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By G. R. Palmer

The success of future electric vehicles will depend greatly upon the power supply choices made today. Research is presently being conducted by automotive engineers and electrochemists to determine what battery type may be the most promising. Not only are product production and application efficiencies being evaluated but also environmental concerns of reclamation and recycling. Rechargeable batteries using nickel-metal hydride electrodes are strong candidates for these electric vehicle applications. The U.S. Bureau of Mines is investigating hydrometallurgical technology that separates and recovers purified metallic components present in nickel-metal hydride battery scrap. Sulfuric, hydrochloric, and nitric acids are all capable of dissolving the battery electrode alloys given the proper operating conditions. Solvent extraction of the leach solutions using D2EHPA removes iron, and selective precipitation shows promise of recovering the other metals in the H2SO4 and HNO, systems.

Jan 1, 1994

By J. Ji

Oxygen requirement during acidic pressure oxidation of sulphide concentrates can he as high as 800 kg/(m3.h) in the first compartment of an autoclave when the total oxidation residence time is shortened to 30 minutes. To achieve such a high oxygen transfer rate while maintaining satisfactory oxygen utilization, a pilot plant campaign was launched at the Placer Dome Research Centre in 1998 to measure the oxygen mass transfer coefficient in a 5 m3 pressure vessel at a total pressure close to 500 psig with a 30 HP gassing agitator. Maximum oxygen flowrate to the pressure vessel was designed at 3 600 kg/h. In this paper, a great deal of information is provided on the gassing agitator, pressure vessel. measurement procedure and results. Without oxygen sparging, the oxygen mass transfer coefficient is 2 600 h-1 with a mixing power input of 5.0 kW/m3 in solution. With oxygen sparging, the oxygen mass transfer coefficient increases to 3 500 h-1 with a mixing power input of 4.0 kW/m3 in solution.

Jan 1, 2004

By D. B. Dow

This report on methods employed for dehydrating oil-field emulsions, is the second of a series prepared as a result of a study of oil-field emulsions recently completed by the writer. The first paper2 dealt with the factors responsible for the formation of emulsions. A third paper will discuss the physical chemistry involved in the formation and resolution of such emulsions. In the early development of the oil fields of Pennsylvania, no emulsion troubles of any consequence were encountered, nor to any serious extent in the oil fields of other Eastern States: However, with the development of fields west of the Mississippi in Oklahoma, Kansas, Texas and California, where heavier oils of different characteristics were found, the problem of dealing with cut oil soon became of great importance.

Jan 1, 1925

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012

By Collin L. Stewart

A summary of the results of a limited subsidence monitoring program at Cyprus Amax Coal Company&apos;s Shoshone Mine No. 1 in the Hanna Basin of south central Wyoming is presented. The monitoring program was designed to meet regulatory requirements for confirmation of subsidence predictions made in the mining permit. The longwall panels were 380 ft to 600-ft wide. Mining heights varied from 11 ft to 13.5 ft. Gate road development included three-entry and two-entry head and tail gates. Overburden depth varied from 150 to 945 ft. The coal seam and overburden dip at approximately 11 degrees. The overburden is very low to low strength mudstone and carbonaceous shale with low to moderate strength, silty sandstone interbeds. Panel W/h ratios varied from subcritical to supercritical. Smax was 0.9 of the mining height. The subsidence ratio was about 0.6 for subcritical width. The draw angle on the up-dip side averaged 20 deg. The draw angle on the down-dip side averaged 12 deg.

Jan 1, 1995

By W. R. Hardwick

This paper describing the mining methods of the Inspiration Consolidated Copper Co. is one of a series being prepared by the Bureau of Mines on mining methods and costs in various mining districts of the United States. The story of mining at Inspiration is of particular interest because, after 127,812,000 tons of low-grade copper ore were successfully mined, the mining method was changed from block caving to open-pit. As the open pit became deeper, many features of the former block-caving operation that were exposed elucidated concepts of the mechanics of caving that previously had been assumed but not observed. The conversion to open-pit mining was accomplished by unique combinations of equipment and the introduction of ingenious engineering and operating practices that have extended the expected life of the mine for many years.

