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By Lawson F

Chrome chemicals are commercially produced by the alkali roasting of chromite ores with sodium carbonate. Results of tests conducted in a laboratory furnace indicated that the sodium carbonate reacted rapidly with part of the gangue material to form a metastable intermediate that later reacted further with the chromite. For the conditions used, the recovery of water-soluble sodium chromate was able to be described empirically as yield % = a tn with a = 0.24 T - 241.3; n = 3.90 - 3.12 × 10-3 T and t is the reaction time in hours.The major rate limiting step in the overall reaction sequence appears to be the rate at which oxygen can get to the reaction sites across the liquid film coating the solid reactants.Sodium sulfate alone was found to be an unsatisfactory source of alkali for reaction with chromite. However when limestone also was added in quantities sufficient to allow the reaction CaCO3 + Na2SO4 + H20 ? Ca SO4 + 2NaOH + CO2 to take place, the results obtained were comparable to those found when sodium car-bonate was used.For chromite particles in the size range -124 + 105 µm, the use of stoichiometric excess of sodium carbonate did not appear to increase the yield or the reaction rate significantly. However, with smaller sized particles, - 53 µm, increased yields of water-soluble chromate were obtained when roasted with more than the theoretical quantity of sodium carbonate.

Jan 1, 1984

Radioisotope X-ray and neutron techniques of analysis can be used for the determination of a wide range of elements in minerals. The most important applications of these techniques to the mineral industry are for on-stream analysis of slurries and solids, and for geological assay. The radioisotope X-ray techniques are the more developed ones and two installations for on-stream analysis are in routine use in mineral processing plants in Australia. Neutron techniques are being developed, and should prove valuable for geological assay of large numbers of mineral samples, for borehole logging, and for specific on-stream analysis when the cost of the equipment is warranted.

Jan 1, 1969

By F. J. Tavera

A study on the electro kinetics of lead carbonate, silica, and alumina, in aqueous media was carried out at different pH values. The behavior of potential was determined for these species in the pH range between 3 and 12. Homocoagulation of lead carbonate in aqueous media is analyzed at its isoelectrical point. Lead carbonate heterocoagulation is analyzed with silica, alumina, and silica ? alumina mixtures at low pH values. The experimental results are considered for their possible application to treat residual water polluted with lead.

Jan 1, 2006

By M. T. Ityokumbul

Flotation is a surfaced-based separation process that exploits the differences in the hydrophobicities of the components. In the present paper, a review of both established and emerging nonmineral applications of flotation (oil removal, paper de-inking and separation of plastics) is presented and discussed. For each application, the theory of the process is compared and contrasted with mineral flotation. It is shown that the mass-transfer approach to flotation offers a good starting point for the analysis of these separation processes.

Jan 1, 1999

When the new No. 3 Shaft is in full operation, the main hoisting duties will be in connection with the raising of: (a) ore from the various mining operations, and (b) mullock, or broken country rock, from development work in extending access to existing levels, opening up new levels, exploratory work, or sinking the shaft to greater depths.

Jan 1, 1957

By Renaud Adams, Vladimir Salatic

"The El Mochito Mine located in Honduras, Central America, has produced lead, zinc and silver in concentrates since the 1950s. The paper discusses changes made in both lead and zinc circuits to reduce costs while maintaining production during the recent period of low metal prices.The intent of this paper is to show that sometimes thinking “outside the box” is beneficial for progress. Also, in striving for better metallurgical results we should not forget the basics of flotation. Sometimes the latest trends may not be applicable to the ore we are treating and may not meet the operating cost constraints.A major beneficial impact on El Mochito metallurgy was achieved when the overall grind was coarsened, eliminating the significant percentage of slimes. Switching from two parallel twostage grinding circuits to one circuit with three-stage series grinding has resulted in a significant reduction in power and steel consumption. With minor layout/reagent modifications, both lead and zinc circuits gained not only in retention time but as well in producing better grade products.Of course, the challenges are still there; they exist and only with the full support of operational data collection and metallurgical laboratory investigation success can come. That is why, we as professionals, can never stop in trying to make the most of what we have.INTRODUCTIONThe El Mochito Mine is owned by American Pacific Honduras S.A. de C.V. (AMPAC) a subsidiary of Breakwater Resources Ltd. Of Toronto, Canada. The mine is located in western Honduras, approximately 220 kilometers northwest of the capital city, Tegucigalpa and 90 kilometers south of the country’s second largest city, San Pedro Sula. The mine began operating in 1948 and to date has produced more than 19 million tonnes grading 240 g/t Ag, 3.5% Pb and 7.4% Zn. Production in 2005 was 700,190 tonnes grading 87 g/t Ag, 1.85% Pb and 6.61% Zn.Decreasing metal content in the ore followed by the lowest zinc price on the market in the last 15 years (see Figure 1) has reduced the cash flow and endangered to stop the operation."

