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By T. R. Cass, M. R. Achter

A technique for measuring the creep and rupture strength of nickel specimens bonded by sintered oxide layers has been developed for the investigation of the role of grain-boundary oxide in the oxidation strengthening of nickel during creep at 817 °C. Prom the inverse dependence of the rate of bonding on the thickness of the starting oxide, it is suggested that the rate of diffusion of Ni++ through NiO is the controlling process at the start of sintering. Cornparisons of the creep and rupture strength and of the microstructure of sintered couples with conventionul creep specimens suggest rupture in nickel is prevented by load-bearikzg, ikltergranular layers of oxide. A number of recent investigations have shown that at high temperature and low stress the creep-rupture strength of nickel and nickel-base alloys may be much greater in air than in an inert gas or vacuum.'-7 For example, at 817°C and 2500 psi, nickep failed in vacuum in 48 hr but not in air after 4000 hr, and a Ni-Cr-A1 alloy5 at 1038°C and 3000 psi failed in vacuum in 4 hr but not in air after 731 hr. Fig. 1 is a typical creep curve in air for materials experiencing this pronounced environmental strengthening. A common feature of these curves is the entry into a third stage of accelerating creep, concurrent with the for-

Jan 1, 1962

By H. M. Day, C. H. Mathewson

THE constitution of the system silver-mercury has attracted the attention of many investigators during the last two decades, but since their results are for the most part in poor agreement, there is little need for a review of their individual contributions. It remained for the very careful thermal and microscopic investigation of Murphy' in 1931 to give the constitutional diagram in its present and unquestioned form, which is shown in Fig. 1. He devised methods for taking cooling curves on alloys under high pressures and for the microscopic observation of alloys which contained liquid mercury as a structural constituent at ordinary temperatures. The compositions of the intermediate phases were confirmed and supplemented through X-ray analyses by Preston2 and Stenbeck.3 According to Murphy, at 276° C. silver is able to dissolve 44 to 45 weight per cent of mercury, which may increase at lower temperatures to about 50 per cent. Preston concluded that the saturation boundary occurred at 46 ± 2 per cent at 100° C. From the values reported in the literature, these are the only ones that may be accepted as lying even in. the right region. PREPARATION OF ALLOYS The silver used in the present investigation was supplied by the United States Metals Refining Co. through the courtesy of the Committee on Industrial Uses of Silver and, since a complete spectrographic and chemical analysis was furnished, no attempt was made to purify it or to further establish the impurities present. The analyses reported by the company are shown in Table 1. Milligan4 has found that the magnesium content is probably less than 0.0005 per cent.

Jan 1, 1938

By Jia Ma, Lu-De Qiang, Zhi-Chao Liu, Chun-Feng Li, Guang Li, Bao-Bin Tang

"At present, research on the surface chemical properties of uranium minerals is very scanty, which restricts the research progress of uranium ore flotation process research. The research aimed at exploring the surface characteristics of two common uranium minerals and providing basis for flotation process to enrich uranium minerals in ore. This paper selected pitchblende and uraninite as the object of study, which are widely distributed in uranium deposits. We chose out the pure minerals of pitchblende and uraninite from different ores collected from different uranium deposits. By means of Zeta potential test and X-ray photoelectron spectroscopy (XPS) test, a preliminary study on surface characteristics of the pure minerals of pitchblende and uraninite was conducted. And the significance of the change of Zeta potential, the elements composition and valence state on the minerals surface for flotation was discussed. The research shows that, the Zeta potentials of pitchblende and uraninite in pure water are negative mainly when the pH value varies from 2 to 11, which maybe a result of the difference of ionization capacity between two kinds of oxy-compounds on the surface of minerals. On the surface of pitchblende and uraninite, the metal elements are mainly U, Th and Pb. U is mainly in the form of UO2, Th is mainly in the form of ThO2, and Pb is mainly in the form of Pb and PbO. Based on the surface characteristics of pitchblende and uraninite, we can select process and reagents appropriately in uranium ore flotation.INTRODUCTION Globally, the major challenges associated with exploitation of low grade ores are about finding economically feasible processes for reducing the mass of gangue minerals (Filippov et al., 2012). Among the beneficiation technologies of low grade uranium ores with complex minerals assemblage, flotation is the common process which is used to reduce production cost and eliminate the acid-consuming minerals (Li et al., 2016; Liu et al., 2015)."

