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By W. C. Browning

The influence of the hydroxyl factor is more damaging to formations penetrated and causes greater consumption of drilling mud additives than previously realized. This hydroxyl effect on clays is essentially independent of the cations present in the drilling fluid and thus differs from the base exchange reactions that have preoccupied mud chemistry with sodium and calcium bentonite concepts for nearly two decades. The new organic polyelectrolyte-con-ditioned muds haw made it possible to use materials other than sodium hydroxide to maintain the alkalinity of such muds. The properties of silicates, as indicated by their dissociation characteristics and buffering action, are such that they can control he pH and alkalinity of drilling muds at the desired level and, at the same time, minimize undesirable hydroxyl effects associated with sodium hydroxide. This use of silicate compounds is different and distinct from prior applications of silicates as deflocculants or shale preservers. Laboratory and field data presented in this report show that silicate compositions can be utilized to adjust the alkalinity of drilling muds and, at the same time, minimize hydmxyl-promoted clay cleavage. INTRODUCTION Studies for improving the efficiency of rotary drilling techniques must consider the chemistry of drilling fluids and of the formations being penetrated. The chemical aspects of drilling must be studied in conjunction with and in relation to the mechanical factors if, for example, penetration rates are to be optimized. Drilling fluid technology has been largely influenced by chemical reactions of the montmorillonite (bentonite) clay minerals. Most of the literature of mud chemistry concerns the properties of bentonite. Clays of the kaolin or illite type, which are nonswelling, are not generally regarded as sources of drilling mud problems. If these nonswelling shale clays are considered, they are commonly regarded as inert solids. Particularly noteworthy is the fact that the relation of surface and colloid chemistry to massive shale bodies has received only scant attention from drilling technologists. Clay studies reported in the drilling mud literature have dealt, for the most part, with the properties of clays in a finely divided state, and often in very dilute suspensions. Yet frequently during drilling, shale problems not related to the rheology of clay suspensions develop in massive non-bentonitic shale sections of zero or near zero permeability. This paper is concerned with surface chemical reactions that can influence the behavior of these non-bentonite clay masses in such a manner as to adversely affect drilling operations. Browning and Perricone1,2 have pointed out that some of the most troublesome shales to drill, such as the Atoka, contain no montmorillonites. They also pointed out that mud problems can frequently be mitigated by reduction of clay cleavage achieved by using drilling fluids with a minimum of available hydroxyl ions. If pronounced clay cleavage occurs during drilling, the borehole may soften, increasing the possibility of sloughing. In addition, the resulting increased incorporation of high-surface-area clay solids into the mud system can reduce penetration rates and necessitate greater chemical treatment. This increase of shale, of colloidal or near-colloidal dimensions, into the drilling mud is due to clay aggregate cleavage and not to base exchange or swelling reactions, such as occur with bentonites. Searle and Grimshaw3 point out the difference between cleavage or slaking reactions of nonswelling clays (such as illite and kaolinite) and the swelling of bentonite. They further state that the speed of slaking is increased in alkaline water. Eitel1 cites Salmang and Becker, who recognized that clay surface reactions impart plasticity and workability to clay masses. Their results clearly show that all liquids which contain hydroxyl groups in their molecules favor the workability of clays. The ancient technique of aging clays in the moist condition to increase their "workability" is evidence that these clay cleavage phenomena are of considerable importance. The same hydration cleavage that occurs during the aging of nonswelling clays for ceramic use also acts to break up cuttings and soften the borehole during drilling operations. The mechanism of cleavage of the crystalline aggregates of illitic, kaolinitic and other nonswelling clays; and the chemical means of controlling this cleavage are therefore of considerable significance to the drilling mud chemistry. Inasmuch as there is little reference in the drilling mud literature to the cleavage reactions of nonswelling clays, the structure of these clays and certain properties that relate to the mechanism of clay cleavage will be reviewed briefly. STRUCTURE OF NONSWELLING CLAYS Clays such as kaolinite, illite and montmorillonite are compmed of alternate layers of (1) silicon-oxygen tetra-

