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By Mohammadreza Khanmohammadi, Kazem Fakharian

"AbstractIn driven piles, the gradual dissipation of excess pore water pressure and consequently the soil setup significantly contribute to increasing the pile capacity with time. The question is risen that how the scale differences affect the stress state variations around the pile shaft and at the pile tip? Would the CPT predictions better correlate with End-Of-Drive (EOD) or Beginning of Restrike (BOR) conditions? On the other hand, are the proposed a and ß parameters for clayey soils mostly predicting the EOD or BOR situation? The main objective of this paper is to back calculate the a and ß parameters from CPT profiles, pile Dynamic Load Tests (DLT) at the EOD and BOR as well as Static Load Tests (SLT) and evaluate how they compare with those suggested in literature. Four precast 400 mm square concrete piles driven in North Azadegan Oilfield in Khuzestan Province were selected for the comparisons. CPT test results were available from the extensive geotechnical investigation at the study site. DLT tests using PDA were carried out at EOD, 1 day and 14-day BOR on all the 4 piles. All the piles were SLT tested as well. The UniCone software was used to estimate the tip and shaft resistances using 4 methods including the Dutch, Eslami & Fellenius, LCPC and Schmertmann. The results indicate that the a-method based on the proposed values in literature has predicted a shaft capacity of 90% of the 14-day BOR. This is while the ß-method has predicted a shaft capacity equivalent to 1-day BOR results only. Therefore, both methods have under-predicted the shaft capacities compared to real capacities measured after the significant soil setup in the study area. Two of the CPT methods have underestimated, one has overestimated and one has matched the estimated 60-day capacity."

Jan 1, 2014

By A. Bozorgzadeh, B. M. Jensen, B. N. Koelling, B. R. Murtaugh

"The Service Base mooring system originally consisted of two general types of structures, 19 timber piles cabled together and steel three-legged pipe piles. The St. Louis District fleet moored to the fleet barges which were tied off to shore-side concrete deadman and supported on the landward side by the timber and steel piles. The purpose of this project was to replace the existing floating wharf mooring system at the St. Louis Service Base. The Marine Design Center of the U.S. Corps of Engineers developed a three pile cluster system concept. The clusters consisted of one vertical pile and two batter piles. Piles in rock sockets were selected to resist the uplift loads due to high wind loads on the tall, spare lock gates stored at the floating wharf. This paper focuses on the design of the rock sockets for steel pipe piles with large uplift loads and the lessons learned during the design and construction of this system.INTRODUCTIONBackgroundThe U.S. Army Corps of Engineers’ St. Louis District is located at the critical transition point on the Mississippi River where it is a “locking river” north of St. Louis and an “open river” to the south. The St. Louis District is responsible for maintaining navigation channels on the Mississippi River, the Illinois River and the Kaskaskia River. It is also responsible for the operation and maintenance of five locks and dams within its geographic boundaries.The St. Louis District utilizes a fleet of vessels (dredges, crane barges, motor vessels, and barges) to support the navigation mission identified above. The St. Louis District Service Base, located in St. Louis, Missouri, serves as the base of operations for the district fleet. This riverfront facility originally consisted of a floating wharf, a railroad trestle, and a walkway down the river bank to the floating wharf. Historically, there have been two fleeting areas at the Service Base. The main fleeting area was approximately 965 feet long and consisted of six fleet barges (Figure 1). This area supported the Dredge Potter and its attendant fleet. The upper fleeting area was approximately 1,050 feet long and consisted of various stop log, crane and work barges, dredge pipe pontoons and work flats."

