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By R. C. Canby

The difficulty of exact neutralization by ammonia of the acid solution obtained in the determination of arsenic by the method of fusion with carbonate of soda and nitrate of potassium, led me to try the effect of neutralization by oxide of zinc. I obtained most satisfactory results, and found a great saving of time. The oxide of zinc being added in excess, there is no delicate testing with lit? mils paper and tedious alternate adding of dilute ammonia arid acid until the proper point is reached. The excess of oxide of zinc, too, seems to hold, from the filter, the gelatinous silica and alumina, which are usually precipitated upon neutralization, and thus to render the washing of the precipitated arseniate of silver almost invariably much more rapid. Except the substitution of the neutralization by oxide of zinc for the more tedious method by ammonia, the details of the process are practically the same as those published by Mr. Richard Pearce, of Argo, Colorado (Proceedings of the Colorado Scientific Society, vol. i.), who shows what very accurate results can be obtained by the fusion process. I have made numerous tests of comparison between the two methods of neutralization, and find that those by the oxide of zinc agree almost exactly with the old method. Increasing the quantity of nitric acid, even to considerable excess, to be neutralized by the oxide of zinc did not affect the precipitation of arseniate of silver. The process may be outlined as follows : Take 4 to 1 gramme finely pulverized ore, and mix in a porcelain crucible with eight to ten times its weight of a mixture of equal parts of carbonate of soda and nitrate of potassium (Kerl. Metallurgische Probirkunst gives 4 to 5 nitre to 14 soda). Gradually bring to fusion and keep so, three to five minutes. Cool. Disintegrate in hot water. Filter and wash with hot water. Acidify the filtrate with nitric acid, and boil to expel carbonic acid and nitrous fumes. Cool. Add an excess of an emulsion of oxide of zinc. The bottom of the beaker should have quite a layer of oxide of zinc, after stirring.

Jan 1, 1889

By G. L. Hopps

Various chemicals, including compounds of copper and lead, were added to a mixture of No. 2 and No. 6 fuel oils that was fired in an experimental furnace. Tests were made to determine (1) the effectiveness of these chemicals in removing soot deposits on probes devised to simulate heat-transfer surfaces in boilers and (2) the effectiveness of the chemicals in preventing the deposition of soot on the probe surface. Test conditions were regulated so that the temperature of the products of combustion adjacent to the probes was in the range of 625° to 700° F. The clean-metal temperatures of the air-cooled probes were comparable with the water-tube temperatures in boilers operated at 40 to 100 p.s,i.g. The dosages of the fuel oil additives used in these tests were generally larger than those usually recommended for most proprietary compounds.

Jan 1, 1962

By Joseph H. Allen

Commercial coke is made to-day in the United States chiefly from the Appalachian, the Illinois and the Colorado coal-fields. The measures of the great Appalachian coal-fields furnish by far the largest proportion, only about 1 per cent. coming from those of Illinois and Colorado. This is not due, however, to a corresponding difference in area. The Illinois field covers about 47,000 square miles in Illinois, Southern Indiana and Western Kentucky. The coal is high in both ash and sulphur, and on this account nearly all the attempts which have been made from time to time to coke it have resulted in failure, so far at least as the requirements of ironmasters are concerned. Nevertheless,. I am able to say from a practical knowledge of this field that the physical structure of the coke is perfect, and

Jan 1, 1893

By Raul Prebisch

El presente texto señala las diversas estrategias para lograr un desarrollo sostenible de la economía latinoamericana. El autor describe el juego de la libre competencia, los acuerdos de competencia industrial y el principio de reciprocidad como elementos que regulan el mercado nacional.

Sep 1, 1964

By K Uchino, M Inoue

Self-potential anomalies are generated by fluid pressure gradient, by temperature gradient or by chemical gradient. On the basis of this principle, a new technique is proposed to locate the fire source of spontaneous combustion of coal by the self-potential method. In order to investigate whether this method can be applied to locate the spontaneous combustion of coal in practice, surveys of self-potential distributions were undertaken in a coal waste pile undergoing spontaneous combustion. The results showed that there is a negative centre of the electrical potential distribution in the measurement area. The potential in this centre is about 140 mV lower than that in the surrounding area. Moreover, the negative centre of electrical potential distribution almost overlaps with the high temperature zone. Therefore, it is concluded that it is possible to locate the heat source by the measurement of self-potential distribution.