Jan 1, 2007

By Luis Martín Tejada Cervantes

Generalmente, después de la etapa de cierre del depósito de relaves, se utilizan sistemas de protección ambiental tales como las coberturas -en tanto evitan el derrame de los residuos en suelos y fuentes de agua y las inestabilizaciones físicas y químicas. En ese sentido, el presente texto describe una evaluación geotécnica de flujo, equilibrio y deformación para la etapa de cierre de minas, considerando aspectos técnicos, de seguridad y medioambientales con fines de mitigación del impacto ambiental.

Jan 1, 2014

The problem of providing adequate thrust to manually operated rockdrills operating at air pressures of 70 lb/in2g to 80 lb/in2g with the aid of an air-leg is analyzed. It is shown that adequate thrust is provided by an air-leg or the stiff-leg if it is inclined at an angle to the floor of about 25°. However, this requires that the leg react against some support or protuberance, as the friction force between the leg and the floor is inadequate to contain the thrust. Conclusions summarizing optimum thrusts, blow frequencies, penetration rates, drill steel life and bit wear are presented.

By R. D. Brown

In the spring of 1977, Revenue Canada announced its intention to proceed in 1978 with a plan to impute a taxable benefit on interest-free and low-interest loans provided to employees. Such loan arrangements are often an important aspect of the compensation packages provided by many companies to their employees. Since the original announcement, there have been many submissions to Revenue Canada opposing this change, and the Finance Minister has now brought down a compromise solution with the introduction of a proposed amendment to the Income Tax Act. The amendment, which would not take effect until the 1979 taxation year, would require an employee, a shareholder or a related person to include a benefit in income measured as the difference between the interest on any such loan computed at bank prime rate and any interest actually paid. Only the amount of such a benefit in excess of $500 in a particular year would be required to be included in income. Of particular interest is the exclusion from these benefit rules of loans up to $50,000 in respect of the purchase of a house on the relocation of an employee and loans provided for the purchase of shares of an employer corporation.

Jan 1, 1978

By William E. Ford, Edward Salisbury Dana

Secondary Twinning. - When there is reason to believe that the twinning has been produced subsequently to the original formation of the crystal, or crystalline mass, as, for example, by pressure, it is said to be secondary. Thus the calcite grains of a crystalline limestone often show such secondary twinning lamella?. The same are occasionally observed (Ilc, 001) in pyroxene crystals. Further, the polysynthetic twinning of the triclinic feldspars is often secondary in origin. This subject is further discussed on a later page, where it is also explained that in certain cases twinning may be produced artificially in a crystal individual - e.g., in calcite (see Art. 282).