Jan 1, 2018

By G. L. Oldright

This paper is the third1 of a series of five papers that is to appear on smelting in the lead blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace be direct experimentation, and to correlate the behavior of the furnace at various times with the main factors governing the operation of the blast furnace, and metallurgical losses. ACKNOWLEDGEMENTS The writers wish to express their appreciation to the management of the international Smelting Company at Tooele, Utah, for their kind cooperation which made possible the assembling of these data.

Jan 1, 1929

By Yang Guangqing, Shao Jiugang, Zhang Jianliang, Wan Dan, Fu Yuandi, Guo Hongwei

"Resource of metallurgical coke is becoming scarce, and although coke can be partially replaced by pulverized coal injection, there are many restrictions for further increase in coal ratio. Mixed charge of ore and lump coal from top to replace more coke was studied in this paper. Softening-melting property of the burden was affected by charge of lump coal. Softening-melting properties of mixed charge of ore and coke, mixed charge of ore and lump coal were tested respectively. Results show: the property of the burden mixed with coke is superior to the burden mixed with lump coal; lump coal would not deteriorate softening-melting property of the burden and some of them can even improve softening-melting property of the burden. Top charge of lump coal would not deteriorate softening-melting process, and this should be a new way to increase coal consumption to decrease coke rate.IntroductionThe blast furnace is still the predominant process for the reduction of iron ore and will probably remain so for the next decades. Metallurgical coke is becoming scarce and expensive, so the cost of hot metal can be decreased by reducing the consumption of metallurgical coke[l]. Coke can be partially replaced by pulverized coal injection, currently the highest rate of pulverized coal reached 266kg/tHM, most of blast furnace PCR is about 150kg/tHM, and it is very difficult to further increase of PCR. Nut coke is charged into blast furnace mixed with iron ore, not only for improving utilization of metallurgical coke, but also for lowering the coke rate. Presently the majority of blast furnaces in the world use nut coke although its amount is very different: from 10-20 to 70--100 kg/tHM and more[2-4].The effect ofnut coke in blast furnace is extensively researched, and the main conclusions recommend: to improve gas permeability of cohesive layer in blast furnace, to promote reduction of iron burden, protect metallurgical coke from the solution in the shaft due to higher reactivity of nut coke. There is no special requirement for the strength of nut coke[5-8]. Nut coke is also used for sintering fuel, which may lead to the shortage of the nut coke charging into blast furnace. So lump coal mixed with iron ore is considered to be charged into the blast furnace, not only to reduce the cost of grinding coal, but also to increase the use amount of coal."

Jan 1, 2013

By Abdolreza (Reza) Osouli

Determining the roof stability condition of underground coal mines in the Illinois Basin is sometimes very challenging. The roof stability of Illinois mines are mostly affected by two types of shales: Anna Shale and Energy Shale. These layers are sometimes weak in parallel bedding when subjected to horizontal stresses. The roof rocks in the Illinois Basin are are typically more moisture sensitive than the other coal fields. In this study the geotechnical properties of some of the shale units as well as limestone layers will be presented. The geotechnical properties of roof rocks consist of moisture content, unconfined compressive strength, slake durability, indirect tensile strength, and point load tests (Axial and Diametral). The correlation of indirect tensile strength versus diametral point load strength as well as unconfined compressive strength versus axial point load test are explored and discussed. These correlations will help in identifying the roof mass index and planning appropriate roof control measures. This study also evaluates the application of CMRR rock mass index for an Illinois coal mine.

