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By J. Richard Kyle

Salt domes, their cap rocks, and the adjacent sedimentary strata represent a major economic resource in the Gulf of Mexico basin. Gulf Coast salt diapirs formed in response to sediment loading of the "mother" Louann evaporite sequence of middle Jurassic age, an effect that is caused by the buoyant nature of the lower density salt. Halokinesis progresses from nonpenetrative deformation that creates broad "pillow" structures into discrete high-amplitude diapirs. Because of its buoyancy, the top of the salt diapir remains near the land surface or the seafloor during much of its history as the basin floor subsides. The salt within the Gulf Coast diapirs is deformed complexly and commonly shows subvertical banding that represents modified sedimentary layers with different contents of nonhalite components. The most abundant impurity is anhydrite, which occurs as individual millimeter-scale crystals or as deformed clasts that generally form about 5% of most salt stocks. Many mature salt diapirs are mantled by a "cap rock" that consists of a lower anhydrite zone and an upper calcite zone, commonly separated by a discontinuous gypsum-bearing zone. The anhydrite zone forms as accreted layers of anhydrite grains and clasts that are left after episodes of halite dissolution. The calcite zone is a product related to petroleum destruction accompanying bacterial reduction of aqueous sulfate. Calcite-cemented siliciclastic strata occur above or alongside diapirs. The mineral resources of the salt-dome setting are remarkably diverse. Major economic products of the salt-dome environment are salt and cap-rock-hosted native-sulfur deposits, as well as petroleum resources that occur on the dome flanks and in the cap rock. Native sulfur forms as a result of bacterial sulfate reduction accompanying petroleum destruction to form hydrogen sulfide, which is subsequently oxidized to elemental sulfur, major amounts of which have been produced by the Frasch process from Gulf Coast salt-dome cap rocks. Some cap rocks have produced limestone, gypsum, and anhydrite for a variety of construction uses. Although traditional industrial-mineral resource production from Gulf Coast salt domes is shrinking, some cap rocks host potentially commercial concentrations of celestite and barite, as well as the metals Zn, Pb, and Ag. Furthermore, caverns, excavated within the salt stocks, serve as major storage facilities for crude oil (including the Strategic Petroleum Reserve), liquefied petroleum gas, and natural gas. These resources are products of fundamental geologic processes that are integral to the evolution of the Gulf of Mexico basin. Whereas production of some industrial-mineral resources, such as elemental sulfur, has declined in recent years, ample reserves of salt will allow production to continue into the foreseeable future. Further, there is potential for other mineral-resource production from cap rocks under favorable economic circumstances. Expanded use of caverns, excavated in the salt masses for material storage and disposal, is likely to continue into the next century.

Jan 1, 1999

By D. M. Wyslouzil

The fundamentals of dissolving silver and silver minerals are discussed in the following sections: 1) Basic chemical reactions in the silver system 2) Leaching of pure silver minerals 3) Leaching of silver-bearing ores 4) Description of processes The basic chemical reactions of silver are an important guide to the mineral processor or the extractive metallurgist, particularly for systems in which complex formations are balanced against solubilities. The competition of other cations for free ligands can shift the equilibrium to the detriment of silver. Solubilities of pure silver minerals in specific solvents may not be a good indication of the solubility of silver minerals in ores. The abundance of silver minerals which usually appear in a typical ore precludes the selection of a single method that would result in the best extraction of silver from all minerals in the ore. Frequently, the recovery of silver from host minerals requires a destructive pretreatment such as intensive leaching, oxidation with or without elevated temperature and oxygen pressure, or roasting. The transformation of the host or the silver minerals does not always result in a leachable species? and this requires additional treatment before the precious metal can be recovered.