Jan 1, 1963

By T. Crivits

"Phase equilibria in the ‘Cu2O’-‘Fe2O3’-SiO2 system, the base slag system in copper production, were recently determined. However, the addition of MgO, commonly present in the slag, drastically changes the phase equilibria in this system. The present study focuses on the phase equilibria in the ‘Cu2O’-‘Fe2O3’-MgO-SiO2 system in equilibrium with metallic copper.Recently, an experimental procedure has been developed that resolved a number of experimental difficulties. This procedure has been successfully applied to characterise several complex industrial copper slags. It includes a high-temperature equilibration followed by rapid quenching and electron probe X-ray micro-analysis (EPMA). The methodology was adapted to the present system and used to determine the liquidus at SiO2 saturation and in contact with high-MgO phases in between 1100 and 1250 °C in Cu2Orich slags.The results indicate a maximum solubility of MgO in the system at 1200 °C of 5 wt%. The boundary line between tridymite and spinel lies 3-4 wt% closer to the SiO2 apex for every 2 wt% MgO added. These new data on the high-copper slags are important for optimisation of the direct-to blister"

Jan 1, 2014

By Al Holmes

"In a recent survey of Canadian work values, 89% of the men surveyed and 97% of the women surveyed described the work in a mine as ""not at all auraetive"", Work in a mine, in fact, was rated by both sexes as the least attractive of all of the types of work surveyed. Confronted with this prevailing attitude, Canada&apos;s mining industry starts out with two strikes against it in its bid to attract and hold on to its fair share of available work force.Behavioural scientists have, for decades, been seeking answers to the questions:• ""Why do people work?""• ""Why do people choose a particular occupation?""• ""Why do people choose a particular organization?""• ""Why do people leave one organization for another?""• ""Why do some people stay in an organization?""• ""Why do some people work harder than others?""Their answers to these questions, although tentative and often contradictory, are being used by more and more organizations to solve people problems. Few industries can afford to ignore them, least of all, perhaps, the mining industry.Consider the following developments:I. General Motors and the United Auto Workers turn around the car assembly plant in Tarrytown, New York in seven years from the plant with the poorest labour relations and production record to one of the best under a program referred to as ""improving the quality of work life.""2. Shell Canada and the Oil, Chemical and Atomic Workers have designed a new petro-chemical processing plant in Sarnia using a set of principles that seek to optimize both the social and the technical system."

Jan 1, 1980

By C. G., Fink

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution.

Jan 1, 1950

By A. L. Mackie

Mine water from base metal mines is generally characterized as having high concentrations of heavy metals and low pH, resulting in the need for treatment prior to discharge to receiving waters. In this study, two high-rate clarification processes were evaluated at bench-scale: the high density sludge (HDS) process and sand-ballasted flocculation. High-rate clarification processes generate larger, denser flocs which settle more quickly than those formed in conventional flocculation processes. The HDS process uses recirculated sludge in order to seed floc formation, whereas ballasted flocculation uses microsand. Both of these high-rate processes require the addition of quicklime or hydrated lime to increase pH and allow for the formation of insoluble metal hydroxides, which can then be removed in the clarification stage. Previous research has shown that cement kiln dust (CKD) can effectively replace quicklime in conventional sedimentation processes for metals and acidity reduction to meet discharge guidelines (Mackie & Walsh 2012). CKD is an alkaline by-product of cement manufacture that has fine particle sizes and varying free lime concentrations depending on the manufacturing process. The lower solubility (i.e., free lime content) of CKD requires larger doses of material to be added to reach treatment pH targets for metals precipitation. The purpose of this study was to evaluate the treatment efficacy of high-rate clarification processes for mine water treatment, compared with conventional sedimentation, at bench-scale with conventional (i.e., lime) and novel (i.e., CKD) pH adjustment additives. Results of the study showed that all treatment processes (i.e., HDS, ballasted flocculation, and conventional sedimentation) were able to reduce target metal concentrations to well below Canadian guidelines (i.e., total zinc and total nickel < 0.5 mg/L, total copper < 0.3 mg/L) using either CKD or lime. Additionally, mine water samples treated with CKD generated lower sludge volumes than those treated with lime (i.e., 50 versus 100 mL for conventional sedimentation and 100 versus 200 mL for HDS) even with increased concentrations of solids introduced during treatment. This is most likely due to slower neutralization rates when using CKD, due to its lower solubility, as well as finer particle size. The sand-ballasted flocculation process was able to reduce final turbidity in CKD-treated samples while the HDS process did not when compared to conventional sedimentation, making the ballasted flocculation process preferable for reducing final solids concentrations in CKD-treated mine water.

