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By John W. Wagner, Robert K. Willardson

Single crystals of Pbl-xSnXTe have been grown from The melt under liquid B2O3 using the Czochralski technique. The PbTe-SnTe crystals were grown from near-stoichiometric melts and from melts with slight deviations from sloichiometry. Crystal growth rates ranging from 1 mm per hr to 1 cm per hr were employed, the latter being generally used. Several investigations were performed to characterize the single crystals grown In this study. The phase diagram of the PbTe-SnTe system was examined. X-ray analyses verified the single-crystal character of the crystals, and powder pattern lattice parameter determinations showed that Vegard's law was followed within the limits of the experimental error. The as-grown crystals were p-type with apparent carrier concentrations of -8 x 1018 to -8 x 1020 carriers per cu cm. Hall coefficients, resistivities, and carrier mobilities were determined as a function of composition. Dislocations were revealed by an electrolytic etch, and the crystals were found typically to contain 2 to 4 x 105 dislocations per sq cm. Microhardness measurements were performed; no maximum in the Vickers hardness us composition curve was seen. Mass spectrometry was used for impurity analyses, and the crystals were found to contain 1 to 2 x 1017 total p-type impurities per cubic centimeter. Distribution coefficients were calculated for the major impurities which were Na, Mg, Al, Si, Cl, and Zn. RECENTLY interest has been stimulated in the preparation and characterization of many alloys of the binary compound semiconductors. This interest is due primarily to the almost unlimited possibilities of adjusting the semiconducting characteristics of these materials by varying the alloy compositions. One alloy system which has been receiving extensive investigation is the PbTe-SnTe system, since these alloys show promise of being useful as emitters and detectors of electromagnetic radiation in the spectral range of 8 to 14 µ. This paper reports on the growth of PbTe-SnTe single crystals by the Czochralski technique and investigations of the general properties of these crystals. The phase diagram of the PbTe-SnTe system was investigated so that specific alloy compositions could be attained. I) CRYSTAL GROWTH The PbTe-SnTe single crystals were pulled from the melt using the Czochralski technique. Generally, the crystals were grown from near-stoichiometric melts, although special growth runs were made from both lead-rich and tellurium-rich melts. Growth of single crystals from up to 5 pct lead-rich melts presented no problems; however, melts with tellurium in excess of -1 pct caused volatilization problems which generally made crystal growth impossible. All melts were prepared from high-purity materials as follows: 1) lead— 6 N— Cominco (Cominco Products, Inc., Spokane, Wash.); 2) tin—5N—Cominco; and 3) tellurium— 5N+— American Smelting & Refining Co., Plainfield, N.J. No further purification of materials was undertaken in this study. The elements were reacted at -1000°C in a vacuum-sealed silica tube for a few hours, a gentle rocking action being used to ensure thorough reaction. The cast ingots were then transferred to a silica crucible for crystal growth. A schematic diagram of the growth apparatus is shown in Fig. 1. The Vycor tube is sealed at both ends by O-ring flanges so that a vacuum or a positive pressure may be maintained in the growth chamber. The pull rod and crucible may be rotated; all crystals produced in this study were grown with the crucible sta-

Jan 1, 1969

Prominent among the ore minerals at Mt. Ellison, in the Brock's Creek district, Northern Territory, are a number of copper-bismuth sulphides wittichenite, aikinite, emplectite, in association with nativebismuth, chalcopyrite, bornite, chalcocite, sphalerite and linnaeite.Linnaeite and aikinite formed first and were followed by native bismuth. Wittichenite was later and substantially replaces earlier minerals. Replacement of aikinite by wittichenite has produced secondaryor reaction bismuth.INTRODUCTIONThe Brock's Creek district of the Northern Territory lies to the south east of Darwin and has been the locale of intermittent mining of small but rich deposits of diverse ore type. Gold, tin, and copper ores were recovered especially between 1890 and 1910 with minor exploitation up to the present time. Copper ores were of prior importance, the main production coming from supergene enriched deposits of chalcocite.The mines are situated in strongly folded Precambrian strata comprising slates, sandstones, volcanics and amphibolites with replaced haematitic rocks (Sullivan, 1953). The strata in the Brock's Creek area immediately north of the Darwin-Birdum railway line are domed around a roughly circular granitic mass some 5 miles in diameter. The Mount Ellison mine is located near the N.E. margin of the granite in metamorphosed basic country rock.Study of a series of polished sections from Mt. Ellison revealed the presence of linnaeite, chalcopyrite, bornite, aikinite, wittichenite, emplectite, bismuth, sphalerite, and chalcocite. With the exception of sphalerite and emplectite each of these minerals is prominently developed and intimately intergrown with the other constituents.

