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By L. Adler

INTRODUCTION The purpose of this paper is to describe in engineering terms the singular and basic operational kinematics of all excavating and bulk handling equipment. The safe and efficient use of equipment will be fostered by enabling the engineer to conceptually duplicate the operators' "tasks" in directing and controlling it. A simple graphical and notational scheme will be introduced to define the essential gross repetitive motions. The significance of this effort includes filling a vital analytical gap at the work face, and in establishing direct communications between the engineer and equipment operator. Since all types and sizes of earth- moving equipment are covered, a major concern has been to integrate equipment specialties into d single encompassing discipline. Equipment types are closely related to the working conditions, and their selection and evaluation are also considered. The extension to human factors analysis is natural and predictable. Since human [actors are involved, the operational analysis can also be considered a catch-all for many subtle vagaries. BACKGROUND Symbolic modelling linked to a notational system will be developed and intensively used. This constitutes the "language of science," providing a shorthand method which gives immediate recognition, is fluent, explicit, reinforcing, unequivocal and provides limitless associations. Many examples of symbolic modelling exist in chemistry, physics, the military, engineering sciences and it is a major tool in mapping. Its use is so ubiquitous that it often goes unnoticed. On the other hand it must be realized that something is lost in simplifying and idealizing what is an extraordinarily complex occurrence. The components describing the basic operational kinematics of equipment include: (1) the vehicular motions as a rigid body and (2) the job-end motions focussing on excavating (Adler, 1985). These provide all of the components in the load-haul-dump sequence (L-H-D) , and will yield three dimensional expressions. Complex patterns can also be assembled from these simple elements. An existing equipment designation employed in earthmoving will be integrated into this approach (Carson, 1961). Along with the basic motions, corresponding working conditions will be noted.

Jan 1, 1986

By J. Güntner

A significant portion of Outotec's business relates to the application of fluidized bed for processing a wide range of industrial materials, including gold ore and gold concentrate. As part of the former Lurgi and Boliden organization, our division constructed the first industrial reactor for roasting sulphur-bearing materials in 1950, based on the principles of fluidized bed technology. This process, when combined with efficient heat recovery and off-gas treatment and its conversion to sulphuric acid, became the standard for processing sulphur-bearing ores. In the last 60 years we have delivered more than 265 plants and developed (in addition to the standard fluidized bed solution) variants of the fluidization technology, such as the circulating fluidized bed and the bubbling fluidized bed. This paper describes the different options of the fluidized bed technology for gold roasting reflecting on main process design criteria.

Jan 1, 2011

Over the past several years, copper prices have surged from under a dollar to over three dollars a pound. However, the long-run trend in real copper prices since at least the early 1970s has been sharply downward. While many now contend that the long-run trend in real copper prices is now upward, the result of structural changes in this market, others are sceptical. Nor is copper unique; the prices for a number of other metals, including aluminium, iron ore, lead, nickel and zinc, have followed similar patterns. This paper examines the forces behind short-run and long-run trends in metal prices. It first focuses on the short run, where it argues that shifts in demand are largely behind changes in prices. It then turns to the long run, where it concludes that production costs and supply largely govern price trends. Finally, it explores several implications of these findings, including those for diversification and market risk, for forecasting mineral prices, for assessing the growth of metal demand in China and elsewhere on metal prices, and for changes in the long-run price trends.

Jan 1, 2006

By G. W. Jones, F. E. Scott

"INTRODUCTION As a part of its program of promoting safety in mining and other industries, the Bureau of Mines investigates the explosion hazards of combustible Gases, vapors, and solids. It also investigates various means and methods of controlling and mitigating explosions.Dichlorodifluoromethane, CC12F2, has been found to be very efficient as a quenching agent for methane flames. 4/ This substance is a gas at ordinary temperatures and pressures and is relatively nontoxic and stable at mod rate temperatures.Tremendous quantities of dichlorodifluoromethane were used daring the late war as an expelling agent for aerosol mixtures in ""aerosol bombs."" At one time during the war the demand for Dichlorodifluoromethane became so gent that there was barely enough of it to supply the Army and Navy and virtually none for civilian needs. During this period of scarcity the Bureau of Mines, in cooperation with the Bureau of Entomology, Department of Agriculture, investigated the possibility of substituting other materials in part for the dichlorodifluoromethane. It was required that the resulting mixtures be satisfactory expellant and noninflammable under all normal conditions of use."