Aug 1, 2013

By Chauncey Berrien

THE Hawkesworth detachable drill steel shank and bit were invented by A. L. Hawkesworth; while he was a mechanical foreman for the Anaconda Copper Mining Co., at Butte, Mont. Mr. Hawkesworth died on June 16, 1925, at the time that his invention was practically a proved success. The first application for patents was made by him in November, 1918, and the bit is now being manufactured under patents issued in 1922 and 1923. The credit, for its development in the early stages belongs to A. L. Hawkesworth, Roy S. Alley, Harry A. Gallwey, E. J. Bowman and various officials of the Anaconda Copper Mining Co. Later improvements, manufacturing problems and the direct usage in the mines were originated and perfected by the mechanical department under C. D. Woodward, E. R. Borcherdt, head of the Rock Drill Equipment Department, Robert E. Kelly of the Mechanical Department, and various operating department heads of the Anaconda Copper Mining Co. The author wishes to acknowledge the assistance of these officials in the preparation of this paper.

Jan 1, 1930

By O. D. Gonzalez, H. A. Wriedt

Alloys ranging from pure iron to pure nickel were saturated with nitrogen gas at 918°, 999°, and 1217°C and analyzed. The solubility of nitrogen at 1-atm pressure was obtained as a function of nickel content for the whole range of iron-nickel alloys and the temperature dependence of solubility is shown for the experimental alloy compositions. The heat of solution and the entropy of solution of nitrogen in the alloys as func-tiom of composition up to 41 pct Ni are given. 1 HE acquisition of more exact thermodynamic information for systems composed of iron with various alloying elements continues to interest ferrous metallurgists. The interstitial alloying elements, especially carbon, hydrogen, and nitrogen, comprise a field of particularly intense study. A recent investigation of carbon solubility in Fe-Ni alloys held at 1000°C in gases of fixed carbon activity showed an unpredicted minimum in the solubility near 72 pct Ni.1 The present investigation was undertaken to see if a similar anomaly in solubility existed for nitrogen in Fe-Ni alloys. The solubility of nitrogen in ? iron at known nitrogen activities has been measured several times.&apos;-&apos; Corresponding information for the solubility of nitrogen in solid Ni and Fe-Ni alloys is not available. Juza and sachsze9 reported that metallic nickel dissolved 0.07 pct N in equilibrium with Ni3N at 445°C. This result was regarded as dubious by Turkdogan and Ignatowicz10 who found less than 0.0004 pct N in nickel specimens equilibrated at 600°C with ammonia-hydrogen mixtures having fugacities of N2 gas up to 35,000 atm. Such fragmentary reports indicate only that nitrogen gas has a very much lower solubility in nickel than in iron. MATERIALS A purified iron from Battelle Memorial Institute was used for solubility measurements. This grade contained more than 99.95 pct Fe, the highest content of any measured individual impurity being 50 ppm for each of As, C, Cu, and Pb. The nickel and iron-nickel alloys, supplied by the International Nickel Co., contained 0.02 to 0.04 pct C, 0.17 to 0.19 pct Mn, 0.04 to 0.08 pct Si, < 0.01 pct P, <0.03 pct S, and <0.20 pct Co as principal impurities. The Fe-0.59 pct Mn alloy was of zone-melted quality, the highest concentration of any individual impurity being 15 ppm Al. The "prepurified" grade of nitrogen gas from Matheson Co. had a nominal nitrogen content of 99.996 pct. An "electrolytic" grade of hydrogen gas from National Cylinder Gas. CO. in which the principal impurity is water vapor was admixed with the nitrogen to prevent oxidation of these specimens. This grade was preferred to a purer grade because the presence of some oxygen helps in suppressing contamination of the specimens, for instance, by silicon from the porcelain furnace tube. EXPERIMENTAL PROCEDURE The specimens were equilibrated in vertical tube furnaces through which a 99 pct N2-1 pct H2 gas was passed at ambient pressure. For the 915", 918", and 999°C runs, a wound-resistance furnace was used, and for the 1217°C runs, a furnace with a tubular silicon carbide element was used. The temperature control system on both furnaces was similar: a Weston "Celectray" controller with a modulator, responding to the electromotive force of a thermocouple with its hot junction in the furnace, switched the furnace current between high and low settings. The temperature distributions in the working zones of the furnaces were determined with calibrated Pt/Pt-10 pct Rh thermocouples. The overall uncertainty in temperature was estimated to be ±3° at 915° to 999°C and ±5° at 1217°C . Consideration of the small temperature coefficients of the equilibria studied, together with the error limits in the method of analyzing for nitrogen, showed that further refinement in temperature uniformity would give no improvement in resultant accuracy. The reactive gas was generated by mixing together "prepurified" nitrogen and "electrolytic" hydrogen directly from cylinders commercially supplied. The flow rates of nitrogen and of hydrogen were fixed by setting with bleeders the pressure drops across the individual calibrated flow meters of constant resistance. For any given alloy, the solubility of nitrogen at 1-atm pressure (% N) was obtained from the analyzed nitrogen content of equilibrated specimens (% Na)according to Sieverts&apos; law, thus