Jan 1, 2017

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By H. W. Hardings

Nearly every mining and metallurgical engineer will recall his early experience and method of producing step- or stage-reduction in preparing ore-samples for assay, in which he employecl idea, step- or stage-reduction simply because it was a self-evident fact that it would be easier to break coarse ore with a hammer than it would be to roll it back and forth under the muller, and alter having reduced it to a size easy for a rubbing or bucking division he then placed it under the muller on the bucking-board and further reduced it in proportion to the physical energy he wished to expend, which was generally the minimum to produce results. After this step in our experience me seem to have ceased to consider stage-reduction as mechanicallg essential, probably because it did not apply to individual exertion. Moreover, me did not retain the mass under the muller until it was all reduced to pass the 80-mesh assay-oftice screen, but practiced further step-reduction by screening out the fine in order that it should not interfere with subsequent work, replacing the coarse for further reduction on the bucking-board. It was many years after the bucking-board stage of metallurgical practice that we mere brought to a full realization that there was a more economical method in applying the crushing forces usually employed in metallurgical work by taking advantage of this individual experience and applying it to mechanical ends. We have made some advance to this end in bringing out the conical ball-and-pebble mill—a device which fairly well automatically adjusts power to the results obtained, mechanically repeating the bucking-board experience. In the action of the conical mill, theory is evolved from practice, rather than practice from theory, as is commonly the case.

Jan 1, 1914

By Gábor Csicsovszki

We have developed a novel method - at the laboratory scale - comprising an ion-exchange separation and a membrane-electrolysis step for the purpose of zero-waste regeneration of spent HCl pickling liquors originating from hot-dip galvanizing of common steels. It is aimed at the parallel regeneration of HCl and iron. Experiments revealed that iron can be electrodeposited at high current efficiencies by maintaining the following conditions: 0.04-0.08 M HCl, 500-1000 A/m2, 20°C and stationary electrolyte in a conventional cell. Zinc in the solution did not disturb the deposition of iron, however it contaminated the product and it poisons the anion-exchange membrane required to tackle acidity during electrolysis. For a preliminary separation, anion-exchange tests were carried out to produce pure iron solutions. Beyond the equilibrium studies, column experiments were carried out showing that low flow rates of the loading solution and the ~1.5 M HCl eluent are essential for separation.

Jan 1, 2006

By B. Tani, K. Anderson, I. Johnson, R. Schablaske

INVESTIGATION of the various rare earth-cadmium binary systems discloses the existence of a compound corresponding to the composition MCd6 in all systems save the La-Cd system. Lattice constants for all of the MCde compounds, except LaCd6 which apparently does not form, and PmCd6 whose synthesis was not attempted, are also recorded herein. Iandelli and Ferro 1 report the existence of the compound CeCd6. No additional information, structural details, and so forth are given. Elliott and Lemons2,3' have measured the vapor pressure of cadmium over CeCd6 and have calculated the activity of cadmium in solid CeCd6. These authors find that CeCd6 exists over a composition range from 5.967 to 6.098 (Cd:Ce ratio) at 584oC, and from 5.971 to 6.118 at 639°C. The following is an excerpt from the paper by Elliott and Lemons: 2 "Recently Mr. F. H. Ellinger of this laboratory has indexed an X-ray diffraction powder pattern of CeCd6.00 which we had prepared by gas phase reaction. The compound has a primitive cubic unit cell with a = 15.783 + 0.001A Based on the volume of the cubes surrounding an elemental cerium or an elemental cadmium atom, Mr. Ellinger finds room for 24.10 CeCd6 formula units in the CeCd6 unit cell; similar calculations based on CeCd2 and CeCd11 yield 24.18 formula units per unit cell. The presence of 24 CeCd6 units per unit cell seems probable with an X-ray density of 8.255 grams per cubic centimeter. The most one can say about in-terstitial~ is that there appears to be room in the crystal even at room temperature." Measurements of the solubility of the rare earths in liquid cadmium4 led to the discovery of GdCd6,

Jan 1, 1964

By A. S. Choudhary

Most of the coal reserves in India are of drift origin and have very poor washability characteristics and a high level of near gravity materials. At least 30 new coal wash plants are expected to be set up in the next 5years.In such a scenario, adequate sampling followed by sink float test work for washability analysis becomes very critical for designing these new plants. For coal sampling purpose, stipulations of different standards are sometimes formidable and on the border of ?impracticality?; sometimes are self contradictory in terms of gross sample weight vis-a-vis minimum number of particles required in each size fraction and in each relative density fraction and also the minimum mass in the latter. Validation of the generated data is another important aspect of washability analysis. These issues can easily be addressed by using straight forward mathematical relationships, well known RR plots and by using simple MS Excel tool, etc.

