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By W. Kuckshinrichs

Metallic raw material flows are characterized by a complex global network of producers and consumers, as well as by a multitude of ecological, economic and social impacts across national boundaries and on different scales. This leads to the need to develop methodologies, which allow identifying obstacles that prevent metallic raw material flows to contribute to sustainable development. From a scientific point of view CRC 525 (Martens 2003) has developed an holistic indicator set consisting of approximately 80 different indicators. This set is taking into account the multi-dimensional character of sustainable development. Moreover the indicators reflect different system boundaries according to different actor levels and decision contexts. The full indicator set is important in scientific considerations and suitable for scientific awareness creation. However, to fulfil the function of a decision support approach for political and economic decision-makers some modifications are of central concern. At first a reduction of the full indicator set by selection of core indicators enables decision-makers to deal with complex issues of contrary economic and societal protection targets. Secondly, as thresholds of indicators justify societal call for action, they are discussed against its political or scientific origin. The proposed methodology is exemplified by indicator-based studies of the material flow of aluminium.

Jan 1, 2003

By J. B. Pullen

THE United Verde mine is in the north central part of Arizona, on the. north-easterly slope of the Black Hills, near the town of Jerome. Ore was first discovered in the district about 1875, and the first mining claims were located by M. A. Ruffner and associates in 1877. In 1888 the late Senator William A. Clark secured control of the property and under his ownership it developed into one of the country's most important copper producers. The property was sold to the Phelps Dodge Corporation in 1935, and since then has been under this Corporation's management. Except for shutdowns caused by general world-market conditions, production has been continuous from 189o to date. GEOLOGY The mineralized zone ranges in area from approximately 12 acres to less than 5 acres. All mineralization occurs in the pre-Cambrian intrusives. The first intrusion, according to geologic records, was the quartz porphyry, which later was intruded by augite diorite. Following the diorite intrusion through a series of intrusions of lesser magnitude, a pipelike mass of massive sulphide, quartz and rock was formed. The diorite forms the hanging wall of this mass, and the porphyry the footwall. Between the footwall and the sulphide a band of chlorite schist was formed, probably owing to metamorphic conditions. Commercial ore occurs along the contact of the schist and sulphide extending into the sulphide, sometimes entirely through the schist, and fingering out into the porphyry. The ore deposit was formed by replacement similar to deposits formed in limestone areas. Faulting and deformation occurred in pre-Cambrian times and again in the Tertiary period, removing approximately 2000 ft. from the top of the main United Verde ore body, forming the United Verde Extension ore body, the only other major ore body in the district. Major development work has shown that the sulphide mass extends to the 3300-ft. level, and diamond drilling below this level has indicated that the mass might extend below the 3700-ft. level, but in a diminished quantity. While many copper minerals exist in the mine, the chief commercial mineral is chalcopyrite. A plan and vertical section of the mineralized zone showing the principal geological features is shown in Figs. I and 2. GENERAL DESCRIPTION AND PHYSICAL CONDITION OF MINE After over 50 years of active production, ore still exists on almost every level of the mine. This condition is due to many causes -mine fires, which broke out as early as 1894, caused the abandonment of certain areas; subsidence and ground movements retarded the cleaning up of others. Furthermore, in the early days there was such an abundance of ore that when mining became difficult it was a simple matter to replace the production by going to a deeper level. Several attempts were made to recover the ore in the fire zone, both by glory-holing