Jan 1, 2005

By J. S. Jacobi

Treating copper ores by heap-leaching and similar hydrometallurgical means is a time-honored practice, which was well known even in the 19th century. Later the method lost ground to better ore dressing processes, particularly selective. flotation. More recently there has been a distinct reversion to leaching techniques, particularly for scavenging operations in old mining stopes, in connection with LPF systems, irrigation of tailings dumps and similar situations. These hydrometallurgical techniques will gain further ground because processing is simple and permits better extraction of copper, particularly from low-grade or partly oxidized ores. In the lixiviation of primary ores at some major operations, copper-bearing liquors may undergo re-circulation in heap-leaching arrangements or the ores may be subjected to systematic percolation treatment. The liquors resulting from this source usually are quite strong (above 10 gpl copper) and copper would normally be reclaimed by electrowinning or cementation. These processes fall out- side the scope of this paper which is concerned with recovery of copper from weak 1iquor.s containing from 0.1 to about 3 gpl copper.

Jan 9, 1963

Your Worship the Mayor, Ron McCullough; the Honourable Tony McGrady M.L.A., Minister for Minerals & Energy; distinguished guests, ladies and gentlemen.It's both a pleasure and a privilege to have been invited by the North West Queensland branch of the AusIMM to speak at a forum in Mount Isa to discuss the potential, and more importantly, the development of the great North West. I spent 25 years of my life proudly living and working in this part of the world, marvelling at its riches, exploring its potential, assisting in its development and responding to its challenges.As President of the North West Queensland branch of the AusIMM in the early 1970's I can clearly recall helping to organize a major symposium extolling the geological potential of the region, revealing the extensions of the Mount Isa copper orebody at depth and describing the potential of the then untapped Hilton Mine. Our optimism in the North West so obviously reflected two decades ago remains today.

Jan 1, 1993

By Bernardo Rubio

La unidad de Ucchuchacua de la compañía de Minas Buenaventura produce concentrados de plomo, plata, manganeso. Sin embargo, el transporte y la comercialización de este último, causó problemas para el medio ambiente puesto que se auto combustionaba en los depósitos del Callao y era un peligro para el embarque. Posteriormente, se inicia la lixiviación ácida de los concentrados con la finalidad de reducir el MnS de niveles en dichos concentrados. Dicha implementación como etapa de limpieza, conllevó consecuencias en el agua, suelo y aire, los que fueron mitigados con la implementación de plantas de tratamiento de relave y planta de sulfuro de sodio. En este sentido, el presente texto describe las medidas para eliminar la lixiviación a través del cambio de reactivos y así reducir el impacto ambiental. Para ello, se realizaron investigaciones con diferentes reactivos de flotación para deprimir la alabandita y obtener un concentrado de 200-300 onz./tcs y 2–4 % de Mn (alabandita).

Sep 13, 2001

By E. H. Tenney

A DISCUSSION of the probable future use of coal for power develop-ment involves the study of several basic factors, such as future demand for power, the quantity and availability of fuels in direct competition with coal, the price of coal, and a closely related factor-the efficiency and cost of fuel utilization. Predictions based on purely statistical analyses of past coal con-sumption have definite limitations. For example, statistics showing the relation between coal utilization and total energy consumption from all sources between the years 1890 to 1930 indicate that during that period, the energy consumption per person in the United States increased five times, while the coal consumption per person increased only twice1, and there has been an actual decrease in per capita coal consumption since 1920. Figures such as these, compiled by authentic agencies, emphasize the need for caution in attempting estimates as to the future use of coal, and, incidentally, would seem to offer little basis for optimism in the coal industry. They also suggest the value of analyzing broadly the part played in the past by the related factors of power consumption, competitive fuels, coal prices and the efficiency of utilization. Proper weight must also be given in such a study to the present status and limitations of power-plant developments, and to the question of what the coal industry itself can do to further its own interests and influence the consumption of its product.