Jan 1, 2014

By Richard J. Haslinger, C. Mark Rebagliati, James L. Oliver

Abstract - Exploration at the Specogna gold deposit has identified a geological resource of 65.0 Mt grading 1.63 g/t Au, which equates to 3 million ounces of contained gold. This resource is hosted in a low-sulfidation epithermal deposit of Miocene age that is localized along the northwesterlytrending Sandspit fault. The fault has juxtaposed Late Cretaceous mudstone of the Haida Formation to the west, with Late Tertiary coarse clastic sediments and lesser andesitic volcanic rocks of the Skonun Formation to the east. A plagioclase porphyritic dacite dike intrudes the Haida mudstone and Skonun sediments along the fault. Gold mineralization, in hydrothermal breccias, veins and stockworks developed mainly in Skonun sediments and dacite. These are formed in an 800 m long zone that roughly parallels the Sandspit fault. The gold zone is funnel-shaped in cross-section, approximately 300 m wide at surface, 220 m above sea level, and narrows to approximately 50 m, at sea level. The deposit lies within an elongate zone of moderate to intense hydrothermal alteration that, at surface, extends over a known area of approximately 2 km2. Its western extent is bounded by the Sandspit fault. There is an asymmetric alteration zonation, with a core of silicic-potassic (adularia) and smectite-illite clay alteration that is bounded to the east by argillic alteration. Similar zoning defined by the distribution of metals reflects the position of the main feeder conduit. Mineralization of altered wallrock is dominated by 1% to 4% auriferous pyrite and marcasite. Gold and silver occur as electrum; individual silver minerals have not been identified. Other sulfides are rare, and are identified only microscopically. The mineral suite is typical of low-sulfidation epithermal systems. Gold occurs in early, multi-phase, variably bladed and banded quartz veins and breccias, which are cut by barren, single phase, drusy quartz veins.

Jan 1, 1998

By Caroline Olsen

The objective of this study was to achieve Zn activation control in an industrial Cu flotation circuit treating a complex Cu-Pb-Zn-Au-Ag sulphide ore at the LaRonde Division of Agnico-Eagle Mines Limited (Québec, Canada). In order to provide process relevant results, a laboratory testing methodology was developed to duplicate plant operational parameters. The action mechanisms of ZnSO4, TETA (triethylenetetramine) and NaHSO3used as depressants in order to limit ZnS activation were examined. Laboratory flotation tests with and without Cu2+ions (the ions responsible for ZnSactivation)were performed. All depressants showed equal or better flotation performance relative to baseline tests. For example, in the presence of Cu2+, the Zn recovery reduced from 32.2% to 17.5% in the copper rougher concentrate after adding ZnSO4(with a dosage of 50 g/t). TOF-SIMS analyses confirmed the relative decrease in surface Cu in the samples treated with ZnSO4and TETA. For the case with TETA, this indirectlyindicates the formation of a copper TETA complex in solution, thereby reducing available Cu for transfer. The TOF-SIMS and XPS data indicate that the addition of ZnSO4and NaHSO3resulted in an increase in surface metal hydroxides and SO3 on ZnS grains inhibiting both Cu and collector attachment.ZnSO4 was subsequently tested with success in the LaRonde concentrator. The addition of 40 g/t ZnSO4 at the conditioning (or cleaning) stage led to a 2% reduction in Zn content in the Cu and PM concentrate. Recently, improvements towards the control of copper sulfate addition in the downstream Zn flotation circuit resulted in the reduction of Cu2+ in process water. As this ?cleaner? water is recycled for Cu and PM flotation, the addition of ZnSO4 is now used only as required.

Sep 1, 2012

By R. E. J. Putman

The past ten years have witnessed substantial development of electronic equipment for execution of process control functions. The methodology of giving instructions to the data-handling system and the organization of the system, both the equipment and instruction coding taken together, have developed simultaneously. Examples of the technology specific to the mineral processing industry can be cited. Approaches to system design developed for the Pinto Valley concentrator incorporating slave and master data processing have been described by Arney, and his associates (1974). Madge (1970) has described the hierarchical systems employed at the operations of Cominco Ltd. The Kennecott Garfield smelter is controlled by a system of microprocessors linked to a general purpose data processor (Marchant, et al., 1977). These systems provide innovative approaches to couple advancing technical capability in electronic data processing to the objectives of process management. The current state of the art described in this chapter is certain to require updating in the 1980's with the advances in technology anticipated.

Jan 1, 1979

By Yizhong Yuan, Dao Li, Nannan Xue, Tao Liu, Yimin Zhang

A new multi-stage counter-current circulation leaching process for extracting vanadium from stone coal was proposed, and the main factors on multi-stage counter-current circulation acid leaching process were investigated. The results show that the vanadium recovery could reach 86% under the conditions of sulfuric acid concentration of 4 M, liquid to solid ratio of 2 mL/g, temperature of 95 °C, reaction time of 60 min, mean particle size of 125 µm and circulation acid leaching stage of three. The losses of vanadium in acid leaching solution appeared during the four-stage acid leaching process. The strong adsorption performance of new formed KAl(SO4)2(H2O)12 crystal was main reason.