Sep 1, 2012

By Robert H. Aborn, J. J. B. Rutherford

It is now well known that troublesome intercrystalline corrosion may occur in austenitic stainless steels following exposure of the metal to a temperature within the range 1000° to 1500° F. (540° to 815° C.). The present paper describes a satisfactory method of estimating the extent of such corrosion, based on the measurement of the electrical resistance of a specimen before and after attack. This new method enabled us to study quantitatively the effect of several factors upon intergranular corrosion in the 18 Cr, 8 Ni type of alloy. The results show that susceptibility to this attack increases with increasing carbon content and grain size and appears to pass through a maximum for certain combinations of temperature of sensitization and period during which the alloy was maintained at that temperature; and are in complete accord with our interpretation of the mechanism of this phenomenon. The method is probably applicable to other metals or alloys subject to intercrystalline attack, such as the aluminum alloys of the duralumin type. The methods hitherto in use for estimating the degree of intergranular attack fall into three types: (1) microscopic examinationll (2) macroscopic examination of fractures, and (3) determination of the time required for complete failure or disintegration.2 None of these lends itself very well to a measurement of the extent of corrosion. The first two are qualitative in nature and the third provides an arbitrary value largely dependent on individual judgment, since failure is a progressive phenomenon and not a sudden event. Our experience is that weight-loss determinations, although valuable in some types of corrosion investigations, bear no simple relation to intercrystalline corrosion in this type of alloy, as is to be expected since the phenomenon probably involves only the thinnest films between adjacent metallic grains. Measurement of electrical resistance has been used recently in the study of some types of corrosion,3 but seems not to have been applied to

Jan 1, 1932

By Edmundo Campos Arzapalo

El presente texto plantea el concepto sistemático a través de una matriz en el método de explotación para un yacimiento con características variadas. Como tal, se consideran condiciones naturales, de la empresa, políticas públicas y la situación técnica (la ingeniaría de minas). Asimismo, el uso de esta matriz considera los parámetros de la geomecánica, geología, entre otras, las cuales son importantes para poder elegir el método apropiado de explotación, ya sea subterránea o cielo abierto de un yacimiento ferroso o no ferroso.

Sep 12, 2011

By L. E. Krys, K. D. Harrison, S. M. Nordwick, C. G. Anderson

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at the Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate, The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper will discuss the outcomes of these recently patented plant-process changes. In particular, a comparison between the previously used method and the new leach method is made. Also discussed is the potential applicability of the process to other materials. A companion publication (Anderson, Harrison and Keys, 1996) indicates possible mechanisms responsible for the success of these process changes.

Jan 1, 1997

By Carlos E. Santa Cruz B

Ante la alta demanda energética de la mina Orcopampa en Arequipa, el costo de la misma se ha incrementado, así como ha generado problemas de transición entre las nuevas fuentes de energía tradicionales y las nuevas. En este sentido, el presente trabajo busca establecer políticas de racionalización del consumo de energía en la operación del complejo minero a costos bajosa a través de un programa de acciones que logre el ahorro de energía. La metodología del estudio comprende 4 etapas: reconocimiento preliminar del sistema, programa de mediciones, procesamiento y análisis de información y definición de un plan de acciones para reducir costos. Finalmente, se comprobó que la aplicación de este programa de acciones propuesto se ajusta de forma gradual al programa de acciones, logrando una ahorro anual de US$ 269 000 0.

