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By Ramana G. Reddy

Thermodynamic modeling and experimental study on impurity capacities and their distribution between mattes or metal and slags in smelting, converting and refining of non-ferrous metals was discussed. A brief review on the recent developments in copper smelting and converting is presented. The analysis showed that, copper smelting capacity increased by a factor of 10 since 60's, smelting rate increased by a factor of more than 5 and process fuel equivalent decreased by a factor of 2. A thermodynamic model for prediction of impurities capacities in slags and their distribution in mattes and slags was developed. The impurities capacities (i.e. sulfur and arsenic) of slags were calculated a priori with no adjustable parameters using the Reddy-Blander model. The capacities predictions were made in a wide range of matte and slag compositions, PSo, and temperatures in conditions pertaining to copper and lead industrial slags. The calculated results for sulfide and arsenate capacities are in good agreement with the available experimental and industrial copper and lead industrial slags data. The sulfide and arsenate capacities in copper slags (fayalite, ferrite and olivine) and lead slags are reviewed. The application of RB model predicted ratios of O2 and S2 partial pressures in industrial copper smelting processes are discussed. Application of this model for the prediction of Sb, Bi and other impurity capacities and their distribution ratios in mattes or metal and slags, in industrial smelting and refining processes is discussed.

Jan 1, 2003

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

This paper describes an interactive personal computer program, ENVIRON, which simulates cooling and ventilating systems on gold mines. An example of the practical application of the program is given and proposed future developments are discussed. The program consists of two main modules, HEATFLOW and VENT- FLOW. HEATFLOW calculates the heat loads and the effect of air coolers, while VENTFLOW estimates the air flow distribution. As the calculation of the heat loads requires a knowledge of the air flow and vice versa, the two modules are run iteratively until the solution converges. The program is written in Pascal and runs on any IBM-compatible personal computer.

Jan 1, 1987

By Susanto A

As part of the current NERDDC funded project studying Dragline/Hopper/ Crusher/Conveyor systems for overburden removal, an investigation was carried out to assess the feasibility of automating the swing-to-dump phase of the dragline digging cycle in order to main- tain consistent performance of spotting the bucket above the hopper prior to dumping. The study involved design of automatic position controls for the hoist, drag and swing drives and simulation of detailed mathe- matical models of the three electromechanical systems and their associated electrical control schemes. The design of the hoist and drag systems to position the bucket in the boom plane is relatively straightforward. Simulation results show fast and accurate performance, with no evidence of interaction between the two drive systems through the ropes. The design of the swing position control system involves special strate- gies to cater for variable inertia and to damp the pendulum oscillations of the bucket. The use of a bucket pendulum model and variable dynamic compensation embedded within the feedback control loop, along with optimal speed/angle slowdown trajectories, has yielded fast and damped positioning responses under simulation.

Jan 1, 1989

By W. C. Smith

This Bureau of Mines report discusses how pull-test data can help establish polyester resin column length criteria for roof bolts in evaporite minerals. The study evaluates the effectiveness of partial to full columns of resin in anchoring 4-ft, No.6, grade 40 rebar roof bolts in potash, salt, trona, gypsum, and borate mine roofs. Pull tests were performed on over 600 roof bolts in 11 evaporite mines. Column lengths ranging from 6 to 48 in (fully grouted) were evaluated for each test site. In general, comparative results among all test sites indicate that pull-out loads in excess of 10 tons (force) were attained with resin-grouted bolts having 13 to 75 pet less than a full column of polyester resin. Ten tons (force) of load-carrying capability compared favorably, in terms of strength, with the calculated yield strength of the rebar used in the tests, which was 8.8 tons (force). The site-specific nature of each test site, due to the unique combinations of geology, mine-induced stresses, and other unknown parameters, prevented the establishment of valid generic column-length criteria. For these reasons, data to evaluate resin-column-length effectiveness are best obtained on a mine-specific basis.

