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By Budiselic C, Hefter G

The uptake of gold by activated carbon from acid chloride solutions involves the reduction of gold(IIl) to metallic gold. Deposition occurs only on the surface of the carbon at localized active sites at first, and subsequently at less active areas. The rate of uptake depends on the surface area of activated carbon, which confirms results from a recently published study (de Siegel and Soto, 1984). Increased rates of uptake were observed at higher temperatures and lower chloride concentrations due to the decreased stability of AuCI4-, the major gold(IIl) species present. Recoveries of gold approached 100 per cent for a contact time of 60 minutes at 20°C in a well stirred solution initially 5 ppm in gold(III) and containing 0.5 per cent w/v coconut-shell carbon. The presence of 0.25 Mnitric acid or 100 ppm iron(IIl) had no detectable effect on either rate or efficiency of gold uptake.

Jan 1, 1985

By May Nyman

Due to the vast diversity of chemical media in which metal separations are executed, a wide range of ion separation materials are employed, This ,results in an ongoing effort to discover new phases with novel ion exchange properties. We present here the synthesis of a novel class at, thermally and chemically stable microporous, niobate-based materials. Ion exchange studies show these new phases are highly selective for Sr2+ and other bivalent metals.

Jan 1, 1999

By E. R. Macgregor, J. Halpern

The kinetics of the reduction of cupric salts in aqueous solution by molecular hydrogen to metallic copper are described. The rate of reduction appears to be homogeneously determined and shows a marked inverse dependence on the hydrogen-ion concentration. Precipitation of copper is more rapid and complete in sulfate than in per-chlorate solution. A mechanism is proposed which accounts for this behavior. IN recent years a number of important hydro-metallurgical processes have been developed in which metallic salts in aqueous solution are reduced by gaseous hydrogen, usually at elevated temperatures and pressures, and thereby precipitated either in metallic form (e.g. Ni, Co, Cu) or as an oxide or salt of lower valence (e.g. VO, and VA).1 ; In connection with applications such as these, most of which involve heterogeneously catalyzed reactions, recent demonstrations"-" that salts of certain metals, e.g., Cu", Ag' , Hg" , and Hg,+ can activate molecular hydrogen homogeneously and thus catalyze hydrogenation reactions in aqueous solution, are of considerable interest. For example, cupric salts catalyze the otherwise slow homogeneous reduction of dichromate and ceric salts by hydrogen, i.e. Cr,O; + 3HL. + 8H1 ? 2Cr'- -- 7H,O [1] 2Ce ' ! H.. ? 2Ce" | 2H . [2] In perchloric-acid solution, where Cu" is not appreciably complexed, the kinetics have been found" " to be of the form -d [H,] _- k,[HJ [CU"]' dt -LCu+' l+ (k ,/k,) [H] [3] where, K = 1x10"' exp [—26,600/RT] 1, mole-' min-' ... [4] and (k ,/k,) - 0.25 at 110°C. This kinetic behavior suggests that the reaction proceeds by a mechanism involving the following sequence of steps kt Cu" +H1CuH' 4-HA [51 k., CUH + CU" ? + 2Cu f H' [GI 6Cu'+ Cr,07 + 14H'+ 2Cr- (¦ 7H,O + 6Cu" ['i] fast The catalytic activities of the undissociated cupric-sulphate and cupric-acetate complexes are somewhat greater (by factors of 6.5 and 120, respectively) than that of the simple hydrated Cu" ion.'" These considerations suggest that, in contrast to the other hydrometallurgical hydrogenation reactions, referred to previously, reduction of cupric salts in aqueous solutions by molecular hydrogen, should proceed homogeneously, and in the absence of an extraneous catalyst. This has already been demonstrated" for acetate-buffered solutions where the product of the reaction is a precipitate of cuprous oxide (Cu,O). In the present paper, an investigation of the reduction of cupric salts in perchloric-acid and sulphuric-acid solutions, leading to the precipitation of metallic copper, is described. Some results for the sulphate system, which is of considerable hydrometallurgical interest, have been reported previously by Ipatieff",' " and by Schaufel-berger' but these do not give a quantitative account, of the kinetics and mechanism of the reaction. Experimental The reduction experiments were conducted in the 1-gal, titanium-lined autoclave described in connection with earlier related investigations," " and using a similar procedure. The solutions were made up by dissolving known amounts of CP grade Cu(ClO,), and HC10, (or CuSO, and HISO,) in dis-tilled water. While in the autoclave, the solution was stirred and maintained at a constant temperature (±loc) and under a constant partial pressure of hydrogen gas. It was ascertained that the agitation (provided by two 3-in., four-bladed stirrers, rotating at 900 rpm) was adequate so that at no time was the rate of reaction limited by solution of hydrogen. During each experiment, samples of the solution were withdrawn periodically, allowed to cool, and the concentration of copper remaining in solution was then determined electrolytically. Some Cu' is formed during the reaction, but undergoes disproportionation when the solution is cooled to room temperature. For purposes of kinetic calcula-

