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By Allan M. Johnson

Since 1974 researchers at Michigan Technological University have been studying mine subsidence in the Iron River District of Northern Michigan. The district, which was active from 1881-1978, has had numerous cases of subsidence. Much of the subsidence resulted from rock mass failure but some appeared to have developed primarily in the thick glacial overburden which is a typical feature of this area. This latter observation led to the recognition that some of the surface subsidence was due to piping; i .e., loss of overburden material to the mine voids by groundwater flow (Johnson and Frantti, 1978). The Sherwood Mine was the last mine to operate in the district. With its closedown scheduled for late summer of 1978, a unique opportunity to monitor the mine as it flooded was presented. It was reasoned that with the cessation of pumping, groundwater would rise in the overburden and the mine would flood. The physical characteristics of the mine were favorable for piping to occur as the mine flooded. With the permission of Inland Steel Mining Company and the support of the U. S. Bureau of Mines, a project to monitor the Sherwood Mine for piping subsidence began in June of 1978. This paper present aspects of this study pertinent to the piping-induced subsidence events which occurred at the Sherwood Mine in 1980 and 1981, including acoustic emission monitoring of the subsidence activity, hydrologic monitoring of the groundwater regime and the flooding mine, laboratory modeling of the piping mechanism, and analytic procedures which are under development.

Jan 1, 1982

By Bruce A. McKinstry

Introduction For many major mining projects the time frame from initial planning to production can be measured in decades. Hecla's Silver Shaft project, scheduled to go into production by the end of this year, includes a complete surface facility, shaft with an ultimate depth of 2.4 km (7,700 ft), complete ore pass and loading pocket system, and 610 m (2,000 ft) of development drifting and stope preparation. The project was conceived in the fall of 1979, and the duration of a mere four years from conceptual engineering to production is testimony to what can be accomplished when a mining company and a contractor work as a team rather than developing into two warring camps, as often happens. Engineering In 1979, Hecla Mining Co. awarded a contract to J. S. Redpath Corp. to perform feasibility investigations and design engineering related to a proposed new shaft facility at the Lucky Friday Mine. The Lucky Friday, in Mullan, ID, is a major producer of silver, as well as significant quantities of lead and some zinc. In late 1979, stoping was in prog-

Jan 10, 1983

By H. J. Handewith, W. D. Coski

This paper describes the development and testing of the RAMEX excavation system. Incorporating a synergy of low velocity, high energy impact and kerf cutting, this machine offers a competitive alternative to drilling and blasting in hard rock. It is a boom mining machine that incorporates the features of a lightweight roadheader and it can mine nearly any shape opening in hard rock. The RAMEX Tunneler has been developed to satisfy industry demands for a non-explosive, flexible, continuous and rapid underground rock excavation system. It will produce minimum ground vibration in the urban environment and allow the flexibility necessary for thin seam mining conditions. It will also reduce initial ground support costs and has a minimum impact on rock integrity. Developed by RAMEX Systems with cooperative research provided by the U.S. Bureau of Mines, this system, could produce the next step in the continuing evolution of mechanical mining systems.

Jan 1, 1989

By D. E. Wolfson

The Bureau of Mines investigated the use of preheated coal in carbonization operations. Liquor yields and coking times were reduced, coke quality was improved, and smokeless pipeline charging to coke ovens should eliminate a serious source of pollution.

Jan 1, 1972

By Mark C. Williams, Thomas P. Meloy

Particle shape characterization is a complex task made more difficult because of the human eye's sophisticated recognition of shapes, giving rise to the assumption that shape analysis is considered a simple problem. Further exacerbating the problem is the question of whether particles have a general shape. Old and new shape measuring techniques are discussed, particularly the new image analysis methods techniques such as Fourier, Haar, Walsh and Delta. Problems with the current image analysis equipment and future research equipment needs are presented.

