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By Tasuku Fuwa, John Chipman

Equilibrium data on the reactions of gases with carbon and oxygen dissolved in liquid iron are reviewed and correlated. A source of error in oxygen analysis of graphitic samples is exposed. New experimental data on the oxygen content of high -carbon iron in equilibrium with carbon monoxide indicate that the activity coefficient of oxygen is decreased by additions of carbon. The carbon-oxygen product decreases slightly with increasing carbon content. In recent years a number of investigations have been reported dealing with the equilibria between carbon and oxygen in liquid iron and gases containing carbon oxides. The laboratory study of these reactions dates back to 1931 with the publication of a paper by Vacher and Hamilton' on "The Carbon-Oxygen Equilibrium in Liquid Iron". The principal object of this study was to obtain data on the reaction shown by Eq. [3] below; their data and others by vacherZ permit evaluation of the other equilibrium constants as well. Subsequent studies have been reported by Matoba, Phragmen and Kalling and by Marshall and Chipman.5 The equilibria may be expressed by the following three equations: C + CO,= 2CO;Kl = Pc° [1] 0-+CO = CO,;K2=-P co, "0.PCO c + O = CO; K3 = In the equilibrium constants, ac and a0 are taken as equal to [% C] and [% 0] respectively in the infinitely dilute solution. At finite concentrations an activity coefficient is introduced such that ac =fc [%C], and so forth. It is to be noted that these equations represent only two independent relations, the third being derivable from any two. Richardson and Dennis have determined the conditions of equilibrium in reaction [I] at temperatures of 1560" to 1760°C. Their results have been confirmed by Rist and chipman7 who have shown how the data may be extended to cover the entire range of liquid compositions at temperatures from the eutectic up to 1760°C. An approximate confirmation has been reported by Fuwa and chipman.' These investigations also established the activity coefficient of carbon which was shown to increase rather rapidly with increasing concentration. For the very dilute solutions the value of Kl is expressed in the equation: log^i = - 7280/T+ 6.65 This equation leads to a value of Kl = 430 at 1540° C in excellent agreement with the average value of Marshall and Chipman.5 It is shown as line 1 in Fig. 1 together with the experimental observations. In the case of reaction [2] the direct experimental results can be supplemented by observations on the corresponding reaction with hydrogen, namely reaction [4]:

Jan 1, 1961

By Wang Mingshu

The pile foundation is a kind of advanced foundations in the filled or soft soil. In this paper, through the actural engineering of coal dressing plant of Western Opencast Coal in Fushun built on the mining dump with large diameter pile foundation, the construction method and mechanics analysis of pile are given. Unless it is in following stadge, the stability of pile cannot be lost due to its small rigidity. The analysis shows that pile foundations of large diameter ellipse section can decreased hotizontal displacement to 60% ?70% of that of equal section an in the design of a single pile and a single column, the ellipse pile and manual dig hole are most favourable. So a large amount of concrete can be saved.

Jan 1, 1991

By A. C. Noble, D. E. Ranta, J. W. Mustard

Skarn deposits present many unique problems in estimating ore reserves, including difficulties arising from the complex character of the mineralization and intricate ore body shapes resulting from structural complexity. Mineralization within skarns occurs in metasomatically altered carbonate horizons produced by magmatic hydrothermal fluids emanating from intrusive stocks. Deposit formation is controlled by both the presence of favorable host rocks and by proximity of these host rocks to a mineralizing intrusion. Ore controls must be defined to account for abrupt changes in grade that occur between miner- alized and unmineralized horizons. Gradational grade changes within the mineralized zones must also be defined in terms of skarn type and included barren rock to assist in reserve estimation. Defining mineralized limits can be further complicated by faulted, rotated, or folded strata affecting the morphology of an ore body. The MacTung copper-tungsten exoskarn deposit, located along the Yukon-Northwest Territories border in Northwestern Canada exhibits a number of unique properties that preclude a simple mathematical approach to ore re- serve estimation. This deposit is used to demonstrate methods for modeling geologic controls and geostatistical properties for a skarn deposit.