Jan 1, 1963

By Steven L. Webb

In 1965, Monsanto started planning of a new dike (No. 15) for use in disposing of ore tailings at its Columbia, Tennessee phosphorus plant. Generally, in the phosphorus industry only clay tailings are produced making it necessary to borrow fill for construction of a retaining dike. Borrow area investigations indicated that weathered shales and limestones adjacent to the dam site would provide adequate construction materials. It was proposed that the more clayey weathered shales would be used for the impervious core and the more granular weathered limestones would be placed in the outer shell of the dike. A dike section is shown in Figure 1 with gradation curves for core and shell materials in Figure 2. Figure 3 shows an aerial view of the tailings pond and dike during first-stage construction. Although the borrow area explorations indicated that the weathering of the sedimen-tary deposits was highly irregular, it was not considered necessary, at the time, to specify special excavation techniques that would ensure a thorough blending of the materials in the borrow pit. Instead, because of the short haul distance, a scraper operation for both clay core and granular shell materials was adopted as the most economical construction method. Using this materials-handling technique, variations in permeability could be expected in the compacted layers inthe embankment. Where continuous layers of less clayey limestones were placed in the core of the dam, extending from the upstream to downstream shells, seepage losses would be expected to increase substantially. Upon completion of the damn 1966, and shortly after reservoir filling, it was apparent that the construction technique used had resulted in the formation of pervious layers through the clay core. Excessive seepage on the downstream face of the dike was noticeable within a very short time. A monitoring program was established, using piezometric observations and flow measurements. These data indicated that seepage should be reduced and the application of an asphaltic emulsion

Jan 1, 1971

PASSING over the derivation of the word as well as the description of the alum that has been written of as a liquid and that was once called natta, I tell you that the alum that is commonly called rock alum today is a congealed earthy substance, clear and transparent, of a hot and dry nature, and of a bitter taste with a certain unctuous saltiness. It has an astringent and corrosive property and is drawn from mineral stones by means of art. All that I have seen is of the same nature but of two colors,

Jan 1, 1942

By E. S. Greiner

THE hot working of chromium was first reported by Hunter and Jones; who used small pellets of the material obtained by the reduction of chromium chloride with sodium. Later, the working of chromium at 600° to 1100°C was reported by Marden and Rich,2 and at 1250°C by Kroll3 The hot rolled material3 had a Brinell hardness of about 150 (62.5 kg, 2.5 mm ball, 1 min) and was brittle at room temperature. Except for that associated with hardness indentations, no plastic flow in chromium at room temperature has been reported to the author's knowledge. Studies described here have shown slip markings in chromium after deformation at room temperature.

Jan 1, 1951

By Seal. Thom

Large heap leach operations around the world contain significant under-leached metal values that present recovery challenges to operators. The first challenge is to find the location of the highest inventory. High resolution resistivity ? has proven sensitive enough to detect such zones in the interior of heap leach pads to target treatment or re-leaching. Newmont Mining Corp. has adapted the high pressure fracturing technology, used in oil wells to stimulate select zones in heap leach pads to add reagents in 3-D for re-leaching, changing zonal chemistry for improved recovery and heap closure. High Resolution Resistivity ? is able to subsequently monitor injected solution flow and determine directional permeability during Hydro-Jex stimulation. The combination of these technologies has shown strong economic success, for selecting targets in the heaps and monitoring solution application. These technologies are now available to the mining industry for adoption.

Jan 1, 2008

Lieut. Louis J. Brunel, now in France, was commissioned on July 27, 1917, as Second Lieutenant in the Engineers Reserve Corps, assigned to the 7th U. S. Engineers, Dec. 10, 1917, and has been with the American E. F. since Mar. 26, 1918. He was assigned to the staff of the General commanding the 5th Field Artillery Brigade, as Engineer Officer, on Aug. 6, 1918. E. Ross Housholder writes that "the record for pontoon bridge building was broken Sept. 25, 1918, by Section A, Co. 4, 5th Engineer Officers' Training School, at Camp Humphreys, Va., of which I am a member. The time was 15 min. 11 3/5 seconds. We then proceeded to break the record for dismantling in 9 min. 57 1/5 seconds. The length of the bridge section was 200 ft. The post band was sent out to meet us, and we feel proud of this record. I have met quite a few A. I. M. E.

