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By L. S. Darken

THE manufacture and treatment of metals comprises operations whose effectiveness depends in large measure upon diffusion phenomena. The significance of such phenomena has, for a few simple cases, long been understood, but in more complex cases it has not been adequately recognized. This paper presents a mathematical analysis of some of the cases in which diffusion leads to the formation of a new phase within the metal, and this analysis provides a basis for interpreting quantitatively many apparently diverse experimental observations recorded in the literature, some of which are outlined in the following pages. OBSERVATIONS RECORDED IN LITERATURE An outstanding instance is the general type of phenomenon in which diffusion of an element into an alloy is followed by a phase change, which most frequently is a reaction (precipitation) of the diffusing element with one or more components of the alloy to form a compound. Thus in certain alloys heated in contact with oxygen not only the usual oxide scale appears but, in addition, beneath the surface, a well-defined zone in which free oxide particles are dispersed with notable uniformity. This zone, commonly referred to as the subscale or zone of internal oxidation, is remarkable in that the visible boundary between it and the unaltered metal is usually sharp. Such a subscale, which appears to have been recognized first in oxidized copper alloys, has been described and studied by C. S. Smith,1 by Rhines,2 and by Rhines, Johnson and Anderson;3 but it appears also in other alloys when they are exposed to conditions that bring about the precipitation of some compound, not necessarily an oxide. Another clear case of this same kind is the diffusion of carbon into a steel containing an element such as molybdenum, chromium, vanadium or tungsten, whose carbide is less soluble in iron than iron carbide, the result being that some part of that element is precipitated as a dispersed carbide. A similar phenomenon may occur on the welding of two alloys each of which contains one of a pair of elements that react to form a compound or a new phase of any sort. But in addition to the precipitation of a compound formed from the diffusing element, other effects may result merely from the presence of the diffusing element. For instance, if homogeneous austenite, nearly saturated with respect to carbon, is heated in contact with silicon in the absence of oxygen, one would expect to find, behind the several iron-silicon phases analogous to a scale, a zone of austenite containing dispersed carbide, because of the fact that silicon decreases the solubility of carbon in iron. As still another example, oxidation of an alloy may result in diffusion toward the surface of one or more of the constituents; for instance, during oxidation of a steel containing an element such as copper, which is less prone to oxidation than iron, there is a notable enrichment of copper just beneath the scale-metal interface. As an example of a yet more

Jan 1, 1942

By W Farnworth, D Fergusson

Estimation of productivity is a key factor in the design of hydraulic mines and in assessing their economic feasibility. A published Russian formula for hydraulic mining monitor cutting rates overstated productivity by up to 2 tonnes per minute (251%) when applied to Solid EnergyÆs hydraulic mines. A new formula, taking into account additional productivity factors, was derived by Solid Energy and produced an acceptable correlation between predicted and actual cutting rates inNew Zealand and overseas hydraulic mines, with an average error of approximately 0.1 tonnes per minute.   Another key factor in hydraulic mine design is the transport of coal slurry via flumes. Solid Energy carried out a series of 80 full scale tests in a surface flume installation, varying the gradient and coal:water ratio. Both steel flumes and plastic-lined flumes were evaluated. A modification of the Chezy Open Channel Flow formula, including a factor for slurry density, gave a reasonable correlation between actual and predicted flows. It is believed that this Solid Energy formula is suitable for the design of flume installations for hydraulic mining.

Jan 1, 2004

By R. J. Wygal, J. Naar

An equation for three-phase (water, oil, gas) imbibition oil permeability is developed, assuming the water to be the dominant wetting fluid. Oil isoperms are obtained for consolidated sandstones characterized by 1/pc2 = CS*. The evolution of an oil-gas system imbibing water from Swi to(Sw,imb )max is shown to proceed along a line of constant oil saturation with increasing oil permeability and decreasing gas saturation. When the gas satuation cannot be reduced further, the system evolves along a line of constant Sg with decreasing oil saturation and permeability. The initial gas saturation is shown to reduce markedly the effect of complete wetting by either oil or water on flow performance. INTRODUCTION Imbibition oil isoperms are required for performance prediction when a well is producing water, oil and gas. This situation occurs in multiphase displacements such as underground combustion, steam injection and the water flooding of highly depleted reservoirs. In a recent paper,1 a model was presented for the prediction of two-phase imbibition characteristics. This paper extends the imbibition model to the case of three phases by assuming that the water is the dominant wetting fluid. The following results were obtained from the model: (1) an analytical expression of oil isoperms; (2) oil isoperrns as functions of reduced water, oil and gas saturations, valid for all sandstones having a capillary pressure curve which can be approximated by 1/PC = CS*; and (3) evaluation of the three-phase flow performance as dictated by complete wetting by either oil or water. The agreement between predicted and observed oil recovery in the presence of a gas phase, reported in Ref. 1, is a partial support for the present development. However, experimental data are not available at this time to check fully the model predictions. Perhaps this paper will stimulate the collection of such data. The imbibition model of a porous medium has been described previously, and the reader is referred to the paper of Naar and Henderson1 for details. In brief, the model is formed by the random interconnection of straight capillaries, with a provision for the blocking of the non-wetting phase by the invading wetting fluid. The following expressions were derived from the model. 1. The amount of oil blocked by the invading water is

