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By J. L. Shultz

The Bureau of Mines extended its investigation of methanation catalysts. The noble metals (platinum, palladium, ruthenium, rhodium, osmium) and rhenium), molybdenum, and tungsten were tested in hydrogenations of carbon monoxide and carbon dioxide at 21 atmospheres in a temperature range between 200° and 600° C. From the 8 metals studied) 25 catalysts represent 5 catalyst types were prepared and tested. The impregnated 0.5-percent-ruthenium catalyst proved to be the most active and versatile of all the catalysts produced. Tungsten and the noble metals other than ruthenium were low in activity and usually required temperatures above 500° C for appreciable production of hydrocarbons. Molybdenum was moderate in activity, but further improvement in molybdenum catalysts seems possible.

Jan 1, 1967

By C. Jay Hodgson, P. J. MacGeehan

"The gold ore zones of the Campbell and Dickenson mines occur within a km-wide, 2 km-long zone of highly altered and anomalously fissile and deformed volcanic and subvolcanic intrusive rocks, cut by a series of mainly post-deformation mafic and quartz-feldspar porphyry felsic dykes.Three main periods of gold ore-forming hydrothermal activity are recognized. In the first, the mine rocks were extensively altered and gold and arsenic enriched; syn-volcanic auriferous veinlet and low-grade chemical sedimentary ores were deposited in what was a major discharge zone of a submarine hydrothermal system. The chemical sedimentary ores are closely associated spatially and temporally with domal rhyolitic extrusions. Because of its mechanical and chemical properties, this synvolcanic alteration zone became the locus of later deformation, and the site of the generation of auriferous hydrothermal solutions, perhaps by pressure solution processes at depth. These solutions deposited, synchronously with deformation and metamorphism, the second and most economically important type of ore zones in the mine: large foliation-parallel and foliation-oblique banded carbonate- 'chert' Rssure-filling veins.In the third and final mineralizing event, high-grade, pipeshaped zones of siliceous replacement-type mineralization, and quartz-arsenopyrite-gold veins, were superimposed on the previous mineralization types after most of the deformation, but before the emplacement of the late dykes. The source of heat and also possibly the fluids for the third mineralizing period may have been the dyke-forming igneous activity. The textures and mineralogy of the banded carbonate- 'chert' veins suggest a near-surface (<3 km) environment of deposition, but their relationship to the fabric of their host rocks indicates they were emplaced in an environment, presumably at considerable depth (5-10 km?), in which the rocks were undergoing intense penetrative deformation. This anomaly is unresolved."

Jan 1, 1982

By H. E. Powell

This Bureau of Mines study describes two processes for recovering zinc, copper, silver, and iron from the magnetic fraction of a waste generated by the primary smelting of zinc in horizontal retort distillation furnaces. The laboratory-scale procedures include reduction melting to produce a high-copper iron and matte smelting to produce a copper-silver-iron matte and metallic iron. Zinc is fumed in each process and recovered as the oxide. Direct reduction melting yields a metallic iron high in copper and a small rich matte from the sulfur contained in the waste. The products of the second process are a matte containing essentially all of the silver, about 80 pct of the copper and 37 pet of the iron, and an iron-copper alloy containing all of the remaining copper. Extraction with metallic lead or sodium sulfate recovers essentially all of the copper from the molten high-copper iron and yields an acceptable foundry iron.

Jan 1, 1973

By C M. Deosthale, V N. Pangal, M N. Rao

New Mangalore Port is the most important port in Karnataka State, on the west coast of India on Arabian Sea. It handles export of iron ore, granite, coffee, spices etc and imports of crude oil, fertilizers etc. Since 1991, after economic liberalisation by the Government of India, the exports and imports at this port got a boost. Hence the Port Trust felt the need to increase the draught by about 3 to 5 meters for access to bigger ships. In response to a global tender in 1995, the Dutch Dredging Company got the contract to remove 30,000 cu.m of hard granite bed rock, covering 28,000 sq.mtr. area for the Turning Circle and oil Jetty. The operations of drilling, blasting and dredging were to be carried out to deepen the area to about 15 m draught without affecting the normal trade at the Port. This was a time bound contract to avoid interruption by severe Monsoon rains.