Apr 1, 1991

By K. Scalise, M. Teixeira, K. C. Kocsis, J. Parrish

"This paper aims to introduce and discuss a newly developed algorithm, which can be uploaded on smart watches and other mobile devices to inform and protect underground personnel working in hot and humid environments. Using this algorithm, the metabolic rate (M) of a worker can be determined in “real-time”. In addition, besides warning signs and alarm signals emitted by the smart watch, the algorithm has the ability to determine work-rest time periods based on the worker’s physiological parameters (e.g. age, height, weight, gender) and the climatic parameters (Td, Tw, flow velocity). This paper also investigates whether a re-designed auxiliary ventilation system can provide appropriate work conditions in the production stopes. INTRODUCTION An underground environment with high temperature and humidity conditions generated from various heat and moisture sources can significantly affect the thermoregulation processes of the human body. This can lead to heat-related illnesses such as heat rash, heat cramps, heat exhaustion, and heat stroke. Heat stroke is a serious illness that carries a high risk of fatality, if the underground workers are not immediately treated and the climatic conditions are not corrected (McPherson, 1993). There are two methods used to control the climatic conditions in underground mines: (1) Using ventilation and cooling systems to reduce the thermal stress on the mine workers, and (2) Reducing the heat transferred to the ventilating air from major sources such as: strata, auto-compression, mining equipment, groundwater, blasting, etc. The heat from strata and auto-compression is transferred to the ventilating air at varying degrees, based on factors such as the virgin rock temperature (VRT), the thermal properties of the surrounding rock formations, and the surface air temperature. However, the use of mining equipment and blasting processes can be managed to reduce their contribution to the mines’ overall heat load. To provide appropriate work conditions, selecting the most suitable cooling method depends on the level of heat to be removed, the location of the problem areas, and economic constraints (Brake & Bates, 2002; McPherson, 1993). Because every mine is unique, it is essential to monitor the climatic conditions to select the most appropriate method of cooling. A majority of the time, simply adjusting or re-designing the auxiliary ventilation system can efficiently remove the heat and dilute the contaminants. This may involve moving the ducting system, changing the size of the duct, changing the size of the auxiliary fan, or switching from forcing to an exhausting fan arrangement. If the required air volumes are higher than the existing primary ventilation system can supply, other measures may need to be taken to increase the airflow delivery. This may include regulating the flow in some areas of the mine to increase airflow to the desired area, adding booster fans, or replacing the primary fans."

Jan 1, 2019

By A. Lam

The use of a liquid fed direct methanol fuel cell (DMFC) as a power source for micro and small portable applications is attractive due to its system simplicity, low temperature, etc. The aqueous methanol is directly oxidized and does not require additional fuel processing steps as in reformate based PEM fuel cells. In addition, the use of a liquid fuel is advantageous with respect to humidification, stack cooling and system energy density. The DMFC however, has technological issues that must be addressed before it can be widely adopted, particularly in larger applications such as small utility and transportation. At present, the crossover of methanol from the anode to the cathode is a major limitation on DMFC performance and fuel utilization efficiency. In this paper we discuss the influence of fuel modification on the control of crossover. This involves the use of different fuel additives and concentrations to minimize crossover. This appears to be the first reported case of the use of fuel modification (additives) to reduce methanol crossover. The rate of methanol permeation under passive conditions is discussed with respect to the different conditions.

Jan 1, 2005

By Ernest Peters, Fiona M. Doyle

The leaching and bulk decomposition of sulfide minerals is of enormous commercial importance in several areas of the minerals industry. These include: direct leaching of ores or concentrates for the recovery of the contained metal values; decomposition of sulfides to recover associated values such as encapsulated gold; and the potentially hazardous oxidation of sulfides in waste disposal facilities. A significant challenge to successful future developments in these areas is to improve our fundamental understanding of the mechanisms of the chemical, electrochemical, and bacterially-mediated interactions between sulfides and aqueous solutions. The paper summarizes current understanding of these mechanisms, and discusses promising new directions for research.

