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By M. J. Mullikin, J. B. Conway

Equations capable of representing combined first -and second-stage creep behavior include the Andrade, Cottrell-Aytekin, Garofalo, and de Lacombe equations along with a third-degree polynomial in t1/3. Employing some recent high- temperature creep data for arc-cast tungsten the effectiveness of these expressions was evaluated. It was found that, in this instance, the most accurate representations were afforded by the third-degree polynomial in t1/3 and the de Lacombe equation. Also noted was the fact that the Andrade equation gave results just slightly inferior to those obtained with the third-degree polynomial, definitely better than those due to the Cottrell-Aytekin equation, and slightly superior to those furnished by the Garofalo equation. EXPRESSIONS designed to describe combined first -and second-stage creep behavior must possess certain specific characteristics. At time zero the equation must reduce to a strain value corresponding to the instantaneous deformation on loading. Then in the early moments following load application transient-creep behavior must be described to reflect a creep rate which constantly decreases with time. And finally at larger time values linear (or at least nearly linear) strain-time behavior must be accounted for to yield the steady state or minimum creep rate. Some equations, such as the one based on the parabolic creep law, yield fairly satisfactory results in transient analyses but are not effective at all when combined first- and second-stage data are to be analyzed. Other equations give equally accurate results in both instances although in general the complexity of the equation is slightly increased. For example the Andrade1 equation: has found fairly general application in expressing first-stage creep behavior. Furthermore the contribution of the exponential term becomes more and more prominent as the time increases and causes this equation to exhibit a point of inflection at large values of time. With a proper selection of equation constants the curve can be made fairly flat in the region of the inflection point indicating a desirable equation form for combined first- and second-stage creep analysis. Another equation form with the proper characteristic is that of Cottrell and Aytekin:2 e =a +bt1/3 +ct [2] Obviously as time increases the first derivative of this expression approaches a constant value to suggest application to combined first- and second-stage creep analysis. Similarly a third-degree polynomial in t1/3: e -a + bt1/3 + ct2/3 +dt [3] has the same characteristics. Expressions of this type have been shown3 to be very effective in the analysis of transient-creep behavior and the fact that the first derivative has the same characteristic as Eq. [2] suggests use in the combined analysis.

Jan 1, 1967

By Y. C. Kim, I. S. Roditis, P. K. Medhi

The strongly skewed grade distributions and the need to estimate the local recoverable reserves in a selective mining environment are the two problems that ordinary kriging (OK) cannot easily handle. With the recent introduction of the non- parametric, distribution-free technique of indicator kriging (IK), the above problems can be solved. This paper describes the result of performance evaluation of IK in an open-pit gold-silver deposit. For performance evaluation, the predictions of local recoverable reserves using IK were compared with the actual reserves based on blasthole information. The IK estimator, although a bit optimistic (or overestimating), performed very well in predicting the total recoverable ounces of gold from each panel on a test bench. The OK estimator was also used to try to predict local recoverable reserves, by treating each panel as either waste or ore, depending on the panel's average grade. Under this criterion, OK was found to be quite biased and pessimistic (or underestimating).

Jan 1, 1988

By Sneyd R. J, Walton M. C

In early 1987 Minproc acquired a license from the inventor to engineer and construct acid plants incorporating the Fattinger technology. The process offers a simple and reliable method of producing sulphuric acid from metallurgical off gases at significantly lower capital and operating costs than the more familiar contact process. The process also offers the simultaneous production of nitric acid, if the NOx content of the off gases is high enough. A development of this latter process has other applications within the minerals industry, particularly in conjunction with refractory gold ore preoxidation.

Jan 1, 1989

Introduction and Background For many years people were aware of the vast deposits of titaniferous magnetite containing vanadium in the Bushveld Complex. From 1957 onwards some exploitation of this ore was carried out by Minerals Engineering of S.A. (later the Vantra Division of Highveld Steel and Vanadium Corporation Limited), who produced vanadium pentoxide via a roast-leach process. Canadian Institute of Mining and Metallurgy The Finance and Executive Committees of the Canadian Institute of Mining and Metallurgy have agreed that members of SAIMM should be invited to register at all future CIM meetings at the same rate as CIM members.