Jan 1, 1999

By G. Chitiyo

Prediction of pothole characteristics is a challenging task, confronting production geologists at the platinum mines of the Bushveld Complex. The frequency, distribution, size, shape, severity and relationship (FDS3R) of potholes has a huge impact on mine planning and scheduling, and consequently cost. It is with this in mind that this study was initiated. Quantitative analysis of potholes indicates that pothole size (area covered) can be described by two partly overlapping lognormal distributions. These are referred to as Populations A (smaller) and B (larger). The range of observed pothole sizes conforms to a simple double exponential growth model based on Newton&apos;s Cooling Curve. A third size range of very large potholes (Population C) that could not be modelled properly within the proposed growth model is interpreted as to represent a very early phase of aggressive regional thermo-chemical erosion and potholing. In general, potholes are dominantly quasi circular with only a subordinate tendency of elongation. In the UG2, potholes with elongated forms are more prevalent in the size range between 20 and 500 m diameter. In the Merensky Reef elongated potholes are more common in the size range above 50 m in diameter. Although not distinctly visible, elongation of potholes in both the UG2 and the Merensky Reef show a net north/south orientation. Using shapes of pothole rims and floor areas, documented for the UG2 in the Waterval Shaft area, it is demonstrated that the northern, down-dip edges of potholes have steeper dips than the southern, up-dip edges. Spatial distribution studies using a uniform quadrant method suggest that in both the UG2 and the Merensky Reef, the potholes are randomly distributed, with a tendency towards clustering. Clustering appears to be more prevalent in the smaller Population A potholes. Bearing all findings in mind, it is found that the model of thermo-chemical erosion of the cumulus floor by new influxes of superheated magma best explains the observed data. Partial to complete melting of the cumulate floor occurred in three phases. The first represents the emplacement of hot magma. This magma, due to turbulent flow and high chemical and physical potential, aggressively attacks the existing floor (crystal mush on the magma/floor interface). Regional erosion is manifested by large, often coalescing potholes. During the second phase, when the magma emplacement process ceased and cooling in situ started, two distinct periods of pothole formation ensued. The first is related to rapid cooling along the relatively steep part of the Newton Cooling Curve, when Population B potholes nucleated randomly and grew rapidly with concurrent convective overturn and largely laminar flow condition. The second period of cooling occurred on the shallow-dipping part of the Newton Cooling Curve. Population A pothole growth became more subdued and nucleation appears to have been, at least locally, clustered. The final phase of this proposed &apos;super magma cycle&apos; was introduced when chromitite crystallization and precipitation terminated pothole formation. This was followed sequentially by pyroxene and plagioclase crystallization to form the typical cyclic units of the Critical Zone. No suitable proxy could be found for the prediction of pothole density of potholes associated with the UG2 (likely due to limited spatial data coverage), and these are best predicted by extrapolation. The Merensky Reef slope index, in contrast, provides a proxy for pothole density, enabling prediction with reasonable confidence. This predictive model has been verified using underground information. The findings made during the course of this investigation have, when implemented, significant impact. Successful implementation will not only allow enhanced resource and reserve definition, but also better mine planning and scheduling.

Jan 1, 2008

By Eiji Iwamura

"Two types of diamond-like carbon (DLC) films with different microstructures were prepared by unbalanced magnetron sputtering, and the tribological properties of the nanoscaled DLC multilayer coatings consisting of alternating layers of graphitelike and amorphous-like microstructures were examined. The DLC microstructure was characterized by certain features of graphite-like clusters, in that some of them had onion-like structures. The films filled with the clusters were obtained in a condition with an incidence of high influx of energetic electrons, and the other films without apparent cluster structures were formed in a condition with ion bombardment controlled by negative bias voltage applied to substrates. Stacking each film layer-by-layer, the nanoscaled multilayered coatings showed superior tribological properties to individual single-layered films due to the combination of properties induced by the difference of microstructures.IntroductionIn various tribologiql applications, it is necessary for diamond like carbon (DLC) coatings to have adequate adhesion, significant hardness and a concomitant low friction coefficient. A number of deposition techniques and coating structures have been proposed to achieve suitable DLC properties [1-3]. However it is still difficult to obtain a satisfactory level of combination of the properties particularly desirable for engineering applications.In this study, the features of unbalanced magnetron sputtering were demonstrated with the effect of ion and electron bombardment. Two types of microstructures , namely amorphous-like and graphite-like, were prepared by changing the condition of the charged particles bombardment during deposition. Using the difference of properties induced by the microstructures, nanoscaled DLC multilayered structures were examined in an attempt to improve tribological properties."