Jan 1, 2014

By F. W. Cox

Exhaust emissions were measured from 25 aircraft turbine engines using Jet A fuel. Analytical apparatus, procedures, and results are described. Carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and aldehydes were measured at engine operating modes representing power levels used in airline operation. Carbon monoxide, hydrocarbon, and aldehyde emissions were highest at idle and lowest at takeoff; oxides of nitrogen were lowest at idle and highest at takeoff. Of the total oxides of nitrogen emitted, nitrogen dioxide constituted from 10 to 100 pct, depending on the exhaust gas temperature. Engines retrofitted with smoke-reducing burner cans produced less carbon monoxide, hydrocarbon, and aldehyde emissions, and slightly more oxides of nitrogen then engines with standard burner cans.

Jan 1, 1972

By H. H. Power, Charles R. Houssiere

THE development of effective and dependable methods for drilling through the so-called "heaving-shale" horizons, particularly in the Gulf Coast area, is believed to comprise a major contribution to drilling technology, and to the task of finding and developing our undiscovered oil pools. Many mechanical remedies have been proposed and are in use in troublesome areas for combating heaving shale. However, in conducting a research program it was concluded that the physical and chemical properties of shales should be investigated, and the effect of added chemicals on such properties determined. As a preliminary step, the effect of chemicals on bentonitic suspensions was determined in accordance with recent contributions in the field of ceramics. The most plausible theoretical explanations for the behavior of the clay minerals involved are offered in the paper that follows. It is hoped that subsequent investigation of actual shale from troublesome wells will be aided by the initial work done on bentonitic suspensions of known composition. INTRODUCTION Formations variously designated as "heaving shale," "sloughing shale" and "caving shale" impede and may even preclude drilling of oil wells, particularly in certain parts of the Gulf Coast. In a previous paper1 it has been stated that the development of effective and dependable methods for drilling through these troublesome beds is believed to comprise a major contribution to drilling technology, and to the task of finding and developing our undiscovered oil pools. Since the attack on the heaving-shale problem by mechanical means was principally a matter of field investigation, it was concluded that a research program should be concerned with the physical and chemical properties of heaving shales, and the effect of added chemicals on such properties. It was realized that a study of shales required an advanced knowledge of the behavior of the individual clay minerals. A thorough review of the literature led the authors to the conclusion that very recent contributions2.3 in the field of ceramics furnished the most plausible theoretical explanations for the behavior of clay minerals. Accordingly, these fundamental ideas will be used in an attempt to explain the behavior of more complex systems whose composition and replaceable ions are known. In order to obtain comparable results it was deemed important to select an easily procurable clay of uniform characteristics. Accordingly, Wyoming bentonite, which is marketed under the name of "Volclay,"* was used for the preliminary investigations. The chemical analysis reported by the distribution is given as follows:

Jan 1, 1941

By James Gardner

IN 1923, Oklahoma took second place as an oil-producing state; whereas in 1922 it was the leader. California surpassed it, in 1923, by nearly 100,000,000 bbl. In 1923, Oklahoma produced, according to statistics of The Oil & Gas Journal, 165,013,685 bbl., or an increase of approximately 10 per cent. over the preceding year; the increase in California was approximately 90 per cent. The number of wells drilled in Oklahoma and the results of the two years are contrasted in the following table from data published in a preliminary bulletin by the U. S. Geological Survey. 1922 1923 Oil wells 4,149,68%. 3,515, 60% Gas wells 571, 9 %u 587, 11% Dry holes 1,428,23% 1,731,29% Total wells 6,148 5,833 The initial production from wells drilled in Oklahoma in 1923, according to The Oil & Gas Journal, was the largest in the history of the state, being 1,277,936 bbl. It has been 32 years since oil development began in the state, last year being the largest in the amount of production. The production of the past year would have been considerably greater were it not for the shutdown order in the Burbank field and curtailment of production in the Hewitt and Tonkawa pools.