Jun 1, 1946

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By John S. Brock

During 1964 and 1965 a mineral exploration program was carried out over an area of approximately 250 square miles, located in the Anvil-Vangorda Creek area of east central Yukon, 125 miles northwest of Whitehorse. The Vangorda deposit, a massive lead-zinc sulphide body discovered in 1953, was centred in the area proposed for exploration, a northwest trending belt located between the southwestern flank of the Anvil Range and Pelly River. Exploration for base metals in the remote Anvil area had previously been restricted by poor metal markets in the late 1950's. Regional geologic information was also limited except for publication of a scale 1 inch to 4 mile map by the Geological Survey of Canada in 1961. To effectively explore this area, a combination of geophysical and geochemical methods were essential due to extensive overburden cover varying in depth from a few feet to over 300 feet. (Figure (i) Key Map) Dynasty Explorations initiated the first comprehensive regional exploration program in the Anvil area, utilizing saturation prospecting methods employing geologic, geochemical and geophysical methods. The program involved an approach demanding continual modification of technical and physical logistics. After a total of 12 months of field work involving an expenditure of approximately $450,00, massive sulphides were discovered which subsequently proved to be an economic orebody. Thirteen properties had been acquired and explored. Ten separate geophysical anomalies had been outlined by a combination of magnetic, electric and gravimetric survey techniques of which five were tested by rotary drilling and two by diamond core drilling. The discovery of the Faro deposit was a direct result of this program.

Jan 1, 1971

By A. Coulombe

"RésuméL’analyse des séquences d’exploitation, actuellement en usage pour les gisements très inclinés, a démontré qu’elles ne sont pas toujours optimales du point de vue du contrôle des terrains et de la concentration des travaux d’abattage (nombre de chantiers simultanément en opération). Effectivement plusieurs séquences sont très propices à la création des nombreuses zones de hautes contraintes, qui sont à l’origine des effets de pilier. L’étude de cas de la mine Lac Shortt a démontré que certaines séquences d’exploitation, actuellement en usage, ne sont surtout pas adéquates dans le cas d’un état élevé des contraintes naturelles. En effet la mine a eu de sérieuses problèmes avec le contrôle des terrains (coups de terrains et les effondrements des épontes). Ces effondrements étaient responsables de la dilution excessive et des pertes importantes des réserves minières. Les deux nouvelles séquences proposées, visent la meilleure redistribution des contraintes d’exploitation en vue d’éliminer la création des effets de pilier. En plus elles permettent une concentration plus élevée des travaux d’abattage.À notre avis les séquences proposées pourraient améliorer substantiellement la stabilité des chantiers d’abattage et par la suite les performances technique et économique des opérations souterraines. ABSTRACTThe planning of underground mining sequences represents an important aspect of the mining operation. The analysis of mining sequences actually in use for very steep orebodies has demonstrated that they are not always optimal, considering ground control and the number of stopes simultaneously in extraction. These sequences are conducive to the creation in the rockmass of several stressed zones caused by pillar effects. The case study of Lac Shortt mine showed that the sequences of exploitation currently in use are not adequate especially in the case of a high state of the natural constraints. Indeed, the mine had serious problems with ground control (rock bursts and collapse of walls). These collapses were responsible for excessive dilution and significant losses of mining reserves. The two new sequences suggested aim for the best redistribution of exploitation constraints in order to eliminate creation of pillar effects. Moreover, they allow a higher number of stopes to be extracted simultaneously. In the opinion of the authors, the sequences suggested could substantially improve the stability of working areas and, thereafter, technical and economical performances of the underground operations."