Jan 1, 1965

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By V. A. Danielson

The Bureau of Mines studied waste disposal methods a1 a coal mine in Kentucky and another in Alabama to develop cost estimates, to provide better knowledge of current practices, and to guide consideration of alternate disposal methods. Costs of the existing waste disposal systems at each mine were estimated using present-day costs of equipment and labor. Costs of waste disposal systems using alternate equipment were also estimated. Although total disposal costs were essentially the same for both operations, reclamation costs will differ because of different reclamation practices.

Jan 1, 1969

By S. V. Shiraishi, H. B. Bell

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J. Cahalan, President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C120-C127, with a contribution by Wright P.A. on the miscibility gap

Dec 1, 1971

'Nothing happens until something is sold' This statement is not original - it is a necessary orientation for marketing industrial minerals. The most important single philosophy of marketing is that it recognises the consumer as the starting point. Production orientation is concerned with producing products that the customer might buy. Market orientation is concerned with finding the needs of the customer and how they can be satisfied. The difference between the two approaches can be recognised in company structures but the most tangible difference is in the approach by a company to selling and development. In other words, it is the market that decides what can be done with a mineral. The markets requirements dictate what mineral, what grade and what price will be paid. Therefore it follows that when pricing a product we should avoid taking the basic cost and arriving at a final selling price through a series of standard markups (unless government insists on it). We should start with the price the market can stand and work backwards to find out whether you have a profitable product or one that will fail because it is too dear. Naturally a thorough understanding of production costs is necessary particularly when marginal markets are concerned.

Jan 1, 1978

By E. L. Spain

The deposits described in this paper occur over much of Wayne County and in the southeast portion of Hardin County, Tennessee, and in the northeast and northwest portions of Mississippi and Alabama respectively. The presence of tripoli in this region has been known for some time and descriptions of various occurrences in Tennessee have been made by Jewelll and Miser2, while Hilgard3, Lowe4 and Logan5 have treated the deposits that occur in the adjacent portions of Alabama and Mississippi, but there has not been a 'general survey of the entire field summarizing completely the geology of the deposits with respect to their origin and stratigraphic relationships. During 1934, while engaged in surveys of mineral resources through this region for the Tennessee Valley Authority, the writer collected data with this in mind, and has assembled them in this report. He is indebted to H. S. Rankin and N. A. Rose, of the Tennessee Valley Authority Geology Division, for field assistance. Location of Tripoli Deposits Fig. 1 shows the locations of deposits of tripoli in a long belt that extends from northeast Wayne County southwestward into northwest Alabama and thence passes into Mississippi, where the formations carrying it are finally covered by Cretaceous sand and gravel of the Mississippian Embayment. Occasional deposits occur also in the southeastern corner of Hardin County, Tennessee. While tripoli is found at nearly all points along this axis where the related formations are exposed, the largest deposits are grouped about three different centers. Waynesboro-Collinwood District.—In the area between Waynesboro and Collinwood, in Wayne County, Tennessee, tripoli of various grades outcrops in the valley of Green River and in tributary valleys on either side. This district is roughly 12 miles long in a northeast-southwest direction and has a maximum width of 5 miles at its northern end. Exposures are found in road cuts, highway chert pits, in the beds of some of the streams, and on hillsides. The greatest number of high-grade