Jan 1, 1990

By C. A. Rowland

Introduction Rod mills are horizontal, cylindrical, rotating, tumbling mills in which steel rods, that are usually about 6 in. shorter than the length of the grinding chamber, are used for grinding media. Fig. 33 shows a cutaway view of a rod mill. Rod mills were first used around 1910 because of their ability to grind in open circuit, consistently produce a uniformly sized prod¬uct, give greater continuous availability, and give lower maintenance costs. They have basically replaced roll crushers and coarse grinding ball mills in comminution flowsheets. The present 20-ft limit on rod length, based on rod manufacturing methods, and the pulp flow char¬acteristics, that influence mill capacity, have established the maximum rod mill sizes' of 15 x 21 Vs ft using 20-ft rods and drawing from 2,200 to 2,300 hp. Rod Mill Uses. The principal uses for rod mills are: preparing feed for ball or pebble mills, grinding gravel or aggregates to the size analysis required for making concrete sand, preparing coarse agitator feed for leaching operations, and for primary grinding circuits, particularly in industrial mineral applications. Wet grinding is the most frequently used grinding process for rod milling. There are a few special cases where dry rod milling is used. Preparing feed for ball or pebble mills is the most common use for rod mills. In ferrous and nonferrous ore concentrators, wet open-circuit grinding is used to prepare ball-mill feed. Figs. 34 thru 37 show the four basic grinding circuits used in these concentrators. In rod mill-ball mill grinding circuits, where the rod-mill discharge contains 25% or more of the grinding circuit product-size material, the rod-mill discharge can be fed to the ball- or pebble-mill classifier as shown in Fig. 34. This is the most frequently used rod mill-ball mill circuit in the nonferrous ore concentrators. In a few concentrators such as Anaconda's Weed concentrator,55 the rod mill discharges to one classification stage which makes the same or a slightly coarser particle-size cut as the classifiers used to close the ball- or pebble¬mill circuits, as shown in Fig. 35. In concentrators where rod mill-ball mill circuits are used to grind low grade magnetic iron ores such as Reserve Mining Co., Silver Bay, Minn.; Erie Mining Co., Hoyt Lakes, Minn.; Eveleth Taconite Co., Forbes, Minn.; US Steel, Mt. Iron, Minn. and Atlantic City, Wyo.; Inland Steel-Jackson County Iron Co., Black River Falls, Wis.; and The Cleveland-Cliffs Iron Co., Adams mine, Kirkland Lake, Ont., the rod mills discharge to rougher magnetic separators (cobbers), the concentrates from which are fed to a ball milling stage as shown in Fig. 36. The same basic circuit is also used with gravity concentra¬tion methods such as spirals (Hanna Mining Co., Groveland, Mich.), tables (St. Joe Minerals, Bonne Terre, Mo.), and jigs. When the rod-mill discharge contains less than 25% of the grind¬ing circuit product size, this indicates an ore that does not readily produce the fines needed to help carry the coarse feed into the ball charge. When this occurs, the fines in the rod-mill discharge are needed in the ball mill or pebble mill so the rod-mill discharge flows direct to the second-stage mills as shown in Fig. 37. Rod mills are used to make feed for open-circuit ball mills such as those used in wet grinding cement raw material (American Cement, Brennan Ave¬nue plant, Detroit, Mich., and Port Huron, Mich., plant, and at the South Dakota State Cement plant, Rapid City, S. Dak.). Grinding gravel or aggregates to the size analysis required for making concrete sand is used in areas where natural sand of the proper particle size gradation required to make concrete is not availa¬ble. Three-quarter inch crushed aggregate is ground to 4 mesh using center peripheral-discharge rod mills (Fig. 38) operating in open circuit. US Corps of Engineers specifications state that the sand product be 93-100% passing 4 mesh and contain no more than 3-7% passing 200 mesh. It may be necessary to classify the rod-mill discharge to remove any excess -200 mesh sand produced in the rod mill. Particu¬larly when processing aggregate with high abrasion indices, center peripheral-discharge rod mills are used instead of hammer mills, fine bowl crushers, and crushing rolls for the production of specification sand. If the -4 mesh size fraction of the rod-mill feed is removed