Jan 1, 1987

"Blasting is an inherently destructive process and inflicts damage to the immediateperiphery of an excavation, which is later manifested as ground control and dilutionproblems. Different explosives release their energy and interact with the rock in differentways."

Jan 1, 1993

By J Watson

Electronic detonator technology has been under development for the last two decades. Currently, there are a number of systems commercially available with several others still under development, each with its own unique features. This technology can offer a significant advantage to the drill and blast engineer through their ability to initiate an explosive charge at the æplannedÆ time. This new technology has created huge interest within the drill and blast community and also raised their expectations to produce better blasting outcomes. In many cases, specifications (or even expectations) of desired blast results are not properly defined. Interaction between the input variables (rock mass characteristics and blast design) and results (fragmentation, throw, damage, ground vibrations, etc) and their mechanisms, or relationship to one another, are not very well defined or understood. That is why rock blasting is still considered by many as an art rather than science. With one of the few remaining variables (cap scatter) now controllable, todayÆs blaster finally has the ability to apply science to his trade. Even though electronic detonators are available and becoming more commonly used, current field practices are not always conducive to extracting or deriving the maximum benefit from this new technology. In the authorÆs opinion, the following need to be understood to derive and sustain the maximum value: clear definition or specification(s) of desired outcomes from a given blast; impact of different features in an electronic detonator system (precision, accuracy, flexibility, reliability, etc) and their impact on the desired blasting outcomes; interaction of blast design variables (energy, energy distribution, timing, blast geometry) and their impact on desired outcomes; impact of rock mass variability and quality of blast implementation on the desired blasting outcomes; and critical need to utlilise appropriate tools and systems in order to measure and quantify benefits.In the authorÆs opinion a scientific implementation process is the key to derive the benefits. This paper analyses the industryÆs preparedness to derive the benefits from this technology and proposes a scientific methodology to understand, evaluate and sustain the value from this technology.

Jan 1, 2004

By James M. Barker

IARC classified crystal-line silica as a Group 2A (probable) carcinogen in humans. Adverse classification by IARC, which is a non-regulatory agency, is very significant because many regulatory bodies follow or consider its findings. California included IARC findings in its listing of toxic materials under Proposition 65. OSHA considered IARC findings while promulgating its regulations on hazardous air contaminants. The impact of these scientific and regulatory trends in the mineral industry will be broad. Minerals and materials bearing silica at very low levels will be affected by the "IARC threshold of 0.1% crystalline silica. The regulatory track should follow that of talc and asbestos including the emotional aspects. Silica is much more common than talc or asbestos so, in the final analysis, it may have the farthest reaching impact on industry. Permissible levels set by California and OSHA have usually been lower than industry desires but higher than environmentalists desire. This pragmatic approach will blunt the impact somewhat.

Jan 1, 1989

Previously, a variety of risk rating systems were used on different mines. However, these were mostly site specific and geology based systems. The purpose of developing a uniform rating system, to be used on all Anglo Coal open cast mines, is to provide an unbiased, standard and quantifiable assessment of the risk from highwall and lowwall failures. This takes into account relative differences in the importance of hazards, as experienced on each mine as a result of different combinations of geotechnical factors and mining conditions. The system is based on critical geotechnical and other parameters that have been identified by mining personnel and rock engineers. The primary advantage of this risk rating system is that all open cast mines in Anglo Coal use an almost identical system, which enables the user to compare their risk to the risk at neighbouring mines and/or other open cast mines. The system can be adjusted to meet local, mine specific requirements. The implementation of this new system (a computer program that automatically calculates the risk) has been made as practical and easy to use as possible. Therefore, this tool can be used by personnel from other mining disciplines not directly related to rock engineering.