Jan 11, 1918

By Madan M. Singh

Mining under bodies of water such as oceans, lakes, rivers, streams, ponds, and other impoundments, is not a new technique. However, in the United States it has been fairly restricted to date. In order to recover the maximum amount of the nation's reserves, in the future, it is important that further mining under such bodies of water be planned. However, it is imperative that this is not done at the expense of danger to the nation's miners or appreciable property damage. If all the bodies of water are considered large, and it is assumed that these constitute a hazard when mining in their vicinity irrespective of their size and geometry, a significant percentage of the coal reserves are likely to be sterilized. How- ever, by adopting special mining plans and procedures, it may be possible to release reserves for exploitation that would otherwise be unmineable since the surface of bodies of water below which they lie are relatively small in size. In 1977, the Bureau of Mines issued Information Circular (IC) 8741, entitled "Results of Research to Develop Guidelines for Mining Near Surface and Underground Bodies of Water". This document was based on the work done by Skelly and Loy (under Contract No. H0252083) and K. Wardell and Partners (under Contract No. H0252021). How ever, these guidelines have limited application, because these did not (1) define the bodies of water of concern, and (2) take into account the nature of the strata being encountered. These guidelines assumed that all bodies of water which would be undermined were large. For the purposes of this discussion, water bodies may be divided into three categories, depending upon their potential to cause damage to the underlying mining activity: ? catastrophic ? major ? limited Bodies of water which pose the threat of catastrophic destruction in the mine, should there be an inrush, include oceans, large lakes, big inland reservoirs, and rivers that could flood the mine complete- ly in a short period. Those with major potential for damage would include lakes and streams which might present a danger to both life and property if not considered in the mining plans. Finite bodies of water which have a volume considerably smaller than the mine volume offer a limited potential for damage in the case of an inrush. These include flowing streams which have a relatively small rate of replenishment and which can be dealt with by pumping or isolation in the event of a breakthrough into the mine. Such bodies of water may be inconvenient and cause a temporary disruption of production, and could even cause some damage to equipment, but only in rare instances would personal injuries occur. The scope of this paper is limited to the exploitation of stratified mineral deposits with overlying -face bodies of water. Vein and dessiminate ore deposits are not discussed, nor are breakthroughs into adjacent mines in the same horizon. Overlying, water-logged strata also pose a serious threat to mining, but are not treated in this discussion. Pending further investigation these strata may be considered as bodies of water with catastrophic potential for damage, with the base of the strata being considered the bottom of the water body. When the body of water is large, so that it may cause catastrophic damage to the mine in the event of an inrush, the guidelines suggested in IC 8741 are applicable. In order to develop criteria and procedures for mining under smaller bodies of water, however, it is necessary that the nature of the strata disturbance due to underground mining be examined.

Jan 1, 1981

By G. Daws, N. Woodward, A. Oxley

Many mines around the world have been seeking ways to achieve sustainable developments and reduce operating costs. Rockbolting is a technology that needs to be considered as it provides a means of reducing operating costs and improving safety whilst allowing improved production to be achieved. The problem is how to introduce this technology in the knowledge that a successful outcome will be achieved. Rockbolting is a complete package and not only includes the consumable materials but also training, production of Codes of Practice, Monitoring Schemes, Refinement of Design and long term management of the systems. This paper explains the methods that have been applied for its successful introduction and discusses several case studies. It does not give fine detail but is intended to allow decision makers to gain a basic understanding of the method used to successfully introduce rockbolting to a mine.

Jan 1, 2011

By M. Shen, T. D. Wheelock

The important characteristics of a gas-promoted oil agglomeration process for cleaning coal particles in an aqueous suspension were determined. Numerous agglomeration tests with scale-model mixing systems of different sizes with controlled amounts of air were conducted. The tests were conducted on high- and mediumvolatile bituminous coals using either i-octane or hexadecane as an oily agglomerant. The performance of the system was characterized by employing the minimum time required to produce spherical agglomerates (tE), the mean agglomerate diameter (dp), coal recovery and product ash content. Among these parameters, tE was found the most useful. It is a key parameter in the scale-up of an agglomeration mixing system. This parameter was found to depend on a number of system and operating variables. By controlling these variables and conducting further agglomeration tests with mixing systems that varied in size, an appropriate size scale-up rule was established.