Jan 1, 1922

By Junto Nishiwaki, Shinji Kumai

"Mechanical and physical properties of the impact welded dissimilar metal joints are controlled by joint interface morphology. An intermediate layer (IML) is often formed at the joint interface and this deteriorates the interface quality in some metal combinations. Numerical and experimental studies were performed in order to examine the formation mechanism of the wavy interface and intermediate layer for explosive welded Al/Cu dissimilar metal joints. The impact welding process consists of (1) high-speed oblique collision of metal plates, (2) metal jet emission and large deformation and temperature increase at collision point and (3) rapid cooling at the joint interface. Euler-Lagrange coupling method, smooth particle hydrodynamic (SPH) method and modified laplacianFoam (LF) method were linked together to simulate a series of processes from (1) to (3), and the final interface morphology including the formation of IML was reproduced. The wavy morphology (wave-height, wavelength) and the position and composition of IML formed at the joint interface of Al/Cu joints were quantitatively in good agreement with those reproduced by numerical analysis. Our simulation results are useful for the control of the interface morphology, reduction of the amount of IML, and improvement of the mechanical properties of the impact welded dissimilar metal joints.INTRODUCTIONImpact welding is a kind of solid state joining method providing extremely high joint strength for both similar-and dissimilar metal combinations. Explosive welding and magnetic pulse welding are representative methods to achieve the impact welding. By a high-speed oblique collision between two metal plates, a metal jet is emitted from the collision point. The metal jet can remove any oxide films and contaminations on the plates and produce an active refreshed surface. Consequently, good metallurgical bonding can be achieved even for dissimilar metals (Crossland, 1982). Solid metals deform like fluids under the high pressure condition at the collision point and characteristic wavy interface is formed. In addition to the wavy interface, an intermediate layer (IML) is often formed at the joint interface in some metal combinations. Elimination or reduction of the amount of IML at the joint interface is desired since the excessive IML formation along the joint interface causes a large reduction in physical and mechanical properties. Formation of IML is considered to result from characteristic thermal history at the joint interface including partial melting due to the local temperature increase and successive rapid cooling behavior at the joint interface. In order to control the IML formation at the joint interface, it is necessary to reveal both heating and cooling processes at the joint interface. However, it is impossible to observe the phenomenon occurring at the joint interface and also difficult to investigate the temperature change at the joint interface directly during the impact welding. Therefore, simulation or numerical analysis is indispensable to overcome this problem. In the present study, the explosive welded Al/Cu joint, which is prone to form IML at the joint interface, was selected for the research. By using a newly developed numerical analysis method, not only the formation process of wavy interface, but also the local temperature increase and successive temperature decrease at the joint interface were reproduced. The formation process of IML was investigated by using both numerical analytic and experimental results."

Jan 1, 2018

By M. D. Scott

Lornex Mining Corporation operates an open pit porphyry copper mine in the Highland Valley southwest of Kamloops with a rated capacity of 43 500 TPD (48,000 TPD). It went into production in April 1972. Its concentrator consists of two grinding and flotation circuits in parallel each composed of a 6 000 KW (8,000 HP) 9,75 m (32 foot) diameter by 4,724 m (15'-6") semi-autogenous primary mill feeding two 3 000 KW (4,000 HP) 5,029 m (16.5 foot) diameter by 7,01 m (23 foot) secondary ball mills each feeding a bank of flotation cells. ,The original tailings system picked up the tailings from the flota¬tion circuits in a concrete collection box in the mill and carried the 36% solids density by weight slurry 488 m (1,600LF) through a 1100 mm (42 inch) diameter wood stave pipeline on a .46 percent slope to three 99,06 m (325 foot) diameter center drive thickeners. From the collection box under the thickeners the tailings line con¬sisted of three sections, carrying 50% solids density slurry. The first section consisted of 1460 m (4,800 LF) of 910 mm (36 inch) asbestos cement pipe for gravity flow from the thickener under flow elevation of 1252,4 m (4,109 feet) to the first pump station at elevation 1207,6 m (3,962 feet). Eight concrete drop boxes were used to limit the maximum slope on the pipeline to 0.5 percent.

Jan 1, 1976

By Helmut Thielsch

During the last three decades a great many arguments have been presented on the subject of "mosaicJ' or "blockJJ structures of metals. Apparently because of insufficient evidence, the "block-structure" theories have never been widely understood among the physical metallurgists in this country, and most investigators among the few that have tried to demonstrate the existence of such an inner strutture Of crystals or grains have failed to recognize also the existence of a lamellar structure. Moreover, little thought has been given to justify the existence of such "lamellar" or "mosaic-block" structures on a theoretical basis. Since properties such as Plasticity; ferro-magnetism, hardness, diffusion, and others may be explained by structural faults in the lattice network of the crystals: the great importance of a more detailed knowledge of the structure within crystals or grains becomes now evident. Because Of the vast extent of the field Of submicroscopic structures, it shall be the purpose Of this paper only to review the more important of the results obtained by other investigators, especially in Germany, where a great deal of attention has been given to mosaic structure during the last three years. The origin of this mosaic patternt and effects of cold reduction and recrystallization will be shown in further studies later on. Imperfections in Crystals The many terms used in the literature to denote structural types of crystals are often not clearly defined. To clear up some of the confusion, the meaning of the more important terms will be given here. ideal, or perfect without any structural imperfections are called "ideal crystals,,or ''Perfect'' crystals,n meaning a Homogeneous interior structure of atoms, ions or molecules, as the case may be. In other words, at every point in the interior of the crystal exactly the same orientation of the crystallographic axes of the coordinate system would exist. The Surface of such a body, if etched with an appropriate etching reagent, would reflect light with perfect uniformity. Crystals of this type are almost nonexistent. Real Crystals.—L'Real crystals"' may contain various types of structural defects, which can be classified into: (I) lineage structure, (2) mosaic-block structure, (3) lamellar structure. The inhomogeneities many,in these groups mean that the orientation of the crystallographic aies will not be the same at every point within the interior of a crystal (or grain of a poly crystalline body). 'Perjecl Real Crystals.—The term "perfect real crystals " is generally used to describe crystals with minute structural or thermo-dynamical inhomogeneities. The former