Jan 1, 1989

By Ji Changsheng

In a large surface mine design, different kinds of mining equipment can be selected. Even though the major purpose of capital investment is to get more profit from mining activities, there are some other complicated factors which influence the selection of mining equipment must be considered as well. A fuzzy evaluation model with fuzzy set theory is proposed in the paper to make a good selection of mining equipment in which different kinds of factors including quantitative and nonquantitative ones can be taken into account at the same time. With the model, mining equipment selection of a large surface mine can take into consideration not only economic factors but also some other factors which play important role in mining system.

Jan 1, 1996

By G. M. Potter, F. S. Wartman, M. D. Schmid

"In matte smelting of copper it has been established that the sulphpr present will combine with copper as long as the latter is present, and that thereafter it will combine with iron. The Cu-Fe ratio in the matte is determined by the Cu-S ratio, presumably owing to the much greater affinity of copper for sulphur or, expressed thermodynamically, the greater stability of copper sulphide in contact with silicate slag. Now, the work of Fournet and of Schütz, which is quoted in many elementary metallurgical texts, indicates that manganese ranks ahead of copper in its affinity for sulphur. Hence, we might expect that manganese could be concentrated from its admixture with iron. Compounds by matte smelting, and Rotts / has patented such a process. This greater affinity of manganese or sulphur is used to advantage in iron metallurgy, also, in which it is well-known that sulphur will combine with manganese and separate from metallic iron as manganese sulphide. Manganese sulphide,however, is quite soluble in silicate slags. 5/ The loss of manganese in slag in any attempted matte smelting is therefore great.If this solubility of manganese sulphide is slag is a physical one and the reaction MnO + FeS MnS + FeOIs substantially complete, then it might be expected that the addition of copper sulphide, which is almost entirety insoluble in slag, would serve to extract the manganese sulphide with the formation of a manganese-copper matte on the other hand, if an equilibrium exists in the above reaction, a copper sulphide layer would displace that equilibrium in one direction or the other, according to whether iron sulphide or manganese sulphide were more soluble in the matter layer."

May 1, 1937

By H. Jung, J. Kim, Y. Lee, Y. Seo

"Shale gas has become an increasingly important source of natural gas supply in North America and around the world. Horizontal drilling and multi-stage hydraulic fracturing are the two key enabling technologies for the economic development of these shale gas reservoirs. It is believed that gas in shale reservoirs is mainly composed of free gas within fractures and pores and adsorbed gas in organic matter (kerogen). It is generally assumed in the literature that the monolayer Langmuir isotherm describes gas adsorption behavior in shale gas reservoirs. In this work, we have analyzed several experimental measurements of methane adsorption from the Horn River Shale core samples that obey the Langmuir isotherm. INTRODUCTION In nature, gas shales are characterized by extremely small grain size, extremely low permeability on the order of nano-Darcy (10-6 md), small porosity, and high total organic carbon (TOC). Shale can serve as both source and reservoir rock. The amount of gas in place in shale is strongly affected by the TOC, clays, and the adsorption ability of methane on the internal surface of solid (Martin et al., 2010). Since a considerable amount of gas in shale reservoirs is adsorbed, investigation of gas adsorption can provide critical insights into evaluation of well performance and reservoir characterization. Generally, natural gas in shale reservoirs is stored as free gas in both larger mineral pores and natural fractures, as well as adsorbed gas within organic matter (Leahy-Dios et al., 2011). EXPERIMENT METHOD & THEORY Adsorption Experiment Several experiments were carried out on 9 shale core samples obtained in a vertical well drilled within Horn River basin (Figure 1). The CH4 adsorption isotherms were measured for the different depth. In order to measure the amount of adsorbed gas, the high pressure Belsorp-HP equipment applying volumetric method was used. The temperature was kept at 298 K and pressure was increased up to 18 MPa. Approximately 5 g of crushed sample was used for each measurement."