By J. I. Mathis

"The failure that was utilized for developing this model was a double bench-scale failure, approximately 20 m in height, in the Misery pit at BHP Billiton’s EKATI mine site. The bench that failed was excavated in biotite schist. Due to previous problems with bench-scale toppling failures, this bench was excavated with a 70° inclined, 30 m deep preshear. Upon exposure, the wall was very clean with half-barrels commonly observed from the pre-shear operation.In August 2003, a bench failure of about 1000 t occurred in this pre-sheared biotite schist (Fig. 1). Upon examination it was noted that the foliation that paralleled and dipped at 70° into the face when excavated was approximately horizontal at the top of the failure (Fig. 2). While the failure mode itself appears complex, the failure was apparently driven by three factors:• a low-angle, low-frictional strength fault or discontinuity at the base of the failure area;• water either contributed meteorically from precipitation and/or from permafrost melt; and• foliation planes providing a viable toppling geometry once toe block motion began to occur.The above details are illustrated in Figure 3.After considerable thought and analysis, a model was postulated for the failure.It is thought that the entire failure had been triggered by displacement of a toe block (Fig. 4). This toe block is bounded on the back by foliation, the bottom by a low-angle, lowstrength fault, and the front by the bench face. Water pressures behind the bench face developed forces on the block as can be seen in Figure 5. These forces were sufficient to induce block motion. As can be seen in the relative shear strength diagram in Figure 6, only a small amount of water is necessary in the face to initiate block displacement. Note that in this figure, a simplistic piezometric pressure distribution was assumed."

Jan 1, 2004

By Victor Benavente

La lixiviación es un proceso hidrometalúrgico que permite obtener el cobre de los minerales que lo contienen, aplicando una disolución de ácido sulfúrico, agua y agentes oxidantes. Este proceso consiste en que los minerales son sensibles al ataque de soluciones ácidas y oxidantes. En ese sentido, el objetivo del texto fue determinar la respuesta de los sulfuros secundarios de cobre a la lixiviación ácida y oxidante utilizando cloruro de sodio como portador de cloruro al sistema de lixiviación. El desarrollo de las pruebas y la ejecución de las mismas, definiió el proceso de lixiviación para minerales sulfurados de Minera Pampa de Cobre.

Sep 12, 2011

By Ernst-Ulrich Reuther, Alexander Donmen

Mine ventilation in the German coal mining industry is concerned mainly with problems of thermal environment arising from greater depths and with increasing emission of methane gas. The development of computer techniques over the past ten years for solving these and ancillary problems is reviewed. The emphasis from a planning and control point of view falls mainly on ventilation network calculations, temperature predictions and advance estimates of methane emission.

Jan 1, 2014

By Christopher Riley

A relatively unexplored lead zinc deposit lies about 12 miles northwest of Revelstoke, B.C., in the highly metamorphosed Monashee Group of rocks of the Shuswap Terrane, Precambrian in age. Host rocks are of sedimentary origin and consist of gneisses, schists, marbles and quartzites with intermediary types. The marbles and quartzites provide good horizon markers. Using these it is possible to interpret the controlling structure which is a syncline overturned to the north, dipping south at about 45°, and plunging east at about 12°. The syncline is truncated at about halfway of its length on a peak on the west side of which a partial cross section together with superimposed minor folds may be seen. The quartzites and the two marble beds may be traced over much of the structure. There are two lodes, above the marble and below the quartzite, which converge eastward and which are the exposed edges of the same host bed -an impure limestone.