Jan 1, 1941

By J. Tuzson, H. McL. Clark

Introduction Wear of pumps, wet cyclones and pipelines by suspended solid particles will impact their operating economies by limiting their useful life, reducing their reliability and increasing the amount of servicing. Erosion is considered a materials problem. The empirical solution consists of testing different materials in field applications. Such tests are time consuming and expensive. The prediction of localized wear rates, life estimates and appropriate material selection demand a better understanding of the slurry wear process in environments corresponding to those found in working equipment. Key words: Wear, Slurry abrasion, Coriolis erosion tester The slurry wear process Solid particles suspended in liquid generally move with the flow, but such particles deviate under the centrifugal and Coriolis forces encountered in pumps. The concentration of particles will increase, and a solid layer or bed may accumulate if the acceleration is directed against the flow passage wall. Large particles in dilute suspensions may impact the wall. dissipating their kinetic energies and removing material. However, particles smaller than about 11)(1 µm encounter great drag when moving through the liquid. and such par¬ticles have little kinetic energy left when they reach the wall. They cannot penetrate the stagnant boundary layers present in pumps. Therefore, small particles tend to form beds that slide along the wall, removing material by a process that could he called sliding erosion or wet abrasion. Wear by impact erosion from large particles in dilute slurries can he predicted by appropriate analytical and empirical methods. However, laboratory tests and calculations of wear rates that correspond to sliding erosion are more likely to correlate with field experience from wear under similar conditions. Specific energy Data from laboratory slurry erosion experiments have shown that the amount of material removed is approximately in proportion to the energy expended in the erosion process. Thus. the specific energy-energy expended in removing by erosion a unit volume of material-offers a simple, practical measure for the erosion resistance of materials. The concept was found to also apply to sliding erosion (Clark et al.. 1997). Generally, the study of the material-removal process in slurry erosion continues to remain a subject of research. Conceptually, if the flow velocities and accelerations could be calculated in a pump or pipeline, the energy dissipated at the passage walls could also be estimated, and the material removal rate would become known from the specific energy determined by laboratory tests. Slurry erosion testing Laboratory devices made specifically for slurry erosion testing may be grouped into the following: jet erosion devices, slurry pots and the Coriolis test machine (Pagalthivarthi and Helmly, 1992). Jet erosion devices use a slurry pump and nozzle to produce a high-velocity slurry jet that is directed at a flat material specimen, either perpendicularly or at some acute angle. Combined impact and sliding erosion are produced. but the processes cannot be separated, and the wear is difficult to assess except by weighing. Slurry pots consist of a cylindrical vessel containing the slurry of interest. In the slurry pot, test specimens are attached to a rotating arm. The samples are rotated in the slurry and experience local flow conditions that result in combined impact and sliding erosion. Wear depth measurements from detailed laboratory experiments have been successfully correlated with results from an analytical model of the process, and specific energy values have been calculated (Wong and Clark, 1995). In industrial use, the samples are weighed to determine the total material loss. Materials are ranked with respect to some reference material. The Coriolis erosion tester (Tuzson, 1984) consists of a rotor with a central cavity, from which two opposing radial passages lead out (Fig. 1). The slurry is fed to the centerof the rotor in one pass from a stirred overhead tank. The slurry particles are subjected to the Coriolis acceleration as they flow out through the radial passages. The material specimens are mounted into the radial passage walls facing the direction of rotation and are eroded by the particles that are pressed against them as they flow out radially. A narrow groove is worn into the sample within a few minutes, using a few gallons of slurry. Material removal is estimated accurately from profilometer traverses across the wear scar at different locations. The energy dissipated by the particles can be estimated, which leads to a well-defined experimental value for the specific energy.

Jan 1, 2000

The development of economical and effective treatment processes for solid and aqueous waste is a critical issue facing the mining industry today. Cyanide, nitrates and acid rock drainage are environmentally sensitive effluents that require treatment or containment for acceptable disposal. In situ biotreatment processes are an emerging technology (Thayer) for cyanide oxidation, denitrification, sulfide mineral alteration and metal re- mineralization. Biological cyanide oxidation is competitive with chemical treatment processes (peroxide, alkaline chlorination) for process solutions, spent ore and tailings detoxification. Microbial denitrification treats mine waste contaminated with nitrates from blasting, processing or nitrification of the host rock. Bio-alteration of sulfide minerals and metal re-mineralization may present the most cost-effective and environmentally acceptable method of dealing with sulfide tailings and leachate solutions. Field test programs for cyanide bio-degradation and denitrification of spent ore and process solutions were designed and run at two mines. Although the treatment bacteria and the application processes are similar, each waste presented site-specific problems for adapting the biotreatment processes. Some of the site problems include climate, ore geochemistxy, field bacteria production, waste microbiology and application engineering. This paper compares treatment design and results for cyanide oxidation and denitrification in heap detox treatments.