Jan 1, 1980

By M. C. Leverett

THE dynamic behavior of a multiple fluid system is completely describable in terms of driving forces and resistances to flow. The latter are proportional to the vis-cosity of the fluid under consideration and inversely proportional to a property of the system termed the " effective permeability" to that fluid, a property therefore defined by this relation. Since three phases are usually present in oil reservoirs, it is essential to know the effective permeabilities to the several fluid phases, and the relationship between the composition of the fluid in the pore space and that of the flowing stream, in order to handle satisfactorily certain problems of oil production. In this regard, there are many unknown factors and parameters, and many that can be evaluated only indi-rectly. However, it is expected that work along lines similar to this present under-taking will help materially in solving these problems. Previous workers in this field have inves-tigated the two-phase systems, water-gas,1 water-oil2 in unconsolidated sands, and water-gas3 in consolidated sands. The ex-tension of the study of the flow of hetero-geneous fluid systems from two to three phases involved only slight changes in technique. The apparatus used in the present work, except for slight changes to be described, was that used by Leverett in his water-oil experiments.2 Correlation and interpretation of data were made by methods analogous to those used in two-phase work. The relative permeability to a phase-the effective permeability divided by the permeability of the system to a homogeneous fluid-was employed through-out in correlating the rate of flow of that phase with the composition of the pore space. Quantitative measurements of two inde-pendent physical properties of the system were required to determine the composition of the pore space. As in the two-phase work, the fraction of water was determined electrically. The gas fraction was deter-mined by measuring changes in volume accompanying measured pressure changes. Suitable account was taken of the solubility of the gas in the liquid phases, and of the vapor pressure of the water phase. Since this work was exploratory in nature, no attempt was made to obtain highly accu-rate numerical results. Reasonable precision and reproducibility were sought.

Jan 1, 1940

By Charles A. Sorrell

Two red muds, two fly ashes, and several aluminosilicate minerals were subjected to direct treatment with concentrated H2SO4 at temperatures of 175°C and below. X-ray analysis showed that virtually all the sulfate reaction products remained in the solid residue because of their low solubilities in x SO Substantial portions of the Al2O3 Fe2O3TiO2, Na2O, and K2O components of the materials reacted to form water soluble sulfates, which were then removed by H2O leaching at 55°C. The solid residue after water leaching consisted largely of amorphous silica and, in lime bearing compounds, CaSO4, The reaction and leaching processes were effective in removing all or nearly all the Al2O3. Fe2O3, TiO2, Na2O, and in lime components in the fly ashes, red muds, china clay, bentonites, the nephelioe fraction of nepheline syenite, and a plaster insulating brick composed of anorthite and mullite. Reaction with potassium feldspar and petalite took place, with formation of alkali aluminum sulfates, but the reaction rates and yields were extremely low. Potassium feldspar can be heated with Na2O and x O in air at 700°C for 24 hours, or with CaO at 1000°C for 24 hours, after which the reaction product kaliophilite, nepheline, and leucite-like phases, prove to be very susceptible to H2SO4, reaction and H2O leaching, providing yields near 100% of the Al2O2 content. An alternative method of H SO treatment consists of heating the sample in a silica tube and passing H2SO4 vapor over it. Preliminary results indicate that this method can be effective in enhancing the kinetics of reaction with the Al O component of potassium feldspar and offer the possibility that formation of Al2 (SO ) Fe2(SO4)3 and TiOSO4 can be accomplished selectively by taking advantage of the fact that the upper stability limits of the respective sulfates in the presence of H2SO4 vapor will be different.

Jan 1, 1982

By R. M. Jara

This work evaluates and characterizes the impact of the support size and mining dilution of a block model in the operation and selection of equipment at an open pit mine. An exploratory analysis and geostatistical modelling of the grades assayed on a set of drill hole samples is performed, which allows constructing a grade model on a dense grid by means of a conditional simulation. The grades are then averaged to greater selective mining unit supports in order to proceed with the study and methodology. First, the metal-tonnage curves are used to analyse the loss of selectivity on the in situ resources caused by a change of support. Concerning the ore reserves and their mining sequence, defined in the pit optimization and analysis process, the same curves prove that the loss of selectivity is more accentuated. Second, the importance of the block boundary dilution produced during mining operations is assessed. Its value depends on the amount of ore in contact with waste, on the loading error of the equipment and on the ore loss/waste dilution criterion assumed by the planner. The dilution percentage and the differences between waste and ore grades become higher when the block size decreases. For these reasons, considering the dilution in the production plans makes mining a small support more constraining. An adequate delimitation of the orebody can improve the mining selectivity, leading to greater income. Finally, a study of the increase in mining cost that provides a zero difference in NPV between the different block size options is carried out, in order to determine the maximum increase in mining costs for which it remains profitable to mine at a smaller block size. Keywords: Mining selectivity, support effect, block boundary dilution, selective mining unit size, block model.