Jan 1, 1961

amounted to about 2000 metric tons. The total output is increasing from year to year. Marine salt is now produced in Haiti in quantity sufficient to supply nearly all the requirements of this Republic, so production tax is now collected. Central America Guatemala-The major production of salt in Guatemala is solar salt derived from sea water, but the Indian population prefers salt derived by boiling coastal marine earth. Salt is taxed by the Government. The industry has been beset by controversies in recent years, especially following the revolution of October 1944. The Government issued a decree in August 1940 designed to control production and price of salt. The creation of a salt consortium was provided for and marketing was to be governed by production quotas. It is understood that the Government pool was later dissolved and the industry is now under older laws whereby production and sales have no limits. South America Panama-Output of salt in Panama in a very recent year was 11,000 net tons of solar-evaporated sea salt. A Government bank is in charge of output and distribution of the product. Colombia-Rock-salt deposits are known in five places-Zipaquira, Nemocon, and Sesquile, in the Department of Cundinamarca, the Cumural y Upin near Restrepo, and San Miguel y Barital, near Medina in Meta Intendency. The latter deposit never has been worked on account of its inaccessibility. Saline springs are worked in four locations. The largest producer among marine salinas is Manare but it is now planned to make Bahia Honda the largest. Some evaporated salt is made in vacuum pans. The deposits at Zipaquira, Nemocon, and Sesquile are believed to occur in the domal type of deposit. All the salt resources are under Government control. Venezuela-The salt industry in Venezuela is under Government control and is taxed. Taxes in recent years, however, have been reduced for salt used in curing hides and salting meats, fish and fish products. Production has approximated 25,000 metric tons yearly but may now be considerably above that figure. The basin on the peninsula of Araya, State of Sucre, which at present is the only important source of salt, could produce at least 175,000 metric tons if more ground were provided-a larger supply than the entire country could consume. This unique landlocked basin of nearly 1000 acres lies 12 ft below sea level. Ecuador-Salt is a Government monopoly in Ecuador and is produced chiefly by solar evaporation close to the shore. The main producing center is on the Santa Elena peninsula, which supplies about 90 pct of the salt. Small fields are at Punta Arenas, Payana, and Chara-

Jan 1, 1949

Temperature Sensitive Polymers as Efficient and Selective Flotation Collectors

Sep 13, 2010

By D. W. Levinson, L. E. Tanner

DURING the course of an investigation of the zirconium-iron-tin system the zirconium-iron system was reexamined up to 55 pct* Fe. The alloys pre- visible melting3 and X-ray diffraction studies were made of samples of the alloys. The ferromagnetic properties of ZrFe2were determined by Professor P. W. Selwood* using a modified Faraday balance.4 The zirconium-rich portion of the phase diagram is presented in Fig. 1 and compared with the work of Hayes et al.1 The maximum solubility of iron in ß is somewhat decreased while the eutectic temperature is raised. There seemed to be no change in the eutectic composition of 16 pct Fe. Since the base material was so low in iron content, it was possible to establish the maximum solubility in a between 0.017 and 0.025 pct Fe at the eutectoid temperature. The observation of fine ZrFe, particles in the micro structure of a specimen of 0.012 pct Fe alloy quenched from 700°C indicated that the solubility drops below this composition at 700° C and lower. Further study was made of the intermediate phase ZrFe2. wallbaum5 identified the compound initially as ZrFe2 with a C 15 (MgCu2) structure, placing it at 55 pct Fe stoichiometrically. Hayes et al.1 believed they found the phase at about 47.2 pct Fe and called it Zr2Fe3 but reverted to ZrFe, in the discussion of their paper.6 Jordan and Duwez7 confirmed Wallbaum's work as well as finding the same single-phase structure to about 62.3 pct Fe or Zr0-61 Fe2-18. In order to establish the ternary phase relations in the zirconium-iron-tin systema the exact position of this phase had to be known. This was accomplished by X-ray diffraction, visible melting, and metallographic techniques. Elliott8 obtained a single-phase ZrFe2 X-ray diffraction pattern from an alloy of about 55 pct Fe. This was confirmed in the present study with an alloy of 54.81 pct Fe. However, extra lines (attributable to a or ß zirconium) were found in diffraction patterns of the 47.42 and 49.83 pct Fe alloys. The melting characteristics of these same alloys were studied by suspending 47.42, 49.83, and 54.81 pct

Jan 1, 1960

By Jr. Watts

The American Mining Congress and the U.S. Bureau of Mines have formed a collaborative research team to develop, implement, and evaluate a comprehensive control strategy to reduce diesel particulate matter concentrations without degrading other air quality parameters at an underground noncoal mine. Other participating organizations include Caterpillar, Inc., the Mine Safety and Health Administration, and the University of Minnesota. After extensive baseline information and air quality data are collected, available control strategies to reduce diesel particulate matter exposures will be implemented, individually or in combination, and evaluated. This paper discusses the objectives and protocol of the collaborative effort to evaluate diesel particulate control technology.