Jan 1, 1998

By Paul Stothart

Context ? Industry is active in urban, rural, and remote regions ? Faces a range of environmental challenges and ?social license? issues ? There are also Aboriginal and northern issues ? Also very active internationally, with associated challenges ? Environmental/social groups often target the industry ? The important contribution of the industry should not be overlooked Useful Minerals and Metals Minerals are intrinsic to the residential, municipal, communications, and transportation infrastructure of modern life. Examples: Hybrid motors - nickel hydride batteries Water purification systems ? nickel, rare earth elements Catalytic converters - cerium Screens and monitors - several rare earth elements Clean electricity - uranium Circuitry - gold, copper, aluminium, lithium, titanium, silver, cobalt, zinc Instruments - copper, silver, nickel, cobalt, copper, brass Protective products ? zinc, calcium carbonate, sulphur

May 1, 2008

By S Arnold

Properties of the soil profile fundamentally control water-limited ecosystems. Soil water availability affects vegetation dynamics of plant communities, but is also affected by these communities in return. Understanding this eco-hydrological interplay and the role of physical soil restoration is crucial for successful rehabilitation and management of post-mining landscapes in semi-arid areas. However, uncertainties exist in both the mathematical description of plant communities within ecological submodels and the predictability of future rainfall events. This study uses information gap decision theory combined with an ecohydrological system model to investigate how both uncertainties impact decision-making in the context of ecosystem rehabilitation. A range of management strategies are investigated to identify the optimal soil thickness for successful rehabilitation of native plant communities in Central Queensland. The results emphasise that thicker soils can counterbalance uncertainty in mathematical description of plant communities by increasing the simulated survival probability of plant communities. However, the influence of thicker soils on the robustness of plant communities against a change in future rainfall amount is rather marginal. By allocating an economic value for restoring a particular thickness of soil layer, these results can be used to evaluate the costs of ecosystem re-establishment with regard to two target measures - the survival probability of the plant community and their robustness against climate change.CITATION:Arnold, S, 2012. Finding optimal soil restoration strategies in the face of uncertain future rainfall amount, in Proceedings Life-of-Mine 2012 , pp 91-96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By Yavuz Ali Topkaya, Aydin Rusen

"In this study, zinc and lead recovery from zinc plant leach residue obtained from Çinkur using hydrometallurgical methods have been investigated by laboratory scale experiments. Considering more than one million tons leach residue (LR) rich in Zn (12.43%) and Pb (15.51%) in the stockyard and environmentally hazardous, it is essentially necessary to process Çinkur LR. Zinc and lead have been recovered in two main stages. As a first step, Çinkur LR was releached by using hot sulphuric acid for zinc recovery. About 72 % Zn was recovered by using 150 g/l H2SO4 at 95 oC in 2 hours with a pulp density of 200 g/l. Secondly, for lead recovery brine (NaCl) leaching tests were performed on the secondary Çinkur LR obtained after acid leaching process. In brine leaching while lead recoveries up to 95 % could be attained at a low pulp density, the maximum recovery obtained was 84.9 % at a high pulp density (200 g/l) with 300 g/l NaCl concentration in 10 minutes at 95 oC. Introduction Zinc and lead have been known and used by humans since ancient times and also they are important nonferrous metals [1]. Zinc and lead have different properties thus they are used in various application areas, ranging from automobiles to construction, from batteries to textile. Zinc and lead deposits are widely distributed in the Earth’s crust. The principal ore mineral for zinc is zinc sulfide, Sphalerite (ZnS), and lead sulphide, Galena (PbS), is the main source of lead in the world [2].Although zinc is generally produced from sulphidic ores (ZnS) or concentrates by Roast – Leach – Electrowinning (RLE) in the world, in Turkey, zinc production is based on zinc carbonate ores (ZnCO3), and at the Çinkur plant zinc was produced from zinc carbonate from its establishment to 1997 due to high reserves of zinc carbonate in that region. Çinkur is the only plant in Turkey that produces Zn from primary ore containing ZnCO3 by Waelz – Leach - Electrowinning route [3]. However, due to depletion of local high grade ores, oxidized ore concentrates were imported from Iran after 1997, until this plant was shut down. Therefore, there are two different leach residues (LR) which are Turkish LR (TLR) and Iranian LR (ILR) in Çinkur stockpiles. It has been estimated that the total amount of leach residue is more than one million tons of which the major part is Turkish leach residue (TLR)."