Jan 1, 2004

By Ibezim J. Anazia

Electrothermal production of elemental phosphorous (P4) generates substantial amounts of highly toxic phossy water and sludges. Because of their high phosphorous content and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations. To date, the sludges are stored in ponds or above ground in special containment vessels at various locations around the country. Two samples of electric furnace phosphorous sludge obtained from the Tennessee Valley Authority (TVA) in Muscle Shoals, Alabama and FMC Corporation in Pocatello, Idaho were investigated using physical separation techniques to recover the elemental phosphorous in the sludge and to render the residual material non-hazardous. The techniques tested include sizing, froth flotation and dispersed air oxidation. Flotation and sizing produced concentrates containing 69 -90% P4 with a recovery in the range of 60 -87%. Dispersed air oxidation of the fines and tailing products was effective in removal of an additional 10 -15% of the P4 in the sludge.

Jan 1, 1991

By Stephen C. Moore

The Grossschloppen vein-uranium deposit, Bavaria, West Germany, was examined utilizing underground workings during 1980-82 by Esso Erz GMbH, an affiliate of Exxon Minerals Company (EMC). Geologic evaluation entailed dense drilling of a portion of the deposit from workings constructed specifically for the program. Discovered in 1977, the deposit was initially explored by surface diamond drillholes which allowed definition of a 30-60 m wide vein system discontinuously mineralized along a 1000 m strike length and to at least a 450 m depth. The underground program was conceived as a cost effective procedure to answer questions on vein correlation, grade continuity and variability. A 1200 m decline allowed access for detailed sampling of approximately 10% of the known area of mineralization. Fanned drillholes, logged by gaga probe, were spaced to provide intersections of veins at 10 to 20 m intervals. Six cross cuts also penetrate the pitchblende and uranophane mineralization which occurs in 0.1 to 2.5 as thick quartz veins. Detailed cross-sections and level plans were constructed for resource estimates of the intensively studied portion of the vein system. The program resulted in the discovery of local, high grade areas and an average grade in the evaluated area nearly double that expected from surface drilling.

Jan 1, 1983

By J. E. Papin

MORENCI ores contain as an average about 0.015 pct molybdenite, MoS2. Incidental to the concentrating operations applied for the recovery of copper minerals, approximately two-thirds of the molybdenite is floated and appears in the final copper concentrate. The economic importance of molybdenum and the success achieved in its recovery in milling operations elsewhere encouraged research directed toward its recovery in marketable form. Several procedures are utilized to effect separation of molybdenite from copper and iron sulphides, but only two have wide application. In the better known of these two methods the molybdenite in the copper concentrate is depressed in a flotation operation using soluble starch as the depressant. The tailing from this treatment thus becomes a low-grade molybdenite concentrate which after thickening, filtering, and low temperature roasting is repulped with water and subjected to additional flotation steps for recovery of the molybdenite. A thio-phos-phate collecting agent is employed in flotation of the copper minerals. Presumably the stability and lasting effects of that collector type necessitated the practice of depressing molybdenite followed by subsequent roasting to insure elimination of copper and iron sulphides from final molybdenite concentrate. The second important method of recovery is applied at various southwestern plants. In those plants xanthates are in use as copper collecting agents. It has been found that xanthates are relatively unstable and their collecting power for sulphides is destroyed by very simple procedures. The method generally applied is to subject the xanthate-acti-vated concentrate, in the form of a pulp, to prolonged heating using steam as the heating medium. A concentrate thus treated may then be subjected to a flotation operation for recovery of the molybdenite, using mineral oil collecting agents, and the copper and iron sulphides will be depressed. Neither of the above processes was applicable to Morenci concentrates. Morenci uses a thio-phos-phate collecting agent in its flotation operation. However, it was established that soluble starch was not a depressant for Morenci molybdenite; therefore the first step in that process was not applicable. AS would be expected the copper and iron sulphides in Morenci concentrates could not be depressed by the heating methods used on xanthate activated concentrates. Low-temperature roasting did eliminate the effects of the thio-phosphate but had to be rejected as uneconomic in as much as the tonnage of concentrates involved was too great. Preliminary research having established the above facts, it became obvious that new methods would have to be developed for the recovery of molybdenite from Morenci concentrates. A broad laboratory investigation was initiated along two general lines, both directed toward depression of copper and iron sulphides. One approach was through the use of water-soluble oxidizing agents with the objective of destroying the thio-phosphate in the concentrate and thus eliminating its collector effect. The other approach involved the use of soluble sulphides, which have long been recognized as sulphide depressants. These efforts resulted in laboratory processes which showed promise. Research was then extended to a pilot plant having a daily capacity of several tons of concentrate. This operation soon demonstrated that soluble sulphide—basically sodium polysulphide—when applied to a pulp made slightly acid with sulphuric acid, proved to be the most effective sulphide depressant. The rate of concentrate treatment in this plant and the low molybdenite content of the concentrate prevented carrying the process to a conclusion, namely, production of molybdenite concentrate of marketable grade. Laboratory treatment of pilot plant concentrate indicated that a marketable product could be made from it, given a tonnage suited to available cleaner flotation machine capacity. Accordingly, the molybdenite plant was enlarged to permit treatment of the total copper concentrate from the extension plant, maximum of approximately 800 tons per day. In the enlarged plant a major difficulty was encountered. No criteria could be established as a basis for control of the process. In the early stages of flotation, because of the small amount of molybdenite involved, there was no visual evidence of the relative floatability of molybdenite with respect to

