Search Documents

By W. J. Pearson

"""POTASH"" is a term applied to the compounds of the element potassium (K) and when used in agriculture and industry is ex-pressed in terms of potassium oxide (K2O), regardless of the actual com-position of the compound. When a chemical analysis is made of a fertilizer, the amount of K is deter-mined and then calculated to the equivalent amount of K2O. However, the compound K2O does not exist in nature. Most of the world's potash supply is derived from mineral deposits similar to those in Saskatchewan and New Mexico. However, there is some production from concentrated surface brines such as occur in Searles Lake, California; Salduro Marsh, Utah; the Dead Sea; and from well brines in Micl1igan."

Jan 1, 1960

By Ross Gilders, Leo Cheung, C. David Desjardins

"For the past twenty years significant progress has been made in bacterial leaching. In fact, a recent article in the Northern Miner has cited that nearly all new copper production is based on bioleaching. The bacteria that play the predominant role in bioleaching is an obligate chemolithoautotroph called thiobacillus ferrooxidans. These bacteria thrive in areas rich in sulphide and prefer low acid media. In the simplest sense, they metabolize sulphide converting it to sulphate either as acid or as soluble metal sulphates. This process is well known because these bacteria generate acid mine water. Over the last five( 5) years, we have been carrying out development work on creating optimum bioleach conditions for the extraction of metals from sulphide rich ores and concentrates. Recently, a study was carried out on a byproduct sulphide concentrate produced in a tin flowsheet developed for the Mt. Pleasant Mine of ADEX Mining Corp. The objective was to determine whether a bioleach process might successfully leach this sulphide material which contains copper, zinc, iron and, what is more important, trace metals such as Indium, Gallium, and Bismuth. The current work describes the successful recovery of these metals achieving extractions of more than 80% by applying bioleaching techniques. An overview of this technical program forms the basis of this paper.IntroductionBio-Oxidation of metal sulphides has emerged to be one of the leading edge hydrometallurgical processes for the economic extraction of metals from ore and concentrates. The fundamental process involves the bacterial assisted oxidation of sulphide to sulphate yielding metal sulphates which can be subsequently leached by conventional means. The bacteria that play the predominate role is an obligate chemolithoautotroph named thiobacillus ferrooxidans (TF). These bacteria thrive in areas rich in sulphide and occur naturally worldwide. In fact, TF is responsible for generating acid in water (acid mine water) from exposed sulphide surfaces primarily through the oxidation of pyrite. TF bacteria thrive under the proper conditions of temperature and oxygen supply in the presence of sulphides and populations in excess of a million per millilitre (ml) of solution are achievable. Typically, at room temperature, the bacteria will bio-oxidize in a pH range of 1.0 to 3.0. Today, bio-oxidation has been applied commercially with great success for the extraction of uranium, copper, and gold."

Jan 1, 1996

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, J. M. A. Geldenhuis

The successful application of solid electrolytes in electrochemical cells for high-temperature thermodynamic studies depends to a large extent on an accurate knowledge of the P. value of the electrolyte (the oxygen partial pressure at which the ionic conductivity and n-type electronic conductivity of the electrolyte are equal). Consequently, the P. value of an electrolyte must be determined prior to its use in electrochemical cells. This paper describes the successful application of a coulometric titration technique in the quantitative assessment of the P. values of a commercially available ytria-stabilized zirconia electrolyte that has been used extensively by local investigators. The experimentally determined P. values of the electrolyte are reported and compared with P. values reported in the literature for a similar electrolyte.