Jan 1, 1935

By Bernt Ellingsaeter, Terkel Rosenqvist

IN the silicothermic reduction of magnesia, burned dolomite is treated with high grade ferrosilicon in an evacuated steel retort at temperatures between 1150° and 1200°C. The following reaction is assumed to occur MgO + CaO + 1/2 Si (Fe) - Mg(g) +- & Ca,SiO, + Fe with the equilibrium constant on the basis of thermodynamic data for the substances involved and assuming unit activity for all solid constituents, Kubaschewski and Evans' calculated the magnesium pressure as a function of temperature logp,, (mmHg) = 15.06-1.61 T- log T- 13,16O/T. Pidgeon and King," who measured the magnesium pressure by means of a flow method, found values about three times the calculated ones. This may be caused by uncertainties in the thermodynamic data, but may also be caused by the formation of other reaction products, such as Ca,SiO,, which is known to be the stable silicate in equilibrium with lime. Whatever the exact reaction may be, it is evident that as long as all other factors are maintained constant the magnesium pressure will vary with the silicon activity, viz: p,, = &,. (p,,) ", where (p,,)" is the magnesium pressure by the reduction with silicon of unit activity. In the present investigation, p,,, was therefore measured for various grades of ferrosilicon and their silicon activities were calculated. The experimental method was similar to that used by Pidgeon and King. Briquettes of burned dolomite and Fe-Si alloys were placed in a 1 in. heat resistant steel tube and were heated to 1200°C. By means of a flow of purified hydrogen, the magnesium vapor was swept into a condenser filled with steel wool. From the amounts of hydrogen used and magnesium condensed the magnesium partial pressure was calculated. First a tube of 28 pct Cr steel, and later a tube of Kanthal D (a ferrous alloy with 22.6 pct Cr, 2 pct Co, and 4.5 pct Al), was used as a heat resistant tube. The latter tube showed the best heat resistance. The dolomite used had the following composition: 43.6 pct MgO, 55.5 pct CaO, 0.2 pct K,O + NalO, 0.2 pct Fe,O,, and 0.3 pct insoluble. The ferrosilicons were prepared from 98 pct Si of technical grade (0.7 pct Al, 0.3 pct Ca, and 1 pct Fe) by melting with various amounts of electrolytic iron of high purity. The alloys thus obtained were analyzed on their iron and silicon contents, which added up to between 99 and 100 pct. The amounts of reactants were chosen so that there would always be an excess of the oxides, and the average decrease in silicon content during the experiments would be about 1 pct. Most of the reaction occurred in the part of the reaction mixture facing the gas flow. The change in the silicon concentration in the part facing the condenser was, therefore, negligible. To facilitate the reaction, about 1 pct fluorspar was added to the briquette mixture. Fluorspar does not enter the reaction, but is known to act as a

Jan 1, 1957

By David J. McDougall

"IntroductionThe production of pig iron, wrought iron bars and castings in Quebec during the 18th and 19th centuries has been so closely identified by historians with the Forges du St. Maurice on the St. Maurice River a few miles north of Trois Rivières (Three Rivers), that one is sometimes left with the impression that it was the only iron works that ever operated in the province. There were however, about twelve others, one of which was so completely re-built that it should probably be considered as a separate entity. All but two were constructed after the midpoint of the 1800s, coinciding with the growing Canadian demand for ""charcoal pig"" for railway car wheels and castings for industry, and about half of them were technically, if not economically, successful. The misconception about the Forges du St. Maurice may have come about either because of its long history of somewhat less than continuous production over a century and a half, or a tendency of Quebec historians to concentrate on events in the French-Canadian rather than the English-Canadian milieu, but whatever the reason, the other Quebec iron work s have been generally ignored. All but one of the Quebec blast furnaces could be described as ""preindustrial"" with capacities ranging between three and ten tons per day, the exception being the Radnor furnace built in 1892 with a maximum production of about 35 tons per day and an alleged capacity of 50 tons per day.Until a railway network was completed in the 1880s, the location of all the Quebec iron works except the Grantham Iron works was dictated by close proximity to adequate ore reserves because horse transport was of little use beyond a ten-mile radius. The other essentials of forest resources (mainly soft woods) for charcoal, limestone for flux and water power, were generally available except within a few miles on either side of the St. Lawrence river. Among the dozen iron works established in Quebec between 1732 and 1880, seven used bog iron ore in charcoal-fired furnaces."

Jan 1, 1983

By B. Burke, R. Colquhoun, K. Thomas, R. Walton, D. Fentie

The new Roasting Facility at Barrick’s Goldstrike Mine in Nevada, U.S.A. was developed to process 12,000 tons per day of refractory gold ore. The process consists of crushing, dry grinding, roasting, extensive gas purification, calcine quenching and leaching in the presence of activated carbon. The new plant is integrated into the existing Goldstrike facility, treating ore from both open pit and underground sources. The process design, procurement, construction and commissioning of the Roaster facility was performed successfully over a 3½ year period with peaks of 400 engineering personnel and 950 construction personnel supporting the project. The US$330,000,000 project was completed ahead of schedule and under budget. The commissioning was well planned and proceeded smoothly through a rapid start-up to achieve all primary goals within three months of the start of processing of ore.