Jan 1, 2016

By V. Bondarenko

The importance and necessity of gas hydrates deposits development followed by natural gas extraction is considered in the present paper. Analysis is given to world sources focused on methane hydrates formation conditions. Information covering the most perspective gas hydrate deposit of the Black Sea is presented in the article. Two most common methods of gas hydrates development ? thermo stimulation and inhibitor injection are analyzed presenting their comparative characteristics. Basic scientific trends and developments of underground mining department in the field of gas methane extraction from gas hydrates are scrutinized. Schemes and methods of natural gas hydrates development are shown together with formulas, parameters and factors influencing the extraction process. Also the analysis is given to the possibility of gas hydrates formation from methane-air mixtures of degassing wells from coal mines of Ukraine. Improved experimental unit for gas hydrates formation under laboratorial conditions is presented with its basic characteristics. General conclusions and basic tasks requiring further research are given in the end.

Aug 1, 2013

By J. L. Ellenberger, T. Miller

"A limestone mine in Ohio has had roof instability problems that have led to massive roof falls extending to the surface. This paper describes a collaborative study of these events undertaken by the National Institute for Occupational Safety and Health and the mine owners. The study focuses on the roles that weak, moisture-sensitive floor and weak bands in pillars play in a general instability that led to roof falls at this mine. The NIOSH Stone Mine Pillar Design software (S-Pillar) does not include analysis for weak floor or weak bands and recommends that when such issues arise they should be investigated further using a more advanced analysis. It is important to recognize that without the impact of the floor or weak bands, the calculated inherent stability factor for these pillars is within the recommended design range. Therefore, to further investigate the observed instability occurring on a large scale at the Ohio mine, FLAC3D numerical models were employed to help determine the failure mechanism. Roof-to-floor extensometers were also installed in the areas predicted to have further instability. This case study will provide important information to limestone mine operators regarding the impact of weak floor causing the potential for roof collapse, pillar failure, and subsequent subsidence of the ground surface. This recent case demonstrates that weak floor can be a significant factor in pillar stability and should be assessed during the design stage of the mine.To an area-wide failure (Zipf, 2001). In that case, it appears that the pillars had actually remained intact. However, moisture-related yield of the weak floor caused deformations which passed through pillars and into the roof, triggering roof collapse around the intact pillars (Esterhuizen et al., 2011). This previous case and the case presented in this study, while not identical, both demonstrate that weak floor and/or bands within pillars can be a significant factor leading to instability."

Jan 1, 2015

By T. N. Andersen

The history of gold and silver analyses shows an interesting duality. On one hand, classical chemical and instrumental methods have evolved to meet changing needs, but on the other hand, the age-old and somewhat empirical fire assay has remained a popular tool. Inasmuch as gold and silver generally have been present in ores at low concentra¬tions, methods have been challenged by a need for sensitivity and selectivity coupled with reasonable assay time. A progressive increase in the importance of low grade materials as ore sources has led to the need for improved methods. Assays of these materials are required for process control and accounting in operating plants as well as for guiding research and development activities. The analytical response to these needs is evidenced by numerous reviews published through 1977-¬e.g., cf Kolthoff and Elving (1966), Beamish and Van Loon (1966, 1972, and 1977), Young (1971) , Mallett (1970), and Sen Gupta (1973). In this paper we present a brief sketch of the history and status of various gold and silver methods. A more detailed summary of atomic absorption spectroscopy (AAS) is Given, as this method has gained in popularity more than other assay methods. AAS methods currently in use are summarized and discussed briefly. This paper is not meant to be a detailed review, as are the above mentioned publications. Rather, we borrow from those works and more recent papers to report trends in gold and silver analyses (particularly in AAS). Also, we discuss some selected poten¬tial problems, and problems that have been experienced by this laboratory.

Jan 1, 1981