Jan 1, 1989

By A. R. Oltrogge

WE have just seen? that resistance is a characteristic of an electric circuit that makes it difficult for current to flow; also, that if, by the application of voltage, we cause a current to flow through a circuit having resistance, heat is generated. This is the principle utilized in the production of heat by electric power in the arc furnace. In order to fully appreciate the problems of the arc-furnace electric circuit, let us examine the characteristics of some of the more commonly used materials that offer resistance to a flow of current and thereby produce heat. Usually the resistance material is a metal or a metal alloy, such as the nichrome ribbon in an electric toaster or the tungsten filament of an ordinary light bulb. These are the materials whose resistance-remains relatively fixed and which therefore permit the flow of a definite amount of current for a given impressed voltage. If we want more current to flow, we must either decrease the resistance or increase the voltage that is causing the current to flow. Such a resistive material has what we call a positive volt-ampere characteristic, which means that in order to get more current we must apply more voltage, and in order to reduce the current we must reduce the voltage. Such a volt-ampere characteristic can be represented by a line plotted on a graph (line B, Fig I).

Jan 1, 1947

By D. G. Brubaker

IN the history of geophysical exploration by the electromagnetic method many procedures and types of equipment have been used. Source arrangements for surveying on the ground have included long wires grounded at both ends, large loops laid on the ground, small horizontal loops, and vertical loops of moderate to small sizes. Receivers have ranged from simple direction-finding coils to combinations of coils and a bridge circuit to measure quantities related to both amplitude and phase of the received signal. Primary considerations in choosing a survey method are effectiveness, speed, and economy. In work on the ground in which locating and outlining conducting bodies is the objective, methods using a vertical coil and a simple direction-finder have been found the most satisfactory. Mason1 and his associates applied such a method by setting up a vertical source loop, fed with low frequency alternating current by an engine-generator set. With a direction-finding receiver they surveyed lines along the ground in the plane of the loop, taking measurements at each station of the azimuth and inclination of the magnetic field direction. Deviations of this direction from the normal direction, that is, from horizontal and perpendicular to the traverse line, indicated a conducting body. Recent advances in design of light-weight generating equipment have encouraged using this and similar methods. In 1950 W. H. Westphal and the present writer developed a variation of this method and the apparatus for carrying it out. Their ideas were also based on experience with the Boliden Mining Co. method, which uses a small source coil and a vac- uum tube oscillator. The new procedure uses a small vertical source coil, powered by a vacuum tube oscillator, apd a direction-finding receiving coil. Source and receiver are kept a fixed distance apart and move as a unit along the survey lines. At each receiver station only the inclination of the magnetic field created by the source is measured. Source Unit: The source coil and a small vacuum tube oscillator together weigh about 45 lb. The source coil consists of about 60 turns of 10-gage

Jan 1, 1958

By D. A. Jacobson

Mining operations, whether new or existing, are constantly looking for ways to maximize production and improve energy efficiency, while keeping the footprint required to a minimum. The Nordberg MP1250 cone crusher was designed with these three goals in mind. A series of side-by-side evaluations comparing an MP1250 to an MP1000 were completed at two Freeport-McMoRan operations. The first evaluation began October 2009 in a tertiary position and the second began March 2010 in a secondary position, where it remains in full production today. Utilizing 25% higher power capacity than the existing MP1000 tertiary crushers, the MP1250 had 29% higher capacity and 17% lower specific energy, adjusted for differences in feed and product size. The MP1250 compared to the existing MP1000 secondary crushers achieved 30% higher capacity at a slightly reduced specific energy, while achieving a finer product. The MP1250?s higher capacity and energy efficiency may have application in many crushing plants. Depending on site specific economic factors, greenfield projects may benefit from a smaller footprint and less ancillary equipment, whereas brownfield projects may benefit from higher capacity or a finer product within the same footprint.

Jan 1, 2012

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

By Ralph Sherman

IN these days of intense competition for the domestic fuel market much is heard of the low efficiencies with which solid fuels, and most particularly bituminous coal, are burned in domestic heating equipment. In contrast to the every-day operating efficiencies of 85 and 90 per cent in large, central, electric-generating stations, efficiencies of 50 per cent and lower are cited for the hand-fired home furnace. Just as the miles per gallon of gasoline is only one of the factors that determine the cost of operation of an automobile, so the thermal efficiency is only one factor in the cost of domestic or other heating. The purpose of this paper is to analyze the total costs of domestic heating by various fuels and types of equipment, to determine the relative importance of efficiency and other factors, and to discuss what this signifies relative to the future of the use of fuels in the home.