Jan 1, 2000

The Callie Underground Mine is located in the Tanami Desert 560 km Northwest of Alice Springs in the Northern Territory and is currently operated by Newmont Australia Limited with all mining activities carried out by Henry Walker Eltin. Callie was discovered in the region in 1991 with the box cut portal commenced south of the pit in 1995 and underground ore production commenced in 1998, after completion of the profitable Callie Open Pit. Development is currently occurring at depths of over 700 m with the decline currently below the 640 Reduced Level (RL) level (surface RL of 1400) with production haulage from 600 m below the surface. The combination of auto compression, a moderate geothermal gradient of 2¦C/100 m and diesel heat transfer causes the wet bulb temperature of intake air at the bottom of the mine to be typically 5¦C higher than on the surface. Wet Bulb temperatures can be up 5¦C higher again in active areas under secondary ventilation. During the 2002/2003 wet season many activities in the lower levels of the mine were stopped due to miners experiencing adverse heat related symptoms or the temperatures exceeding the Underground Heat Management Procedure stop job criteria of 32¦C wet bulb. To improve the working environment, combat the heat related illness and improve operational efficiency, a temporary 1.8 MW refrigerated cooling plant consisting of three 600 kW modules were installed underground to provide bulk air cooling for the lower levels of the mine during the 2003/2004 wet season. Several studies have been conducted in relation to future ventilation demands at Callie and all came to the conclusion, that some mine cooling will be necessary for Callie to meet the high production and development demands. This paper will describe the ventilation network at the Callie Underground operation focusing on the installation, operation and effectiveness of the temporary underground refrigeration plant.

Jan 1, 2005

By Stephen Day, Maria Falutsu, Gary Coulter

Open-pit mining began at Red Dog in 1989. Mining is expected to continue past 2030 but closure planning is an ongoing process. Geochemical studies of rock and tailings were begun in 1996 as part of development of closure plans to address leaching of metals and ARD. The deposit has many different primary and secondary sulfur minerals in amounts that preclude the use of conventional geochemical characterization methods. This paper will describe development of a specific chemical method to estimate the speciation of sulfur and classify wastes according to reactivity.

Jan 1, 2000

By Charles Austin

IN a recent paper the authors1 discussed the reactions to tempering of hypereutectoid steels quenched from 1000° C., as revealed by studies on changes in hardness, electrical resistivity, coercive force and metallo-graphic characteristics. The data, which related specifically to temper-ing temperatures of 550°, 650° and 710° C., for varying periods up to 125 hr., permitted the following important conclusions: 1. The rate of softening of the steels at the temperatures examined differed markedly although the steels were of "similar" general chemi-cal composition. 2. The temperature of maximum softening spread over a range from about 650° C. to the eutectoid inversion. 3. The divergence in behavior was ascribed, at least in part, to a profound difference in tendency to graphitization on annealing at sub-eutectoid temperatures. 4. The mode of spheroidization of the cementite, as revealed by metallographic studies, also varied considerably in the different steels. The purpose of the present investigation is to pursue further the study of the difference in behavior of the steels on tempering over a wider range of temperature. To this end the following features have received particular attention: 1. Comparison of temperatures of maximum softening of the various steels when the quenched samples were tempered for 5 hr. and for 75 hr. followed by furnace cooling and by quenching in water. 2. Determination of the effect of quenching temperature, prior to tempering, on the rate of softening. Quenching temperatures of 1000° and 850° C. were used in the investigations. 3. Examination of the microstructures obtained with the various heat-treatments employed.