Jan 1, 1956

By Raj K. Singhal

Canada is a world class producer and exporter of minerals and mineral products. Canadian open-pit mines are highly mechanized and use state-of-the-art equipment and support technology. During the past few years, productivity improvements at Canadian open-pit mines have been achieved by taking advantage of larger equipment, in-pit crushing and conveying, truck dispatch systems and electronic management tools. The most recent developments are related to hydraulic transportation and the application of global positioning systems (GPS). Mine planning has become computerized. Environmental issues are dealt with in all phases of planning. Equipment modifications are pursued with vigor to keep the equipment functioning in the hostile Canadian north. In 1997, the mining and mineral processing sector employed 370,000 Canadians, contributing $26.2 billion to Canada's gross domestic product (GDP). The value of production of the Canadian mineral industry, including coal, amounted to $19.1 billion in 1997. Gold remained Canada's leading mineral with production valued at $2.8 billion. This was followed by copper ($2 billion), coal ($1.9 billion), zinc ($1.6 billion) and nickel ($1.9 billion). [ ] Synthetic crude oil from oil-sands mining operations in Alberta represents an important part of Canada's petroleum production. In 1997, the value of synthetic oil production was $2.87 billion. Canadian oil-sands mining has contributed significant technology developments in Canada.

Jan 1, 1999

By D. L. Crouse

The worldwide talc industry has experienced significant changes since the 1980's. Consolidation of companies and operations in Europe, Australia, and North America has altered the face of supply and distribution. Imports of Chinese and Australian crude have increased competition and product options. The number of processing operations without local mines has moved competition closer to the market area. Quality controls related to ISO certification and tighter specifications demanded by the customers have altered the way our mines and mills operate. Ceramics, coatings, and paper applications continue to consume the majority of processed talc.

Jan 1, 1997

By V. Annamalai, J. B. Hiskey, L. E. Murr

The kinetics of copper cementation on rotating disks of body and tear-top beverage can aluminum alloys were studied as a function of temperature and copper ion concentration. Both alloys followed the two-step kinetic regions, an initially slow rate followed by an enhanced rate. Experimental activation energy determinations (9.04 to 19.62 kJ/mol) indicated that ionic diffusion controlled the reaction mechanism between 20° and 60°C. At low temperatures (< 20°C), the system appeared to be controlled by the presence of an aluminum oxide surface film. The results of this study showed that cementation kinetics for the beverage can aluminum alloys are similar to those for pure aluminum. It was also found that the chemical removal of the oxide layer is less important for the alloys than /or the pure aluminum system. The characteristics of the resultant copper deposits were studied under a scanning electron microscope, and the reaction kinetics seemed to depend strongly on the nature and morphology of the deposits. In addition, maximum rates occurred when the deposit structures were fine feathery dendrites.