Jan 1, 1992

By H. L. Washburn, W. A. McConnell

There is not a coal preparation engineer alive who would equip his newest and most modern preparation plant with all new and untried pieces of equipment. He may install a few such pieces in which he has great confidence, but he will also spend much time assuring himself that everything else in the plant has been subjected to the test of time. He may arrange these units in a unique manner, but in general, they must have proven themselves elsewhere before he will approve them for his plant. A modern coal preparation plant contains only a few items of processing equipment, the remaining items being devices for materials handling. Consequently, pure automation is almost impossible. Although the main aim of automation is conservation of manpower, it generally results in uniformity of product, lower maintenance costs, and the many intangibles that make a better plant.

Jan 8, 1961

One item of general interest in MINING ENGINEERING Trends, May 1952 gives the wrong impression of the scale of the ilmenite operations in North Carolina It also implies there are known deposits of rutile which "guarantee self-sufficiency for many years" So far as we know this is not true At present, rutile is in such short supply in the United States that the Defense Mineral Authority is encouraging prospecting for new deposits So far none have been found of any consequence and our needs have to be met largely from the deposits near Jacksonville, Fla, and rutile imported from Australia JAY P WOOD VICE-PRESIDENT HUMPHREYS GOLD CORPORATION The reference to self-sufficiency was meant to apply to the ilmenite-bearing sands, not rutile, but improper phrasing failed to make this clear However, the press release that the Glidden Co circulated stated that this deposit of ilmenite was one of the largest in North America -Editor

Jan 1, 1952

By I. H. Warren, F. A. Forward, D. E. Pickett, Ernest Peters, Alvin H. Ross, I. M. Masters, N. P. Finkelstein, R. Derry, A. W. Fletcher

In this section the chemical, physical, and mechanical principles of hydrometallurgical processes are developed and reviewed. Plant practice is not discussed other than to note the metals which are processed using the various systems that are available. These notations will permit the reader to refer to the appropriate section in Part II of the Handbook for specific details on a particular metal or mineral. The equipment used to accomplish the desired unit operation is de¬scribed. Comparative data are presented to illustrate performance characteristics of unit operations, process, and equipment. The economic efficiency of individual processes is outlined. Some of the chapters contain material that is covered in detail in other sections of the Handbook Such chapters are developed only sufficiently to indicate the specific application of the techniques to hydrometallurgical processes. In this section considerable cross-referencing to the other related sections has been done.

Jan 1, 1985

By R. W. Raymond

Alexander Brinton Coxe was born in Philadelphia, Pa., Jan. 19, 1838, the second of five sons of Hon. Charles Sidney Coxe and Ann Maria Brinton. A more extended history of his family and its important relations to the development of the United States will be found in my Biographical Notice of his younger brother, Eckley B. Coxe, published in 1895. It is therefore sufficient to say here that Dr. Daniel Coxe, a clis-

Jan 1, 1907

By Fred C. Bond and

This paper is a continuation of two earlier papers,12 and presents new data on the grindability of various ores and other materials—the results of several years of intermittent research work on the nature of grinding and interpretation of test results. It is divided into five parts: 1. The tabulated results of several hundred grindability tests on a wide variety of ores. 2. A method of correcting screen analyses and calculating from them the surface and other properties. 3. A description of a new method of measuring the "surface energy" of an ore by pendulum impact tests. 4. Test results. 5. A general discussion of the test results and their application to grinding problems. 1. GRindability of Various Ores This part is a continuation of the paper listed as reference No. 1. The method of testing is described in detail in that paper. The sample to be tested is crushed to all through 6 mesh in rolls set at 1/16-in. opening in closed circuit with a screen. Of this sample 700 C.C. is ground dry in a laboratory ball mill under constant conditions of mill speed and ball charge in closed circuit with a screen of the desired size at 250 per cent circulating load. The mill is cylindrical, 12 by 12 in., and rotates at 70 r.p.m. It contains a charge of 285 iron balls weighing 20,125 grams and ranging from 1½ to ¾ in. in diameter. Each test is continued for a sufficient number of periods to establish equilibrium at 250 per cent circulating load, or until the composition of the circulating load is constant for successive periods. Tests are conducted at the mesh size to which the ore is to be ground in practice, and the results are expressed as the net production in grams of screen undersize per revolution of the mill. This is designated as the