Jan 1, 1938

Jan 1, 1940

By E. H. Griswold, W. J. Wilkins

Pressure control of oil wells may be defined as the adjustment of pressures within a well to obtain the most efficient and economic utilization of the natural gas energy with a minimum of sand troubles or irregular water encroachment. The purpose of this paper is to present the methods used by the writers in applying pressure control and a discussion of the various effects occurring within the wells affected. The benefits to be derived from the conservation of natural gas energy have been so adequately discussed and demonstrated in prior papers by various engineers that the effects on ultimate production will not be discussed other than to mention a few representative cases. The detrimental effects of irregular edge-water encroachment and of sanding up arc of general knowledge to the industry. Effect on Ultimate Production One of the strongest objections voiced against pressure control is that of the danger or inadvisability of deferring oil production by cutting the rate of production. It has been our experience that such deferred product'ion is returned within a few weeks or months rather than years and that an increased cumulative oil production is obtained in the early life of the well by conserving the natural energy. In many cases the rate of production is increased rather than decreased by the adjustment of pressures to obtain the minimum gas factor. Fig. 1 shows the history of a Wilcox sand well in northern Oklahoma, which was pressure-controlled from completion. It is noted that during the early months while flowing naturally through the casing the gas factor was decreased rather than allowed to follow its natural tendency to increase. A string of 21/2-in. tubing was run to restrict the flow and resulted in a decreased gas factor with a more sustained rate of production. When first placed on gas-lift the gas factor again tended to increase, but after the proper pressure adjustments were made, remained approximately steady. It was necessary to defer 100 bbl. per day of oil production in order to maintain this low gas factor. In March serious

Jan 1, 1929

By Michael Kelly

Current research in longwall mining in CSIRO Exploration & Mining is focused within five major projects and several minor projects. The major projects are: 1 3D Aspects of Longwall Geomechanics. This was reported to the conference last year and a final report will be available by mid-2001. 2 Mine Gas Control. This just completed project centred on Dartbrook Colliery which has a longwall gas make of more than 8 cubic metres per second. 3 Rapid Roadway Development This includes the construction of an autonomous conveying and bolting module (ACBM) that sits between the miner and haulage system. 4 Top Coal Caving In conjunction with the YanKuang group in China, CSIRO and the University of NSW are conducting a prefeasibility study of the Top Coal Caving method in Australian conditions. 5 Longwall Automation. In partnership with the Cooperative Research Centre for Mining Technology and Equipment (CMTE), the CSIRO has conducted a scoping study on this issue and will commence an initial three-year demonstration project in July this year. This paper describes these protects in more detail with particular focus on the last three in the above list.

Jan 1, 2001

By O&apos, Malley G. B

The properties of bearing metals are of considerable interest to mine engineers, since continuous running of mine and mill machinery is of vital importance. Of the several available types of bearing metal, the low melting point lead or tin base alloys are most generally used in mining plant because of the ease of replacement and the possibility of remelting scrap metal from old bearings. The most valuable property of these "white metals," however, is the plasticity which gives a self-aligning character to the bearings, enablingthem to adjust themselves to inequalities which may exist at the time of fitting, or which may develop during running. The object of the present paper is to explain in general terms the physical structures of white bearing metals, and to point out that constitution rather than composition determines the physical properties of these alloys. The same, indeed, is true of most engineering alloys. In steels, for example, a change in the structure may affect the properties to a far greater extent than a change of chemical composition.Structural changes in steels are produced chiefly by heat treatment. In the case of bearing metals no good purpose is served by heat treatment; the microstructure is determined by the conditions of casting, and striking differences in constitution (and therefore in properties) are encountered in an...

Jan 1, 1932

By Silvia H. M. Grimaldi, Afonso H. Martins

The scope of this experimental work was to study the yttrium extraction and stripping behaviour in a solvent extraction system with mono(2-ethylhexyl)2-ethylhexylphosphonic acid (IONQUEST 801) in a chloride system The study was performed for only one contact between organic and aqueous phases The experiments were carried out according to a factorial design. Due to the statistical analysis and its experimental proof, the optimum conditions for maximum yttrium loading into the organic phase of the extraction stage were 16 minutes for time of contact between phases, 980 rpm of stirring intensity and pH=2.3 for the aqueous phase of the sovent extraction system. The optimized experimental conditions by the statistical approach for the stripping stage were: time of contact between phases equal to 20 minutes, 1050 rpm of stirring intensity and 1.75 M HCI into the stripping aqueous solution.