Jan 1, 2008

By John P. Dunford, Lewis A. Martin

Researchers from the Spokane Research Laboratory, National Institute for Occupational Safety and Health, in cooperation with engineers from the Department of Mining and Geological Engineering, Montana Tech, Butte, MT, conducted tests to evaluate the tensile strength, fiber count, and adhesion of shotcrete applied to panels at the Chief Joseph Mine, a research and training facility operated by Montana Tech. The tests were conducted in the mine ramp 45 m (150 ft) inward from the access portal at a 15.25-m- (50-ft) long test area divided into five 3-m- (10-ft) long sections. The shotcrete was applied with an Aliva 240.5 machine fitted with a predampener. Different amounts of fiber were entrained for each panel. Background data for the tests were obtained from earlier tests in Nevada, where the typical amount of fiber in the shotcrete is 6.54 kg/m3 (11 lb/yd3). All shotcrete was applied to a minimum thickness of 76 mm (3 in). Cylindrical cores were drilled at the wall-rock interface, and adhesion was tested after 28 days of curing. The goal of this research is to reduce the need to install multiple supports at the advancing face by creating a safer mining system that limits the time miners are exposed to unprotected roof.

Jan 1, 2005

By Yang RL, Bailey ML

During overburden blasting operations in dragline pits, coal edge losses along the lowwall edge of the new pit are often experienced. In tonnage terms, losses can be significant. With the thick seams at Callide Mine, 20,000 tonnes of coal can be lost along a 600 metre pit. In addition to the immediate dollar value of the coal, replacement of this coal (from which overburden has been removed) will be from higher ratio and higher cost pits in the future. Unit costs of production for the remainder of the coal uncovered in the current pit increase. Experiments involving variation of blasthole inclination and/or amount of standoff on the front row of blastholes have given no significant improvement in the coal edge loss control.

Jan 1, 1988

By Robert Franke

(Butte Meeting, August, 1913.) IN view of the prominence which the conical mill has attained in the fine-crushing field .within the few years since its introduction, the following comparison with its more mature forerunner, the Chilean mill, based on extensive tests, is submitted in the interest of the milling profession. Soon after designing the concentrating plant of the Miami Copper Co. in 1909, the Hardinge conical mill made its appearance in the milling forum. . Its possibility as a suitable crushing device for the plant was well recognized, but in view of the lack of commercial demonstration, at the time, as to capacity, efficiency for desired product, and the still more uncertain factors of cost of maintenance and power consumption, it was deemed that the immediate adoption of this machine throughout the plant would be a hazardous undertaking. For these reasons it was decided to equip the majority of the immediately required units of the plant with Chilean mills, the fine-crushing proficiencies of which were better known, and one section with Hardinge mills, to serve as a test unit for the guidance of future installations and replacements. Thereby, after 1.5 years' operation with both types of mills, a thorough test as to metallurgical efficiency and cost economy has been obtained. The conical mill used in these tests is the 8-ft. Hardinge pebble mill, having a cylinder 22 in. in length. The cylindrical portion of this mill is lined with cast-iron liner plates, and the conical extensions with silex bricks bound together by cement. Each. liner plate carries a projecting lifter, the function of which is to increase the height of drop of the lifted material. Danish No. 5 pebbles, obtained from the coast deposits of Denmark, are used for the grinding charge. The Chilean mill used is a fast-running, 3-roller, 6-ft. Saturn mill, with screens of 0.037-in. opening. The feed to these mills is the oversize of Callow screens having 0.029-in. openings, which. follow rolls crushing to 0.5 in.