Jan 1, 1988

By G. M. Swinkels

Sherritt Gordon and Cominco, with financial assistance from the Canadian Government through PAIT, have developed a hydrometallurgical process for refining copper from sulphide concentrates. The main objective of the project was to develop a process applicable to a wide range of concentrates with respect to copper content, other metals content and impurities, within the economic parameters set by present smelting and refining practice. Other important objectives were to recover sulphur in its elemental form and not as sulphur dioxide to assure improved hygienic conditions and a negligible impact on the environment. For the most abundant and relatively refractory chalcopyrite concentrates, the first step of the process is thermal activation with hydrogen to decompose chalcopyrite and pyrite, commonly associated with it, into more reactive sulphides more amenable to leaching. The iron is then selectively extracted by sulphuric acid leaching and subsequently rejected as jarosite. High-bornite concentrates do not require thermal activation and acid leaching; they are subjected to another hydrometallurgical iron removal step. The high-grade copper sulphide resulting from iron removal, and containing all of the initial precious metals, is then leached under oxygen pressure to produce elemental sulphur and copper sulphate solution . After suitable solution purification, the copper is recovered by high-current-density electrowinning as wire-grade product. Precious metals remain in the leach residue and are recovered after separation of the gangue materials and elemental sulphur. The laboratory and pre-piloting test work had indicated copper and precious metals recoveries comparable to those achieved in current practice. The process was shown to be suitable for handling relatively low-grade concentrates and, in addition, it was capable of high recoveries of associated zinc, molybdenum, nickel and cobalt in saleable form.

Jan 1, 1978

[Participating Scholarship Colleges and Universities 144 Andalex Resources, Inc 91 Behre Dolbear & Company, Inc 93 Canyon Fuel Company, LLC 92 Big Sky Coal Company 114 Commercial Testing & Engineering Company 96 Continental Conveyor & Equipment Co 97 Copper Mountain Resort 108 Cove Shoe Co., Inc 110, 111]

Jan 1, 1999

By B. M. Moudgill, T. V. Vasudevan

Marine sedimentary deposits account for 80% and igneous deposits 17% of the total world output of phosphate rock. The phosphate mineral is well crystallized and exhibits a greater floatability in the igneous deposits than the sedimentary ores. Both silicates and carbonates contribute the major gangue associated with the sedimentary ores. Although removal of silica from sedimentary phosphates by froth flotation has been in practice for several decades, with the depletion of high-grade reserves, new attempts are being made to improve the efficiency of current silica removal technology and to develop new processes for beneficiation of phosphate ores associated with the carbonate gangue. In this paper, recent developments in processing of sedimentary phosphate ores containing carbonate and silica gangue are discussed.

Jan 1, 1987

By R. Hans

Removal of toxic anions from aqueous solution was studied using a Magnetic Ion Exchange (MIEX) resin which is a polyacrylic, strong base resin. Gravity based settling is made more efficient due to the magnetic nature of the resin which is advantageous over conventional ion exchange resins. In addition, the magnetic microspheres of MIEX have larger surface area in comparison to conventional ion exchange resins. Over the years MIEX has been successfully used and has gained significant popularity for efficiently removing dissolved organic matter from wastewater and groundwater. In the present study the efficiency of the MIEX resin was tested for the removal of chromium(VI), molybdenium(VI), vanadium(V) and arsenic(V) anions. Effects of pH (2-10) and temperature (25oC-55oC) were examined. In general, low solution pH values were favorable for anion uptake by MIEX. Except for chromium(VI), the metal ion uptake was significantly increased by the increase in solution temperature. The adsorption data were analysed on the basis of chemical speciation and heterogeneous kinetic models.

Jan 1, 2014

By Sidney A. Swensrud

This paper reviews the subject of gasoline margins, discusses some of the more current marketing problems, and gives some consideration to the main urges to marketing expansion, or overexpansion, in the oil industry. Margins In an earlier paper1, some comparisons were shown for the years 1929, 1930 and 1931, of the margin between the refinery cost of gasoline in Oklahoma, the market price in Oklahoma, and the average retail price in 50 representative cities of the United States. These figures indicated a small margin for the refiner in 1929 between his gasoline cost and the wholesale price, which, however, had turned into a loss by 1931. The margin between either refinery costs or wholesale prices and the retail price in the 50 cities showed a continuous decline during the three years. We have now worked out these figures on a similar basis for a longer period—from 1928 through 1936. The figures for refinery gasoline cost are slightly different from those in the earlier study, owing to the use of