Jan 1, 1995

Jan 1, 1914

Mr. P. F. THOMPSON said this matter was one of very great importance to producers of lead. His association with the matter was that he happened to be the Institute representative on the Committee of the Standards Association of Australia charged with formulating a standard for chemical lead, that is, lead used in technical chemistry for acid chambers and the like. The British standard had this test incorporated in it, but those on the committee felt that it should not be included in the specification. The main objection was that in an accelerated corrosion test one was endeavouring to do in a few seconds what in natural conditions would take years; and it was now being recognised that such tests were of little value in assessing the corrosive properties of a metal.The flash point test was carried out with boiling hot strong sulphuric acid; but no chemical manufacturer would be likely to use such in contact with lead. There were many factors such as the formation of steam, the chemical reduction of sulphuric acid, the evolution of hydrogen, the catalytic effect of the surface lead, affecting this test, other than the presence of the segregated impurities upon which this test throws the onus of the whole imperfection of the lead. Mr. Russell had shown that lead which had stood the test of time often gave a low flash point. They were endeavouring to find rapid methods of estimating minute amounts of the more important impurities, which would eliminate the labour and expense of a full analysis.Mr. H. St. J. SOMERSET thanked Mr. Thompson for his remarks. He supposed some of those present knew that the Broken Hill Associated Smelters was responsible for Mr. Russell's investigations at the University, and he could only agree with Mr. Thompson that the flash point test, which had been accepted at the present time...

Jan 1, 1930

By Robert J. Ramsey, Robert D. Jeppson

Introduction The Utah Copper Division of Kennecott Copper Corporation will present its contribution to the A. M. Gaudin Flotation Symposium in four parts. The first two segments will discuss briefly the historical development of the Utah Copper Division and describe the ore body. The third segment will review the facilities and operating procedures for the Utah Copper division's newest plant, the Bonneville Concentrator. The fourth segment describes flotation process circuitry, including molybdenite recovery procedures, at the Arthur and Magna concentrators. (The Bonneville concentrator is a crushing and grinding unit and does not have its own flotation plant). I. Historical Development Progress through change has been the key to the successful operation of the Utah Copper Division for more than 70 years. As the original low-grade copper operation, the pressures to remain competitive and profitable have dictated the timing and extent of each change. Much of the change has occurred through technological and economic advancements in the area of ore concentration. The Utah Copper Division of Kennecott Copper Corporation had its origin June 4, 1903, when the Utah Copper Company was organized. The initial mill of 300 tpd (tons per day) capacity was built at Copperton a few miles below the present Bingham Canyon mine site. From 1904 to 1910, the Copperton mill was expanded to a capacity of 1,000 tpd, and all of the known apparatus for gravity concentration were evaluated.

Jan 1, 1976

By J. H. Bowden

The shaft-plant here described was put in operation in September, 1895, and the No. 6 slope-motor was started in May, 1896. The plant comprises : One Norwalk three-stage compressor l21/2, 91/2 and 5 in. diameters of air- and 20 in. diameter of steam-cylinder, all 24 in. stroke; capacity at 100 revolutions, 296 cu. ft. of free air per minute, compressed to 600 Ibs. per sq. in. A main pipe, 5 in. diameter, 4380 ft. long, with five charging-stations in No. 6 Shaft, and a branch of 3 in. pipe, 3100 ft. long, with three charging stations, in No. 6 Slope. These pipes on each line charge a Porter compressed-air motor, with 7 by 14 in. cylinders, and four 24 in. drivers, weighing about eight tons, with a tank-capacity of 130 cu. ft. of air at 550 lbs. pressure in the main tank, reduced to 160 lbs. in the 8-in. auxiliary tank of 4.2 cu. ft. capacity, supplying the cylinders. The No. 6 shaft run averages 4000 ft. each way on grades of $ to 23/4 per cent., and averaging close to one per cent. in favor of the loaded cars. The No. 6 slope run averages 2100 ft. with nearly the same grades. The mine-cars weigh 2800 Ibs. empty, and about 9800 lbs. loaded, and are hauled in trips of 12 to 20, averaging about 15 cars. The shaft-motor now hauls about 355, and the slope-motor 320 cars per day of 10 hours, replacing in the shaft 17 mules, and