Jan 1, 1959

"HPGRs operate in a wide array of applications in mining and minerals. These range from relatively coarse crushing of copper and gold ores at one end of the spectrum to the processing of fine iron ore pellet feed and fine industrial mineral products at the other. Traditionally these circuits involve the treatment of relatively moist materials in pre-grinding circuits; using single stage HPGRs in open circuit or as a closed circuit operation with screening or partial product recycle. More recently, HPGR is increasingly deployed in dry grinding in combination with air classification. The high throughput demonstrated by larger HPGRs has stretched the application towards coarser size reduction duties for a number of new projects. At the same time, the basic principle of inter-particle crushing for generating a product with a high fines proportion gives ground to investigate applying the technology further towards finished product duties. The advantages that HPGR brings are clear. Multi Stage grinding enables energy efficient size reduction across more of the comminution circuit. Primary HPGR serves for a coarse grinding duty, whereas a secondary HPGR is geared towards generating a fine product for downstream processing or even a finished product. This publication summarizes some of the features of staged HPGR circuits and discusses some examples of operating and projected applications.INTRODUCTION In most HPGR applications, the grinding units are used as a single process stage, either in open circuit, such as for pebble crushing [Rose 2002, Westermeyer 2000, Van der Meer 2015] or in closed circuit with classification [Van der Meer 2009, 2012] or product recycling [Van der Meer 2010]. Where a higher plant capacity is required, the HPGRs are commonly installed in multiple lines in a parallel arrangement [Parker 2005, Koski 201, Vanderbeek 2006]. HPGRs can take a wide range of feed size distributions, and grind this down to a product with a high fines content. In general view, there is a limit on the size reduction range that even an HPGR can provide. Grinding down from a very coarse ore (e.g. 70-100 mm) to a very fine product (e.g. 100 microns range) is stretching the ability of a single stage HPGR circuit. Fine grinding generally requires a classification stage that returns the classifier oversize to the head of the HPGR circuit. From one point of view, it can be demonstrated that when recycling a large proportion of fines and middlings back to the HPGR feed results in an effective feed with an overrepresentation of middlings and fines, which will eventually reduce the grinding efficiency and consequently result in an increased recirculation mass flow [Van der Meer 2014]. From another point of view the large recycling mass puts a strain or even a limit on the capacity of present-day conveyor capacity."

Jan 1, 2018

Incompetent ore and country rock have caused stability problems in longhole open stopes. Fully grouted pre-placed cablebolts have reduced these by preventing ground relax- ation and joint dilation to maintain a self supporting rock structure. Larger atope spans can now be opened with the same or smaller pillar. Mining methods are expected to become less dependent on original ground conditions. Effect of spacing, orientation and stress distribution along the cablebolt is not fully understood at this stage and requires more Observation.

Jan 1, 1977

The old Trekelano mining area is situated in the Cloncurry Gold and Mineral Field 14 km east-south-east of Duchess. It connected with the main Cloncurry-Dajarra railway line by a private line from Juenburra, a distance of 10 km. The distance by rail from Townsville is 561 km. The area was first mentioned circa 1902 - 1903 when a very short report said, that a Tony Allis had taken a parcel of copper ore out of a mine which, he called æThe InheritedÆ. After that report, nothing further was printed until about 1906, when traces of copper were noticed on a wagon track going to Kiama Well. The Trekelano deposit did not outcrop, with the cap covered by about two metres of soil. The deposit was named after an early pastoral holding. The early prospectors were however disappointed by TrekelanoÆs low copper grades, approximately five per cent Cu. This is understandable when, in those days, about 25 per cent was the cut-off grade for mines in the district. Meanwhile, The Hampden Mining and Smelting Company were constructing a smelter to treat their sulphide ores at Kuradala that was replacing their high grade oxides ore. By about 1910, the Hampden Mining and Smelting Company was experiencing smelting problems, and needed suitable oxidised copper ore to blend with the Kuradala pyritic ore. Someone must have remembered the Trekelano low-grade oxides, resulting in agreement to mine and cart the ore to Duchess, from where it was railed to Hampden, as Kuradala was known at that time.