Jan 7, 1913

By John A. Dresser

Seventy years ago a period of prospecting and mining activity began in the Eastern Townships of Quebec that seems to have been quite equal to that of recent years in the Rouyn field. In the following six or seven years a large amount of work was done over a widespread area. About fifty deposits gave some shipment of ore, from a few tons upwards, and as many as five hundred occurrences of copper were made known in the district by official records. Comparing the scale of commercial undertakings of that time and of the present day, these developments must have occupied quite as large a share of the capital and man-power of the Province as northern Quebec employs today. Working conditions at that time were not very favourable. The country was then only newly opened for settlement, and colonists were few and widely separated. Roads of the class built today were unknown. A single line of railway, the Grand Trunk, crossed the district from east to west. Colonization companies controlled large blocks of land on which they owned mining rights and usually reserved these rights in whole, or in part, when selling the lands. Then, as now, the precious metals belonged to the Crown. Yet the work was not without its successes. One of the first deposits discovered, the Acton, was, for a few years, one of the most profitable producing copper mines of its time. Another, the Eustis mine, has been in almost constant operation ever since, and is now vigorously pushing further development. At least two others, now quiescent, proved profitable operations, and several made considerable production. The manufacture of sulphuric acid in Canada was begun by the founder of the Nichols Company at Capelton, on a deposit that is now being re-developed, after a long and creditable career.

Jan 1, 1928

By Valenta R. K

Copper-gold deposits associated with iron oxide rich rocks (ironstones) form a distinctive and significant ore association which occurs widely, but not exclusively, in the Proterozoic. The ironstone association is geochemically distinct from the BIF-hosted gold association (Phillips and Groves, 1983). Not only is the former association higher in its copper and commonly uranium, FEE, ¦bismuth, molybdenum contents, but also the ironstones in many cases do not originate as chemical sediments. Although both associations form in metamorphic environs, they reflect differing tectonostratigraphic settings and with consequent differences in ore-forming fluids and ore-forming mechanisms. This paper discusses the nature and origin of the ironstone-related copper-gold association, with particular reference to the Tennant Creek district in northern Australia, and emphasises the two stage origin of mineralisation. The genetic model developed has significant implications for other ore-bearing environments.

Jan 1, 1990

THE FRENCH occupation of the Ruhr valley and other districts on the eastern side of the Rhine continued during March to be the pre-dominating feature in European affairs. There were sporadic troubles and disorders, but on the whole the Germans were passive while the French were consider-ate. However, it became more and more evident that France is not in this way going to succeed in collecting the reparations, to which of course she is entitled. It appears to be a case of Germany being unwilling to pay what is claimed from her and France being unable to make her do it. However, as the month drew on it became reason-ably clear that both the French and the Germans were becoming more and more disposed to get out of an impossible and dangerous situation. It was suggested that the basic principles upon which Germany now is ready to resume reparations payment are as follows: (I) appointment of a commission to establish Germany's ability to pay and to fix limits to the reparations; (2) a series of international loans; (3) the amount to be paid cannot exceed approximately 30,000,000,000 gold marks. From Russia came numerous reports reflecting economic and political changes there. One of these told of a Cossack insurrection in the southeast of European Russia. Another reported that the expatri-ated Russians recognized the solidity of the Bolshevik government and would contest it no longer, and would reunite with other Russians if they would recognize the rights of private property and validity of former debts. This is the same position that is taken by most of the foreign governments, and especially Great Britain and the United States, with respect to recognition of the present government of Russia. Secretary Hoover announced that it is no longer necessary to give famine relief to the Russians, their present need being for credit, not food. Lenine was reported seriously ill and probably incapacitated for further activity. Administration of the government, in succession to him, by a triumvirate was suggested.