Jan 1, 1901

By William D. Riley

The U. S. Bureau of Mines has developed technology to recover by-product materials from aluminum scrap using engineered scavenger compounds (ESC). ESCs are structural oxides with a channel or tunnel structure that allows them to hold ions of a specitksizes and charges. The scavenging reaction is easily reversible allowing the ESC to be recharged for continued use and the ion is recovered as an electro deposit. Key features of this novel technology are; a) ESC ,systems are designed to have a high degree of selectivity for a desired ionic species. b) The recovered mater.ial requires little or no additional reprocessing prior to reuse. Two current uses for the ESC technology that are described in this paper are the removal and recycle oflithium (Li) from lithium aluminum (Li-AL) alloys; and, using ESCs as a replacement for the conventional demaging (magnesium removal) technology used by the secondary casting industry. Research indicates that the ESC technology proposed for both these applications has either 'distinct economic and/or environmental advantages over previously employed methods of recovering. metal values from aluminum scrap.

Jan 1, 1995

By A. Arrott, G. S. Ansell

A model is proposed to account for the observed strengthening behazlior of ferrous martensites. me model is based upon the inheritance of carbon-rich regions by the martensite which were present in the FERROUS martensite is formed by a nucleation and shear mechanism when austenite is cooled, at a rate which is fast enough to suppress the formation of pearlite, below a critical temperature (Ms ). Although the mechanism of the transformation process appears to be well understood,1,2 the mechanism re- austenite prior to transformation. These carbon-rich regions strengthen the martensite in a manner analogous to the strengthening effect due to a finely dispersed second phase. sponsible for the observed high strengths exhibited by ferrous martensites is uncertain. In this paper, a model is proposed to account for the strengthening of ferrous martensite. MODEL The maximum solubility of carbon in austenite is 1.98 wt pct as compared with a maximum solubility of 0.025 wt pct in ferrite. Prior to transformation, the carbon in the austenite is nonuniformly dis-

Jan 1, 1963

By F. Gray

Diamond tool fabricators expect strong growth in most applications for 1995 and 1996. Overall growth projects range from 8% to 10%. Diamond grinding is forecast to grow between 5% and 8%, while cubic boron nitride grinding should grow between 10% and 12%. A strong automotive industry is a major factor in this projected growth, as is continuing demand for other durables

Jan 1, 1995

Jan 1, 1888

By Hernando Labarthe

"El siguiente texto describe la importancia de la actividad del Banco Minero en el Perú, a través de la instalación y operación de sus plantas de beneficios, como las ventajas, las instalaciones, organización y proyecciones futuras de dicha actividad. Dichas Plantas de beneficio inician sus actividades en la concentradora N°1 La Virreyna, extendiéndose posteriormente a 5 operadoras más como: Sacracancha, Huachocolpa, Dorado, Tonsuyoc, Huarochirí. De otro lado, el significado de la instalación y operación de estas manufacturas de beneficio supone un doble aporte a la minería, en el sentido que ayuda al minero en la inversión de sus utilidades -en tanto elimina el control de otras actividades en la operación-, como fomenta la producción a través del inicio de nuevas operaciones, incrementando las entradas fiscales. Por último, la sección Plantas de Beneficio del Banco Minero del Perú se encarga de la operación y control de las concentradoras, de los estudios, diseños y proyectos de nuevas plantas, del control de préstamos y habilitaciones a los minerosabastecedores. "

Jul 20, 1956