Jan 1, 1939

The recent installation of top gas temperature probes in blast furnaces at Australian Iron & Steel Pty. Ltd. - Port Kembla, has provided the means for studying radial gas flow distribution in blast furnace shafts. This paper describes the top gas temperature probes and outlines their development and results of initial studies aimed at obtaining a suitable relationships between temperature profiles and furnace parameters. The effects of various combinations of burden materials have been outlined by the results reported. The use of probes has also helped to clarify the effect of casting cycles on furnace operation leading to increased emphasis on the reduction of the interval between gun-up and drill-out. Areas for future studies are also broadly Outlined.

Jan 1, 1975

By Henry Tobelmann

THE location, mode of occurrence of ore, and preliminary tests leading to the development of the present leaching process and the building of the present plant on the property of the New Cornelia Copper Co. at Ajo, have been described in previous papers presented to the Institute and in the, discussions thereof.1 It is sufficient to say that these tests began early in July, 1912, and were continued to the close of January, 1916; that small tests at Douglas were followed by the construction of a 1-ton plant at the mine; and this was followed by the operation of a 40-ton plant for 14 mo. In all about 15,000 T. of ore were treated experiment-.

Jan 2, 1919

By Nicholas Kyriazi

It is of interest to know how to obtain as high an absorption efficiency as possible from a CO2-absorption canister used in closed-circuit breathing apparatus. In this study the Bureau of Mines found that varying the bed depth and the cross-sectional area of a canister changes its absorption characteristics. In tests using four ,1 rectangular, variable-depth canisters with different cross-sectional areas, the Bureau found that, given a constant weight of the chemical absorbent, LiOH, and a constant COa input, the canisters with a greater cross-sectional area reached C02 levels of 0.5 volume-percent in the effluent gas sooner than did the canisters with a greater bed depth. However, resistance to flow through the canister increases with bed depth, and a trade-off is inevitable. It was anticipated that the efficiency of a canister would increase with increasing intergranular air space approaching the tidal volume of the breathing waveform and then level off at some point under 100 percent. This postulation was partially substantiated. Cylindrical and radial canisters were also tested and compared. It appears that shape is not as important a factor in absorption efficiency as bed depth, since neither canister differed significantly from the rectangular canisters with regard to absorption efficiency values.

Jan 1, 1980

Upon cessation of mining activity open-cast mine pits typically fill with water, forming a æpit-lakeÆ. The water in these lakes, in some instances, contains high concentrations of ædeleteriousÆ material. Containment and/or dilution typically requires an understanding of how stratification in the pit-lake will develop over a long timescale (say 100 years). Vastly different transport rates can develop due to differing hydrogeochemistry, basin morphology and climate. Numerical (computer) modelling is the most likely approach for successful prediction over long times. While lake modelling tools are available, useful numerical modelling requires improved understanding of transport in such systems because they are different to natural lakes in a number of ways. Notwithstanding the effort required to improve our understanding, the modelling provide a means of testing approaches to active management of pit-lakes.