Jan 1, 1946

By M. Melih Demirkan, Juan J. Gutierrez, Raghav Ramanathan

"As the capital of the United Arab Emirates (UAE), Abu Dhabi is one of the world’s fastest-developing cities. To sustain its significant growth rate, Abu Dhabi must surmount challenging engineering problems in the most efficient manner. One of the challenges facing Abu Dhabi is ground settlement caused by poor groundwater control practices in inherently difficult subsurface conditions. For construction projects in Abu Dhabi located near the Arabian Gulf, groundwater is frequently encountered and must be accounted for and addressed during design and construction. Abu Dhabi City CenterRecently, the Abu Dhabi government developed a geodatabase by digitizing, processing and qualifying an extensive amount of existing information (i.e., more than 26,000 borehole logs). Because of the evaluation and processing of the geodatabase, detailed maps of geotechnical and hydrogeological surface features were generated using 3D modeling. Ultimately, the geodatabase was used to develop risk maps indicating geohazards, such as sabhka (or salt flats), uncontrolled fill and cavities. This information identifies the location and extent of the areas vulnerable to surface subsidence. Dewatering can change pore water pressure, which, in turn, alters the effective vertical stress in a soil mass and can affect groundwater chemistry. Changes in pore water pressure and groundwater chemistry can significantly affect soil and rock. The potential effects of dewatering include:• Change in effective stresses and shear strengths in soils• Increase in seepage velocities and pressures• Erosion or transport of soil particles and piping• Settlement• Collapse of subsurface cavities or voids• Transport of groundwater containing contaminants• Dissolution of soluble materials, such as rock salt or gypsum"

Jan 1, 2017

By Oswaldo Carhuancho

El presente trabajo señala la filosofía de trabajo en equipo desarrollada en la mina Pierina, Lima. La política de trabajo se sustenta en el pensamiento de Barrick, donde las prácticas administrativas basadas en la seguridad, salud ocupacional y el medio ambiente repercuten en el beneficio de sus empleados, accionistas y las comunidades en las que opera. Por ello, la primera preocupación de la empresa debe ser el trabajador y no las máquinas, así como la labor de los jefes no se limita a una actitud paternalista, sino a una democrática, de forma que el empleado asume sus responsablidades con seguridad y eficiencia. Como consecuencia de ello, se redujeron la cantidad de hombres-accidentess, se elevó el costo de producción y se redujo, la cantidad de personas en la supervisión de operaciones mina.

Sep 13, 2001

By C. W. Goodale

As an appendix to the above-mentioned paper, a drawing of the vertical projection of the Knoxville mine workings is here given. In my paper it was stated that the ore-chimneys are found along a crack or plane of cleavage in the limestone ; and as this crack is not parallel with the strata, it is safe to assume that the manganese was not deposited where it is now found before the tilting-up of the strata, but rather that the crack was caused by the folding, and that tile formation of the ore was entirely subsequent to the change of position of the limestone. There are here four chimneys, which have produced, as far as explored, over 12,000 tons of ore, containing at least 7000 tons of manganese oxides, and it is very difficult to apply Prof. W. P. Blake's theory of segregation from the surrounding limestone in accounting for the origin of this ore, as cross-cuts and drifts in the countryrock, even at short distances from the ore-chimneys, have not shown manganese in appreciable quantities. It is easier to believe that, in the language of .Mr. S. F. Emmons, in speaking of Leadville ore-deposits, there was a metasomatic interchange between the minerals brought in in solution and the limestone, and not a deposition in already existing cavities. This in-