Jan 1, 1962

By Ahmad Hemami

A working code is developed to simulate the forces that are involved in the process of penetration of a bucket into bulk media during loading and excavation. The result of this work can be integrated with the simulation software that many manufacturers of heavy earthmoving machines introduce for training purposes. The simulator programs for machines such as backhoes, loaders, LHDs and the like, used for operator training, are usually only based on the kinematics of the machine. As a result, there is no indication of the effect of the medium when the cutting tool of such a machine touches the excavation material. This is like moving the machine in the air. Feeling the resistance force of medium to cutting by a bucket or blade during loading and excavation is more realistic, both mentally (by vision) and physically (feeling resistance in pedals and levers). The results from force simulation can be used by feedback in creating simulated resistance in these training gears, similar to what is done in flight simulators for aircrafts. In addition to serving for the above purpose, the results of this work can be used as a tool for examination and verification of the effect of a control policy for automation of loading and excavation of bulk media. So far no commercial product has been introduced that has such a capability, despite some extensive research on the subject.

Aug 1, 2013

By Arthur L. Bishop

INTRODUCTION Purpose The in-situ leach method for uranium extraction is a relatively new and innovative method of uranium mining. In 1975, the first commercial in-situ facility began operation in south Texas. Since that time numerous other operations have been initiated as either pilot or commercial ventures. Considerable literature has been published that deals primarily with generalities of the process or environmental concerns. Several federal agencies have published documents which do not reflect the true operating or environmental nature of the in-situ leach method of uranium extraction. From an environmental standpoint, this is also evident in the promulgation of rules and regulations. Hence, the purpose of this paper is to present experience with an environmental concern--non- production zone excursions--such that the industry and the regulatory agencies will gain greater insight devoid of preconceived ideas and misconceptions. General Process Description In south Texas, in-situ leach mining is utilized to extract uranium from permeable sandstone ore deposits 61 to 213 meters (200 to 700 feet) below the surface. Uranium is present as an insoluble uranium oxide. In the in-situ or solution mining technique, anoxidizing lixiviant is injected into the formation through injection wells. The solution reacts with the insol uble carbonate complex. This soluble uranium complex is produced at recovery wells, each containing a submersible pump. During production there is a constant sweeping of lixiviant through the formation from the injection wells to the recovery wells. Injection and recovery wells can be arranged in any of a number of geometric patterns dependent upon ore body configuration, aquifer permeability, and operator preference. Submersible pumps in the recovery wells pump the uranium rich pregnant solution to the initial processing facility. Monitor wells surrcsund the pattern area and are screened in appropriate stratigraphic horizons (production and non-production zones) to detect any lixiviant migration that may occur (Fig. 1).

Jan 1, 1980

By S. M. Matthews, D. J. Maconochie, L. G. Alexander, V. H. Tillmann

Case studies of the behaviour of large open stopes at the New Broken Hill Consolidated Mine, Broken Hill and the CSA Mine, Cobar, N.S.W. are considered. Deformations were measured by multipoint rod extensometers in sufficient detail to note the phases of rock behaviour, from intact through to rock-fall. In one case readings were obtained from a zone of stress failure in which two bumps, felt as ground tremors, occurred. In this case noise and stress were also monitored. Deformations were analysed in relation to previously measured in situ rock stress, and conclusions drawn about the degree of conformity to, and the areas of departure from, elastic model behaviour. Attempts to describe the growth of instability utilize reduction factors of the apparent modulus, a magnification factor for the apparent Poisson&apos;s ratio, and a correlation between progressive noise count and displacement. Monitoring itself is seen as an aid in determiing the final dimensions of stopes and pillars. One large stope, of intermediate dimension 80 m, was mined essentially without change of plan, whereas a change in mining plan was necessary in other stopes. Aspects of interest to mine planners, and areas where futher research is needed, are indicated.