Jan 1, 1937

"Cobalt refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because certain compounds of both metals carry risks for adverse health endpoints by inhalation exposure, it is critical to understand the aerosol concentrations of specific substances and the metallurgical processes through which they enter the air. Vale Canada has therefore decided to describe the histories of its Ni-related operations and to report industrial hygiene measurements when available. This paper describes electrolytic Co operations carried out at Port Colborne, Ontario (1954–1966), and provides aerosol measurements (1995–2008) for current Co electrowinning operations.RÉSUMÉ L’affinage du cobalt chez Vale Canada (anciennement Inco) a été associé à la production de nickel. Puisque certains composés de ces deux métaux comportent des risques d’effets néfastes pour la santé par exposition à l’inhalation, il est essentiel de comprendre les concentrations en aérosol des substances spécifiques ainsi que les procédés métallurgiques par lesquels ils entrent dans l’air. Vale Canada a donc décidé de décrire les historiques de ses opérations liées au nickel et de divulguer les mesures d’hygiène industrielle lorsqu’elles sont disponibles. Le présent article décrit les opérations électrolytiques effectuées sur le Co à Port Colborne, Ontario (1954–1966), et fournit des mesures de la teneur en aérosol (1995–2008) pour l’extraction électrolytique actuelle du Co."

Jan 1, 2015

By The SME Sustainable Development Committee

The evolution of sustainable development in mining is recognized as a key contributor to sustainable development (SD), which is defined as the ability of current generations to meet their needs without compromising the ability of future generations to meet their own needs (Brundtland, 1987). This includes, in equal parts, social, economic and environmental impacts ? triple bottom line (Munashinge and Shearer, 1995). Alternately, sustainability has been defined in relation to social, natural, human, physical and financial capital. Our way of life relies significantly on the materials provided by mining, while mining activity affects the triple bottom-line or the five capitals. The mining community and its professionals have come to realize the importance of engaging all stakeholders in the discussion on sustainability. SME, as the leading professional mining organization, has been involved in these discussions. The society has various initiatives in sustainable development for members and stakeholders. The objective of this article is to: provide historical context for current trends in mining and SD and share SME sustainability initiatives ? their goals and rationales ? with the broader mining community. This article is timely because the past year saw two landmark forums on sustainable development: Rio+20 ? the 20th meeting of the United Nations Conference on Sustainable Development, and MMSD +10, the Mining, Minerals and Sustainable Development project 10 years on. Furthermore, this year marks the 10th anniversary of the Milos Declaration on the minerals professional?s responsibilities in achieving sustainable development, forums in which SME was involved.

May 1, 2013

By S. M. Shelton

Ferrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced; although it is well-known that there are largo deposits of low-grade ore in the United States, production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stock piled ore is depleted through inability to obtain adequate supplies from foreign sources. Consequently, a program of laboratory and pilot-plant investigations designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines. This paper is one of a new series that will include reports of results obtained in the various investigations conducted under the manganese program. The scope of the program and the organization that was set up to direct and supervise the work were discussed in the foreword of the first paper of this series, Report of Investigations 3506, Manganese Investigations 1. Concentration of Manganese Ores from the Drum Mountain District, Utah, by S. R. Zimmerley, J. D. Vincent, and C. H. Schack. Other reports will be published as the work progresses.

Jan 1, 1942

By Eckart Schneider

PROJECT The Walgautunnel is the heart of a new hydro scheme in Western Austria, which is supposed to go into operation in 1984. With it's length of 21,4 km, a bored diameter of 6,25 m and an internal operating pressure of 13,5 bar it will be the largest water conducting tunnel in Austria. Even compared with some of the country's world-famous highway tunnels like 'Tauern' or 'Arlberg' it has to be regarded as a major tunneling project. Owner is the Vorarlberger Illwerke AG, a power corpo¬ration founded in 1924. In the course of the past 6o years this company developed the 'Werksgruppe Obere Ill - Lünersee', consisting of 6 major power plants and 4 large reservoirs. The installed capacity is 1.114 MW in the generating and 529 MW in the pumping mode. The total power output amounts to 1.916 GWh. The water for power generation comes from the glaciers of the Silvrettagroup, as this corner of the Austrian Alps between Vorarlberg , Tyrol and Switzerland is called. The Walgauwerk utilises all the water accumulated by the existing schemes as well as the so far unused run-off water, passing by in the river Ill. The intake to the Walgau-Tunnel is situated right beside the lower reservoir of the recently completed pump-storage plant 'Rodund II' at an elevation of 64o m above sea level. Though the head is a mere 162 m, 1 billion m3 of water will generate 356 GWh per annum. The power-output of the two Francis turbines is 86 MW.