Jan 1, 2006

Council for 2005/2006 President W.H. van Niekerk President-elect R.P.H. Willis Vice-presidents Senior R.G.B. Pickering Junior A.M. Garbers-Craig Immediate Past-president F.M.G. Egerton Honorary Treasurer J.A. Cruise

Jan 1, 2006

By C. B. Ndimande, C. Ntsele, M. Lisso, L. Arlow

"In the processing of UG2 platinum ore, stirred milling technologies are dominating regrind applications that require grinding the particles to P80s’ in the region of 45 µm. For this application stirred mills are 30–40% more energy efficient and require a smaller foot print compared to traditional tumbling mills. In this work a study was carried out using a batch pin mill and three scales of Stirred Media Detritors. A laboratory scale pin mill, a pilot scale Stirred Media Detritor with an installed power of 18.5 KW and two industrial scale Stirred Media Detritors in continuous operation, with an installed power of 355 KW and 1,100 KW were used. The industrial scale SMDs were in the secondary grinding section of a mill floatmill float (MF2) UG2 processing plants. The tests were focused on assessing the effect of feed rate and percent solids on power consumption and product fineness at lab scale, floatation response of the SMD product at pilot scale and on an industrial scale, the effect of feed rate on energy consumption and product fineness. The measurements obtained were feed flow rates, mill power and from the samples cut, particle size distribution of both feed and product. Specific energy was observed to increase with increasing percent solids over the 30wt% to 80wt% studied. Floatation response tests of the pilot scale SMD products show improvement in grade. Specific energy and reduction rations are observed to decrease with an increase in feed rate.INTRODUCTIONThe purpose of comminution in most mineral processing applications is to liberate the valuable minerals from gangue so that they can be recovered in subsequent separation stages. Most precious and base metal plants treat low grade fine-grained ores which require a higher degree of size reduction to yield the necessary degree of liberation (Partyka & Yan, 2007). Many authors have shown that the relationship between product size and grinding energy consumption is exponential, the finer the product from the comminution device, the higher the energy consumption (Gao & Weller 1993; Napier-Munn, Morell, Morrison & Kojovic, 1996; Jankovic, Valery & La Rosa, 2003). The suggested reason for this kind of relationship is that smaller particles have fewer flaws and higher strength than larger particles. Particles with fewer flaws and higher strength require higher energy for breakage to occur. One of the challenges most plants face is that of efficient energy utilisation in the liberation of the mineral from these complex ores. Conventional tumbling mills are not energy efficient in fine and ultra-fine grinding applications because some of the energy is spent on moving the charge and does not go directly into breakage. Stirred mills have been found to be about 30% to 40% more efficient and require a smaller foot print compared to traditional tumbling mills for regrind applications that require product size with P80s’ in the sub 45 µm regions (Radziszewski & Allen, 2013). Stirred mills are able to produce fine product because they can achieve a high number of stress events per unit time and volume compared to tumbling mills (Kwade, 1999a). To minimise energy usage without compromising product quality, the mining industry has adopted stirred milling technologies for fine and ultra-fine grinding (Radziszewski & Allen 2014; Kwade, 1999b). The south Africa platinum group metal (PGM) industry alone had over 40 stirred media mills installed by 2011 (Rule, 2011). Of that 40, 13 were in the ultra-fine grinding (UFG) application and the rest in main stream inert grinding (MIG)."