Jan 1, 1985

By D Hope, D Mitchell, B Metcalfe

In recent years there has been a major change among mining companies in their mining methods. This has been driven by the need to increase shareholder value and optimising the value from an operation. With this understanding there has been a need for all producers to become more efficient in their mining processes. An analysis of the coal losses at Mount Thorley Operations indicated that the major losses were in the dragline section of the mine due to coal damage from throw blasting. This damage was evident after the removal of the overburden by the dragline.Coal and Allied Mount Thorley Mine in partnership with Orica Explosives developed a process to reduce the coal loss associated with the throw blasting of Mt Thorley. Orica provided its specialised knowledge and experience in the drilling and blasting area and combined this with the local mining knowledge and expertise of Mount Thorley Operations personnel to conduct the project. This partnership reduced coal loss in excess of 50 per cent whilst maintaining targeted dragline productivity.

Jan 1, 2001

Upper Peninsula W. O. HOTCHKISS, Chairman C. H. BAXTER, Secretary-Treasurer, Michigan College of Mining and Technology, Houghton, Mich. S. R. ELLIOTT RUDOLPH ERICSON W. H. SCHACHT Utah Meets second Thursday of each month, October to May, inclusive B. L. SACKETT, Chairman C. T. VAN WINKLE, Vice-chairman G. L. OLDRIGHT, Secretary-Treasurer, U. S. Bureau of Mines, Salt Lake City, Utah A. E. RING L. A. WALKER

Jan 1, 1932

By George M. Fowler, Joseph P. Lyden

PaGE Scope of this Report.................................................... 206 Production of Tri-State District.......................................... 207 Historical Sketch....................................................... 207 Location and Topography............................................... 211 Geology............................................................... 212 The Tri-State District.............................................. 214 Stratigraphy........................................................... 217 General Geological Section in Tri-State Region....................... 217 Stratigraphic Section of Mineralized part of Boone Formation........... 218 Stratigraphic Section Bird Dog Well.................................. 219 Metamorphism........................................................ 220 Structure............................................................. 225 Regional.......................................................... 225 Due to Metamorphism.............................................. 229 Ore Deposits.......................................................... 231 Types............................................................ 232 Hard-ground Deposits.......................................... 232 Brecciated................................................. 232 Stratified............................................ 232 Sheet Ground............................................. 232 In Dolomite............................................... 233 In Shale.................................................. 233 Soft-ground Deposits.......................................... 233 In the District as a Whole....................................... 233 Ore Minerah and Analysis......................................... 233 Paragenesis....................................................... 234 Conclusions........................................................... 236 Structure.......................................................... 236 Genesis of the Ore.................................................. 237 Future of the District............................................... 239 Acknowledgments..................................................... 239 Discussion............................................................ 239 Scope of This Report The Tri-State district. as outlined in this paper. refers to the entire mineralized area in sout'hwestern Missouri. southeastern Kansas and

Jan 1, 1932

By E. M. Norris

DURING the winter and spring of 1917, an unprecedented number of underground fires occurred in the Butte district. With one exception, these fires were caused by the failure of electrical equipment, and called attention to the increased fire hazard in underground mining operations occasioned by the extensive use of electricity. Five local conditions that contributed toward a heavy fire risk were (1) The heavy continuous timbering necessary for mine supports; (2) the strong ventilating pressures in the shafts and main airways; (3) the subsidence and faulting movements in the country rock, which ruptured cables and displaced trolley and lighting wires; (4) the strongly acid mine waters, which quickly developed any weak points in the electrical insulation;(5) oxidation in old stopes containing large amounts of timber. In the summer of 1917, a comprehensive plan of fire prevention was begun by the Anaconda Copper Mining Co., which involved a thorough and intensive development of the preventive measures then in use. These were as follows: Fireproofing, remodeling and strengthening electrical insulations, extension of underground water system, control of ventilation, maintaining efficiency of fire-fighting crews, and reorganization of fire patrol.