Jan 1, 1998

By D. T. Van Zandt

IN the late 1920's rotary drills began to replace the churn drills in the petroleum industry, but until the middle 1940's the churn drill was the only widely accepted means of drilling large-diameter blastholes for quarry operations. The Calcite plant of the Michigan Limestone Div., U. S. Steel Corp., was one of the first to experiment with rotary drills for quarry blasthole drilling, and the first to employ compressed air on a fully rotary rig to cool the bit and raise the cuttings to the collar of the blasthole.

Jan 8, 1954

The Similkameen mine is located about 100 miles east of Vancouver, British Columbia, and ten miles west of Princeton, where the mine personnel live. Princeton was the first town in the British Columbia interior, originally the home of Cree and Blackfoot Indians and later settled by men of the Hudson's Bay Company, miners, cattlemen, and others looking for gold. After gold, there were coal mines and then copper mines . The Granby Consolidated Mining Company, Limited, operated the Copper Mountain ore bodies from 1926 to 1930 and from 1937 to 1957, mining 34 million tons of about 170 copper ore, mainly from underground. In 1966, Newmont Mining Corporation acquired the Ingerbelle property on the west side of the Similkameen River. Newmont then purchased the assets of Granby and formed Similkameen Mining Company to develop and operate the Ingerbelle and Copper Mountain ore bodies on both sides of the Similkameen River canyon. The Ingerbelle and Copper Mountain ore bodies lie within rocks composed of andesite tuffs, agglomerates, and argillites. Chalcopyrite mineralization occurs as a dissemination. Original ore reserves were estimated at approximately 75 million tons grading 0.52% copper. Mining is carried out on a three-shift, seven-day-week schedule at a rate of about 60,000 tons of ore and waste per day with four 10 cu yd P & H 1900 shovels which mine and load a fleet of 100-ton Lectra Haul trucks. Among the unique features of the design and construction of the Similkameen project was the construction of 4. 5 miles (7. 24 km) of new Trans-Provincial No. 3 highway by the company to the specifications of the British Columbia Department of Highways. The old highway traversed the Ingerbelle pit area. Along the relocated highway is a 4, 000 ft (1219 m) long berm which conceals the mine pit. This area has been replanted and now looks like the original forest scenery. Another interesting feature is that the tailings from the concentrator flow by gravity over a 1000 ft (34% m) suspension bridge, which crosses the Similkameen River canyon then passes through a tunnel to the dam site, a distance of 59,000 ft (17,980 m) to the cyclone station. When the Copper Mountain ore bodies are mined, the ore will be transported by belt conveyor on a second suspension bridge across the canyon to the Ingerbelle concentrator. After being loaded by the shovels into the 100-ton trucks, the ore is

Jan 1, 1978

By Jack Parker

Critical width Before we go further into pillar design, we should look into the matter of "critical width," because of its effect on pillar behavior. Critical width refers to the greatest width that the rocks above the mine can span before failure or, if there are pillars, the width to which we must mine before the pillars accept the full weight of the overlying materials. There are theories to help calculate that probable width, and they usually boil down to one-quarter or one-third of the depth of cover; but they don't always fit, and it would be better for us to understand the factors that control local conditions. Critical width may be controlled by the thickness or strength of one or more of the strata above the mining horizon. In a gold mine, we might have a thick granite or basalt above us, perhaps capable of bridging across most or even all of a small ore body. In that case, pillars might have to support nothing, or perhaps just the weaker or damaged rock below the strong main roof. Obviously it would be wrong to design for tributary load on pillars based on some lab-determined rock strength. In some coal mining districts in Utah, huge steps can be seen in the mountain sides, with slopes on weathered shales and vertical cliffs 100 or 200 ft high in thick, hard sandstones. The sandstones are capable of bridging across hundreds of feet, often making mining deceptively easy at first, but it becomes more difficult as greater areas are opened. Sometimes such a mining sequence leads to violent bumps and bursts as the wide spans of sandstone sag and bear down on the working faces, like giant nutcrackers, or as bridges eventually fail, releasing much pent-up energy.