Jan 1, 1938

An EAF dust generated in a Swedish steel mill has been leached in hydrochloric acid at The solution obtained has been subjected to purification by cementation followed by precipitation of zinc with sodium carbonate. The thermal decomposition of the precipitate was studied using thermal analysis and X-ray diffraction. The results show that during the calcination of the precipitate three different reactions occur. The decomposition of the solid phases Zn5(CO3) (OH)6, CaZn(CO3)2 and CaCO3 occur completely at 370°C, 560°C and 940°C respectively, yielding a final product containing 61.9% ZnO and 38.1% CaO. Methods to minimize calcium and manganese in the final product are discussed.

Jan 1, 2003

By Harold H. Fukubayashi

The effect of various zinc electrowinning solution impurities on the surface morphology of deposited zinc was investigated. Impurities studied included Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, Pb02, PbSO4, and HC1. Also, the effect of animal glue, gum arabic, and Na2SiO3 additives on the deposited zinc surface structure was studied. Results were compared with deposits from a pure electrolyte consisting of H2SO4 and Zn+2, 200 and 65 gpl, respectively. Zinc was deposited on a Al cathode, 99.9 pct pure, using Pt anodes. Time, temperature, current density, and impurity concentrations were con¬troller The bulk of the tests were conducted at 40° C and 75 A/ft2 (82 mA/cm2). A scanning electron microscope (SEM) was used to examine the surface morphology. X ray diffraction techniques were used to determine crystal orientation and nondispersive X-ray spectrometer analyses were employed in an attempt to locate impurity concentrations on the zinc deposit when pitting or re-solution occurred. The impurities were categorized by their effect on current efficiency, morphology, and apparent mechanism of H2 evolution from the cathode.

Jan 1, 1974

By Paul Sainato, J. Steven Gardner

Sustainable development is defined as ‘development that meets the needs of the present without compromising the ability of future generations to meet their own needs.’1 There has been considerable debate of late between environmentalists and mining operators concerning the current regulation and operation of mountaintop mining. To those not familiar with the practice, it essentially applies an area mining method to a mountaintop, removing all overburden above coal seams, resulting in full recovery of the resource with the excess or swell spoil material - (rock and dirt) being deposited in engineered fills in hollows to the side (known as hollow fills or valley fills - very similar to highway fills). Because most of the dialogue has been adversarial and mining’s response is perceived to be primarily reactive instead of proactive, a rift in communication and value systems between the two sides has widened. Since 1999, the global mining community has been concerned that there is a disconnect between mining practices and the values of today’s society.3 Working through the World Business Council for Sustainable Development (WBCSD), the International Institute for Environment and Development (IIED) was created to review mining practices in a project entitled Mining, Minerals and Sustainable Development (MMSD) driven by the following four goals:

Jan 1, 2005

By R. L. Grayson, S. Yuan

A stochastic model for evaluating the impact of the reliability and maintainability of shovels and trucks on the operational effectiveness of shovel-truck mining systems is presented. In the model, the Markov modeling technique is used to analyze the operating status of a shovel-truck mining system. Then, simulation is used to study the productivity of a shovel-truck system in a particular state. Finally, the relationship between the effectiveness of a shovel-truck system in terms of productivity and the reliability and maintainability of equipment is established. This relationship may be very useful to mine managers in making decisions in surface mining (e.g., regarding production process control, equipment replacement, and maintenance planning). A quantitative study is given to demonstrate how the reliability and maintainability of equipment affect the system effectiveness and how to pinpoint the parameter that has the most significant effect on the system effectiveness. The quantitative study indicated that in order to improve the system effectiveness significantly, the reliability and maintainability of the equipment need to be improved simultaneously.

Jan 1, 1995

By A. L. Holley

The application of scientific methods to the investigation of natural laws and to the conduct of the useful arts which are founded upon them, is year by year mitigating the asperity and enlarging the outcome of human endeavor. More notably, perhaps, are these the facts in that system of productive and constructive arts of which engineering is the general name. In metallurgical engineering especially, within the period of our own recollection, how rapid has been the rate and how wide the scope of progress: the scientific discovery and mining of metalliferous veins; the economical separation and reduction of ores of every grade; the production and regulation of high temperatures; the varied improvements in the manufacture of iron, in saved heat and work, in uniformity and range of products; and, most important of all, the creation and the utilization, to be counted by the million tons a year, of the cheap constructive steels. Wonderful as this range and degree of development may appear to the public eye, the close and thoughtful observer must, nevertheless, conclude that neither the profession nor the craft of engineering may congratulate themselves too complaisantly, but that they should rather acknowledge to each other the embarrassing incompleteness of the union between engineering science and art. There is a small school of philosophers whom we may designate as original investigators, men who come close to nature, who search into first principles, and who follow that scientific and therefore fruitful method by which the relations of matter and force are discovered, classified, and brought within the reach of practice. These wonderful men do not indeed create the laws of nature, as they sometimes almost seem to, but they go up into the trembling mountain and the thick darkness and bring down the tables upon which they are written.