Jan 1, 2002

By B B. Beamish

Long-hole directional drilling for in-seam exploration was introduced to New Zealand at Huntly West Mine in 1989. Following the success of this initial drilling program the Coal Corporation of New Zealand (CoaICorp) purchased its own drilling equipment and proceeded to adopt the technique with in-housetraining. From July 1991 to September 1992 a total of 15 455 metres was drilled at Huntly West Mine. During this period several modifications were made to the drilling technology to suit the ground conditions. The resulting interpretations of the drill information enabled reliable seam definition to be incorporated in mine planning. Since January 1993, the technique has been transferred to the Huntly East Mine to assist with seam definition for the planned development westwards under the Waikato River. The benefits of this drilling technique to coal mine planning are now well documented in Australia and New Zealand as well as other overseas countries. The possibilities of adapting the long-hole drilling technique to hard rock applications has been illustrated recently with successful cross-measure drilling at Huntly East Mine.

Jan 1, 1993

By W. L. Barry

A review of the practices of analyzing for precious metals at the Reno Research Center, U.S. Bureau of mines, is presented. A general description of fire assaying, the physical layout of a fire assay laboratory, and the use of fire assaying in combination with atomic absorption, induction coupled plasma, and emission spectroscopy is reviewed. The combination of techniques significantly decreases the detection limits for precious metal analyses and simplifies the analysis of the platinum-group metals. Methods of protecting personnel from ingestion of lead are also discussed.

Jan 1, 1982

The excavation of ramps and tunnels often requires high-speed development with (or without) the use of high-energy mining equipment such as loaders, dump trucks, TBMs and roadheaders. This high-speed development creates a challenge in terms of providing a safe and productive working environment. For example, heat from continuously exposed surrounding rock, heat from broken rock, heat generated by mining equipment, potential in flows of hot ground water, pollution from associated diesel equipment and the distance of the advancing face from fresh through-ventilation all have to be taken into account when designing ventilation systems for high-speed ramp and tunnel developments. This paper discusses methods of achieving acceptable environments at the face and along the length of the tunnel. The methodology has been successfully implemented in the development of long (up to 20 km) TBM drives in the Lesotho Highlands Project and in mining projects in hot rock using drill and blast methods as well as mechanized methods using continuous miners and roadheaders. The determination of heat loads includes calculation of the heat flow within the surrounding rock, evaluation of the operating cycle of the equipment and the contribution to the overall heat load of the broken rock as it travels out of the tunnel. The determination of heat loads from surrounding rock in new tunnels required a modification of the algorithms generally used for established excavations. The paper also examines the use of, for example, mobile duct and fan systems to ensure that fresh air is delivered to the specific areas where workers are located.

Jan 1, 2000

By J. C. Norman

The boron review did not arrive in time for publication in the June issue. The United States was the world's largest producer and consumer of boron compounds during 1992. The US Bureau of Mines estimated that boron mineral concentrate and chemical production in the United States totaled 1Mt (1.1 million st) in 1992, yielding 521 kt (574,000 st) of B203 for a total estimated value of $333 million. That was about 20% less than 1991 revised production figures, and less in value by $107 million. The United States continues to provide essentially all of its own boron supply while maintaining a strong position as a source of sodium borate products and boric acid to foreign markets. Domestic employment in the mining and beneficiation of boron products in 1992 was about 900 people, the same as in 1991. In 1988, 1250 people worked in the boron industry. The Bureau estimated that total world production of boron in 1992 was about 3 Mt (3.3 million st), or about 1.2 Mt (1.3 million st)of B2O3. World production in 1992 was about equal to revised 1991 levels. US production Mines and processing operations in southern California were the only domestic sources of boron mineral concentrates and chemicals. US producers, in order of quantity of production, included:

Jan 1, 1993

By M. J. Pool, P. J. Spencer

Using liquid tin as the solvent metal, the heats of solution of silver and gold in dilute Ag-Au-Sn alloys have been determined at 723°K by solution calorimetry. From the values obtained, the various enthalpy interaction coefficients in the liquid solutions have been calculated. The self-interaction coefficients Au and Ag values of 2413 and -6322 cal per g-atom in binary Au-Sn and Ag-Sn alloys, respectively. For an alloy containing 0.04 mole fraction Ag, Au is equal to 2443 cal per g-atom, and in an alloy containing 0.04 mole fraction Au, Ag has a value of —8883 cal per g-atom. Ag Au has been determined as —2650 cal per g-atom. ADDITION of a second solute to a dilute binary alloy may cause striking changes in the thermodynamic characteristics of the alloy. As yet, such influences cannot be reliably predicted and it is only by accumulation and critical assessment of data that definite patterns can be established. Solute interactions in dilute solutions were first treated mathematically by Wagner,1 who derived expressions for the Gibbs energy interaction coefficients. For an alloy consisting of. two dilute solutes, i and j, in a solvent s, these coefficients are given by: where yi is the activity coefficient of component i and x represents the mole fraction of solute or solvent. Other interaction coefficients have since been established in terms of the various partial molar thermodynamic properties of an alloy; the definitions of these are summarized in a recent paper by Lupis and Elliott.2 Mathematical and experimental studies of such coefficients have received much attention recently, providing a very useful theoretical background to an understanding of the nature of solute interactions taking place in dilute solutions. One of the definitions to arise from such work has been the extension of Wagner's treatment by Lupis and Elliott4 to include an enthalpy interaction coefficient, defined as. where ?Hi is the relative partial molar enthalpy of component i. ?Hi is related to the relative partial molar enthalpy at infinite dilution, ?Hio, and to the enthalpy interaction coefficients by the expression: Values of ?Hi can often be obtained with a high degree of accuracy by calorimetry, and, if the composition of the alloy is carefully controlled by making calculated solute additions throughout a series of measurements, application of Eq. [2] will enable reliable enthalpy interaction coefficients to be determined. Partial heats of solution must be investigated as a function of solute concentrations down to xi = 0, and, since ? values are obtained from the slope of mi plotted against x, great care must be taken to obtain precise data. The data for binary systems which are presently available often require extrapolation of ?Hi values from compositions as great as xi = 0.05 or even 0.1 to obtain limiting heats of solution. Reliable enthalpy interaction coefficients are thus impossible to obtain from published data for most of the alloy systems already investigated. The aim of the present work was to determine values of Au, Ag, Ag, and Au in the limit xsn -1 for the relatively simple Ag-Au-Sn system and from these results to gain some insight into the possible influence

Jan 1, 1969

By J. A. Flinn

Phelps Dodge’s Morenci copper mine has had six drills, six track-dozers, 16 shovels, two loaders, and 90 haul trucks equipped with either Caterpillar, Aquila, or Modular GPS systems for nearly three years. The Caterpillar Computer-Aided Earthmoving System is an open-architecture system, which allows for inputs to enhance orientation solutions and system functionality. This system has begun a new phase that leads to an intelligent mining system. Optimization techniques of the current system and inputs are reviewed. In addition, some practical issues of implementing new technology in a mining environment have been identified to aid in this new phase.

Jan 1, 2000

By J. Howarth

Two electrochemical processing methodologies have been used to electrogenerate bromine-laden solutions for gold-leaching purposes. In the first process, a laboratory-scale cell in which the anode and cathode compartments were separated by a cation-exchange membrane was employed. The bromine produced by electrolysis of a 4% bromide solution was used to leach gold from a low-grade ore. The pregnant leach solution was then returned to the cell to recommence the cycle. High current efficiencies (90-93%) were maintained over six cycles. In the second process, an undivided hypochlorite generating cell (Chloropac"') was used to generate bromine from a simulated leach solution. Electrolyses were performed on a pilot-scale (100-150 gallons) with solutions containing different levels of bromide ion. The current efficiencies were also high (80-90%) and unaffected by the bromide concentration (over the range 2.5-5%) provided the electrolysis was run to low conversion « 15%). The Chloropac module was capable of delivering 0.6 kg bromine per hour at a power cost of $0.09 per kg. Using these figures, a detailed economic assessment for a 1000 metric tonnes (MT) per day gold ore processing plant was made. Electrolytic regeneration of bromine in a gold leach/recovery circuit dramatically improves the process economics over cyanidation.

Jan 1, 1991