Jan 1, 2001

By M. S. Klima, P. T. Luckie

Proper analysis of washabiity data can lead to the development of a maximum yield coal preparation plant flow sheet. Simulations, as simple as spreadsheet mass and water balancing, are important in examining yield maximization and middlings liberation. Key to such attribute tracking flow sheet simulations is the distribution model, expressing the probability of a species reporting to the product stream. There are many such models in the literature. This paper examines a functional form that can represent or fit most of the proposed distribution functions.

Feb 24, 1997

By W. E. Roscoe, H. Agnerian

The contour method can be used to estimate the mineral resources of a mineralized body. It relies on geological interpretation and allows the geologist to determine the plunge of a mineralized ore shoot along the dipping plane of the mineralized body. The technique is best applied to estimate tonnage and average grade of relatively planar bodies, i.e., where the two dimensions of the mineralized body are much greater than the third dimension, such as Archean lode gold vein deposits or mantos of massive sulphide mineralization, based on exploration drilling. For these types of deposits, the contour method can provide a clear view of the “mineralization landscape” with “peaks” and “valleys” along the plane of the mineralized vein. The technique also reduces the “nugget effect” of local high values commonly present in gold deposits. With sufficient drill hole information, the contour method may be used to estimate the tonnage and average grade of individual blocks within a mineral deposit. General procedures for the contour method are described in this paper, along with examples and explanatory notes.

Jan 1, 2002

By J. Arce

Recientemente algunos mineros han empleado métodos instrumentales de operación del subsuelo. Sin embargo, dado el paso del tiempo, las técnicas varían en efectividad, por lo que se hace necesario estar a la vanguardia de los nuevos instrumentos de exploración. En ese sentido, el presente trabajo analiza algunos estudios geofísicos en el pasado, así como sus posibilidades de uso en el Perú. Asimismo se anota lque os métodos de polarización inducida para exploración terrestre prfurida; los de activación neutrónica y fluorescencia de rayos para análisis químico en campo y los de análisis de gas de mercurio para campo y laboratorio, son los métodos que deberán utilizarse en el futuro cercano, así como algunas técnicas de sensores remotos serán especialmente útiles para evaluaciones regionales o continentales.

Nov 20, 1972

By K. Zipf, Z. T. Bieniawski

"An extensive mixed-mode fracture toughness testing programme was conducted on coal from three coal fields. A special mixed-mode testing fixture for coal and other geologic materials was developed together with reliable specimen preparation procedures. Dynamic modulus measurements made on each of the 116 fracture toughness specimens showed that these coals exhibit certain degrees of anisotropy. The fracture toughness testing programme systematically varied the loading rate, specimen orientation and fracture loading mode. Loading rate did not significantly effect the fracture toughness over the quasi-static range tested. Orientation did have a significant effect on measured fracture toughness. In the coals tested, the divider orientation and arrester orientation had higher fracture toughness than the short transverse orientation. Data showed that one orientation could have almost twice the fracture toughness as another. The fracture toughness testing enabled certain evaluations of three mixed-mode fracture theories: maximum tangential stress, maximum energy release rate and strain energy density theory. Due to the extreme heterogeneity of the coals tested, definitive conclusions regarding the best mixed-mode fracture theory are not possible; however, data do tend to support the strain energy density theory. INTRODUCTIONThe major aim of this research is to ·develop a fundamental understanding of how fine· fragments of coal (respirable dust) are generated during a fracture process. In a related paper [l], a hypothesis was presented for the mechanism of fine fragment formation during a generic coal material/cutting tool interaction. In this hypothesis, fine fragments are created during coal material/cutting tool interactions that are best described as general mixed-mode fracture processes. Data are required on the mixed-mode fracture behaviour of coal, the physical character of the newly-created fracture surfaces and the character of the inherent flaw structure of the coal material. Accordingly, a test programme was designed that provided some information in each of these areas. The testing effort seeks to measure critical fracture toughness under mixed-mode loadings as a material parameter characterizing in part the tendency of various coals to generate undesirable quantities of fines and respirable dust."