Jan 1, 1980

By S. E. Craig

Jen Inc., operator of the Cord mine, in the Big Indian district of San Juan County, Utah, has a contract with a milling company that provides a small bonus for proper grading and preparation of uranium ores shipped. To obtain maximum returns on this contract very close grading is required with settlements made on individual lots, which vary from 250 to 300 tons. Another feature of the contract, and one that is rather unique in this country, is that the ore is sold over truck scales at the mine. Grade is determined at the buyer&apos;s sample plant. It is necessary to take a moisture sample of each truckload shipped for ac- curate weighing and this is done by the representative of the buyer, using facilities supplied by Jen Inc. The sample is hardly more than a grab sample and includes only the finer and smaller pieces of the ore shipped.

Jan 10, 1958

By W. B. Triplett, H. I. Aaronson, G. M. Andes

THE morphology and mechanism of the proeutectoid a and the eutectoid reactions have been recently investigated in some detail in an iodide-base Ti—7.22 pct Cr alloy.&apos; These studies have now been extended to an iodide-base Ti—10.8 pct Cr alloy in order to evaluate the effects of composition on the proeutectoid and eutectoid transformations in titanium-chromium alloys. The alloy used in this investigation had the following composition: 10.8 Cr, 0.0327 0, 0.011 N, 0.0063 H, and 0.011 pct C. Specimens of this alloy were heat treated in evacuated and internally get-tered Vycor capsules. The specimens were solu-

Jan 1, 1959

By G. H. Bishop

The kinetics of the inter granular penetration and embrittlement of [100] tilt boundaries in 99.998 pct pure nickel upon exposure to bismuth-rich Ni-Bi liquids have been determined in the temperature range from 700° to 900°C. The kinetics of penetration are parabolic in time at constant temperature over most of the temperature range. In a series of 43-deg bicrystals the rate of penetration is anisotropic with respect to the direction of penetration into the grain boundaries. In lower-angle bicrystals the penetration rate is isotropic. The rate of penetration decreases with tilt angle at 700°C. The activation energy for penetration in the 43-deg bicrystals is 42 kcal per g-atom independent of direction. It is concluded that the intergranular penetration and embrittlement in the presence of the liquid proceeds by a grain boundary diffusion process and not by the intrusion of a liquid film. This was confirmed by a determination that the kinetics of penetration and embrittlement were the same in the 43-deg bicrystals upon exposure to bismuth vapor under conditions such that no bulk liquid phase would be thermodynamically stable. WhEN solid metals are exposed to a corrosive liquid-metal environment, the grain boundaries are sites of preferential attack. Depending on the temperature, the composition of the liquid, and the composition, structure, and state of stress of the solid, a number of modes of attack are possible. This paper reports a study of the kinetics of intergranular penetration and embrittlement of high-purity nickel bicrystals upon exposure to bismuth which, together with an earlier study by Cheney, Hochgraf, and Spencer,&apos; demonstrates that there are at least two modes of intergranular attack possible in the Ni-Bi system. In the study by Cheney et al., columnar-grain specimens of 99.5 pct pure nickel were exposed to liquid bismuth presaturated with nickel in the temperature range 670" to 1050°C. They found that the majority of the boundaries, which were predominantely high-angle boundaries, were penetrated by capillary liquid films, the attack proceeding by a process which will be termed grain boundary wetting. This process occurs in a stress-free solid when twice the liquid-solid surface tension is less than the surface tension of the grain boundary,* i.e., when 2yLs < YGB In this case the penetration of the grain boundary by the liquid occurs at a relatively rapid rate, resulting in the severe embrittlement of a polycrystalline solid. Grain boundary wetting is a common mode of intergranular attack in systems in which the lower melting component is relatively insoluble in the solid, but the solid has an appreciable solubility in the liquid, for example, the Ni-Bi system, Fig. 1. In systems of this type at temperatures above the range of stability of any intermetallic phases, once the liquid is saturated with respect to the solid so that no gross solution occurs, chemical gradients are small, and surface tensions become major driving forces for attack, provided the solid is stress-free. The results of Cheney et al. appear to be typical of those encountered when grain boundary wetting occurs.&apos; Capillary films were observed in the boundaries after quenching from the exposure temperature. The mean depth of penetration increased linearly with time, and the activation energy for the process was found to be 22 kcal per g-atom. In a study of the Cu-Bi system Yukawa and sinott4 found that the depth of penetration of bismuth into high-purity copper bicrystals of orientations from 22 to 63 deg of tilt about (100) at 649°C ranged from 0.05 to 0.25 in. after a 12-hr anneal. This corresponds to a linear rate of 6 to 15 X 10~6 cm per sec. At the same reduced temperature of 0.68 the rate for the Ni-Bi system&apos; was 7 x lo-&apos; cm per sec. In another study of the Cu-Bi system, Scheil and schess15 determined the kinetics of grain boundary wetting in hot-worked commercial rod. While there were several complicating factors present in this study, there is general agreement with the above results. The kinetics of penetration were linear, the activation energy was 20 kcal per g-atom, and at 650°C the rate of wetting was 2 to 5 x 10-6 cm per sec. The rate of wetting in the A1-Ga system6 is somewhat