Jan 1, 1983

By J. P. Powell

Systematic waterflooding was first tried in Washington County, Okla., in 1937, when a 40-acre project was begun in secs. 24, 29, 32, and 33, T. 27 N., R. 13 E., jointly by the Keener Oil Co. and the Phillips Petroleum Co. The property later was sold to Lee Morrison. A second project was begun in 1941 in sec. 14, T. 6 N., R. 12 E., by the Oklahoma Oil Corp. Both projects were abandoned by the end of 1942. A third project was begun in 1945 and the fourth in 1948, but 1949 actually was the beginning of intensive waterflooding development in Washington County. The results of previous waterflooding projects are described in Bureau of Mines Reports of Investigations.2 3 4/ Oil production in the county followed a similar trend, dropping to a low of 990,000 barrels in 1945, then steadily increasing until 1956, when more than 4 mil-lion barrels of oil was produced. Most of the increase in oil production is directly attributable to water injection.

Jan 1, 1957

By Kenneth N. Ham

Hydrometallurgy covers a wide spectrum of areas and its knowledge base is enlarged and enhanced by contributions from many other fields. Dissolution of metals and alloys in aqueous media will be used to illustrate how rich the field of metal extraction can be. Comprehensive understanding of the fundamentals of metal and alloy dissolution in aqueous systems requires creative application of thermodynamic principles, solutions chemistry, ligand complexation theory, electrochemistry, transport phenomena and heterogeneous kinetics. In addition, recent developments in instrumentation in the fields of interfacial phenomena and corrosion have tremendously advanced the field of metal extraction in aqueous system. The close relationship between metal extraction in aqueous systems and various physicochemical phenomena occurring in corrosion and interfacial systems will be discussed and illustrated with examples.

Jan 1, 2002

By J. L. Robson, C. M. Bristow

mass flow rates of particles and air (the loading ratio).

Dec 1, 1994

By W. K. Connor, O&apos

The U.S. Bureau of Mines investigated the Sheep Creek prospect in the north-central Alaska Range to evaluate the Pb, Zn, Ag, and Sn resources. The studies included field investigations, mineralogical characterization, and concentration tests. Mineralization at Sheep Creek consists of disseminated, banded, and massive pyrite, sphalerite, and galena. Tin occurs as grains of cassiterite (Sn02) in the quartz-mica matrix and within pyrite and sphalerite grains, and Ag occurs in solid solution within the galena. Three bulk surface samples and two sets of core samples were collected at the Sheep Creek prospect for this study. Gravity concentration yielded products with up to 30 pct Sn, and the best result was a product that recovered 52 pct of the Sn at a grade of 22 pct Sn. Bulk sulfide flotation yielded products that recovered up to 89 pct of the Zn, 73 pct of the Pb, and 75 pct of the Ag, but grades were relatively low; selective flotation would significantly increase the grades.