Jan 1, 1995

By D. M. Wyslouzil

"Micron or sub-micron size gold inclusions in sulphide minerals cannot be extracted by conventional cyanidation. The gold surfaces must first be exposed by decomposition of the sulphides. As an alternative to roasting, pressure oxidation was found to be a most satisfactory method to decompose the sulphides and expose the gold particles. For cyanidation the pressure oxidation pulp has to be neutralized and stabilized with lime. It was found that thiourea can extract the gold directly from the pressure oxidation pulp without pH adjustment and oxidant addition. The main obstacles against the common use of thiourea are circumvented by a recently described control method of the emf during leaching.INTRODUCTION Amalgamation and cyanidation are the most conventional processes for gold extraction. The prerequisite for gold extraction is the possibility of gold surface to be contacted by mercury or by the cyanide solution. Encapsulated gold has little chance of contact and this leads to poor extractions.The reasons why a gold ore may be refractory are: micron or sub-micron size gold particles included in the sulphide minerals, such as pyrite and arsenopyrite; presence of and association with antimony, arsenic, tellurium and carbonaceous minerals. Some alternative processes, such as double oxidation(1,2), pretreatment with lime , H202, chlorine and Caro's acid, roasting and thiourea leach, have solved some of the problems of ""refractory"", but the sub-micron gold in sulphide minerals still shows little response. Roasting and the cyanidation of the calcine was one of the most successful approaches for this type of gold ore.There are two disadvantages to the roasting process: (1) the generation of sulphur, arsenic, antimony and mercury containing gases is undesirable and the control is extremely expensive; (2) gold particles might be fused in the roasted product and the oxidized base metals in the calcine might reduce the cyanidation efficiency. In recent years the pressure oxidation process has been considered as one of the more effective and satisfactory methods to decompose the sulphide minerals and expose the gold surface to the cyanide leach solution. The pollution problem could be better controlled and the gold extraction is more amenable."

Jan 1, 1985

By Nadia C. Miller

In situ metals research to characterize the hydrology of a fractured crystalline rock mass in under-ground mine stopes is discussed. The objective of this study was to find the potential direction, velocity, and concentrations of a lixiviant plume, should leaching solvents (lixiviants) escape from a test stope. The study was conducted by the U.S. Bureau of Mines at the Colorado School of Mines Experimental Mine in Idaho Springs, CO. Since this was a method evaluation site, the lixiviant was simulated using water and acceptable tracers. The site is located in moderately fractured Precambrian migmatite-biotite gneisses of the Idaho Springs Formation. The data required for the characterization were obtained from geologic maps and reports, core logs, and air and water permeability tests. The acquired data were analyzed and applied to a computer model that calculated' the characteristics of a lixiviant plume originating at the stope. A sensitivity analysis showed that dispersivity, ground water velocity, fracture porosity, and fracture spacing had notable effects on the concentration of the plume. Assuming a saturated rock mass, the lixiviant plume would disperse to undetectable levels in a very short time because of a high fracture density at the mine site.

Jan 1, 2010

The Industrial Minerals Division met jointly with the Materials and Equipment Division of the American Ceramic Society at State College, Pa, Sept 24-26 Headquarters were at the Nittany Lion Inn Thurs- day afternoon was devoted to a tour of inspection of the Bell Mine, American Lime and Stone Co , Bellefonte, Pa The party returned to State College for dinner and in the evening the Division's executive committee held a brief session There were four technical sessions Friday morning, Mining, afternoon, Beneficiation, Saturday morning, Industrial Minerals and Beneficiation There was an informal banquet at the Nittany Lion Inn Friday night with 93 present Edward Steidle was toastmaster Brief talks were made by President F C Flint and Secretary Ross Purdy, of the American Ceramic Society, Oliver Bowles, Chairman, Industrial Minerals Division, Adrian Morse, assistant to the president, Pennsylvania State College, and George Otis Smith, past president A I R'I E

Jan 1, 1937

By S. K. Nicol, A. R. Swanson, J. C. Day

Addition of oil to a suspension of hydrophobic coal particles can influence its dewatering characteristics. An agglomeration process occurs in which coal particles are held together by negative capillary pressure at particle/oil/water contacts. Consequently, the units round which flow can occur are enlarged and this improves dewatering parameters such as drainage rate, solids recovery, and equilibrium moisture content. This paper discusses processes which attempt to use this principle, in terms of metallurgical and economic efficiency. The discussion is augmented by results of recent experiments on the effect of oil addition to centrifuges and vacuum filters.