Jan 1, 1993

By Oscar Marreros Daza

Dada la complejidad de las rocas y cuerpos mineralizados en el Tajo Mc Cune de Cerro de Pasco, es más difícil calcular los parámetros óptimos de perforación y voladura por métodos manuales. En este sentido, el presente texto describe un programa en Basic para la computadora IBM Pc, donde se puede hacer un análisis de estándares de voladura y costos para cualquier diámetro de explosivo, tipo de roca, explosivo y altura de banco. Asimismo, se considera el método de cálculo de los estándares de perforación y voladura perteneciente a Richard L. Ash y se realiza el análisis de voladura con ANFO para los diferentes tipos de roca dado su bajo costo y rendimiento

Nov 24, 1986

Jan 1, 1900

By M. Jaramillo

The expanded west pit of the 15 Mta (13.6 stpy) El Cerrejon mine will eventually reach a maximum depth of 270 m (890 ft). Slope-stability evaluations indicated that this depth, combined with structural complexities, would create a serious risk of footwall instability. Stabilization calls for anchoring the footwall by the installation of 9- to 33-m- (30- to 108 ft-) long multistrand steel cable bolts. For each of the 15-m- (50-ft-) high mining benches, a row of bolts is installed with variable horizontal spacing, depending on the dip magnitude. Cable bolting is now standard operating practice, and an estimated 11,800 bolts will be installed during the life of the mine. Results to date have been satisfactory in terms of the stability condition of the bolted slopes.

Jan 1, 1997

The process of pile driving disturbs the soil around the pile. The nature and magnitude of disturbance depends upon 1) the pile size, and 2) the nature of soil. Therefore, the prediction of a single pile behavior based on soil properties of undisturbed soil samples may not match its performance. Under lateral loads, the pile may loose contact with the soil near the ground surface especially in clays. The soil pile interactions are influenced the most by pile behavior in this zone. This situation further affects the tally of prediction and performance. Piles are used in groups. The zones of overlapping stress from one pile to the other both around the pile and below their tip particularly in soft soils, contribute to group effects. Empirical solutions have been developed for prediction of the pile group behavior. The group action is more involved under vibrations. Several cases of single piles and pile groups under static and dynamic loads from published records have been analysed. It has been shown that single pile test is the best source of information on the soil-pile-soil interaction effects.

Jan 1, 1989

By C. J. Bise

One area of study for the Coal Mine Injury Analysis project was to illustrate how loss control can be used as a foundation for mine safety training. After an initial review of the principles of loss control, the instruments often used for worker/worksite appraisal, such as incident reporting, analysis, and investigation, workplace observation, worksite inspection, and safety audits and checklists were evaluated for their effectiveness. The findings were then applied to the continuous-miner worksite at several mines to modify the techniques for use in a highly dynamic man/machine work environment. Before the information gathered from the review of the various continuous-miner worksites was presented at the annual retraining sessions at five mines, a trainability analysis procedure was developed to separate training shortcomings from those problems resulting from improper equipment design or unsatisfactory working environments. Also, several microcomputer-based training programs were developed to aid in conveying the loss-control concepts to the trainees. Finally, the results from the implementation and evaluation of the loss-control-based training programs were documented, including the complete training script for one of the case-study mines. The procedures outlined in this study will aid mine training specialists in developing focused, pro-active accident-prevention strategies and training programs that are based on sound loss-control principles.

Jan 1, 1993

By Llewellyn A. Rubin

Under Bureau of Mines Contract H0122007, Telcom, Inc., with the assistance of Fenix & Scisson, Inc., conducted a 17-month research and development project aimed at provid¬ing a field-test model of a guidance system for use with the Bureau of Mines Probe Drill. The Probe Drill is a part of the Bureau's Mine Rescue System developed under Contract H0101262. Volume I of this report is subdivided into seven sections. Volume II consists of a number of supporting appendices. In addition, there were delivered under the Contract, a number of other documents which are referenced in the text. Section 1 deals with essential contract information, Program Background, and a general system description. Section 2 covers the project chronology in brief. Section 3 is a digest of design considerations and implementation related to the requirements of the Contract. Section 4 is a description of the System, including illustrations of the hardware, and software. Section 5 is devoted to Operation and Maintenance. Para. 5.1 describes step-by-step field assembly and disassembly of the downhole unit. Para. 5.2 covers Operation. Para. 5.3 covers various aspects of maintenance from the lowest field echelon possible. Higher level maintenance must be accomplished in the laboratory, for the present field-test model. Para. 5.4 covers system calibration. Para. 5.5 covers detailed step-by-step operational sequences. Section 6 covers the results of the field testing, post-test evaluation, and recommendations. Essentially, we conclude that the present hardware (field-test model) has proven every aspect of system performance, but failed to provide reliable assurance of an operationally ready system. Telcom, therefore, recommends a three-phase continuing effort devised to provide the operationally-ready model of the system.