Jan 1, 1990

By Joseph A. Dos Santos

The Expanded Conveyor Technology, a rationalization of the conventional conveyor technology, allows us to apply the theory and principles beyond the current (perceived) limits. This was first prompted by the writer's advancements in Sandwich Belt High Angle Conveyors. The introduction defines the Expanded Conveyor Technology and outlines the range of applicability for the wide variations in conventional and non-conventional conveyors. The writing deals with the theory and design of sandwich-belt, high-angle conveyors in the context of the Expanded Conveyor Technology, including the equations of friction, hugging pressure and the continuity of hugging principle; curvature constraints and criteria for tension, curvature, trough, and belt construction; and drive and tension analysis, load sharing and traction, including "derived load equivalents."

Jan 1, 2000

By E. M. MacKevett

The only source of uranium ore in Alaska that has been mined commercially is the Ross-Adams deposit, a gently inclined, fusiform orebody in alkali granite in which uranothorite and uranoan thoria-nit? ale the chief ore minerals. In mode of occurrence, apparent genetic association with the granite, and to a lesser extent in mineralogy, this type of deposit is uncommon. The mine is in the southern part of Prince of Wales Island (Fig. 1) at an altitude of about 950 ft on the southeast flank of Bokan Mountain. A steep unpaved road 1 3/4 miles long leads to the dock on the West Arm of Kendrick Bay, which can be reached by boat or seaplane from Ketchikan, some 35 miles to the northeast. The southern section of Prince of Wales Island is covered by dense forests interspersed with swampy tracts of muskeg. Most of the higher peaks support only sparse vegetation, and in areas underlain by alkali granite bare rocky slopes prevail to as low as 800 ft. Numerous fiord-like embayments penetrate this part of the island, and their shorelines provide near-continuous rock exposures. Rainfall is heavy, about 150 in. annually. Throughout the year the climate is relatively mild. History and Production: In May 1955 two members of a Ketchikan prospecting group, Don Ross and his wife, found the deposit while working with an airborne geiger counter. Later they confirmed their discovery by ground investigations. During the summer Climax Molybdenum acquired controlling interest in the property and started exploratory diamond drilling, resuming the drilling on a larger scale in the summer and fall of 1956. Climax began mining in July 1957, shipping the ore by barge and train to the Dawn Mining Co. mill at Ford, Wash. The open pit workings, about 370 ft long, between 25 and 75 ft wide. and 25 ft deep (shown in Fig. 2) were shut down in October 1957. As of September 1958 the pit was still inactive, although a small tonnage of known reserves remains in the southern part. The operators believe the 15,000 tons of uranium ore already produced will average 0.80 pct. GEOLOGY The Ross-Adams mine is within a small stock or boss of alkali granite, about 1000 ft from the southeast margin of the granite (Fig. 3). The area around the boss is underlain chiefly by plutonic rocks of intermediate composition and by metamorphosed sedimentary and volcanic rocks. The oldest rocks in the area probably are the metamorphosed volcanic rocks that are well exposed adjacent to the South Arm of Moira Sound. They are considered by Buddington and Chapin1 to be of Devonian age. These light gray to dark gray rocks mainly represent a layered volcanic sequence. They are commonly porphyritic with plagioclase pheno-crysts in an altered, fine-grained groundmass. The

Jan 1, 1960

By Hans von Michaelis

There has been a renaissance in gold and silver extraction and recovery that has taken place over the last fifteen years, since the price of gold was freed from the $3510~ level. Despite major advances in such areas as carbon adsorption processes for gold recovery, refractory gold ore treatment, crushing and grinding, process control, etc., there still remain several gold and silver mineral processing frontiers. Frontiers related to environmental management present significant challenges especially in the USA. More than ever it is appropriate to optimize total economics by adopting a "systems approach" that integrates mining, mineral processing and environmental management.

Jan 1, 1993

PITTSBURG MEETING The One Hundred and Ninth Meeting of the Institute, for the presentation and discussion of technical papers, will be held at Pittsburg, Pa., Oct. 8, 9 and 10, 1914. This meeting is to be under the auspices of the Iron and Steel Committee, the Committee on Petroleum and Gas, the Committee on Coal and Coke, and the Committee on Non-metallic Minerals. Thirty papers have been secured by these Committees and will be presented at the meeting. These papers will be published in the September and October Bulletins. The Local Committee of Arrangements for this meeting is as follows: SAMUEL A. TAYLOR, Chairman. FRANCIS C. PHILLIPS. GEORGE S. RICE. C. F. V. Rys. KENNETH SEAVER. JOHN S. UNGER.

Jan 9, 1914