Jan 2, 1922

The paper reviews recent valuations of mineral properties, many of which are at an early stage of exploration. The various methods used are outlined. The problem of comparing, in terms of whether it is fair and reasonable, a highly subjective opinion of the present value of a portfolio of exploration tenements with a vendor consideration, the real value of which, in most cases, lies at some indeterminate time in the future because of the application by the Australian Stock Exchange (ASX) of escrow conditions, is highlighted. Examples are given of some of the questionable logic used by consultants in handling this difficult issue. A proposal for revision to current flotation and listing practice which, the author believes, would circumvent the problem and at the same time provide better protection for the investing public is offered for Consideration.

Jan 1, 1994

By T Davis

The 500 orebody in the upper levels of Mt Isa Mines in north-west Queensland was mined by sublevel caving and block caving from 1962 to 1969. The hot and reactive rock mass of this orebody provided significant mining challenges including ground temperatures above those resulting from the geothermal gradient. Recently Xstrata Copper has been studying the potential to mine this orebody by modern caving techniques. Part of the study process has included re-accessing the ore zones for diamond drilling and trial development. A cross-cut trial drive, the first primary development into the orebody in more than 30 years, encountered a temperature increase in development holes from low sixties to almost 80¦C in less than 10 m advance. The issues associated with managing this risk include sourcing suitable quantities of reactive ground explosives for a single small heading and the temperature limitations of the explosives and detonators. Risk management outcomes included controls to mitigate the safety and reliability risks relating to misfires. The control that dealt directly with the challenge of continuing development in elevated temperature ground was to cool the holes before and during charging. The most effective and practical cooling medium proved to be water. Rapid rock temperature recharge time meant cooling had to continue as close to firing as possible. Reticulation systems were constructed to allow cooling to take place up until withdrawal for firing. No misfires occurred with the cooling system and additional controls in place. This proved that developing safely and effectively in the elevated ground temperatures of the 500 orebody is practicable.

Jan 1, 2008

The first stage in the refining of lead blast furnace bullion is the removal of copper and is normally done as a batch process in open kettles.A number of attempts have been made to establish continuous processes operating in reverberatory type furnaces, but the growth of accretions in the furnace has always presented a serious problem.The Broken Hill Associated Smelters Pty. Ltd. (RH.A.S.) at Port Pirie have overcome this problem by constructing a reverberatory furnace and ancillary cooling system of a novel design.Although a number of mechanical and metallurgical problems still remain to be solved, it is claimed that a workable continuous copper drossing process has been established.INTRODUCTIONLead bullion emerging from the blast furnaces at Port Pirie is at a temperature of about 1100°C and contains, among other impurities, about 1 per cent of copper.The first stage of refining is the removal of this copper by a drossing operation and in the past this was done, batchwise, by allowing the bullion to cool back in 100 ton kettles.At about 700°C, copper dross begins to separate as a crust on the surface of the kettle and this separation was allowed to continue down to about 450°C when the crust was brokenup and skimmed manually using a long handled, balanced, spoon. The dross was then smelted in a reverberatory furnace to produce a saleable copper matte and separate out lead bullion, which was returned to the drossing kettles. The copper content of the drossed bullion was then further reduced by a sulphur treatment process.The drossing operations involved hard manual labour under arduous conditions and the pouring of hot bullion into...

Jan 1, 1963

By W. O. Crosby

The crystalline belt of the Atlantic Seaboard, south of New York, attains its maximum breadth of 220 miles on the northern border of North Carolina; arid in this State it is most widely characterized by the occurrence of gold in workable deposits. Half a dozen auriferous belts have been recognized by Nitze and Hanna.' These are, in the main, coincident in position and trend with the NE.—SW. zones of metamorphic slates and schists, which, more than any other feature, give character to the geological map of North Carolina. The central gold-belts, accompanying the main zone of slates and as-