Jan 4, 1923

By Inn-Joon Park

Major problems associated predicting soil-structure interaction behavior are based on the fact that soil is neither homogeneous nor elastic and soil properties are spatially variable. There also exist significant coupling problems between the behavior of the structure and geologic media. When designing foundation or other geotechnical structures, the load transfer between the soil and structure takes place at the contact surface. This surface is called the interface. The behaviors of interface play an important role in the load-deformation response of soil-structure interaction systems. The purpose of this study is to develop improved model for simulation of saturated sand-steel pile interface behavior based on a general concept, called the disturbed state concept (DSC), which can characterize the behavior of saturated soils under dynamic loads. In this study, the Disturbed State Concept (DSC) constitutive model is calibrated and modified for steel pile-saturated sand interface and interaction by using the continuous hardening model for relative intact (Rl) state and the critical state model for the fully adjusted (FA) part in the saturated sand material. The general formulation for implementation has been developed. Then, the DSC model with modification for interface and saturated sand is implemented in finite element program based on the generalized Biot's theory. The interface tests under one-way monotonic and two-way cyclic loading and cyclic triaxial tests are executed for defining the parameters for interface and surrounding soils. Based on these parameters, steel pile-saturated sand interface and interaction are numerically simulated using the finite element program modified in this study. The DSC predictions show improved agreement with the observed results from laboratory test.

Jan 1, 2002

By A. Nel

The gold mining industry in South Africa stands to benefit much from the implementation of the self-directed work team concept. Its introduction implies flatter hierarchical structures, empowerment of the workforce and increased participation. Research indicates that half of the initiatives to implement self-directed work teams, however, fail, and it is therefore imperative for companies to be aware of the factors impacting on the effectiveness of self-directed work teams in order to focus on these early in the implementation phase. The objective of the study was to qualitatively determine these factors. Semi-structured interviews based on the phenomenological method were carried out. The sample included members of, and individuals involved with, self-directed work teams (N= 26) from a large gold mining company in South Africa. Results show that most respondents rated the availability of resources to do their work as the most important factor affecting their effectiveness.

Jan 1, 2006

By Brison Robertson, W. P. Fishel

THE carbide-forming tendencies of the various steel-alloying elements, or their affinities for carbon, is a subject that has received considerable attention, but little more than a probable arrangement of the elements as to their carbide-forming tendencies has been proposed. The physical properties of alloy steels depend upon the relative proportions of the elements present and their combinations. One important phase of this subject is the distribution of carbon between the various elements present. The distribution of carbon between iron and other elements evidently will depend upon: (I) the affinity of each for carbon; (2) the relative atomic masses of the elements present; and (3) the possible formation of compounds between the alloying elements and iron and between the elements themselves. In ternary steels the case is simplified, especially in systems in which the element and iron form no compounds. In such systems iron and the alloying element are competing for the carbon present. In this work the distribution of carbon between titanium and iron has been studied by measuring the relative amounts of iron carbide and titanium carbide present in a series of annealed steels in which the ratio of titanium to carbon extended from 0.527 to 4.61. EXPERIMENTAL PROCEDURE Ten Fe-Ti-C alloys, weighing about 250 grams each, were prepared by melting under a vacuum, in an induction furnace, Armco iron, carbon-free ferrotitanium (25 per cent Ti), and pure carbon. Vacuum melting prevented the formation of titanium oxides and nitrides, which would complicate the problem. The melts were made in graphite crucibles lined with sintered magnesium oxide. The ingots were cooled in the furnace under a vacuum and were then completely annealed at 950°C. The determination of the amount of titanium carbide present was based upon the established insolubility of titanium carbide in boiling dilute (I :4) sulphuric acid, and the complete solubility of free titanium and titanium-iron compounds in this acid. High-carbon ferrotitanium, which had been treated to remove free Ti and Fe, was found to be completely insoluble in the acid; and the carbon-free ferrotitanium used in making the alloys was found to be completely soluble. Others 1,2 have reported the insolubility of titanium carbide in sulphuric and hydrochloric acids. Turnings from the ingots were digested with boiling sulphuric acid (1:4) until all action had ceased. The carbide residue was filtered off and analyzed for titanium, and in some cases for carbon. This represents the titanium that was united with carbon. The filtrate from the carbide residue contains the portion of the titanium that wasin solid solution in the ferrite. Titanium

Jan 1, 1944