Jan 1, 1933

By V. Koump, T. F. Perzak, R. G. Olsson

The vate of dissolutioz of carbon in molten Fe-C alloys urns studied by votating- cylindrical g-vaphite sairlples in a stationary crucible containing the melt. The rate of dissolltion was determdined from the change in the bnth co)npositiorz. Alccss-tvansfev coeffi'cients, calcilated with the assurlption that the inte)yacial liquid ulas saturated with carbon, were found to be in agreement with an existing Correlation fov mass transfer jroni votating cylinders. It is corzcllrded tlat, itz the wnge of- Reynolds' numbers itzvestigated (790 to 18,000), the vate of dissolutio of carborz in Fe-C alloys is controlled by tile rate of carbon difirsion from the interface. The dissolution of carbon in molten Fe-C alloys has been the subject of a number of investigations. Most of these investigations have been inconclusive because of poorly defined experimental variables. Two of the more sophisticated studies are summarized below. Dahlke and Knacke' studied the phenomenon by, in part, immersing graphite rods into 0.5 pct carbon-steel for different lengths of time. Since the experiments were conducted in air or in CO atmospheres, the melt was strongly agitated by gas evolution. It was concluded that the change in bath composition as a function of immersion time was in agreement with the assumption that the dissolution process was transport-controlled. The hydrodynamic conditions in these experiments, however, were not well-defined and gave no indication of the nature of the dissolution process at higher fluid velocities. In a recent study Shurygin and ruk investigated the dissolution of carbon in molten Fe-C, Fe-Si, Fe-P, and Fe-Ni alloys. Small graphite disks were rotated in a crucible containing molten alloys under such conditions that only the lower face of the disk was exposed to the melt. The results of this investigation indicate that, over the range of velocities (100 to 1000 rpm) and bulk liquid concentrations (0.7 to 4.5 wt pct C) considered, the dissolution of carbon in the iron alloys is limited by the diffusion of carbon from the interface to the bulk liquid (a transport mechanism). For the particular geometry used by these authors, exact analytical solutions of hydrodynamic and diffusion problems are aailable. Hence the experimental results obtained by Shurygin and Kryuk permit the evaluation of diffusion coefficients of carbon in the four systems investigated. In the present investigation a series of experiments were conducted in which the rate of dissolution of carbon in Fe-C alloys was measured under conditions which permitted wide variation of the fluid velocity and the carbon concentration of the bulk liquid. Graphite cylinders were rotated at different speeds in a stationary concentric crucible containing various molten Fe-C alloys. THEORETICAL DEVELOPMENT In general, the resistance to mass transfer from a solid interface to a turbulent liquid is assumed to reside in a laminar boundary layer adjacent to the interface. If it is also assumed that the diffusion coefficient is independent of concentration, the steady-state rate of dissolution for the case of arbitrary liquid and solid densities can be obtained from the integration of the equations of continuity. The derivation is similar to that used by Lommel and chalmers4 for the case of pl = ps. The solution, expressed in terms where N = rate of diffusion of the solute from the interface. Exact analytical solutions of the hydrodynamic equation for the boundary layer thickness are available for only a limited number of geometries. Consequently, a mass-transfer coefficient, k, is usually