Jan 1, 2016

By Gift Makusha, Dave Minney

Anglo Coal South Africa mines coal for both the domestic and export market using open cast and strip mining methods. To establish a mine, a process is set in place to gather ever increasing amounts of geological and metallurgical data to confirm a proven reserve. Increasingly, geotechnical data are also included in this process to confirm that reserve is easily and safely mineable. The mine design process is an iterative one using a combination of numerical modelling and empirical data to arrive at a mining layout that is both, practical, productive and safe. In South Africa it is a legal requirement to compile a code of practice to combat rock fall and slope instability accidents and these have to be revised annually, reinforcing the iterative process of continual improvement. To ensure best practise occurs, all Anglo Coal operations are subjected to annual 2nd party audits and ad hoc 3rd party audit by independent consultants. This paper attempts to explain the process described above in a concise, but understandable manner. 1.0 GEOLOGICAL SETTING The Ecca sediments date from the Permian period and the coal deposits were formed in glaciated valleys on a basement of Dolomite, Ryolite or Granophyre rock types. The sediments overlying the coal deposits are typically flat lying and multiple bedded. The sediments consist of mudstones, shales and sandstones and are generally capable of forming stable highwalls given the time that they must stand up for. Anglo Coal extracts coal from the Witbank, Highveld and Vereeniging coalfields. The Witbank coalfields contain five seams numbered from the base upwards, 1 to 5 Seam; Highveld coalfield the 2 and 4 Seam and the Vereening area the seams are described as Top, Middle and Bottom seams. Coal deposited over the basement Dolomite formation display very erratic dips, as contemporaneous subsidence occurred in some instances over sinkholes that were forming, resulting in local thickening of the coal deposit and resulting in strata that dips toward the centre of the sinkhole.

Jan 1, 2006

By Susumu Ukita

We have developed first a conveyor belt for transporting large lumps, i.e. Rock Belt successfully, in June 1976. The First Rock Belt had been delivered to Myodani site of Kobe City Developing Board in Japan, and its' successful operation has attract keen interests in customers from over the world as well as Japan. However, this First Rock Belt was removed in arch '81, viewing it has satisfactory expired its service life of about five-year, and also original location of this belt become to be far from the site due to long-years earth collecting work. Taking this opportunity, we introduce the Second Rock Belt applied for Rock Belt Loader as ell as three types of application of our Rock Belt working for rationalization of quarry of major company in Japan, and, view the prospect of Rock Belt:

Jan 1, 1981

By Zhiqing Zhang, Changyun Chen, Qing Liu, Lin Lin, Zhihong Jia, Guangjie Huang, Lipeng Ding

The effect of interrupted quenching (IQ) treatments on natural aging and bake hardening response of Al-Mg-Si alloy was investigated by hardness measurements, tensile test, differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The results show that interrupted quenching at 100oC could effectively suppress natural aging and improve bake hardening response. The optimized interrupted quenching treatment is 100oC for 45min, which gives the alloy a relatively low T4 temper strength and higher bake hardening response. The formation of highly dense cluster(2) during the interrupted quenching could be the reason for suppressing the natural aging and accelerating the precipitation of ß? phase during the paint bake treatment. In addition, interrupted quenching at higher temperature (170oC) results in unfavorable properties in both T4 temper and paint bake treatment. The formation of large precipitates is responsible for these undesired effects.

Jan 1, 2015

By Joseph Chalmers

PROBLEMS dealing with the movement or ,migration of fluids through porous beds have been the subject of much research. The subject is not peculiar to the production of oil and gas, as many investigators have studied the nature of this movement and its relationship to the problems of other industries. Darcy1 conducted a series of experiments relating to the percolation of water through filter beds. King2 carried on an extensive series of laboratory experiments with the object of formulating some conception of the rate of movement of water through soils and sand strata in the drainage of surface water into underground channels and subsequent recovery of this water through wells drilled into the source beds for irrigation purposes. Slichter3 undertook a study. of the same problem from a mathematical standpoint, and more recently Furnas4 has investigated the flow of gases through beds of broken solids with particular reference to blast-furnace operation. With specific reference to gas production, Muskat and Botset5 of the Gulf Research Laboratory undertook an experimental study to establish quantitatively the characteristics of and laws governing the flow of gases through consolidated and unconsolidated porous materials of fine texture with a view of predicting the performance of gas in an underground reservoir. There seems to be a general agreement that many of the relationships between the numerous factors influencing the flow of fluids through porous materials are far too complicated to be attacked by analytical methods based upon a knowledge of hydrodynamics. For gases, the laws of