Jan 1, 2002

By J. A. Rowland

Magnesium alloys containing nickel, nickel and manganese, lithium, lithium and manganese, and lithium and aluminum were investigated. Melting, casting, and mechanical working techniques and the heat treatment of various compositions were studied. Amenability to cold and hot working was shown for many compositions. The magnesium-nickel and magnesium-nickel-manganese alloys failed to develop superior mechanical properties and were very low in resistance to corrosion. The magnesium-lithium series, although entirely plastic, had low strength properties. The addition of small amounts of aluminum to the Mg-Li base did not affect greatly either the ductility or the strength; further additions developed increased strength, but only at room temperature, and the alloys became brittle with age. Continued study, concentrating on the ductile lithium-rich beta phase as a base composition for ternary and quaternary systems, is recommended.

Jan 1, 1956

By A J. Minns

This paper addresses the question: how can the minerals industry remain viable; viable in the sense that we are able to access land for exploration and discovery, we are able to develop and operate mines (and processing plants) safely and profitably and we are able to close operations in a responsible manner, so that modified landscapes are restored to acceptable community standards?Many of the answers to this question can be addressed through the theme of this conference û that of eco-efficiency. The eco-efficiency concept is very useful, since it does help to translate principles of sustainability into business value at the operational level. To provide some context to how this can be achieved, the paper discusses what is happening at the international level, outlines some key industry initiatives within Australia and then discusses what work is being done within companies.

Jan 1, 2004

By M. Tiedtke, T. Crary, P. MacPhail, M. Ounpuu

"The SGS carbon-in-pulp (CIP) / carbon-in-leach (CIL) model was used to evaluate and optimize the carbon circuit at Alamos Gold’s Young-Davidson Mine. Plants samples (pulp and carbon) were tested in a series of small scale batch experiments to determine rates of gold leaching and adsorption on carbon from a combined flotation concentrate/tailing product. The testwork data, along with existing plant data were then used to model the performance of the existing CIL plant and optimize the circuit to improve performance and overall recovery. The primary purpose of the modelling exercise was to determine the most cost effective way to lower solution losses at the plant. The modelling was also used to learn how the various parameters in the CIL circuit affect solution losses and the gold inventory tied up on the carbon. This resulted in recommendations for minor changes in the CIL flowsheet, which were successfully implemented in the plant. The approach, results and plant changes are presented.INTRODUCTION This paper presents the details from testwork conducted on samples from Alamos Gold’s Young- Davidson gold mine which is located near the town of Matachewan, approximately 60 km west of Kirkland Lake in Northern Ontario, within the southwestern part of the Abitibi Greenstone Belt. The objective of the test program (completed by SGS Canada in 2013) was to investigate and model the combined flotation concentrate / tailing carbon-in-leach (CIL) circuit and suggest ways to improve gold recovery. The metallurgical test program included mineralogy, rheology, and carbon modelling testwork. Plant information was provided during the test program and used in the optimization process. Upon completion of the testwork, plant changes were recommended and implemented at site (October 2014). Plant results from 2014 to 2017 confirmed the modelling results."

Jan 1, 2018

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By J. C. Stankus, J. J. McCaffrey, S. Guo, S. S. Peng

An innovative concept in longwall tailgate support is discussed. This new concept utilizes a high-capacity roof-truss system to replace conventional wooden cribs. The first field test was conducted at the Bailey Mine and was very successful. Similar tests were installed in other mines and seams. An extensive instrumentation plan was designed and implemented in the truss test area. The test data demonstrated that the dynamic roof-truss system effectively controls the various abutment pressures caused by longwall mining. Thus, a stable tailgate entry is maintained

Jan 1, 1997

By Frank M. Stephens, Robert D. Macdonald

As processes for handling low-grade or complex ores become more complicated and as new methods are found, the need arises for more complete and detailed pilot-plant studies to protect the capital investment required for a full-scale plant. Occasionally a process is firm technically, but there is a need for a demonstration plant that will convince nontechnical men of the wisdom of investing in a full-scale operation.