Jan 1, 1967

By E. J. Dulis, A. Kasak, R. C. Westgren

The potential of uirought tungsten- and tantaluw-rich alloys of the W-Ta-Mo-Cb system was investigated for high-strength structural applications above 2500° F. Appreciable strengthening of tung-sten and tantalum—essentially attributable to solid-solzction effects—was obtained with binary, ternary, and quaternary alloys. Tensile strengths as high as 67,000 psi were achieved at 3000 OF. ThE quest for wrought structural materials which possess good strength properties at temperatures above 2000°F has led to a considerable research effort during the past decade. In addition to exploring the potential of various high-melting-point refractory metals (such as molybdenum, columbium, tantalum, and tungsten) for very high-temperature structural applications, alloy-development programs have been undertaken to achieve greater strengths than could be achieved with unalloyed refractory metals. The methods of strengthening refractory metal alloys have included both solid-solution and dispersion strengthening. General relationships among the relevant properties (melting point, recrystallization temperature, and high-temperature strength) of refractory metals indicate that the highest strengths at temperatures of 2500°F or higher would be obtained with tungsten-or tantalum-base alloys. Therefore, the present investigation was undertaken to determine the high-temperature strength potential of solid-solution strengthened alloys based on the binary system W-Ta; to effect further strengthening, minor additions of molybdenum and columbium (at the 6 and 12 pct levels) were made. The portion of the W-Ta-Mo-Cb quaternary alloy system of interest is shown schematically in Fig. 1. The component metals—W, Ta, Mo, and Cb—have a bcc structure at all temperatures, and their binary systems are mutually completely soluble.' Complete solid solubility in the W-Ta-Mo and W-Ta-Cb alloy systems has been demonstrated,' and, therefore, it was expected that the quarternary alloys of the system would also exhibit complete solid solubility at all temperatures. In the virtual absence of contamination by interstitial elements, all the alloys would be truly solid-solution strengthened. Twenty specific compositions of this investigation included binary, ternary, and quaternary alloys of the W-Ta-Mo-Cb system as well as unalloyed tungsten and tantalum. The compositions are shown in Table I. EXPERIMENTAL PROCEDURE Consumable-electrode vacuum-arc melting with ac power was used to produce small laboratory-sized, cylindrically shaped ingots (1-1/4 in. in diameter and 2 to 3-1/2 in. long) of the twenty compositions. A furnace was specially constructed to melt as many as four electrode rods simultaneously into molds lined with tungsten or tantalum sheet. High-purity rods of tungsten, tantalum, molybdenum, and columbium were used for consumable electrodes; the diameter of each rod was determined by the desired weight percentage of the component metal in a given alloy. The details of the construction and operation of the melting furnace will be discussed in another p~blication.

Jan 1, 1964

By Seksak Asavavisithchai, Natthida Jareankieathbovorn, Areeya Srichaiyaperk

"Recycling of ADC12 alloy scraps for fabrication of open-cell aluminium foams has been conducted via pressure infiltration method of replication process. The scrap, up to 50 wt.%, was melted with pure aluminium billet, followed by infiltration in a replicated mold of polyethylene foam structure. Compared with the pure aluminium foam, the compressive strength and hardness are higher for the foams with recycled scraps. The increase in foam mechanical properties is due to the presence of Si hard phase in Al matrix. The strength and hardness of the foams also increase with increasing contents of the scraps.IntroductionRecently, open-cell metallic foams have been brought to considerable attention of many industries due to their superior properties; such as large surface area, high specific strength, thermal conductivity, high service temperature and excellent anti-microbial activity, that cannot be found in conventional materials [1, 2]. Typically, open-cell foams are used in functional applications for which a requirement of high strength materials is not demanded. Good examples of such applications include heat exchangers, bone-replacement implants, interconnects, catalyst supports, and sound insulators.Among all types of open-cell metallic foams, aluminium (Al) is the most widely used base metal, due to low material cost, low density, low melting temperature and good corrosion resistance. To improve mechanical properties of Al foam, modification of foam microstructure with addition of alloy elements or ceramic particles is commonly carried out [3, 4]. ADC12 alloy is a typical die-casting Al alloy with high content of silicon (Si) close to the eutectic point in Al-Si binary phase diagram. The alloy is extensively used in the casting industry, due to high wear and corrosion resistance, low coefficient of thermal expansion and excellent castability [5]. The mechanical properties of Al-Si alloy are strongly dependent of Si content."

Jan 1, 2012

By A. B. Hooker, L. C. IlsLey

"Field inspections and data relative to the use of rubber-sheathed trailing cables in mines show that much cable is ruined or its probable life shortened by being overheated in service.The length of cable required to make connection from a source of supply to a machine at the face workings may be 100 to 500 feet. As a rule, the cable is carried on a reel and unreeled as required; and thus in most cases soma of the cable is not removed from the reel. The overheating generally occurs in that part of the cable which is left on the reel.Factors that determine the heating of trailing cables are:1. The size of the conductors in the cable.2. The maximum energy to be supplied through the cable, based upon the horsepower of the motor and the degree to which the motor is loaded.3. The voltage of the supply and the variation of the voltage at the receiving end.4. The time length of current flow and whether continuous or intermittent.5. The kind of current (direct or alternating).6. The amount of ca· le left or the reel.7. The type of cable used.8. The kind of reel used.In connecti0n with an investigation of the general performance of rubber-sheathed trailing callas, the Bureau of Mines has made a limited study of some of these factors, including the following points:"