Jan 1, 1973

By Frank C. Townsend

Centrifugal model embankments with varying geometries and materials were constructed of- coal waste material, accelerated From 100 to 120 times earth's gravity, and subjected to various throughflow rates until failure occurred. Complementary laboratory tests were performed on the waste materials to obtain strength and permeability parameters for analytical calculations to predict observed centrifugal model behavior. Failures in the form of deep.-seated failure, or erosion and sediment transport or a combination of both, occurred in model embankments with 1V:1-1/2H and 1V:2H slopes when the phreatic surface due to seepage exited on the downstream slope: Positive seepage control, i.e., a toe drain successfully prevented sloughing and failures. Slope stability analyses agreed well, albeit conservatively, with observed model performance. Factors of safety ranged from 0.7 to 1.02 at the instant of failure for models with retrogressing slips as compared with 1.05 to 1.7 for stable embankments, These models verified existing criteria of a minimum safety factor of 1 3 and the necessity of positive seepage control.

Jan 1, 1980

Terramin Australia LimitedÆs Angas Lead and Zinc Mine operates in the unique and picturesque environment of Adelaide Hills, 60 km South East of the Adelaide city centre itself. The mine was granted approval for construction by the South Australian Government in April 2007 and the Process Plant was constructed and commissioned in July 2008. This paper outlines the background to the plant design and the approval process given the close proximity to the local town of Strathalbyn, with a major focus on the commissioning learnings from the Concentrator startup for future reference and a review of the operational performance of the Concentrator throughout the first year of successful production versus design and expectations.

Jan 1, 2009

By Eldon Keith Stanek

This annual report deals with four distinct tasks related to research on the safety and reliability of mine electrical power systems. Task one is to develop tests and the associated instrumentation to detect incipient faults on a mine or any low-voltage power system. Task two is a dual effort related to the digital prediction of electrical transients on mine power systems and laboratory testing of transient suppression devices. Task three is also a dual effort. This task consists of both theoretical and laboratory work to assess both the reliability and the fail-safe characteristics of several items of protective equipment used in mine power systems. Task four consists of an effort to use programmable calculators and/or computer terminals to check overcurrent protective device coordination.

Jan 1, 1976

By Clarence Karr

THE BUREAU OF MINES is investigating methods for upgrading tar produced by the low-temperature carbonization of bituminous coal. This survey was undertaken to compile information needed for identifying the ether constituents of low-temperature tar. Physical properties are listed for 1,024 aromatic ethers. The compounds include cyclic and noncyclic, polyfunctional and monofunctional ethers with oxygen joined directly to either one or two aromatic rings. Alkyl groups up through butyl are included. The compounds are divided into 37 groups ranging in complexity from alkoxybenzenes to dibenzopyrans. Compounds containing aromatic ether groups are important constituents of the neutral oxygen components of low-temperature tar. For example, at Morgantown, W. Va., the Bureau of Mines has identified and determined the amounts of benzofuran, 2-, 3-, 5-, 6-, and 7 -methylbenzofuran, diphenyl ether, dibenzofuran, 2,3-dimethyldibenzofuran, and two other dimethyl-dibenzofurans in the neutral oil from a low-temperature bituminous coal tar (103, 104).3

Jan 1, 1962

By G. F. Kuncir

The time-cost-risk analysis described herein was performed as part of an evaluation of the Advancing Oil Shale Mining Technology Program performed by The Aerospace Corporation. The objectives of this analysis are to assess the feasibility of the program relative' to time and cost constraints, and to determine the probabilities of achieving various technological goals. A combination of standard program planning and analysis techniques were used to achieve these objectives. These included a critical path analysis, a resource allocation analysis, and a risk analysis.

Jan 1, 1977