Jan 5, 1959

By Frank Doxey

Louis A. Turnbull (U.S. Bureau of Mines, Washington, D. C.)—This paper is a well-organized concise discussion of progress in mechanization at coal mines in Nova Scotia during the last 50 years. It shows the perseverance and resourcefulness of those responsible for the production of high-quality coal essential to steel production in the area. The development of the Dosco miner and its use in longwall mining at the Sydney

Jan 1, 1955

By Morris A. Steinberg

Because of the broad scope of my topic I will discuss my subject from the point of view of a present status of the metallic materials that are used in structures and will dwell primarily on those structures related to high- performance aerospace systems. Thus, I can best portray the status of these structural materials as related to existing transportation systems, delineating some of the highlights of alloy development, fabrication, and properties obtained. I shall point out what are, in my opinion, the needed solutions to pressing unsolved metallurgical problems connected with certain selected metals: aluminum alloys, beryllium, titanium, steels, superalloys, refractory metals and some metal-matrix composites. Aluminum Alloys For a number of years a series of strong aluminum alloys used for airframes has had an important bearing on the development of minimum- weight, highly efficient structures. Among these alloys are such familiar ones as 2024-T3, 2014-T6, 7075-T6, 7079-T6 and 7178-T6. A review of the development and use of strong aluminum alloys in aircraft structures indicates that before about 25 years ago there was very little application of products other than forgings in the high-strength tempers produced by precipitation heat treating to T6- or T8-type tempers. 1 As stated by Dix in 1944, "There has been a gradual evolution in engineering viewpoint regarding the mechanical characteristics which are required in a structural material suitable for aircraft. Formerly, emphasis was placed on a generous spread between yield and tensile strengths, on elongation, on impact strength and on resistance to corrosion. Aircraft structural engineers still differ widely as to the importance which they attach to these proper tie.” 2 It is fair to say that this evolution is still taking place, that the problem is much the same in 1970 as in 1944 - except that strength levels have advanced some - and the question remains as to how far we can go in that direction. In the meantime, a new group of alloys has received acceptance and widespread use. The first alloy of this group, 7075-T6, was formally introduced by Dix's 1944 paper. The drastic changes that have taken place in the size and configuration of components employed in air-

Jan 1, 1971

By Carl Allen

INTRODUCTION IN any discussion of mining one is repeatedly confronted with the difficulty of dealing with so many variable conditions. It is not an exact science and in the choice of a method each varying factor has a certain weight, which, in many cases, experience alone can determine. In mathematical terms, it is a function of many variables. A discussion of mining also loses much of its value unless, costs are considered, because the expectation of profit is the only excuse for carrying on mining at all. As conditions vary they cause fluctuations in cost and there are few operations to which a definite cost can be assigned. The character of the ore may make it difficult to drill, yet because of the ease with which it breaks the total cost of drilling and blasting may be low. In preparing this article the attempt has been, not to cover the whole field of mining, but to describe the different methods of stoping and mining which have distinct principles. In addition to this an effort has been made to show the advantage of dissecting the methods into their detailed operations and applying to these a mathematical study as an aid to the judgment in determining which is the best method to adopt, or in attempting to reduce the cost of a method already in use. Methods of mining include stoping, caving, and various methods of working large deposits which, in addition to the method of actually breaking the ore, require elaborate and definite plans of, development of the orebody. The ordinary methods of stoping are too familiar to all for any elaborate discussion, but it has seemed advisable to review the subject and give the principal advantages' and disadvantages of the different methods.

Jan 8, 1914

By R. C. Kellner

Duval Sierrita Corporation, a wholly-owned subsidiary of Duval Corporation, operates an 86,000 STPD copper-molybdenum concentrator near Tucson, Arizona. Shortly after production commenced in February, 1970, it became apparent that the reduction crushing system represented a limitation to reaching the design capacity of 72,000 STPD. The development work performed on the reduction crushers in order to first meet design capacity, and to subsequently increase production to 86,000 STPD is described in this paper. The Sierrita plant is a conventional three stage crushing sys- tem. All crushers were supplied by the Allis-Chalmers Corporation and consist of two 58 x 89 Superior gyratories, four 138b EHD hydrocones, and ten 384 hydrocones. Screening is performed prior to and subsequent to secondary crushing and in closed circuit with the tertiary crushers. Typical throughput rates and equipment sizes are presented in Figure No. 1.

Jan 1, 1975