Jan 1, 1908

By S. S. Sephton

The La Perla Mine, owned by Altos Hornos de Mexico, S.A., is located approximately 100 miles east of the City of Chihuahua in the State of Chihuahua, Mexico. The mine began operations in 1958. Existing ore beneficiating facilities, consisting of heavy media and jig plants, upgrade the ore prior to shipment by rail to the Altos Hornos steelmaking complex in Monclova. Sizable reserves of two distinct ore types, which were not amenable to treatment in the existing beneficiating plant, or usable in the blast furnaces, have been mined and stockpiled in order to uncover the treatable ores. One of these ore types has been labeled "Diseminado" ore, and is low grade containing approximately 42% Fe with sulphurs ranging from 1 to 2%. The other ore type has been labeled "Pulverulento" ore, and is high grade containing approximately 65% Fe and 0.1% S, but at 80% minus 325 mesh, is too fine grained for efficient sintering. Late in 1968, Arthur G. McKee & Company became involved with the problem of improving the above ores for their efficient and economical use in Altos Hornos' blast furnaces. Early in 1969 representative samples of Diseminado ore were obtained for laboratory bench-scale testing at the University of Minnesota, Mineral Resources Research Center. Concentration tests incorporating magnetic roasting, wet magnetic separation, high intensity separation, high tension magnetic separation, anionic flotation of apatite, cationic flotation of silica and oleic acid flotation of iron were performed. Laboratory testing was concurrently carried on at La Perla Laboratory, which resulted in plans to construct a 10 TPD pilot plant. The pilot plant was operational in September, 1969. Analyzing laboratory results as well as pilot plant results, Altos Hornos and Arthur G. McKee & Company metallurgists agreed that the most promising flowsheet for the low grade Diseminado ores entailed wet magnetic cobbing, desliming, and oleic acid flotation of the non-magnetic fraction. A combined concentrate of

Jan 1, 1972

By Carlos Bermúdez Ortega

El presente texto señala el aspecto geológico de las estructuras más importantes de las minas Orcopampa, perteneciente a la compañía de minas Buenaventura en Castilla, Arequipa. En este sentido, se describe la zona mineralizada, geología estructural, depósitos minerales, texturas, alteración hidrotermal, descripción de las vetas, reservas, yacimientos similares y los prospectos. Asi como se realizan las interpretaciones preliminares del zoneamiento y paragénesis de veta Calera y Santiago Este.

Nov 8, 1982

By Paul Billingsley

The Asientos-Tepezala district is in the north of the State of Aguasca-lientes, about 30 miles north of the city of Aguascalientes, the capital. The district is reached by a standard-gage railway on the west side through the junction, Rincon de Romos, which is on the main line of the National Railways of Mexico from El Paso to Aguscalientes. The terminal is Tepezala. On the east side a narrow gage connects Asientos with the junction, San Gil, on the main line, Asientos to San Luis Potosi. Tepezala on the west side of the Asientos hills is about 2 miles from Asientos on the east side. The area between the two mining centers is separated by a low subdued divide which forms the central part of the hills. The district is in a group of isolated hills surrounded by characteristic bolsón plains. The hills rise above the surrounding plains about 6500 to 10,000 ft.; the highest peak is Alta Mira. The two mining districts lie somewhat upon the flanks of the hills at about the same elevation, 7200 ft. The district is an old one and has been known since early in the 17th Century when the mines were worked by the Franciscan Monks. Their mining operations, which were limited to the oxidized ore above the water level, consisted chiefly in extracting silver from the Santa Francisca vein. To judge from the old workings and the remains of surface plant, the operations were on a large scale. By modern mining operations since about 1900, the various mines of the district have been one of the principal sourees of ore for the smelter located at Aguascalientes. Topography The topographic features of the Asientos hills are largely controlled by the character of the underlying rocks. During the Tertiary period, the entire group of hills was probably covered by extrusive volcanic material in the form of cones and lava flows. The central part of these have since been carried away by erosion, so that remnants have been left along the borders of the hills. These remnants form rather conspicuous peaks,