Jan 3, 1924

By Ronald D. Hill, Elmore C. Grim

1. Potential groundwater pollution resulting from large-scale surface mining in western states should be evaluated. 2. Criteria should be developed for the design, construction, operation, and abandonment of sediment ponds for maximum removal of suspended solids. 3. Methods should be developed for reducing suspended solids discharges from surface mines to less than 30 milligrams per liter. 4. A manual should be developed in the form of guidelines for sediment and erosion control planning and implementation. These guidelines must be designed to cover all phases of the coal surface mining operation (i.e., before, during and after mining). 5. A mine road manual should be developed for use by surface mine operators and State and Federal Agencies. Erosion, water control, and dust control should be covered in detail. 6. The block-cut, head-of-hollow fill, and mountain-top removal methods and techniques of contour mining should be evaluated, designed, and ultimately demonstrated in steep, mountainous terrain. Designs should be prepared for single and multiple seam applications. The demonstrations must show that these mining systems will secure rapid achievement of reclamation require¬ments and provide maximum, safe, economic coal recovery in an environmentally safe manner. 7. A Blasting Manual should be developed for use by industry and enforcement agencies. Stress should be placed on how to keep vibration levels and air blast pressures well below accepted safe criteria. Also, methods that can be used to control noise should be listed. 8. Investigations should be conducted on the effect of continued vibrations from blasting on structures that are near quarries. 9. Additional guidelines need to be developed for sampling and analysis of overburden material and associated coals for trace elements and noxious strata. Samples are extremely sensitive, and the source and manner of their collection, handling, storage, and treatment, as well as the techniques of analysis, need to be developed and described. This information can be used to predict possible future problems.

Jan 1, 1974

By J L. Mauk

 Broken Hills is an adularia-sericite epithermal Au-Ag deposit, hosted in flow-banded rhyolites and overlying rhyolitic pyroclastic rocks in the eastern Hauraki Goldfield. The 7.1 Ma deposit was the largest producer of gold in the eastern Hauraki Goldfield, and was one of very few economic deposits hosted in Pliocene rhyolites. This paper presents the results of a recent study in the upper levels of the deposit. Maps and cross-sections constrain structural and lithological relationships, and the lateral and vertical extent of a breccia pipe û the major feature of the upper levels.   Previous studies in the upper levels of Broken Hills have shown that gold and silver values are concentrated around and within a large breccia pipe, mined by a series of æcaveÆ stopes and in veins. Contour diagrams of Au-Ag data from channel samples indicate that the breccia pipe was a major fluid channel-way for mineralising solutions.   The breccia pipe deposits are part of the dynamic geothermal system that formed the Broken Hills ore bodies; they developed as a result of hydrothermal brecciation in areas of structural weakness within a rhyolite pyroclastic unit that overlies a massive rhyolite lava-flow unit. The main breccia pipe begins near the rhyolite/pyroclastic contact, having the shape of an inverted, inclined cone, and consists of silicified breccia, stringers of quartz, and irregular patches of clay-altered country rock. Smaller zones or pockets of hydrothermal eruption breccia are silicified and contain low grade gold in the matrix and in the adjacent silicified wall rocks.   Quartz has been classified according to its physical characteristics as seen in situ and hand specimens indicate that vein definition decreases upwards, perhaps as a result of changing lithological conditions and/or increasing proximity to the paleosurface. Hydrothermal quartz is widespread as veins and as a replacement mineral, or lining fractures and cavities and overgrowing rock fragments. Breccias contain vein quartz, but some quartz veins cross-cut breccias, indicating that vein and breccia formation was relatively synchronous and overlapped in time.   Disseminated gold-silver mineralisation is associated with vein quartz and silicic alteration of the wall rock within the breccia pipe. The auriferous zones are highly irregular and erratic, and sampling results show a wide range of gold-silver ratios, suggesting that highly volatile physiochemical conditions prevailed during mineralisation.