Jul 1, 1931

By K. G. Thorne, D. R. Lentz, A. F. Park

"The Main zone of the Clarence Stream gold deposit is hosted by a shear zone adjacent to the Saint George batholith in southwestern New Brunswick. The mineralization history relates to progressive deformation in the shear zone and the intrusion of the Magaguadavic granodiorite.Of three phases of deformation that have affected the area (D1-D3), D1 is not observed in the Clarence Stream shear zone. Two suites of igneous rocks intrude the shear zone: post-D2, pre-D3 gabbro; and granitic dikes, which crosscut the gabbros. Granitic dikes show a diverse range of relationships to D3 features, from pre-syn-D3 mylonitic fabrics in transposed and highly deformed enclaves, to nondeformed and entirely discordant dikes (post-D3).A variety of veins occur within this shear zone. Zoisite-bearing and later, crosscutting epidote-bearing veins are preserved as relics in quartz-mylonites, and predate quartz veins that host gold mineralization. The epidote-bearing veins are associated with pseudotachylitic cataclasite dikes, consistent with transient brittle failure during ductile deformation.Deformation relates to right-lateral strike-slip motion across the shear zone, and subhorizontal and near-vertical stretching lineations imply transpression. A late (late- or post-D3) dip-slip phase of motion is also apparent, and cooling followed a metamorphic peak early in D2-D3 history. Deformation of the shear zone, and more localized transient brittle failure, provided the permeability for fluid movement and vein emplacement. This scenario is similar to the findings of other studies, in which geochemical, tracer isotopic, and age-dating (U/Pb, 40Ar/39Ar) results suggest that the adjacent Magaguadavic granodiorite provided heat and metals. La zone principale (Main zone) du gisement d’or de Clarence Stream est encaissée par une zone de cisaillement qui longe le batholite de Saint George dans le sud-ouest du Nouveau Brunswick. L’historique de la mise en place de la minéralisation accorde un rôle important à la déformation progressive dans la zone de cisaillement et à la mise en place de la granodiorite de Magaguadavic.Des trois phases de déformation à avoir affecté la région (D1-D3), les effets de D1 ne sont pas observés dans la zone de cisaillement de Clarence Stream. Deux suites de roches ignées se sont mises en place dans cette zone de cisaillement : un gabbro post D2, pré-D3 et des dykes granitiques qui recoupent le gabbro. Les dykes granitiques montrent une grande diversité de relations avec les structures D3, allant de précoces à synchrones aux fabriques mylonitiques D3 dans des enclaves transportées et fortement déformées à des dykes complètement discordants et non déformés (post-D3).On note diverses veines dans cette zone de cisaillement. Des veines contenant de la zoisite ainsi que des veines d’épidote sécantes plus tardives, lesquelles sont préservées comme reliquats dans les mylonites à quartz et sont plus vieilles que les veines de quartz contenant la minéralisation aurifère. Les veines d’épidote sont associées à des dykes de catacalasite à texture de pseudotachylite, compatibles avec une rupture cassante épisodique durant la déformation ductile.La déformation résulte d’un mouvement décrochant dextre le long de la zone de cisaillement et les linéations d’étirement subhorizontales et quasi-verticales impliquent de la transpression. Une phase tardive (tardi- ou post-D3) de mouvement selon le pendage est aussi apparente, et le refroidissement succède à un pic métamorphique tôt dans l’histoire D2-D3. La déformation de la zone de cisaillement et la rupture cassante épisodique ont fourni la perméabilité nécessaire au mouvement des fluides et à la mise en place des veines. Ce scénario est similaire à celui proposé par d’autres études, dans lesquelles les résultats de géochimie, de traceurs isotopiques et de géochronologie (U/Pb, 40Ar/39Ar) suggèrent que la granodiorite de Magaguadavic avoisinante a fourni la chaleur et les métaux."