Jan 1, 1981

By M. J. Langley

Zinc ores were first discovered in Tennessee in 1856 at Jefferson City where a deposit of oxidized ore became known as the Mossy Creek Mine. From that time until 1913 small scale attempts at prospecting and mining were made in various parts of the district. The actual systematic development of the zinc deposits dates from 1913 when the American Zinc Company started operations at Mascot. Six mines are in operation by three companies and a seventh mine is being developed by a fourth company. The total daily production from the field is 11,000 tons of crude ore, which grades from 3 to 6 per cent zinc. Most of the ore bodies are large and ramiform, resembling asyrmetrical networks in which the ore shoots form channel like branches with areas of non-comercia1 rock, called blank islands. Most of the orebodies are adapted to large scale mechanization.

Jan 1, 1962

By John A. Breslin

This publication provides an historical overview of research undertaken by the U.S. federal government over the last 100 years to improve the health and safety of our nation?s miners. Federal research efforts began with the establishment of the U.S. Bureau of Mines (USBM, or the Bureau) in 1910. They have continued over the past century, even after the Bureau?s closure in 1996. It is hoped that this publication will give the reader an appreciation for the work of mining health and safety researchers over the past century, and of the miners served by this research. Although not a comprehensive history, this report highlights the key organizational changes made within the Bureau and the federal government that affected mining safety and health research. Some mention is also made of Bureau research not directly related to mining health and safety. Note that the work classified as safety and health research has varied over the last century. For example, before 1970 the Bureau separated mining research and safety and health research. At that time, mining research included ground control and methane drainage because they had direct implications for mine safety. Explosives research was also reported separately from health and safety, even though permissible explosives research was obviously related to safety. Therefore, where budget figures from the Bureau are mentioned in this report, it is often not possible to separate safety and health research from other types of research. This history is generally chronological, with a few exceptions. Because of their prominence and direct links to Bureau research, most of the Public Health Service mining studies completed before 1970, when NIOSH was established, will be discussed in a single section, even though the work spanned many decades. Likewise, for convenience, the brief histories of the Bureau?s mining research centers are located in one section.

Feb 1, 2010

The comparatively low winter rainfall, exposure to heavy salt laden coastal winds, and the consequent high evaporation rate, are important considerations in the rehabilitation of the Maslins Beach Sand Pit. The deficit of rainfall over evaporation is assessed at 1085 mm per annum. Such a coastal environment complicates the establishment of plants. The endemic flora found on the Sand Pit environs is mainly low wind-planed shrubs and mat plants. The dunes near the coast support an association dominated by Atriplex cinerea, Spinifex hirsutus, Scirpus nodosus, and Olearia axillaris. The coastal cliffs carry a more diverse vegetation dominated by Beyeria lechenaultii and Eutaxia microphylla. Overburden is used to develop a new landscape to screen operations, batter final faces, and cover rubbish at the nearby Council dump. The early overburden dumps were built with little regard for stability, but the more recent practice of using scrapers has resulted in more stable dumps. The erosion problems created by poor compaction have been controlled by contour banks, diversion drains, bitumen lined run-off drains, and hay mulching.

Jan 1, 1976

The Yilgarn Block of Western Australia presents (figure 1) a number of problems for conventional diamond exploration based on heavy indicator mineral sampling. These problems are due to the geology and unique geomorphological development of the Yilgarn Block.Essentially the Yilgarn Block is a pene- plain developed on a craton composed of Archaean intrusive granitoid rocks with meta- morphosed greenstone; which, apart from regional uplift, has not been tectonically disturbed since planation by glaciation in the Permian. Therefore since the early Plesozoic the Yilgarn Block has been subjected to terres- trial weathering conditions. Bettany et al., (1984) identify two phases of particular importance in the development of the present landforms: 1. Periods of lateritization during the Tertiary which result in the ~lassi~al laterite profile (figure 2). Duricrust indurated : Fe and Al oxides Mottled zone : Clay and Fe oxides Saprolite or pallid zone : leached clay grading into fresh rock. 2. Subsequent periods of aridity and semi- aridity during which laterite development was truncated and reworking of laterite Occurred.

Jan 1, 1988

By W. D. Hall, M. Norris, J. R. Henke

Dewatering wells producing iron-rich water experience rapid declines in yield and drawdown due to the formation of ferric (Fe3+) hydroxide deposits in well screens, pump intakes and riser pipes. Precipitation is caused by a combination of dewatering-promoted iron oxidation and iron oxidizing bacteria. Physical and chemical well rehabilitation techniques, as well as alternative well-construction and well development techniques, were evaluated in this study. The addition of acid downhole feed systems to dewatering wells that are prone to iron encrustation can, in many cases, prolong their operational lives up to 500% that of unacidified wells.

Jan 1, 1992