Jan 1, 1932

The concept of the Unified Comminution Model (UCM) was presented at the 23rdIMPC. The model utilises computational techniques to calculate the mechanical environment in any comminution device, and then incorporates the outcomes from rock breakage tests to predict the product from a device. The model is fully mechanistic, and incorporates the capability to simulate novel equipment. This paper presents the progress on the first application of this concept to applied comminution equipment. This novel comminution model aims to integrate all comminution models within a single struc-ture. This will provide a step change in the predictive power of comminution models, and include a wide range of particle properties that will enable it to be linked to the upstream and downstream process of mining and recovery. Major advances over current models will be the capability to predict liberation, preferential grinding, performance of new and novel devices, and to have power as an integral driver of the comminution simulation process. The methodology and model structure have been developed. An equation within a population balance framework has been derived as the basis for the UCM. A set of SAG mill pilot has been used as the first test case. The breakage characteristics of the ore have been extensively tested utilising a new range of breakage tests required by the rigorous UCM structure. The mill was simulated with the EDEM - DEM software. A partial test simulation of the pilot SAG mill has been conducted. This serves to demonstrate the feasibility of this modelling technique, but still lacks important ore characterisation components that are under development. The study has raised a number of significant challenges to the accepted understanding of the comminution process. Through addressing these challenges considerable insight has been gained into the energy environment in mills and the requirements of breakage testing. The ore characterisation methods and energy transmission derived from DEM simulations remain as major research items.

Jan 1, 2014

By M. I. Brittan

Discussion Dr R. E. Robinson (Fellow): The author must be congratulated on a very meticulous and self-contained piece of work. It is indeed a pleasure to read a paper that is so clearly and systematically laid out, and where the conclusions and the testwork conducted have been so clearly described. The paper is complete in itself, which makes it very difficult for someone who is not intimately involved in the whole Torco project to make any comments on its content. However, two points that, strictly speaking, fall outside the scope of the paper are of considerable interest. The first relates to the particle size of the material treated. In the paper, the testwork is confined to one standard particle size (minus 60 plus 100 mesh). The essential feature of the paper is to indicate that the rate-controlling reaction in the whole segregation process is the rate of reaction of the ore particles with the reducing agent and the hydrogen chloride. One wonders, therefore, to what extent this relatively slow rate of reaction is affected by the particle size of the ore itself. One imagines that the reaction must take place by contact of the hydrogen chloride with the surface of the mineral particles, and it is reasonable to suspect that the rate of diffusion of the copper ions to the surface is a relatively slow process and is thus the limiting factor in this particular rate of reaction. It is possible, for example, that the improvement obtained, when the ore is subjected to reducing conditions before the chlorination, is due to a breakdown in the crystal structure of the original particle. This breakdown is brought about by the reduction and by the consequent increase in surface area available for reaction with hydrogen chloride. Can the author indicate whether any work has been done along these lines, and whether it has been established that the reaction depends on the surface area available? The second point relates to the application of this kinetic study to the actual operation of a Torco reactor. It was once planned to feed the sodium chloride, together with the reducing agent, into the top of the segregation chamber. In the paper, the author mentions that it has now been established that the segregation chamber behaves, to all intents and purposes, as a fluidized bed, and that there is, therefore, a rapid evolution of gas in the lower regions of the chamber, which, it is imagined, displaces the gas phase rapidly. Since the reaction between sodium chloride, water vapour, and the aluminium silicates in the ore is extremely rapid, one wonders how much of the hydrogen chloride produced is removed from the reaction zone before it has had time to react with the copper minerals. The extremely low consumption of sodium chloride (which is a vital feature of the Torco process) must depend on an extremely rapid circulation of the hydrogen chloride gas to all the ore particles in the segregation chamber. One wonders, therefore, if a system for the introduction of the sodium chloride into the bottom regions of the chamber might not result in even greater efficiency in the utilization of sodium chloride. ProC D. D. Howat (Fellow): All of us who have been concerned with the study of chemical reactions at high temperatures are keenly interested in kinetics and are well aware that this is not an easy study experimentally. Dr. Brittan is to be congratulated on the development of neat experimental methods and for his full discussion of the results obtained. Although the segregation process for the extraction of copper from oxide and silicate ores has been known for almost fifty years, the fundamental chemical and physical changes involved have been little understood and the fundamental data are very scanty. The work now in progress at A.A.R.L., together with that sponsored by the Anglo American Corporation in other research institutions throughout the world, is bound to produce new fundamental data and a much more complete understanding of this rather fascinating process. It is already apparent that some of the old and well-worn chemical reactions that were postulated to occur, just cannot take place in the way which was formerly accepted. Dr Brittan's work, carefully conducted and thoroughly analyzed as it has been, still leaves us with one great outstanding problem. The thermodynamic data and the possible reactions set out in Table I (page 281) of his paper leave us asking, in complete despair, how can copper be converted into a volatile chloride in the presence of HCl, CO and carbon at temperatures about 800°C? The thermodynamics all combine to show that copper should be reduced to metal as the first step in the process. This brings us right up against the second problem. If copper were reduced to the metal how would HCI convert it to the volatile chloride? On top of these problems is the unknown reason for the very high speed of reaction between CO, HCI and the ground copper ore. Still further into the region of the unknown is the reaction by which gaseous hydrochloric acid is produced in the actual process. Perhaps Dr Brittan is feeling grateful that he doesn't have to try to explain this reaction-at this stage of the research programme at least. The results very clearly show that both CO and HCl gas are essential for rapid production of the volatile copper chloride. Dr Brittan states that 18 minutes were required to attain 83 per cent extraction with HCl gas alone and this was reduced to 4 minutes when CO was