Jan 1, 1992

By Jin Kim, Jerry C. Tien

Water is still the most economical and popular means of controlling dust underground. It is a process that captures dust by bringing water droplets into intimate contact with coal particles. Wetting agents, also known as surfactants, can be added to greatly facilitate such a process since they tend to reduce the interfacial tension between the coal particles (usually hydrophobic) and the liquid. The surfactants used in the study were first chosen on the basis of their HLB (Hydrophile-Lipophile Balance) value, and later tested in order to select the right type and amount of surfactants to give the best performance. Both static and dynamic tests were later conducted using different types of surfactants to examine their respective wetting effectiveness on coal particles. Experimental results show close correlation with the theoretically calculated collection efficiency that is based on a horizontal tunnel and a solid-cone water spray.

Jan 1, 1993

By R. S. Fowkes

The degree and manner of packing of bulk materials influences all phases of their loading, such as by a front end loader or a dragline, and their mechanics of flow, such as through a binhopper or an ore pass. The most important quantity in analyzing the handling of a bulk material is its shear strength which depends primarily on the same parameters as those that determine the packing state. Some of these are size, size distribution, moisture content, particle shape, particle orientation, and cohesion. The variables that affect the packing state arc vibration, pressure, intensity of deposition, velocity of deposition, and, when the material is confined, container used. The analysis of packing by a number of investigators has been done almost entirely with spherical particles. Most of these studies have dealt with monosized spheres. There is scant information on particles with angular shapes. Since most of the investigations by far have been concerned with ceramics and powder metallurgy, the particle sizes and ranges of size distribution have been small compared to those generally found in mining after fragmentation.

Jan 1, 1974

By V. I. Lakshmanan, D. A. Mackie

"1. INTRODUCTIONIn the past two decades, low-grade gold and silver ore bodies in the United States have been exploited by heap leaching, primarily with sodium cyanide solutions. This method has proven to be a viable alternative to conventional milling due to its low capital and operating costs. Successes have been made, particularly in Nevada, where ores are well oxidized and the climate is conducive to this method. in recent years, heap leaching has been tried in northern latitudes with some success, however, in using this method, operators face more severe limitations than do their neighbours to the south.This paper evaluates the limitations of heap leaching with particular emphasis on northern climates and introduces an alternative method to recover precious metal values in a continuous vat. This proprietory technology, known as the Mackie Vat Leaching Jig, shows promise, with improved gold recovery and potential to operate in cold climates.2. WHAT ARE THE LIMITATIONS TO HEAP LEACHING?Heap leaching of non-refractory ores is subject to the following limitations:1. Minimum amount of free gold and nuggets in the ore.?. Minerology of the ore--accessibility of gold to lixiviant.3. Minimum particle size and size distribution of crushed product to allow percolation of lixiviant through the heap.4. Minimum amount of clays or clay-like slimes that can cause coating of ore particles and channelling of lixiviant.5. Minimum strength of ore particles or agglomerations to allow economic height of heaps to be built.6. Amount and suitability of real estate.7. Amount and type of precipitation.8. Ambient temperatures.9. Possible poorer lixiviant diffusion.10. Possible lower oxygen content in dissolved cyanide solution with higher heaps, particularly with ice and snow cover."

Jan 1, 1989

By Francis J. Fratttali, Verda McLendon, Stanley J. Green

"INTRODUCTION During the first phases of the war emergency the shortage of aluminum prompoted the Bureau of Mines to investigate methods for using low-grade bauxites of high silica content and also clays as raw-material sources of this strategic metal. The Bayer process treats low-silica bauxites to provide the industry with a major portion of the purified alumina, which contains very low percentages of silica and other impurities. One of the methods investigated in the laboratories of the Bureau of Mines for low-grade materials is the lime-soda sinter process, which was studied on a pilot-plant scale. In this process, the alumina content of the alumina-bearing minerals Bs made water-soluble by sintering the raw material with limestone and soda. Simultaneously, the siliceous material is rendered insoluble. The sinter is extracted with an alkaline liquor, and the resulting extract liquor is treated as follows to recover the alumina: (1) Autoclaving with lime to remove silica as a zeolitic complex and (2) treatment with CO2 to precipitate alumina as the trihydrate (A1203.3H20). Figure 1 is schematic flow sheet of this process.As the process is cyclic, it is necessary that nearly all of the soda and alumina remaining in the plant liquors after carbonation be recovered. Upon passing through one cycle, these liquors contain 14 to 15 percent NaCO3 2 to 5 percent NaOH, 1 to 3 percent A1203, minor amounts of silica, and, with certain materials such as Pennsylvania diasporic clays, 0.5 to 1.0 percent Na2S04. Approximately 50 percent of the Na20 in these liquors must be returned, as soda ash, to the dry-grinding and raw-materials blending operations. Previous work (6)5/ on sulfate-free solutions demonstrated that two methods for recovering Na20 were feasible, namely: (1) Salting out Na2C03.H20 by evaporation of the carbonated solutions and (2) crystallizing Na2C03.10H20 by cooling the concentrated carbonated solutions."