Jan 1, 2005

By John W. King, S. Ralph Austin

Spurred by recent forecasts of greatly increased demands for uranium by 1980 and beyond, interest is once again focusing on America's western uranium deposits. One of the principal producers in this area is the Gas Hills district in Wyoming, the site of approximately 12% of the known uranium in the U.S., including past production and current reserves. Located on the south flank of the Wind River Basin, the Gas Hills deposits have been recently studied by the Atomic Energy commission for clues to and guides for discovering similar-occurring ores. The ore deposits are confined to a permeable sandstone unit, up to 350 ft thick, at or near the base of the upper Wind River formation of early Eocene age. The uranium occurs in three principal north- south "ore trends," each of which is about six miles long, one mile wide, and separated from each other by approximately three miles (Fig. 1).

Jan 5, 1966

By W. O. Philbrook. K M Goldman, M. M. Helzel

RADIOACTIVE calcium has been used to learn whether calcium can be detected in iron saturated with carbon after it has been melted under CaO- A12O3- SiO2 slags similar to those used in the iron blast furnace. It was hoped that the radioactive tracer technique might make possible a general study of steelmaking reactions in which calcium or calcium oxide are involved. No calcium could be found in the metal under conditions which were favorable for the reduction of calcium, and it has been concluded that the calcium content of the iron was less than 6 x 10 - pct. Some of the problems encountered have been instructive with regard to pitfalls and limitations of tracer methods. Calcium oxide occurs in almost all iron- and steelmaking slags, and it is essential to the success of all commercial basic steelmaking processes. Calcium alloys are sometimes used in the deoxidation of steel and for the innoculation of gray iron. The element calcium is therefore almost as ubiquitous in the steel industry as are carbon and oxygen, but calcium has been thought to be completely immiscible with iron in both the liquid and the solid states.' It does not seem entirely unreasonable to Suppose, however, that some low concentration of calcium might exist in liquid iron under a basic slag with other conditions being favorable, just as silicon and other elements can be introduced into iron by reduction of their oxides from slags under appropriate circumstances. The radioactive tracer technique offered a more sensitive method than chemical analysis of testing this supposition. The reasons for interest in this investigation were strong enough to justify a recognized risk of failure. On the theoretical side, information on the distribution of calcium between liquid iron and a slag and the rate at which the equilibrium distribution is approached would contribute strongly to the general theory of slag-metal interface reactions. Furthermore, any evidence on the presence of calcium in liquid iron might provide a vital clue to the mechanism of the desulphurization of iron by slags. All of the reactions which have been proposed to explain desulphurization postulate that the sulphur ultimately becomes fixed in the slag as calcium sulphide, but the mechanism by which sulphur

Jan 1, 1951

By A. N. Veltmeyer

"INTRODUCTIONTeck-Corona Operating Corporation's David Bell Mine is located 35 Km east of Marathon, Ontario. In conjunction with its 1000 tonne per day gold concentrator, the company operates an effluent treatment plant for the treatment of mill, mine and site effluents prior to environmental discharge. This paper provides a brief overview of treatment strategies and methods, employed to detoxify final effluent.WATER MANAGEMENTThe tailings impoundment basin, located 3 Km south of the plant site, provides storage capacity for all process effluents and site run-off. Basin supernatant (reclaim water) is recirculated to the plant for reuse as process water, in order to minimize fresh water consumption. As site run-off and limited fresh water intake exceed natural losses due to evaporation, reclaim water in excess of process requirements is passed through the effluent treatment (ET) facility to control tailings basin level by providing regulated discharge of environmentally acceptable effluent. (Figure 1)PASSIVE TREATMENTTo reduce treatment costs and burden on the ET facility, reclaim water is fed to the plant to take maximum advantage of natural destruction processes occurring in the tailings basin.These include: volatilizationphotodecompositionbiological oxidation and precipitationstorm water dilutionConcentrator recovery techniques (Figure 2) are directed toward maximizing gold recovery while limiting the addition and extraction of contaminants requiring disposal and eventual treatment.Currently ore ground to 90% -200 mesh is pre-aerated at pH 9.0 with lime for 18 hours prior to 30 hours cyanidation at pH 9.5 with low cyanide ion excess (70 ppm).Pre-aeration passivates cyanicides prior to cyanide contact. This reduces cyanide consumption and the formation of cyanide complexes. In conjunction with recovery requirements low pH is maintained to retard the dissolution of stibnite into its antimony and sulfide components."