Jan 1, 1980

By Webster Smith

El presente texto describe la historiografía del cobre en el mundo. El cobre fue el primer metal usado ampliamente por el hombre. Posteriormente, las propiedades de resistencia de corrosión del cobre, bronce y latón hizo que estos metales permanecieran no solo como decorativos, sino como funcionales durante la Edad Media hasta nuestros días. Ya en el siglo XIX, Gran Bretaña fue el mayor productor del metal rojo. Pero nuevas minas se abrieron en EE. UU, Chile y Africa, hasta que en 1911 la producción mundial de cobre fundido excedió a un millón de tonelada por año. Con el avance de la Revolución Industrial, se descubrieron nuevos e importantes usos para el cobre, así como producir numerosas y nuevas aleaciones. Actualmente, se produce más de cinco millones de toneladas de cobre y este metal desempeña una parte vital y progresiva en muchas ramas de la tecnología moderna.

Nov 1, 1967

By B. J. Beaudry

The preparation of alloys containing one to two percent of the volatile lanthanide metals Sm, Eu, Tm and Yb in the high melting point (HMP) rare earth metals Sc, Y and Lu was accomplished by a vapor deposition, diffusion method without crucible contamination. The method avoids the melting of the HMP metals which would introduce impurities from the crucible, generally Ta or W. Plates of the HMP metals were hung from the lid in the upper part of the Ta crucible. The volatile metals were placed on the bottom and the lid welded in place under an atmosphere of helium. By proper selection of thee alloying temperature, the effusion of the metal vapors, through the helium atmosphere was slow enough to permit diffusion to occur and prevent refluxing of the newly formed alloy. Very volatile metals such as Mg required a Knudsen cell with a suitably sized hole to prevent too rapid transfer of the low melting metal. Electron microprobe analysis of a cross-section of the HMP metals showed a homogeneous distribution of the volatile metals. The time and temperature required to obtain a homogeneous rare earth alloy without contamination are given. The use of a Knudsen cell to form magnesium-rare earth alloys is reviewed.

Jan 1, 1992

By Champigny N, Grimley P. H

To a bank that granted his request for a loan, the late American humorist Robert Benchley responded, `I don't trust a bank that would lend money to such a poor risk'. This quotation is unlikely to be the norm among mining companies that secure project financing. However, a poor appreciation of one of the key risks of a mining project, the reserves, often results in disastrous financial consequences. This conclusion is the subject of the discussion and analyses presented in this paper.

Jan 1, 1994

By W. R. Ingalls

THE bases of the work by the committee whereof I am chairman were (1) the abolition of extra-lateral rights and (2) the preservation of the maximum of the existing laws. The matter of extra-lateral rights had been under prolonged discussion among mining men and up to the time when our com-mittee began its work (in 1917) the expression of opinion in every way whereby it could be made known -and those ways were extensive-was only a little short of being unanimous that extralateral rights ought to be abolished. I have not observed important evidence indicating a change of opinion on the subject since 1917. ABOLITION OF DISCOVERY LOGICAL Now, when it be decided that extralateral rights ought to be abolished, there can not be merely a simple change to that effect, but it is found that consequential changes are necessary all the way through the existing laws. Abolition of extralateral rights implies abolition of discovery as a prerequisite to location, for otherwise there would be no legal means for locating claims on the dip of a vein. Quite apart from this consideration, abolition of discovery as a prerequisite to location is supported by other good reasons. Among these are the occurrence of orebodies with no exposure on the surface and which often are hidden at great depth. A prospector who has reason to suspect the occurrence of such an orebody must have legal means for the location of a claim within which to explore, and obviously he may. not be able to make any discovery on the surface sufficient to locate and hold legally such a claim under the terms of the law as it stands at present. As a matter of fact, discovery as a prerequisite to location was abolished by common consent many years ago, not only for the reasons that I have given here-inbefore but also for others. It is highly desirable to revise the mining law in this respect, so that it will conform to the conditions of practice and not require people to perjure themselves in making locations, even if it be for praiseworthy purposes.

Jan 6, 1922

F A. THOMSON, president of the Montana School of Mines, gave an interesting talk on mining schools of the past, present and his ideas of the future before a recent meeting of the Montana Section of the A. I. M. E. He covered the history .of the various mining schools and com- pared the three main types of schools; those attached to or forming part of an endowed college or university such, for example, as' the Columbia School of Mines, the Mining Department of the Massachusetts Institute of Technology and the Mining Department of Stanford University. These resemble in a general way the second class, those attached to the state universities and colleges. The schools of this general type have had varied success.

Jan 1, 1928