Jan 1, 1969

By Jan A. Nemcik

Steel mesh has been used successfully for many years to control friable roof conditions and prevent loose roof and rib material from caving into the roadway. Despite its extensive use, the installation of steel mesh is difficult to automate and many other products have been evaluated as an alternative for skin control. Ideally, the properties of these new products should be similar or better than those of the steel mesh. In particular, development of a strong and resistant shell that minimizes movement along the fractured rock and coal surfaces between the bolt anchors is recommended. A strong surface adhesion and the strength of a reinforced polymer skin can provide the necessary toughening mechanism required to enhance roadway surface support by forming a reinforced polymer/rock surface layer. Most of the Thin Spray-on Liners (TSL) evaluated in the mines are weak with slow curing times, and the plastic mesh currently used to support the coal ribs is relatively weak. Therefore, neither material can seriously compete with steel mesh. Currently, a new polymer product that cures in seconds and forms an instantaneous strata binder that surpasses the properties of steel mesh is under development at the University of Wollongong.

Jan 1, 2009

1. Book review . Australasian coal mining practice, edited by C.H. Martin. Reviewer: R.B. MacGilIivray This book is an extremely comprehensive coverage of coal-mining practice in Australasia, the countries covered being Australia, New Zealand,and Papua New Guinea. 2. From The Institute of Metals The folowing are available from The Institute of Metals, 1 Carlton House Terace, London SWl Y 5DB. Physical and elastic characterisation, edited by M. McLean. 1989. 228 pp. £25.00. High nitrogen steels, edited by J. Foct and A. Hendry. 1989. 461 pp. £49.50. Proceedings of the First International Calcium Treatment Symposium. 1988. 116 pp. £15. New cored-wire injection techniques, particularly as Design for recyc/ability, by Michael E. Henstock. 1988. 150 pp. £15. Solidification processing. 1988. 549 pp. £45. Marine engineering with copper-nickel. 1988. 103 pp. £18. Characterisation of High Temperature Materials. 3. New journal FMJ International Publications Lid have announced a new quarterly publication, Aluminium Today. 4. Other new publications Algorithms in real algebraic geometry, edited by Denis S. Arnon and Bruno Buchberger. London, Academic Press, 1988. 274 pp. £15.95. Proceedings, Foundry and Heat Treatment 88. R150 per set of 5 volumes, or R40 per volume.

Jan 1, 1989