Sep 1, 1947

By C. L. McKenzie

American Girl Mine is located in the Cargo Muchacho Mountains in the southeastern Imperial Valley of Southern California. Production from the current open pit mine and heap leach recovery system began in early 1989. Previous mining and gold recovery took place commencing in 1987 at the Padre Madre site, situated adjacent to the American Girl site to the southwest. In mid-1990, a 790-tonne-per-day underground gold mine and mill went into production. Approximately 6,500 troy ounces of gold per month are recovered from the combined open pit underground mine operation. Copper in the form of Azurite [Cu3(CO3)2(OH)2] and Malachite [Cu2CO3(OH)2] are abundant in the mined ores (Henshaw, 1942). The high solubility of these minerals in caustic cyanide solutions has a negative impact on carbon adsorption and electrowin processes. This paper presents the results of monitoring programs, process chemistry, and control changes introduced at American Girl Mine to abate production complications in the refinery and measures taken to minimize solution gold losses in the adsorption circuit(s).

Jan 1, 1993

By Jens Classen, Thomas Kurth, Karl G. Holter

High performance sprayed concrete equipment installed on two 9.4 m diameter hard rock TBMs enabled a continuous sprayed concrete lining for the entire contour in both tunnels to be performed concurrently with the advancing TBMs. Innovative layout of the sprayed concrete arrangements comprised ring beam constructions each with two independent spraying robots. Each of the spraying robots were independently connected to sprayed concrete pumps, as well as a high capacity concrete logistics system on the backup. The mix designs focused on long open-time, excellent pumpability and tough requirements on strength development. The achieved output capacities of the sprayed concrete amounts to an average of 15 m3 per hour. Peak capacities of 24 m3 per hour have been realized.

Jan 1, 2003

By O. Mellgren, A. M. Gaudin, P. L. De Bruyn

In the January 1956 issue: TP 4137B. Adsorption of Ethyl Xanthate on Pyrite. By A. M. Gaudin, P. L. de Bruyn, and Olav Mellgren. P. 65. Since P. L. de Bruyn is now a member of the AIME, the word "associate" should be removed in describing his status. The address of the third author, Olav Mellgren, should read: 74-2 Chingola, N. Rhodesia. P. 68, second paragraph, last line: the word "300-fold" should be replaced by "3000-fold." Also in the January 1956 issue: TP 4158B. Energy Transfer by Impact. By R. J. Charles and P. L. de Bruyn. The authors wish to express their disapproval of the omission of the abstract from the article, since they believe that an abstract fulfills a very important function in every paper.

Jan 1, 1957

By E. L. Piper

Natural graphite has been known for many centuries, having first been reported as a distinct mineral form by Gessner in 1565. At that time, graphite was used extensively as pencil "lead" because of the ease with which it marks paper. It is a black, unctuous material found as flakes, lumps, or needles in scattered locations throughout the world. The less crystalline, or "amorphous", natural graphites are thought to have been formed from coal under conditions of high temperature and pressure. The more crystalline varieties, such as those mined in Ceylon, probably were precipitated from molten solutions or were pyrolyzed from gaseous carbon compounds. Recognition of the good thermal and electrical conductivity of graphite, together with its highly refractory nature, led to an increasing number of appli¬cations for this material. Clay and pitch bonded natural graphite has been used in crucibles, refractories, foundry facings, and other high-temperature appli¬cations. These forms constitute the most important current uses for natural graphite in the United States. Other products containing natural graphite include batteries, lubricants, pencils, brake linings, etc.