Jan 1, 1927

By J. F. Myers, F. M. Lewis

The selection of the proper type of flotation machine involves the consideration of a wide variety of factors. Under any condition, all types of machines will promote some kind of separation. Obviously, the correct way of deciding which type of machine is best suited for a particular problem would be to set up all types of machines and test them out in a competitive manner, but the vast number of small concentrating plants are unable to make such complete and exhaustive tests. The experience of the authors of this paper indicates that if all the factors involved in any particular problem can be determined, and if all the flotation-machine characteristics are understood, some basis for selection could be arrived at other than actual comparison. This paper is presented to show how the process factors and machine characteristics have been combined at the mills of the Tennessee Copper Co. from studies of several types of flotation machines. At the two mills of the Tennessee Copper Co. in the Ducktown Basin of Tennessee, four distinct flotation separations are made on the complex sulphide ore. Three different concentrates are produced from the ore—in the order of their importance: iron concentrate, copper concentrate, and zinc concentrate. Four different types of flotation machines are used. The selection of these four machines, for the plant operation, was based upon the study and operating experience of the machine units shown in the following list: Fagergren machine; square cell, size 56 inches Fagergren machine; level type, size 56 inches Denver machine; conical disk impeller, size 24 inches Denver machine; receded disk impeller, size 24 inches Minerals Separation Sub-A, size 24 inches Munro-Pearse deep cell, pneumatic Southwestern air machine, Hunt principle To date the study of flotation machines has been confined almost entirely to the rougher circuits. The various cleaning operations, being relatively a much simpler matter, have not been investigated so thoroughly. Table I shows a typical analysis of the two ores as well as of the mineral content.

Jan 1, 1947

By M. L. Mendes, J. Q. Nojiri, S. C. Botelho, A. P. Campanha

In February 28, 2001 JOULE coordinated the first tests with an electronic detonator in South America at an iron ore operation - ITABIRA MINES from the Brazilian COMPANHIA VALE DO RIO DOCE (CVRD) - the largest producer and exporter of iron ore in the world. ITABIRA MINES (CAU and CONCEI O) belong to one of the complexes, called the Southern System, producing 56 million tons of ROM as well as concentrated products and pellets. This paper is going to describe the tests at ITABIRA MINES with results indicating the improvement in the excavator productivity and reduction of the mining global costs (due to the better performance of the equipment and potential reduction of the maintenance cost).

Jan 1, 2002

By R. N. W. DiLabio

"In a continuing program of mapping glacial dispersal trains, near-surface till samples were collected down-ice from a copper-silver-gold prospect at Onaman River, Ontario, and down-ice from the past-producing gold district at Oldham, Nova Scotia. The program is designed to aid exploration by illustrating glacial dispersal from various types of known occurrences and by identifying postglacial processes that control drift composition at a detailed scale.Native gold was mined at Oldham from arsenopyrite-bearing saddle reef quartz veins in a dome in Early Paleozoic slates of the Meguma Group. Gold abundances greater than 10 ppb in till form a dispersal train at least 1900 m long. Gold abundances between 40 and 100 ppb occur in clusters up to 600 m down-ice from gold-bearing bedrock. Anomalous arsenic abundances in till form a broad train 1100 m long that is significantly different in shape from the gold train.At Onaman River, subeconomic amounts of Cu-Ag-Au occur in quartz lenses in Archean mafic volcanic rocks. A dispersal train defined by the distribution of mineralized boulders and increased abundances of Cu, Ag and Zn in till extends 600 m down-ice from mineralized bedrock. Gold abundances between 10 and 70 ppb do not define this dispersal train, but occur instead in clusters 300 to 600 m down-ice from mineralized bedrock. In vertical sections in the upper 2 m of copper-rich till, Au abundances vary sympathetically with Ag and Cu levels; however, there seems to be no preferential site of Au enrichment in the mineral portion of the soil profile.Several of the mineralized boulders at Onaman River are richer in Au and Ag than the mineralized bedrock from which they were derived. Although some of the high Au and Ag assays were caused by biased sampling of sulphide-rich portions of the boulders, many were caused by leaching of sulphide minerals from 'the boulders, which left a limonitic boxwork that is enriched in Au and Ag. A few of the Au-rich boulders may have been derived from an unknown bedrock source."