Jan 1, 1890

By L. D. Ricketts

' In recent years the metallurgical field of the copper industry has expanded greatly, the copper ores have become lean add diverse in charactcr, and we are obliged to treat such ores on a very large scale. On the commercial side, the operating and consulting staffs of the great mining companies have been enlarged and organized, and no great capital expenditure is decided upon until it has been investigated and recommended by a highly organized force of specialists as a committee. I believe that in the scientific field and in the most valuable proceedings of our -various societies the old idea of one-man point of view and one-man treatment of principle and detail together has been splendidly developed and should continue, but for the advancement of our art we should deliberately discuss subjects among ourselves in order to do away with the idiosyncrasies of the individual and to gain a composite view reprcscnting the best thoughts of many men. In the development of new ideas leading to the introduction of new methods, the societies could enlarge their present great field of usefulness if such discussion be had, and in my opinion further great good could be done if a number of men of different qualifications and experience would join in preparing a joint book, each dealing with his particular problem, but consulting the other men. In this way individualism would be preserved and various processes would be described, and if properly reviewed the paper would be palpably capable of analysis, and the student would have at his command the associated efforts of a group of qualified engineers. I have neither the time nor the qualifications to make an investigation and study in detail of hydro-metallurgical processes, but for some years I have foreseen the development of such processes, and I have a deep interest in the subject and have given some of its phases careful consideration from a long-distance viewpoint. I have assisted in directing many experiments and in reviewing the merits of many processes, and am glad to make some introductory remarks with the understanding that other gentlemen present will freely and candidly enter into the discussion and help to fill out the few bare bones that I can uncover.

Jan 1, 1916

By Viraj Parekh, Kinnor Chattopadhyay, Sina Mostaghel, Xiao Zhang

Electric arc furnace steelmaking is a dominant approach in North America and controlling EAF emissions is a key issue today because of stringent permit limits imposed by various regulatory bodies. In the present study, an attempt has been made to mathematically model EAF emissions, and use the models as a predictive tool for fine tuning the process. CFD modelling has been used to model various fume release scenarios, and optimize the exhaust conditions for maximum capture. Thermodynamic calculations have been used to analyze various chemical reactions which lead to the emissions of hazardous air pollutants with special emphasis on Zinc, Lead and Manganese.

Jan 1, 2015

By B. Mishra

Calcium and lithium gallides have been synthesized by powder metallurgy techniques in the stoichiometries that can be used as reduction alloys for the Rocky Flats Plant Salt-Scrub (SS) process. The SS process is performed to recover valuable metals from salts generated in the electrorefining and the molten salt extraction processes. Combustion synthesis has been optimized for variable heating rates up to the reaction ignition temperature and for green densities of the powder compacts in terms of the ignition temperature and the exothermic heating of the product in an effort to develop LiGa and CaGaz alloys. The problems arising from the melting point and density differences of calcium, lithium and gallium have also been studied. The SS alloy compositions were produced by mixing, pressing and sintering the metal-powders. The efficiency of the intermetallic alloy, Ca-17 wt. pct. Ga, as a reductant and the effect of gallium on salt clean- up has been discussed. Measurement of actinide recovery has been studied with cerium as the surrogate for the actinide metal. The development of an alloy for SS reduces a major contaminated waste disposal problem besides recovering the valuable reactive metal.

Jan 1, 1993

By A. D. Davis, C. J. Webb

Brohm Mining Company's Gilt Edge Mine in the northern Black Hills was a surface heap-leach operation that was active from the 1980s until 1999. Financing problems and acid drainage concerns at the mine were reported in the late 1990s. In February of 1999 the Governor of South Dakota announced plans to request the U.S. Environmental Protection Agency to help clean up acidic water at the mine and reclaim the site. In July 1999 the parent company of Brohm, Dakota Mining, filed for bankruptcy in Canada. Because of the bankruptcy and environmental problems, the State of South Dakota intervened and began water treatment. The mine was declared a Superfund site in 2000. Hydrologic issues include the potential for acidic drainage from the site. The mine is at the headwaters of Strawberry Creek, which drains into Bear Butte Creek. About four miles downstream, Bear Butte Creek loses its discharge to swallow holes in the karstic Madison Limestone aquifer, a regionally extensive and valuable ground-water reservoir. Other concerns at the site include treatment of acidic water in mine pits and a waste rock dump.

Jan 1, 2002