Jan 2, 1970

By H. D. Yoo, M. R. Tek, D. L. Katz

The behavior of gas-storage reservoirs subject to water drive is investigated through analog simulation on an electronic differential analyzer. The simulation technique developed on an LM-10 computer permits the prediction of reservoir volume or pressure resulting from the movement of water in the surrounding aquifer. The method developed on the analog computer consists of setting up an appropriate transfer-function circuit and feeding the arbitrary time-varying boundary conditions as an input signal. The input may be specified as gas reservoir pressure, pore volume or the water flux. Several cases studied include an isolated gas reservoir on a limited aquifer, interference among three reservoirs adjacent to a common aquifer and the growth of gas-storage volume on an aquifer. It is concluded that the method developed on an electronic differential analyzer provides an excellent technique to simulate and investigate the behavior of gas reservoirs subject to water drive. The agreement between the reservoir performance as predicted from the simulation technique and as measured from actual field data is found to be better than the range usually encountered in predicting water-drive behavior. INTRODUCTION It is generally known that some gas-storage reservoirs are located on top of blanket sands of large extent, saturated with brine called aquifers. Because the volume of the body of water associated with aquifers is usually very large and water is compressible, the cyclic pressure variations encountered in normal storage service inevitably cause unsteady, compressible flow conditions in the adjacent aquifers. The solution to radial diffusivity equation for a limited aquifer for constant terminal conditions has been know111 since the early 1930's. The solution for the constant terminal conditions for an infinite aquifer was puhlished in 1949.2 The proldem of handling the unsteady flow of water through a porous medium with time-varying boundary conditions has been studied by many investigators through the use of graphical,3 digital4 computing techniques or on an R-C type of electrical analog called a reservoir analyzer.5 The digital computer performs a series of arithmetic calculations to superimpose the solutions of constant terminal conditions, while the R-C type of analyzer permits the simulation of the continuous medium by means of "lumped-cell" electrical resistance and capacitance elements based on finite-difference approximations. The graphical method is based on the convolution integral solution of the partial differential equalion. The purpose of the present study was to simulate the behavior of an aquifer on a general-purpose, electronic differential analyzer to obtain the influx of water or the change in pressure at the reservoir continuous1r and quickly. The use of the electronic differential analyzer was based on well known solutions for the constant terminal conditions already available in the literature.2,6-8 THEORETICAL DEVELOPMENT MODEL. The gas reservoir (R) is described in relation to an aquifer in Fig. 1. The permeability and porosity of an aquifer sand, the viscosity of the brine, and the compressibility of the brine and the formation are assumed to be constant. It further is assumed that the blanket sand is not thick enough to give appreciable vertical pressure distribution. The model in consideration is circular with radial geometry. The aquifer radius can be of limited or infinite extent. The gas-water interface is assumed to be fully segregated, and the displacement of the gas by