Jan 1, 1982

Servicing School Opening of a special factory training course in servicing earthmoving equipment is announced by the Euclid Road Machinery Co. Four [ ] beginning and four advanced one week training courses will be offered to representatives of distributors and customers. Circle No. 1 Core Drill The new Acker "Teredo" core drill, is named after the "boringest little animal in the world" to underline its function as a light, compact, portable core drill capable of depths to 600 ft. While light enough to be truck or jeep-mounted, it offers the combination of a three-speed totally enclosed transmission with either hydraulic or screw feed drill heads. Full 24-in. travel gives maximum footage per shift, 360° rotation permits freedom of hole location, a transmission mounted cathead winch is used in pulling rods and casings, and a power take-off is provided for a pump. Circle No. 2 Plastic Pipe Planned production of both flexible and semi-rigid plastic pipe is announced by Triangle Conduit & Cable Co. Rigid and high-impact pipe will be added to the line later. Three types: non-toxic, industrial, and suction, are being made and in sizes from 1/2 to 6 in. Circle No. 3

Jan 1, 1952

By H. B. Lumsden

This paper is intended to deal merely with the commercial development of some of the principal non-metallic mineral resources in the three prairie provinces- Manitoba, Saskatchewan, and Alberta. Coal is not included in this summary. Building Stone First and foremost, mention may be made of the building stone now being produced at Tyndall, Manitoba. This is a mottled limestone and is declared by experts to be one of the finest building stones in America, both as regards durability and appearance. It has been used very extensively both for exterior and interior work, not only in western Canada, but also in the principal cities as far east as Montreal. The stone is the "'Upper Mottled Limestone", which forms the summit of the Trenton (Ordovician) strata in the Lake Winnipeg basin. Quarries are at present being operated at Garson and Tyndall . The area where this stone is known to be available extends in a north and south direction for a distance of three miles, and the main productive ridge is probably about one half mile wide. The outlook for the future of the industry is extremely promising, as the stone is becoming increasingly popular in Eastern Canada, more particularly for interior work.

Jan 1, 1928

By A. C. Fieldner, W. A. Selvig

For purposes of coal classification it is desirable to know the composition and calorific value of the pure coal substance; that is, of the coal free from its ash-forming minerals. Two methods suggest themselves: (1) To free the coal from most of the ash-forming material previous to the analysis; and (2) to analyze the coal as received and calculate the analysis, with certain more or less arbitrary corrections, to the pure-coal basis. Calculation methods are obviously more apt to give correct results with low-ash than high-ash coals. With coals of unusually high ash it would appear preferable to remove, previous to the analysis, as much of the inorganic matter as possible, by float-and-sink or acid-treating methods. Effect of Ignition on Inorganic Constituents of Coal The need of corrections in calculating analysis to the pure-coal basis is due to the fact that the ash, as determined by ignition, is not the same, in either weight or composition, as the inorganic mineral matter in the coal. On ignition a number of changes occur in the coal such as loss of water of hydration of the shaly material, conversion of pyrite (FeS2) to ferric oxide (Fe203) with evolution of the sulfur as sulfur dioxide or possible fixation of more or less of the sulfur in the ash as calcium sulfate (CaSO4), and decomposition of calcite (CaC03) to calcium oxide (CaO). The amount of sulfur from pyrite which remains in the ash as calcium sulfate depends on the amount of calcite and pyrite in the coal. Certain coals high in both calcite and pyrite show relatively large amounts of sulfate sulfur in the coal ash. The determination of total carbon and hydrogen in coal includes, besides the organic carbon and hydrogen, the carbon of inorganic carbonates such as calcite, and the hydrogen of the water of composition of some of the ash-forming minerals. For detailed discussion of corrections proposed for calculations of coal analyses to the " pure "

Jan 1, 1930