the CSA Mine, a high-grade copper operation in Cobar, New South Wales. Analysis of a trial battery electric loader compared to existing diesel machines is performed with regards to infrastructure, technical and operational issues. Key benefits of battery electric vehicles over conventional diesel-powered vehicles are discussed, including lower energy consumption and greater efficiency, reduction of emissions and heat, reduced need for ventilation and lower operating costs. Challenges of introducing BEVs into an operation, along with the results from the comparative study are addressed under impacts to energy consumption, equipment selection, effects on ventilation and cooling, mine design and economic viability for future fleet implementation scenarios whilst meeting production targets.

Mar 29, 2023

By D J. Brake

The importance of mine ventilation to health and safety in both coal and metalliferous mines has been long recognised. The primary and secondary ventilation systems in most metalliferous mines incur 50 per cent or more of the total mine electrical power consumption and frequently about 10 per cent of total underground mine operating costs. The requirements for ventilation-related horizontal and vertical development, fans and cooling have a significant impact on mine capital costs and also on mine schedules and start-up times and hence cash flows. There are increasing pressures on regulators and miners to reduce airborne contaminants such as diesel particulatematter, nitrogen dioxide and heat (wet bulb temperatures), and significant pressures to reducegreenhouse gases such as fugitive methane emissions from coalmines and the carbon dioxide footprint of both coal and metalliferous mines. Many previously Australian miners are now globaloperators and have extensive overseas mining operations where local ventilation standards and expertise may not be consistent with Australian practices. The role of the site ventilation officer is also changing with strict new requirements for the statutory position being introduced into Queensland metalliferous mines and the potential for this to become more widespread. Recent regulator and parliamentary review committees have identified systematic shortcomings in mine ventilation compliance, and statutory certificates in both Queensland and NSW now require continuing professional development to maintain currency. Public and investor support for mining are also increasingly contingent on safe, healthy and environmentally responsible practices and the standards for these are frequently tightening. Good ventilation design and operating practices that are consistently well executed therefore contribute significantly not only to a safe and healthy mine but also to a productive and cost-effective operation and the ongoing social licence to operate. There are a variety of ways of providing technical design and oversight into a mine’s ventilation systems; this paper explores some current trends in ventilation standards and statutory requirements, as well as ways to support and develop mine ventilation staff for both domestic and international operations and also the emerging senior technical roles of Group/Principal/Corporate mine ventilation engineer.

Oct 12, 2022

By F C. D Michelin

As mines get deeper, the critical underground temperature limits will be exceeded, and an increasing number of mines will need to implement, expand or modify cooling systems. Surface cooling plants have many advantages over underground cooling such as efficient heat rejection, and lower relative capital cost; however the delivery of cooling through long underground distances can result in lost refrigeration capacity before the chilled air reaches the areas it is needed most. Refrigeration plants are therefore often overdesigned in size and capacity to compensate for underground losses.More mines are now utilising real-time monitoring and automated control of ventilation airflow and fan systems to ensure the conditions underground are safe and productive, and power consumption is efficiently managed. There may be significant opportunities to extend ventilation monitoring and control into the refrigeration delivery and control system.Energy reduction is an effective way to reduce costs and CO2 emissions, which is an increasingly important part of corporate governance. More efficient refrigeration control is a further step toward reducing energy consumption. This paper looks at an added step in how real-time monitoring can assist in controlling the output and chilled air delivery of a cooling plant. The requirements, implementation, benefits and challenges will be discussed.

Oct 12, 2022

By A Turns

In a survey conducted by symplexi with underground miners in Australia; 78 per cent of participants believed that ‘safety’ is all about people. If ‘safety’ is about people, then is the mining industry focusing on the wrong thing? It would be fair to say that the mining industry is heavily systems focused. Companies develop a safety management system and use this to show regulators that they comply with legislation – however, that is only half of the picture.

May 5, 2022