Jan 1, 1989

By E. H. Cho, Q. Luo

Pittsburgh No. 8 coal, cleaned by conventional froth flotation, was oxidized in a 2-L Parr stirred bench-top autoclave. Autoclave tests were carried out for up to 5 hrs under the following conditions: 150 to 225ºC, 60 to 500 psi 02 and 15 to 60 g of coal per 600 mL of distilled water. The oxidation of coal was evaluated by measuring the total acidic group formed on the surface of the coal and by measuring the adsorption (under standard conditions) of calcium ion from a solution. The degree of oxidation of the coal increased continuously, without much leveling off, with increasing oxygen pressure. With increasing temperature, the oxidation of the coal increased sharply between 150 to 175ºC and then leveled off above 175 °C. The adsorption of calcium was >3% on coal oxidized under the most favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The loss in Btu was found to be sensitive to oxidation temperature. This study concluded that the optimum oxidation of coal is achieved over 3 hrs at high oxygen pressures (e.g., 500 psi) at ~170ºC. This study also concluded that, when measured in terms of calcium adsorption, Btu loss and reaction time, the oxidation achieved in an autoclave is far superior to that achieved in a fluidized bed.

Jan 1, 1996

By Barton J. Suchomel

Introduction Despite perennial economic turbulence, Argentina continues to push ahead with efforts to develop its fledgling hardrock mining industry. The country lacks the infrastructure and mining history of neighboring Chile, but contains vast areas of great resource potential. The eastern slope of the Andean Cordillera in west-northwest Argentina is a relatively little-explored region offering geology highly conducive to the occurrence of base and precious metals deposits. Past exploration has concentrated on locating and evaluating porphyry copper-molybdenum (Cu-Mo) type occurrences. Comparatively little attention has been given to precious metals potential. An interesting and important group of base and precious metals prospects in northwestern Argentina occurs within and adjacent to the Upper Miocene Farallon Negro volcanic complex in Catamarca province. The volcanic complex contains numerous base and precious metals vein occurrences, high gold porphyry copper prospects, and possible disseminated gold targets that have attracted relatively minor attention in the past. Various geologic aspects of the region have been reported by several workers (Llambias, 1970, 1972; Caelles et al, 1971; and Sillitoe, 1973). Regional geology The Farallon Negro volcanic complex is located within the Sierras Pampeanas morphostructural province about 200 km (125 miles) east of the main Andean Cordillera (Fig. 1). The Sierras Pampeanas is characterized by north-south-trending basin and range topography that developed during the Miocene and Pliocene. Uplifted blocks are composed mainly of lower Paleozoic metasediments and granitoid plutonic rocks unconformably overlain by Tertiary redbeds and minor carbonates. A consistent landward migration of volcanic and intrusive ac¬tivity occurred in this region of the Andes from the early Mesozoic through the mid-Tertiary. An eastward extension of magmatism during the Miocene and Pliocene resulted in the formation of the Farallon Negro volcanic center. Volcanism at Farallon Negro ini-

Jan 8, 1988

By David J. Kruse

Although it may be perfectly acceptable to neglect the belt's elastic behavior for many conveyor designs, this can lead to disastrous consequences for others. So how can a designer know in advance if a dynamic analysis is required? Unfortunately, in many cases it is impossible to foresee or predict dynamic problems prior to performing the actual analysis. However, a basic understanding of the principles of conveyor dynamics, as well as knowledge regarding common problem areas, can significantly help the designer make more educated decisions during the initial design stage. This paper will demonstrate how static calculations alone can incorrectly represent the true behavior of the conveyor system. It will also discuss the importance of correctly sizing and locating the take-up system to provide the most economical conveyor design. The use of capstans will also be discussed followed by two examples demonstrating their proper operation.

Jan 1, 2002

By E. J. (Kirk) Conway

The objectives of this project were to: (1) determine the extent to which maintainability design concepts and principles have been applied to the design of underground coal mining equipment, (2) try to assess its impact on productivity and personnel safety, and (3) develop maintainability guidelines to enhance the design of new or rebuilt equipment. An equipment design review was completed at ten operational coal mines. The purpose was to identify design approaches and features that enhanced and degraded the maintenance process. Mine management, safety, and maintenance personnel were also interviewed to identify machine specific design problems. Six original equipment manufacturers were visited and the procedures used to enhance the maintainability of Their equipment discussed. Volume I of the Final Technical Report presents an overview of procedures and protocol used and a summary of the findings. Volume II includes the maintainability design guide for mobile underground mining equipment.

Jan 1, 1988