By V. K. Karra

A mathematical model for the performance of a vibrating screen is developed in terms of an oversize partition curve. This is a normalized curve for any assemblage of particles presented for screening when their size is normalized with respect to the 50 per cent passing size (d50 ) under the prevailing screening conditions. Based on the throughfall aperture (hT) of the wire mesh on the deck, the effects of oversize (% >hT), half-size under (% <0.5 hT), deck location and feed rate were evaluated using the existing screen sizing information. All these variables and also the near-mesh (1.25 hTx 0.75 hT) content (%) of the feed affect the d50. Performance data from different decks of a double-deck screen with various feed rates, size distributions and screen apertures were used to evaluate the near-mesh factor. Effects of wet screening and material bulk density are also incorporated in the model. This generalized model is useful for the simulation of a multiple-deck screen. It furnishes the sieve analysis information of all the deck output streams and therefore has a potential use in the over-all circuit evaluation when used in conjunction with relevant crushing and grinding performance models. An example illustrating the prediction capabilities of the model is given.

Jan 1, 1979

By O. G. Paasche, Yuan-Shou Shen

THERE is a disagreement among the various authors about the exact manner of transformation of ZrCr2. Rostokerl and others2 stated that ZrCr2 had a C-14 (MgZn2) type of structure below 1000°C and a C-15 (MgCu2) type of structure at temperatures above 1000°C. Alisova3 and others4 reached the opposite conclusion and stated that the transformation temperature is close to the melting point of ZrCr2. A literature survey shows that various investigators3&apos;= who homogenized the specimens at a temperature higher than 1000°C have concluded that ZrCr2 had the C-15 structure at room temperature. Meanwhile, Jordan et al.4 reached similar conclusions without annealing the specimen. Other investigators1,2,6,7 who X-rayed the specimens in the as-cast condition without annealing reached different conclusions. The investigation reported herein was conducted with the aim of exploring the exact manner of transformation of ZrCr2 by various heat treatment tests. The alloys for this examination were prepared from iodide-reduced zirconium crystal bars, 99.9 pct purity, and electrolytic chromium, 99.9 pct purity. They were melted in a nonconsumable electrode arc furnace with water-cooled copper crucible in a helium atmosphere. The melting loss of each alloy was less than 1.5 pct by weight. Chemical analysis of a randomly selected specimen indicated that there was a very close agreement between calculated and analyzed compositions. Before being heat-treated each specimen was encapsulated in a vycor or quartz tube inside which an argon atmosphere was maintained at a pressure of lower than 1 atm. In determining the crystal structure of each specimen with a Debye-Scherrer camera, the standard procedure8 for X-ray quality analysis (Hanawalt method) was followed. The different series of heat treatment tests in this investigation are tabulated in Tables I and 11. The tests in Series I, specimens from 1-1 to 1-9, which were similar to Rostoker&apos;s experiment1 indicated that the transformation temperature seemed to fall between 870° and 900°C and that the crystal structure of ZrCr2 at lower temperature seemed to be of the C-14 type. However, once the compound is transformed to C-15 type, it is impossible to reverse the transformation back to the C-14 type by first heating the specimen above 900°C and then annealing it slowly below 900°C as shown in Experiments II-1 to II-3. Thus, it appears that the specimen of ZrCr2 will transform from C-14 to C-15 structure when heated above 900°C but will not transform from C-15 to C-14 when annealed slowly passing 900° C even after the extremely slow cooling process such as indicated in the experiment of Specimen II-3. As a valid transformation temperature is a temperature at which the transformation is reversible, therefore the temperature 900°C (or other temperature close to 900°C) is not the transformation temperature for ZrCr2 and the C-14 structure is not the stable structure of ZrCr2 at lower temperatures. The C-14 structure is retained at room temperature because the transformation to C-15 structure is very sluggish and the fast cooling after melting does not allow enough time for the transformation to take place. Additional energy is required to alter the metastable condition of the C-14 structure. The sluggishness of this transformation was again demonstrated through another series of experiments. Four specimens with C-14 structure were taken. Then they were annealed at 900°C but each specimen was soaked for a different period of time, Table 11. X-ray diffraction patterns of this group indicated that the C-14 structure gradually disappeared as the soaking period was lengthened. The figures listed under the column "C-14 Structure, pct" were estimated from the intensity of the d = 2.330 line of the diffraction pattern corresponding to the structure. Notice that the intensity of this line became weaker for longer soaking periods. To determine the transformation temperature of ZrCr2, specimens with C-14 structure (as-cast condition) were annealed at 1300°, 1400°, 1500°, 1550°, and 1600°C, respectively. A final specimen was first heat-treated to 1500°C in order to transform it to C-15 structure, then heat-treated at 1600°C again. From the X-ray analyses of this series of tests, Specimen Nos. III-1 to III-6, it is evident that a transition from C-15 structure at lower temperatures to the C-14 structure occurs at some temperature between 1550° and 1600°C.