Jan 1, 1973

By S. K. Bradford

For years past I have traveled in quest of promising mining-properties, over almost impassable mountain-trails to remote places in the mining-regions, usually many miles from an assay-o5ce. If, upon examination, the fornlation and the ore-deposit appeared favorable, a quick determination of the value of my samples was necessary, in order that I might take intelligent action with reference to the acquisition of the property. A journey with my samples to civilized regions often meant weeks of delay, and perhaps loss of opportunity. How many, under similar circumstances, have returned with their assay-results from such a journey, only to find that some audacious speculator had optioned" the property! True, a first payment could have been made and the chances taken on the results; but experience has taught that rich-looking ore is not of necessity valuable. Personally, I would not hazard a ten-dollar bill on any property without first determining by assay the value of the ore. To carry the usual complete assay-paraphernalia over such mountain-trails was impracticable by reason of the loss of time involved, the great expense of transportation (charged -

Jan 1, 1911

By A. Kontopoulos

The Olympias Mine in Northern Greece is producing an extremely refractory gold-bearing arsenical pyrite concentrate, containing on the average 41 3 S, 40 3 Fe, 10-12 3 As, 25 ppm Au and 35 ppm Ag. During the process selection stage, more than a dozen alternative technologies? were considered and an in-depth analysis was prepared for the three most promising, ie roasting, pressure oxidation and biological oxidation. Detailed capital and operating cost estimates were prepared, based, where appropriate, on laboratory and pilot-plant tests. A number of criteria was used for process evaluation and selection, including capital and operating costs; environmental impact, gold' recovery, stage of development, etc. Based on the above evaluation, the Sherritt Pressure Oxidation Process was finally selected. A detailed description of the process selection stage, supported with laboratory and pilot-plant test results on many of the processes considered, will be? presented.

Jan 1, 1989

By Oren C. Baptist, Eliot J. White

Samples of four reservoir sands having different degrees of water sensitivity were subjected to several laboratory tests to determine differences in capillary behavior attributable to clay-mineral effects. The degree of water sensitivity was estimated by the difference between gas and water permeability. Unsaturated pore volumes determined with mercury injection were comparable to irreducible water saturations determined with the semipermeable bar-rier method only for the non-sensitive sands that contained small amounts of non-swelling clay minerals. Irreducible saturations were independent of salinity of the water, which suggests that most residual water is adsorbed 0.7 a film over solid surfaces and that internal retention by clay minerals is relatively insignificant. The water-sensitive sands imbibed water to higher saturations than did non-sensitive sands, and this result is believed to be a combination of the effects of clay minerals and preferential wettability; however, the relative importance of each of these effects is riot determinable. Thus it is concluded that the semipermeable barrier method is the best of the laborafory methods used for estimating formntion water .saturations in the sands studied. INTRODUCTION This investigation is a continuation of studies of the role of clay minerals in petroleum production in the Rocky Mountain area. Previous work has shown large differences in gas and water permeability in numerous reservoir sands; these water-sensitivity effects observed in the laboratory have been correlated with well behavior in the field, and the degree of water sensitivity imparted to reservoirs by the various clay minerals has been determined.'.' The effect of interstitial clay minerals on formation water3 saturations is not so well known. It has been reported that formation water saturations probably are higher in clayey than clean sands,' but this effect has not been evaluated in the laboratory, and the relative effect of the various types of clay minerals on formation water saturation has not been determined. The clay-mineral groups of most importance to this study and to petroleum production in general are kaolinite, illite, and montmorillonite. The minute layers of montmorillonite are loosely bound to one another so that water enters between them, causing great expansion of the particles. Kaolinite and illite do not exhibit interlayer hydration, but they do immobilize considerable amounts of water owing to their large surface areas, which are of the order of 15 to 97 m2/gm of clay.5 The four Wyoming sands used in this study were selected to represent a wide range of water sensitivities. These sands, with the number of wells and fields from which the samples were obtained, are: Second Frontier, five wells in two fields; Newcastle, six wells in one field; Tensleep, two wells in two fields; and Lower Muddy, five wells in one field. EXPERIMENTAL METHODS AND PROCEDURES Water-displacement data were obtained by the semipermeable barrier method," using both fresh water and brines having either 16,500 ppm sodium chloride or calcium chloride. A displacement pressure of 35 psi was found to be sufficient to obtain the practical irreducible water or brine saturation (IWS, IBS) in most samples. Mercury-injection data were ob-tained with equipment and pro-cedures similar to those described by Purcell.7 Exceedingly high pressures are required to attain complete mercury saturation by this method; however, since saturations in most samples change very little with large pressure increases above 1,000 psia, the maximum pressure used was 1,400 psia. To facilitate comparison of mercury-injection and water-displacement results, it is convenient to express mercury-injection data in terms of unsaturated pore volume. The abbreviation, (100 - SHg)min, is used to denote the pore volume unsaturated by mercury at 1,400 psia injection pressure. Gas permeabilities, ki, were deter-mined by the method proposed by Klinkenberg.8 Methods of determining types and amounts of clay minerals by X-ray diffraction analyses, as well as methods of determining water permeability, have been described previously.' The imbibition characteristics of