Jan 1, 1989

By Thomas A. Thorson

Bentonite is a common name applied to a variety of clays that develope swelling properties when associated with water. Useful bentonite deposits occur in many Western and Southern states. Their origins may consist of the alteration of volcanic sediments or the decomposition of shallow lake deposits. The specific type of bentonite that will be discussed in this review will be only the Western or high swelling sodium type bentonite that is mined primarily in Wyoming. Wyoming bentonite first entered the market in the late 1880's when it was used as an oil absorbing cosmetic. In the 1920's it was discovered that superior binding properties were present which created new opportunities in pharmaceutical, animal feed, and steel foundries. The swelling properties that were exhibited by the high swelling Wyoming bentonites soon led to its use in oil exploration when the rotary drilling process developed a need for multipurpose fluids. Bentonites in general and Wyoming bentonite in particular have fascinated chemists and process development specialists since the 1920's. There exists a long list of industrial uses that has led to hundreds of patents and extensive literature reviews. The binding and swelling properties are developed as a result of large surface areas and high cation exchange properties. Water, being a di polar molecule, attaches to the ionic vacancies and forms a network of tightly held water particles which in turn produces an impermeable seal or a binding characteristic in unconsolidated powder. Newer uses for Wyoming bentonite that once again utilized the binding and swelling properties include the pelletizing of iron ore and a vast array of civil engineering applications including slurry trenching, lagoon sealing, and garbage landfill sealing.

Jan 1, 1983

By M. Kaufman, A. E. Palty

The phase structure and aging characteristics of two nickel-base alloys, Inconel 718 and 702, were investigated. Wrought and cast Inconel 718 showed ArisCb as the major hardening phase, as well as ture was positively identified. Inconel 702 had Ni3Al as the major hardening phase, as well as Cr7C3-of the phase amounts with temperature was determined. 1 HE value of phase structure and aging rate information in the utilization of alloys has been well established. As part of a continuing program, the results obtained on two nickel-base alloys, hconel 718 and Inconel 702, are presented here. Inconel 718 is a relatively new alloy considered for application in both sheet and cast form. Its novelty lies in the use of high columbium tantalum levels in a Ni-Cr-Fe base. No previous work on this type of alloy has been reported in the literature. Inconel 702 is being used now as an oxidation-resistant sheet alloy. Occasional fabrication problems spurred work on its basic structural behavior. The composition of 702 is essentially nichrome plus aluminum and titanium for strengthening and added oxidation resistance. This puts it in the basic class of other nickel-base alloys which have already been studied. The two alloys will be treated separately. INCONEL 718 Phase Study Methods. The phases present after the various conditions investigated were determined by X-ray diffraction analysis of two different elec-trolytically extracted residues and microscopic examination. The extraction methods, using 10 pct HC1 in alcohol and 10 pct H3PO, in water and the X-ray technique have been described previously.' The effect of temperature on the phase behavior was studied on sheet material using the following heat treatments: 2250°F, 2 hr, ice brine quench 1300 100 hr, water quench 2250°F, 2 hr, ice brine quench 1400°, 100 hr, water quench 2250°F, 2 hr, ice brine quench 1500°F, 100 hr, water quench 2250o 2 hr, ice brine quench 1700°F, 48 hr, water quench 2250°F, 2 hr, ice brine quench 1850°, 24 hr, water quench 2250°, 2 hr, ice brine quench 2000°F, 6 hr, water quench The high solution temperature was an attempt to dissolve as many phases as possible without causing melting. Aging exposures were made longer than normal heat treating times in order to approach equilibrium conditions more closely. Cast material was examined only in the as-cast condition and with the normal heat treatment (1700°F, 1 hr, air cool 1325oF, 16 hr,air cool). Materials. The full phase study was performed on sheet specimens approximately 1/2 in. by 2 in. by 1/16 in. The cast pieces were cut from the gating system of a vacuum-cast test piece. An all weld-metal specimen was made by running many weld beads on the sheet using filler made from the sheared edges of the sheet. All external contamination was removed by belt-sanding followed by an electro-polishing treatment. The typical composition of wrought Inco 718 is as follows: The alloy is air-melted. Cast hco 718 may have higher molybdenum. Due to the expectation of finding a Ni-Cb phase (Ni, Cb) for which no X-ray diffraction pattern was available in the ASTM Index, a special 5 Ib heat to the stoichiometric composition of this intermetallic

Jan 1, 1962