Jan 1, 1969

Mining is big business in Ontario. The province is Canada?s leading mining region. It consistently ranks among the top 10 jurisdictions worldwide for exploration spending, reaching about C$1 billion in 2011. More than 26 percent of all exploration and appraisal dollars spent in Canada are invested in Ontario. Minerals produced include nickel, copper, platinum group elements (PGE), cobalt, zinc, diamonds, gold and silver. It was reported that there are more than 600 mining exploration projects in the province. And, recent discoveries of chromite in northern Ontario?s Ring of Fire will add to the province?s mineral production in the coming years.

Jan 1, 2013

By James A. Everts

Calcined bauxites are classified by their major end uses - abrasives and refractories. Target properties are dictated by application and processing requirements. The chemical and physical properties of premium grade calcined bauxites are far more stringent than metallurgical bauxite and this limits the sources and availability. Premium grade calcined bauxites are considered to be strategically critical to the industrialized countries of the world. Subject to disruptions in the key source countries, adequate supplies of premium grade calcined bauxites are anticipated in the foreseeable future.

Jan 1, 1984

By Tim Ross

Slurry injection into mined-out panels is an attractive alternative for disposal of coal preparation plant fines. however, in areas where surface subsidence cannot be tolerated, either by law or necessity to protect surface structures or aquifers, special consideration trust he given to the effect of slurry injection on panel stability. Slurry injection can lead to panel failure and unplanned subsidence by degrading roof, pillar, and floor strength. Water degradation is of particular concern where clay is present in the floor. Recently. unplanned subsidence related to slurry injection occurred at an Indiana room-and-pillar coal mine subject to weak floor conditions. This paper discusses the efforts of the mine operator to determine the causes of the panel failure and to design panels and injection procedures to allow for future economic slurry injection without subsidence. The numerical and empirical/analytical techniques applied give the operator a rational approach to pillar panel design for future injection panels under various cover depths and weak floor conditions.

Jan 1, 1998

The need for geological control in orebody estimation and modelling is self- evident to geologists and mining engineers engaged in practical day-to-day estimation. It is only fairly recently, however, that attempts have been made to incorporate explicitly such requirements into published accounts of geostatistical estimation; see, for example, Dowd and Scott (1982, 19841, Rendu and Readdy (1982), Dagbert et al. (1984), Dowd (1984), Benest and Winter (1984). In practice, many geological controls in automatic or semi-automatic estimation and modelling are essentially geometrical controls. The aim of this paper is to present two techniques for geological/geometrical control. Whilst the applications are new, neither technique is entirely original and both have been adapted from other fields and sources. Both techniques are, in some sense, types of estimators and/or interpolators of shapes. The first is a method for fitting spline surfaces to control orebody boundary estimation and to unroll orebodies. The second is an application of Minkowski addition to interpolate shapes such as orebody outlines or stope boundaries and to control estimations.

Jan 1, 1986