Jan 1, 1958

By Petter Östberg

Having brought with me to this meeting a couple of "Mitis'' wrought-iron castings, I have found that they attracted a great deal of attention from steel manufacturers, and especially from those experienced in making castings, among whom some have said that they felt inclined to "unhesitatingly dcclare their manufacture an impossibility," if they had not seen the samples. The consequent demand for explanation of the method of manufacture has been SO great that I accept with pleasure the request by the President to address the meeting on the subject. My object in this address shall be only to explain the main features of the manufacture, referring those who take more interest in the matter to Mr. Th. Nordenfelt's paper, read before the British Iron and Steel Institute, reprinted in many American papers, and containing both a historical sketch of the inventions and many interesting details. As the manufacture of castings from steel by others is, at least to some extent, a success, I shall, in my explanations hereafter, refer to wronght-iron, although our mode of manufacture is equally applicable, with corresponding advantage, to steel of any temper. The successful manufacture of castings depends upon several very important matters, besides the necessary skill of the workman. You must have a suitable metal as raw material; you must have an eacient and suitable furnace for smelting, so as not to injure the metal; you must be able to handle the metal in a suitable way, from the time it is ready in the furnace until it is poured into the moulds; you must have a suitable moulding material. I claim that in every one of these different branches we have made great

Jan 1, 1886

By F. W. Smith

This paper is based largely on a study of experimental data obtained by the Bureau of Mines in its comprehensive 25-year survey of the carbonizing properties of American coals. Although the Bureau was interested in and conducted carbonization research-from time to time ever since it was organized in 1910 (1),4/ no systematic studies of the coke-, gas-, and byproduct-making properties of American coals were undertaken until 1927, when the American Gas Association appointed an advisory committee (2) to cooperate with the Bureau in developing equipment and techniques to obtain-data for the accurate assessment of the behavior of coals on carbonization. It was found, in general, that small-scale laboratory tests were unsuitable for the complete evaluation of the coking properties of coal; hence, larger pilot-plant-scale equipment was designed and used (3). It was decided that the scale of the test should be large enough to determine both the yield and quality of the products and yet small enough to maintain adequate control of the process variables (4). These considerations led to development of a carbonizing retort and furnace-of 80 to 200 pounds of coal capacity, suitable for operation at various temperatures up to 1,100° C. (2,0120 F.) and equipment for recovery and measurement of gas and byproducts. This apparatus and the standardized procedure for its operation became known as the Bureau of Mines-American Gas Association (EM-AGA) method or retort (5).

Jan 1, 1955

W. P. Blake, Shullsburg, Wis.: I desire to express my admiration of Prof. Posepny's memoir, and particularly of the charming manner and spirit of the introduction. With respect to his mention of the ore-deposits of Missouri and Wisconsin, reference may be made to my paper presented at this meeting (Trans., xxii., 621)) showing the existence of dislocations and breaks in the bedding, and their apparent close relation with the localization of the ore-deposits as claimed by Dr. James G. Percival, and also so claimed by Dr. Jenney in his paper before us (Trans., xxii., 171). I have in my paper given reasons for believing that the zinc- and lead-ores in the strata above the compact Trenton limestones were formed by lateral secretion and concentration from above downwards, substantially as shown by Prof. J. D. Whitney, and not by the ascent of solutions through the fissures, as Prof. Posepny (p. 304) seems inclined to believe. In regard to the contemporaneity of the ore and the rocks, and in favor of a later introduction of ore through fault-fissures, Prof. Posepny (p. 310) cites the influence of these fissures. In my paper, already referred to, I have endeavored to show how faults may have influenced the deposition of ore without being themselves channels for the flow of mineral solutions, and how they may have caused the contemporaneous formation of metallic sulphides from sea-water in the body of a forming rock; the faulting fissure being formed at an early period in the foundation rocks, and probably continuing to be a plane of break and movement in the deposits of later formation.