Jan 1, 2008

By Nicholas Kyriazia, John P. Shubilla

A performance study of oxygen self-rescuers of varying durations from the United States and other countries was undertaken as an assessment of present worldwide technology. The apparatus were tested on a Breathing and Metabolic Simulator in the Life Support laboratories of the Bureau's Pitts- burgh Research Center. Parameters monitored during the testing were inhaled levels of C02, 02, inhaled gas temperature, and breathing resistance. The metabolic demand placed on the apparatus represented the average demand of the 50th percentile miner performing a 60-min man-test 4, as described in 30 CFR 11H. Results presented include apparatus service life and subjective comments as well as averages and peaks of monitored parameters.

Jan 1, 1986

By Jon C. Jenkins

In order to plan the most efficient mine installation, a company should take advantage of all available information and tools. One of the first factors of a coal reserve that needs to be determined as accurately as possible is the quality of coal the mine will have access to during the life of the installation. With the aid of many types of well logs and computor analysis, we are investigating several methods of log correlation to determine such data as moisture, ash, sulphur, and BTU on an in place basis. It may be possible to determine this data more accurately in this manner than by using diamond drill cores for analysis and thus allow for a more profitable mine installation. The production of an underground mine is based on many factors, two of these being roof control and line water, where present either in the roof or coal seam. Using many of the same logs obtained from reserve and active mine areas, we have attempted to determine roof and floor characteristics such as strength, lithology, and moisture properties. Using data obtained from this program, we will make comments on possible length of bolt to be used, possible mining width, and pillar size as they would pertain to these reserves and active mine areas.

Jan 1, 1969

By A. R. Laplante

The mineralogy of the Joe Mann mine differs from that of other deposits of the Chibougamau area that are exploited by Les Nines Camchib Inc. It is characterized by very fine first generation gold and very coarse second generation electrum. Successful processing required adjustments of the processing flowsheet, which includes gravity, flotation, and cyanidation. A study of coarse gold liberation in the gravity/grinding circuit is described. Modifications to the flotation circuit and the reconditioning of a small capacity cyanidation circuit are presented.

Jan 1, 1989

By R. A. Vik

The influence of thermal treatments on the grindability of low-grade hematitic iron ores from Michigan and Minnesota was examined in bench-scale tests. Treatment factors were roasting temperature, roasting atmosphere, and ore cooling conditions. Bond ball mill grindability and work indices were used as response indicators in evaluating the condition of the ore. Of the three treatment factors evaluated, roasting atmosphere, which brought about the con version of iron oxides to magnetite, had the most significant effect; roasting temperature had the next most important effect; and cooling condition had the least effect. Optimum grindability was obtained with reduced-quenched products of both ores at 650° C, near the alpha-beta phase transformation of quartz.

Jan 1, 1971

A process was developed based on the thermal hydrolysis and precipitation of iron from solutions resulting from the leaching of zinc plant residue. A study was made of the hydrolysis of iron, at temperatures in the range 140-220°C, in both pure solutions of ferrie sulphate and in leach solutions derived from plant spent electrolyte.At 200°C hydrolysis of pure ferric sulphate solutions results in the precipitation of ferric oxide, Fe2O3, at low acid. concentrations, and a basic salt, Fe2O3.2S03.H20, at hIgher acid concentrations. At 180°C ferric oxide is precipitated at low acid concentrations, but at higher acidities. carphosiderite, 3Fe203.4SO.3.9H20, is the stable phase. Frequently a mIxture of ferric oxide and carphosldente IS produced at 180°C, the ratio of phases being dependent on the non-equilibrium experimental conditions.With solutions derived from plant spent electrolyte hydrolysIS at elevated temperatures results in the precipitation of jarosite compounds of the type NaFe3(S04)2(OH)6 The precipitation of natrojarosite jarosite, and ammonio-jarosite was studied in detail. Temperature, free acidity, and the concentration of sodium potassium, and ammonium ions are critical factors which affect the extent of precipitation.A process based on ammonio-jarosite precipitation was tested in a pilot plant.An alternative method of iron removal based on the addition of zinc oxide calcine, to neutralize excess acidity, and the precipitation of ferric oxide was also tested in the pilot plant. Both processes appear economically favourable...

Jan 1, 1967