By D. A. Elgillani, M. C. Fuerstenau, M. C. Kuhn

The species responsible for flotation when xanthate is added as collector for pyrite is dixanthogen. Measured oxidation potentials of these systems show that xanthate should be oxidized to dixanthogen, and the presence of dixanthogen on the pyrite surface is confirmed by infrared absorption. Zeta potential measurements are presented and related to collector adsorption. In spite of the normal presence of pyrite in most sulfide ore deposits, only a modest amount of study has been devoted to the xanthate-pyrite flotation system in the absence of activators and depressant~.'-~ As a result, little is known about the mechanism of xanthate adsorption on pyrite. From the few studies that have been made, however, a number of significant observations have been forthcoming. For example, the dependence of flotation response on the state of oxidation of the surface was noted in two studies — one conducted by Plante and Sutherland4 and a later one by plaksin.~ In another study, Gaudin and wilkinson3 found that ferric xanthate was not present on a pyrite surface. In a later investigation, however, Gaudin' and his colleagues did extract a small amount of ferric xanthate into benzene when pyrite was ground in an evacuated mill with water, benzene, and xanthate. This quantity was apparently

Jan 1, 1969

By Hemendra N. Kalia

Several attempts have been made in the past sixty or so years to commerciliaze the vast oil shale deposits of the United States of America. However, the industry has yet to become viable and economic. To date, it has not been possible to produce oil from the oil shales at a competitive price when compared to the oil produced from oilfields by conventional methods. However, the development work has been quite fruitful in furthering the art of thick bed mining and technology of in situ retorting. The in situ method has the potential of recovering oil from thick beds and the resource recovery potential is much greater than that from underground mining and surface retorting. In situ methods require that the shales/ marlstones be fragmented ' in place to induce adequate porosity and permeability to allow in situ' heating of the fragmented shales. This can be accomplished by using explosives. However, it has been found that the existing blasting systems, though very efficient, are somewhat lacking. The explosive become insensitive when shot in multiple vertical decks. They can also become insensitive when spaced horizontally at close proximity to other charges. Also, since the blasting is done in a very limited free face, this limits the delay time that can be allowed between charges. Consequently it is not always possible to predict the performance of the blasting system on a routine basis. Furthermore, since it is not possible to undertake secodary blasting, it is imperative that the blast design function properly. Recent, successful retorting by Occidental Petroleum Company of retorts seven and eight suggests that some of these problems may have been overcome. This paper addresses some aspects of in situ retorting and problems those have impeded the development of a viable oil shale industry in the U.S.A.

Jan 1, 1983

By Andrew P. Ritter, James W. Reil, Douglas A. Anderson, Stephen R. Winzer

We have developed a method for predicting and controlling ground vibration from blasting using a rigorous scientific approach. The method is based upon the superposition of seismic waveforms generated by a single-hole free-face shot, recorded at seismographs deployed in an array that includes environmentally sensitlve locations. Waveforms generated by single-hole shots are shown to be reproducible. The waveforms for each of the sites are used to construct synthetic seismograms for delayed shots based upon linear superposition. A computer code systematically constructs the seismograms for the delayed shots, with incremental delays between holes of 1, 2, or 3 milliseconds (ms). A Fourier amplitude specs-rum is calculated for each synthetic seismogram and the spectra are plotted on a map in delay-frequency space, i.e., each row of the map represents the Fourier spectrum for a blast with a particular delay interval. For single-row shots, the delay between holes in a row is used; for multiple-row shots, the delay between holes In a row is kept constant and the delay between rows is incremented. Predicted vibration varies strongly as a function of delay and h

Jan 1, 1985

By H. W. Kilau

The Bureau of Mines evaluated synthetic fluorspar as a substitute for natural fluorspar flux in basic cupola ironmaking. The synthetic fluor-spars tested were prepared from waste fluosilicic acid generated during the processing of fluorapatite ore. The cupola trials showed the synthetic products to be the equivalent of natural fluorspar from an operational standpoint. However, wet scrubber sampling showed that substantial losses of volatilized fluorine occurred from the cupola during operation. The losses during synthetic fluorspar trials considerably exceeded those from natural fluorspar trials. Laboratory viscosity testing, using a high-temperature rotational viscometer, confirmed this finding and indicated that fluorspar volatility in slags is related to slag basicity. Synthetic fluorspar is accordingly recommended more for highly basic cupola operation (>1.3 basicity) than for neutral or acid operation, because of the increased potential for pollution and baghouse filter detezioration"

Jan 1, 1989