Jan 1, 1894

By J. L. Holman

The Bureau of Mines is investigating recovery of Ni, Co, Cr, and other metals from mixed contaminated supera110y scrap. The scrap is melt-refined and cast into anodes for electrodeposition of recyclable Ni-Co alloy. Melt oxidation using roasted superalloy grinding sludge as oxygen source can divert the Cr to the slag but with excessive Ni-Co loss. Melt oxidation-carburization or direct melt carburization retains -95 pct of the Ni-Co in the anode alloy. With direct carburization, -90 pct or more of the Cr and other refractory metals report to the anode alloy, largely as carbide phases insoluble in electrolysis. Electrorefining data relate parameters such as controlled cathode potential, Fe and Cr impurities, pH, and compartmented cell use, to current efficiency and Ni-Co deposit quality. Recovery of -90 pct of the Ni-Co in the scrap can be achieved. Preliminary experiments to recover Cr, W, and other metals from the anode sludge and other byproducts are discussed. 347

Jan 1, 1987

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016

By L. D. Jaffe

IN 1945-1946, the author measured temper brittle-ness in ingots of varying composition prepared by remelting SAE 3135 bar stock under vacuum. Since other investigators1-" have been referring to this hitherto unpublished work, belated publication seems worthwhile. Steel in 7 lb batches&apos; was induction melted with nickel additions in a magnesia crucible under a pressure of 10 microns of Hg or less and cast into a 2 in. diam chill mold. The compositions of ingots A, B, and C prepared in this way are shown in Table I; the vacuum melting lowered carbon, manganese, sulphur, and nitrogen content. Ingot B was homogenized 24 hr at 1095°C; ingots A and C were not homogenized. Blanks, M in. square, were cut from each ingot, austenitized 1 hr at 870°C, water quenched, tempered 1 hr at 595"C, and water quenched. Half the blanks from each ingot were given an embrittling treatment of 50 hr at 455°C and water quenched. A few specimens, embrittled and unembrittled, were finally heated 1 hr at 580°C and water quenched. Charpy specimens machined from the blanks were V-notched on the side closest to ingot mid-radius and paired as to radial position in the ingot, one of each pair having received the embrittling treatment and the other not. Specimens were broken in a standard impact machine at various temperatures, the same temperature, in general, being used for both bars of a pair. Fig. 1 shows the results. It is evident that temper brittleness, as measured by the increase in temperature of transition from brittle to tough failure introduced by the 455°C treatment, was decreased but not eliminated by reducing carbon to 0.006 pct, manganese to < 0.004 pct, and nitrogen to 0.001 pct. In another study," temper brittleness was apparently eliminated by -reducing carbon to 0.003 pct, with 0.80 pct Mn and 0.0015 pct N (ingot D)." • Analyses given for carbon below 0.02 pct were made by Jensen method; for nitrogen, by Kjehldahl method. Values quoted else-where&apos;-&apos;." for carbon content of ingot C and for nitrogen content of ingot D were obtained by conventional combustlon and by vacuum fusion methods, respectively, and are considered much less accurate. The 580°C final treatment removed previous em-brittlement (ingot B particularly), indicating that this was "reversible embrittlement."" Metallographic examination of ingot C with 1 pct nital etch revealed only ferrite; ingot A had carbide spheroids uniformly distributed in a ferrite matrix. With ethereal picric acid plus zephiran chloride etchant.&apos; no differences between embrittled and un- embrittled specimens of ingots A, B, or C were noted. Fracture of C and D below the transition temperature was predominantly transcrystalline, with traces of intercrystalline, in both embrittled and unembrittled conditions. The corresponding fracture of unembrittled B was mixed transcrystalline and intercrystalline; of embrittled B, predominantly intercrystalline with some transcrystalline areas. . . . Acknowledgment The efforts of J. C. Leschen, formerly of National Research CO~P., in preparing the ingots are acknowledged with thanks.

Jan 1, 1956